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1. 发明授权

US5648310A Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture 失效
公开(公告)号：US5648310A
公开(公告)日：1997-07-15
申请号：US494796
申请日：1995-06-26
申请人： Eric Paul Wasserman , Mark Wilton Smale , Timothy Roger Lynn , Robert Converse Brady, III , Frederick John Karol
发明人： Eric Paul Wasserman , Mark Wilton Smale , Timothy Roger Lynn , Robert Converse Brady, III , Frederick John Karol
IPC分类号： C08F4/42 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927
摘要： Metallocene-containing catalyst compositions that include inert filler, a method for their preparation, and a method for their use in production of polyolefins are disclosed and claimed. The catalyst compositions contain solid particles of a mixture comprising a) a metallocene catalyst; b) a cocatalyst capable of activating said metallocene catalyst; and c) particulate filler material having an average particle size of less than about 10 micrometers that is unreactive with the metallocene catalyst and the cocatalyst. They are prepared by spray drying a slurry of the constituents.

2. 发明授权

US5674795A Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture 失效
公开(公告)号：US5674795A
公开(公告)日：1997-10-07
申请号：US486412
申请日：1995-06-07
申请人： Eric Paul Wasserman , Mark Wilton Smale , Timothy Roger Lynn , Robert Converse Brady, III , Frederick John Karol
发明人： Eric Paul Wasserman , Mark Wilton Smale , Timothy Roger Lynn , Robert Converse Brady, III , Frederick John Karol
IPC分类号： C08F4/42 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , Y10S526/943
摘要： Metallocene-containing catalyst compositions that include inert filler, a method for their preparation, and a method for their use in production of polyolefins are disclosed and claimed. The catalyst compositions contain solid particles of a mixture comprising a) a metallocene catalyst; b) a cocatalyst capable of activating said metallocene catalyst; and c) particulate filler material having an average particle size of less than about 10 micrometers that is unreactive with the metallocene catalyst and the cocatalyst. They are prepared by spray drying a slurry of the constituents.

3. 发明授权

US5672669A Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture 失效
标题翻译：用于聚烯烃制造的喷雾干燥填充的茂金属催化剂组合物
公开(公告)号：US5672669A
公开(公告)日：1997-09-30
申请号：US478909
申请日：1995-06-07
申请人： Eric Paul Wasserman , Mark Wilton Smale , Timothy Roger Lynn , Robert Converse Brady III , Frederick John Karol
发明人： Eric Paul Wasserman , Mark Wilton Smale , Timothy Roger Lynn , Robert Converse Brady III , Frederick John Karol
IPC分类号： C08F4/42 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , Y10S526/943
摘要： Metallocene-containing catalyst compositions that include inert filler, a method for their preparation, and a method for their use in production of polyolefins are disclosed and claimed. The catalyst compositions contain solid particles of a mixture comprising a) a metallocene catalyst; b) a cocatalyst capable of activating said metallocene catalyst; and c) particulate filler material having an average particle size of less than about 10 micrometers that is unreactive with the metallocene catalyst and the cocatalyst. They are prepared by spray drying a slurry of the constituents.
摘要翻译：公开并要求保护含有茂金属的催化剂组合物，其包括惰性填料，其制备方法及其在生产聚烯烃中的用途。催化剂组合物含有包含a）茂金属催化剂的混合物的固体颗粒; b）能够活化所述茂金属催化剂的助催化剂; 和c）平均粒度小于约10微米的与茂金属催化剂和助催化剂不反应的颗粒填料。它们通过喷雾干燥组分的浆料来制备。

4. 发明授权

US6069213A Mixed catalyst system 失效
标题翻译：混合催化剂体系
公开(公告)号：US6069213A
公开(公告)日：2000-05-30
申请号：US991688
申请日：1997-12-16
申请人： Thomas Lloyd Nemzek , Frederick John Karol , Sun-Chueh Kao , Robert Converse Brady, III
发明人： Thomas Lloyd Nemzek , Frederick John Karol , Sun-Chueh Kao , Robert Converse Brady, III
IPC分类号： C08F2/34 , C08F4/02 , C08F4/60 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16 , C08F4/06 , C08F4/72
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , Y10S526/943
摘要： It has been found that the use of at least one unsupported metallocene polymerization catalyst with at least one supported metallocene polymerization catalyst in the polymerization of olefins allows for better control of the polymerization, especially gas phase polymerization. Such a system takes advantage of the high activity of the unsupported catalyst and the stability of a supported catalyst. Additionally, the relative timing of the addition of the supported and unsupported catalysts to a reaction system can be used to control a continuous polymerization reaction by stabilizing the reactor bed with the supported catalyst prior to addition of the unsupported catalyst.
摘要翻译：已经发现，在烯烃聚合中使用至少一种未负载的茂金属聚合催化剂与至少一种负载的茂金属聚合催化剂可以更好地控制聚合，特别是气相聚合。这种系统利用了无载体催化剂的高活性和负载型催化剂的稳定性。此外，将负载型催化剂和未负载的催化剂加入到反应体系中的相对时间可以用于通过在加入未负载的催化剂之前用负载型催化剂稳定反应器床来控制连续聚合反应。

5. 发明授权

US5756416A Catalyst composition having improved comonomer reactivity 失效
标题翻译：催化剂组合物具有改善的共聚单体反应性
公开(公告)号：US5756416A
公开(公告)日：1998-05-26
申请号：US563702
申请日：1995-11-28
申请人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
发明人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
IPC分类号： C08F4/44 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S526/901 , Y10S526/943
摘要： A catalyst composition comprising A) an aluminoxane-impregnated support prepared by contacting an aluminoxane with an inert carrier material and heating to a temperature of at least about 80.degree. C.; B) a metallocene of the formula: (L).sub.y (L')MY.sub.(x-y-1) wherein M is a metal from groups IIIB to VIII of the Periodic Table; each L and L' is independently a cycloalkadienyl group bonded to M; each Y is independently hydrogen, an aryl, alkyl, alkenyl, alkylaryl, or arylalkyl radical having 1-20 carbon atoms, a hydrocarboxy radical having from 1-20 carbon atoms, a halogen, RCO.sub.2 --, or R.sub.2 N--, wherein R is a hydrocarbyl group containing 1 to about 20 carbon atoms; n and m are each 0, 1, 2, 3, or 4; y is 0, 1, or 2; x is 1, 2, 3, or 4; and x-y.gtoreq.1; C) a bulky aluminum alkyl of the formula: AlR.sup.1.sub.x R.sup.2.sub.(3-x) wherein R.sup.1 is a hydrocarbyl group having 1 to 12 carbon atoms; x is an integer from 0 to 2; R.sup.2 is a hydrocarbyl group of the formula --(CH.sub.2).sub.y -- R.sup.3, wherein y is an integer from 1 to 8; and R.sup.3 is a saturated or unsaturated hydrocarbyl group having 3 to 12 carbon atoms containing at least one ring, and D) methylaluminoxane is provided. The catalyst composition may be used to prepare olefin polymers having increased short chain branching frequency.
摘要翻译：一种催化剂组合物，其包含A）通过使铝氧烷与惰性载体材料接触并加热到至少约80℃的温度而制备的铝氧烷浸渍的载体; B）下式的茂金属：（L）y（L'）MY（x-y-1）其中M是元素周期表IIIB至VIII族的金属; 每个L和L'独立地是与M键合的环二烯基; 每个Y独立地是氢，具有1-20个碳原子的芳基，烷基，烯基，烷基芳基或芳基烷基，具有1-20个碳原子的烃基，卤素，RCO2-或R2N-，其中R是含有1至约20个碳原子的烃基; n和m各自为0,1,2,3或4; y为0,1或2; x是1，2，3或4; 和x-y> / = 1; C）下式的大体积的烷基铝：AlR 1 R 2（3-x）其中R 1是具有1至12个碳原子的烃基; x是0到2的整数; R 2是式 - （CH 2）y -R 3的烃基，其中y是1至8的整数; R3为含有至少一个环的碳原子数为3〜12的饱和或不饱和烃基，提供D）甲基铝氧烷。催化剂组合物可用于制备具有增加的短链支化频率的烯烃聚合物。

6. 发明授权

US5852143A Production of polyethylene using stereoisomeric metallocenes 失效
标题翻译：使用立体异构金属茂生产聚乙烯
公开(公告)号：US5852143A
公开(公告)日：1998-12-22
申请号：US838182
申请日：1997-04-16
申请人： Purna Chand Sishta , Eric Paul Wasserman , Frederick John Karol
发明人： Purna Chand Sishta , Eric Paul Wasserman , Frederick John Karol
IPC分类号： C08F2/34 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/901 , Y10S526/943
摘要： Polyethylene having a broad molecular weight distribution, a narrow comonomer distribution and excellent processability is easily and cost effectively made using stereoisomeric mixtures of bridged metallocene catalysts containing cycloalkadienyl ligands with facial chirality.
摘要翻译：具有宽分子量分布，窄共聚单体分布和优异加工性能的聚乙烯使用含有环链二烯基配体的桥连金属茂催化剂与面部手性的立体异构体混合物容易且经济地进行。

7. 发明授权

US6028151A Catalyst composition having improved comonomer reactivity 失效
标题翻译：催化剂组合物具有改善的共聚单体反应性
公开(公告)号：US6028151A
公开(公告)日：2000-02-22
申请号：US30436
申请日：1998-02-25
申请人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
发明人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
IPC分类号： C08F4/44 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S526/901 , Y10S526/943
摘要： A process for producing an olefin polymer, which comprises contacting at least two olefin monomers under polymerization conditions with a catalyst composition comprising A) an aluminoxane-impregnated support prepared by contacting an aluminoxane with an inert carrier material and heating to a temperature of at least about 80.degree. C.; B) a metallocene of the formula:(L).sub.y (L')MY.sub.(x-y-1)wherein M is a metal from groups IIIB to VIII of the Periodic Table; each L and L' is independently a cycloalkadienyl group bonded to M; each Y is independently hydrogen, an aryl, alkyl, alkenyl, alkylaryl, or arylalkyl radical having 1-20 carbon atoms, a hydrocarboxy radical having from 1-20 carbon atoms, a halogen, RCO.sub.2 --, or R.sub.2 N--, wherein R is a hydrocarbyl group containing 1 to about 20 carbon atoms; y is 0, 1, or 2; x is 1, 2, 3, or 4; and x-y.gtoreq.1; C) a bulky aluminum alkyl of the formula:AlR.sup.1.sub.x R.sup.2.sub.(3-x)wherein R.sup.1 is a hydrocarbyl group having 1 to 12 carbon atoms; x is an integer from 0 to 2; R.sup.2 is a hydrocarbyl group of the formula --(CH2).sub.y -- R.sup.3, wherein y is an integer from 1 to 8; and R.sup.3 is a saturated or unsaturated hydrocarbyl group having 3 to 12 carbon atoms containing at least one ring, and D) methylaluminoxane is provided. The catalyst composition may be used to prepare olefin polymers having increased short chain branching frequency.
摘要翻译：一种制备烯烃聚合物的方法，其包括使聚合条件下的至少两种烯烃单体与催化剂组合物接触，所述催化剂组合物包含：A）通过使铝氧烷与惰性载体材料接触而制备的铝氧烷浸渍的载体，并加热至至少约 80℃。 B）下式的茂金属：（L）y（L'）MY（x-y-1）其中M是元素周期表IIIB至VIII族的金属; 每个L和L'独立地是与M键合的环二烯基; 每个Y独立地是氢，具有1-20个碳原子的芳基，烷基，烯基，烷基芳基或芳基烷基，具有1-20个碳原子的烃基，卤素，RCO2-或R2N-，其中R是含有1至约20个碳原子的烃基; y为0,1或2; x是1，2，3或4; 和x-y> / = 1; C）下式的大体积的烷基铝：AlR 1 R 2（3-x）其中R 1是具有1至12个碳原子的烃基; x是0到2的整数; R 2是式 - （CH 2）y -R 3的烃基，其中y是1至8的整数; R3为含有至少一个环的碳原子数为3〜12的饱和或不饱和烃基，提供D）甲基铝氧烷。催化剂组合物可用于制备具有增加的短链支化频率的烯烃聚合物。

8. 发明授权

US06562750B2 Catalyst for the production of olefin polymers 失效
公开(公告)号：US06562750B2
公开(公告)日：2003-05-13
申请号：US10042797
申请日：2002-01-09
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F7/003 , C08F210/16 , Y10S526/901 , C08F4/64189 , C08F4/6028 , C08F4/64048 , C08F210/14
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.

9. 发明授权

US6066703A Process for the production of olefin polymers 失效
标题翻译：生产烯烃聚合物的方法
公开(公告)号：US6066703A
公开(公告)日：2000-05-23
申请号：US977583
申请日：1997-11-25
申请人： Walter Thomas Reichle , Xinmin Yang , Frederick John Karol
发明人： Walter Thomas Reichle , Xinmin Yang , Frederick John Karol
IPC分类号： B01J31/22 , C08F4/64 , C08F4/642 , C08F4/649 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/65912 , C08F4/6592 , Y10S526/901 , Y10S526/943
摘要： A process for the polymerization of an olefin which employs as the catalyst composition the reaction product of a) a monocycloalkadienyl catalyst precursor; b) an activity enhancing cycloalkadiene; and c) an activating cocatalyst is disclosed.
摘要翻译：烯烃的聚合方法，其用作催化剂组合物a）单环烷二烯基催化剂前体的反应产物; b）增强环二烯的活性; 和c）活化助催化剂。

10. 发明授权

US5852146A Catalyst for the production of olefin polymers 失效
公开(公告)号：US5852146A
公开(公告)日：1998-12-22
申请号：US670507
申请日：1996-06-27
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： C07F7/00 , C07F7/28 , C08F4/60 , C08F4/602 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C07F7/006 , C08F210/16 , Y10S526/901
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.

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