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1. 发明授权

US5142005A Process for producing crystalline vinyl aromatic polymers having mainly a syndiotactic structure 失效
标题翻译：生产具有主要结构结构的结晶乙烯芳族聚合物的方法
公开(公告)号：US5142005A
公开(公告)日：1992-08-25
申请号：US133055
申请日：1987-12-15
申请人： Enrico Albizzati , Umberto Giannini , Giovanni Giunchi , Romano Mazzocchi , Luigi Resconi
发明人： Enrico Albizzati , Umberto Giannini , Giovanni Giunchi , Romano Mazzocchi , Luigi Resconi
IPC分类号： C08F12/08 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/6592 , C08F12/00 , C08F12/04
CPC分类号： C08F12/04 , C08F10/00 , C08F12/08 , Y10S526/941
摘要： A process for the production of primarily syndiotactic vinyl aromatic polymers by polymerizing or copolymerizing vinyl aromatic monomers such as styrene or styrene derivatives in the presence of a catalyst system comprising the product of the reaction between:a) a compound of a transition metal (M) different from titanium and containing at least a bond M-O, M-C, M-N, M-P, M-S or M-halogen, andb) an organoaluminum compound containing at least an oxygen atom bound to the aluminum atom or bound between two aluminum atoms.Compound a) can be used as such or may be supported on a suitable carrier.

2. 发明授权

US5369186A Alpha olefins functionalized polymers 失效
标题翻译： α-烯烃官能化聚合物
公开(公告)号：US5369186A
公开(公告)日：1994-11-29
申请号：US790630
申请日：1991-11-12
申请人： Maurizio Galimberti , Umberto Giannini , Romano Mazzocchi , Enrico Albizzati , Umberto Zucchini
发明人： Maurizio Galimberti , Umberto Giannini , Romano Mazzocchi , Enrico Albizzati , Umberto Zucchini
IPC分类号： C08F8/00 , C08F8/12 , C08F8/26 , C08F10/00 , C08F210/00 , C08F210/06 , C08F210/16 , C08F214/16 , C08F226/06
CPC分类号： C08F210/00 , C08F210/06 , C08F210/16
摘要： Disclosed are polymers and copolymers of CH.sub.2 .dbd.CHR alpha olefins where R is hydrogen or a 1-6 carbon atom alkyl radical, containing in the chain from 0.1 to 40 mole % of monomeric units ##STR1## where X is selected from the group consisting of (CH.sub.2).sub.r CH.sub.2 CH.sub.2 Y ##STR2## where r=0-10, Y is a halogen atom, R.sup.1 is a hydrocarbon radical with 1-18 carbon atoms.
摘要翻译：公开了CH2 =CHRα烯烃的聚合物和共聚物，其中R是氢或1-6个碳原子的烷基，其中链中含有0.1至40摩尔％的单体单元，其中X选自（CH2）rCH2CH2Y CH2）rCHCH2（CH2）r + 2OCOR1（CH2）r + 2OR1（CH2）r + 2CH（COOR1）2（CH2）r + 2OH（CH2）r + 2CH2COOH 其中r = ，Y是卤素原子，R1是具有1-18个碳原子的烃基。

3. 发明授权

US06355758B1 Crystalline copolymers of propylene 失效
标题翻译：丙烯的结晶共聚物
公开(公告)号：US06355758B1
公开(公告)日：2002-03-12
申请号：US08473006
申请日：1995-06-07
申请人： Luigi Resconi , Enrico Albizzati , Romano Mazzocchi
发明人： Luigi Resconi , Enrico Albizzati , Romano Mazzocchi
IPC分类号： C08F1004
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/943 , C08F2500/17 , C08F210/08
摘要： Novel crystalline copolymers of propylene with minor proportions of ethylene and/or alpha-olefins, endowed with very good mechanical properties, a low melting point and a limited solubility in xylene at 25° C., and the process for preparing them by means of the polymerization of mixtures of propylene with ethylene and/or alpha-olefins of suitable composition, by using catalysts obtained from stereorigid and chiral compounds of zirconium, and methylalumoxanic compounds.
摘要翻译：丙烯与较少比例的乙烯和/或α-烯烃的新型结晶共聚物具有非常好的机械性能，在25℃下具有低熔点和在二甲苯中的溶解度有限的方法，以及通过通过使用由立体刚性和锆的手性化合物得到的催化剂和甲基铝氧烷化合物，聚合丙烯与乙烯和/或合适组成的α-烯烃的混合物。

4. 发明授权

US5516866A Crystalline copolymers of propylene 失效
标题翻译：丙烯的结晶共聚物
公开(公告)号：US5516866A
公开(公告)日：1996-05-14
申请号：US279671
申请日：1994-07-25
申请人： Luigi Resconi , Enrico Albizzati , Romano Mazzocchi
发明人： Luigi Resconi , Enrico Albizzati , Romano Mazzocchi
IPC分类号： C08F4/645 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/06 , C08F210/06 , C08F210/16 , C08F4/642
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Novel crystalline copolymers of propylene with minor proportions of ethylene and/or alpha-olefins, endowed with very good mechanical properties, a low melting point and a limited solubility in xylene at 25.degree. C., and the process for preparing them by means of the polymerization of mixtures of propylene with ethylene and/or alpha-olefins of suitable composition, by using catalysts obtained from stereorigid and chiral compounds of zirconium, and methylalumoxanic compounds.
摘要翻译：丙烯与较少比例的乙烯和/或α-烯烃的新型结晶共聚物具有非常好的机械性能，在25℃下具有低熔点和在二甲苯中的溶解度有限的方法，以及通过通过使用由立体刚性和锆的手性化合物得到的催化剂和甲基铝氧烷化合物，聚合丙烯与乙烯和/或合适组成的α-烯烃的混合物。

5. 发明授权

US4107415A Process for the stereospecific polymerization of alpha-olefins 失效
标题翻译： α-烯烃的立体有择聚合方法
公开(公告)号：US4107415A
公开(公告)日：1978-08-15
申请号：US778963
申请日：1977-03-18
申请人： Umberto Giannini , Antonio Cassata , Paolo Longi , Romano Mazzocchi
发明人： Umberto Giannini , Antonio Cassata , Paolo Longi , Romano Mazzocchi
IPC分类号： C08F4/02 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/903 , Y10S526/904 , Y10S526/906
摘要： Alpha-olefins C.sub.3 -C.sub.6 are polymerized stereospecifically with the aid of catalysts obtained by mixing(a) a catalyst-forming component which is an addition and/or substitution product of an electron-donor compound (or a Lewis base) with an aluminum trialkyl, or an addition product of an electron-donor compound with an alkyl aluminum compound containing two or more Al - atoms bound to each other through an oxygen or nitrogen atom with(b) a supported catalyst-forming component which is the product obtained by contacting a titanium compound, preferably in the form of an addition product with an electron donor, with a carrier which is a mixture of an active anhydrous Mg or Mn dihalide and a solid organic material which is inert to all other components of the catalyst including the Mg or Mn dihalide carrier.
摘要翻译：借助于通过混合（A）作为添加剂的催化成分组分和/或电子衍生物化合物（或路易斯碱）的替代产物）与三烷基铝（III），将α-烯烃C 3 -C 6聚合而立体特异性地聚合或电子给体化合物与含有两个或更多个Al原子的烷基铝化合物与氧原子或氮原子相互结合的加成产物与（B）相互连接形成的产物的催化成分组分钛化合物，优选与具有电子助剂的添加剂产品的形式，其中载体是活性无机Mg或Mn二卤化物的混合物和固体有机材料，其对包括Mg的所有催化剂的所有其它组分是惰性的或Mn二卤化物载体。

6. 发明授权

US5196496A Syndiotactic crystalline copolymers of propylene and 1-butene 失效
标题翻译：丙烯和1-丁烯的共聚物结晶共聚物
公开(公告)号：US5196496A
公开(公告)日：1993-03-23
申请号：US721049
申请日：1991-06-26
申请人： Maurizio Galimberti , Enrico Albizzati , Romano Mazzocchi
发明人： Maurizio Galimberti , Enrico Albizzati , Romano Mazzocchi
IPC分类号： C08F4/642 , C08F4/60 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F210/06
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/901
摘要： Essentially syndiotactic crystalline copolymers of propylene with minor proportions of 1-butene, endowed with good mechanical properties, lowered melting point and limited solubility in xylene at 25.degree. C. and the process for their preparation by polymerizing mixtures of propylene with 1-butene, by using catalysts obtained form stereorigid and chiral zirconium and hafnium compounds and from polymethylalumoxane compounds.

7. 发明授权

US4613655A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4613655A
公开(公告)日：1986-09-23
申请号：US225366
申请日：1981-01-15
申请人： Paolo Longi , Umberto Giannini , Romano Mazzocchi , Domenico Deluca
发明人： Paolo Longi , Umberto Giannini , Romano Mazzocchi , Domenico Deluca
IPC分类号： C08F4/02 , C08F4/50 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F4/022 , C08F10/00 , Y10S526/906
摘要： New catalysts for the polymerization of olefins and more particularly of ethylene and mixtures thereof with higher alpha-olefins and/or diolefins, are disclosed. The catalysts are prepared by mixing (a) a hydride or an organo-metallic compound of a metal belonging to Groups I, II or III of the Mendelyeev Periodic Table with (b) the product obtained by contacting a titanium compound (1) with a mixture of an anhydrous magnesium halide (2) in a particular active form and an anhydrous compound of a metal belonging to Group I or II of said Periodic Table, (3). In the particular active form to which it is converted, during or prior to the contacting the anhydrous magnesium halide is characterized in that, in its X-ray spectrum, the diffraction line which is most intense in the X-ray spectrum of the normal, inactive magnesium halide shows a decreased intensity, and/or the active magnesium halide has a surface area greater than 3 m.sup.2 /g.
摘要翻译：公开了用于烯烃聚合，更特别是乙烯及其与高级α-烯烃和/或二烯烃的混合物的新型催化剂。催化剂通过将（a）属于门多利夫周期表第I，II或III族的金属的氢化物或有机金属化合物与（b）通过使钛化合物（1）与具有活性的无水卤化镁（2）和属于所述周期表第I或II族金属的无水化合物的混合物，（3）。在其转化的特定活性形式中，在接触期间或之前，无水卤化镁的特征在于，在其X射线光谱中，法线的X射线光谱中最强的衍射线，无活性卤化镁显示出降低的强度，和/或活性卤化镁的表面积大于3m 2 / g。

8. 发明授权

US4614727A Polymerization catalyst 失效
标题翻译：聚合催化剂
公开(公告)号：US4614727A
公开(公告)日：1986-09-30
申请号：US701530
申请日：1985-02-14
申请人： Paolo Longi , Umberto Giannini , Romano Mazzocchi
发明人： Paolo Longi , Umberto Giannini , Romano Mazzocchi
IPC分类号： C08F4/64 , C08F10/02
CPC分类号： C08F10/02 , Y10S526/906
摘要： Polymerization catalysts, more particularly catalysts for the polymerization of ethylene and mixtures thereof with other monomers copolymerizable therewith, are disclosed. The catalysts are prepared by mixing (A) an organometallic compound or hydride of a metal belonging to Groups I, II or III of the Mendelyeev Periodic Table, with (B) the reaction product of (1) a titanium compound of the type (NR.sub.4).sub.p Ti.sub.m X.sub.(n.m)+p, in which R.sub.4 is hydrogen and/or hydrocarbon radicals, X.sub.n.m represents halogen atoms or, in part, OR' groups in which R' is an organic radical; n represents the Ti valence, and m and p are the whole numbers 1, 2 or 3; and (2) a carrier comprising an anhydrous magnesium halide.
摘要翻译：公开了聚合催化剂，更特别的是用于乙烯聚合的催化剂及其与可与其共聚的其它单体的混合物。催化剂通过将（A）属于门多利夫周期表第I，II或III族的金属的有机金属化合物或氢化物与（B）（1）钛化合物（NR4）的反应产物）pTimX（nm）+ p，其中R4是氢和/或烃基，Xn.m表示卤素原子，或部分地是其中R'是有机基团的OR'基团; n表示Ti价，m和p为整数1,2或3; 和（2）包含无水卤化镁的载体。

9. 发明授权

US4226963A Process for the stereoregular polymerization of alpha-olephins 失效
标题翻译： α-烯烃立体定向聚合的方法
公开(公告)号：US4226963A
公开(公告)日：1980-10-07
申请号：US959604
申请日：1978-11-13
申请人： Umberto Giannini , Antonio Cassata , Paolo Longi , Romano Mazzocchi
发明人： Umberto Giannini , Antonio Cassata , Paolo Longi , Romano Mazzocchi
IPC分类号： C08F4/02 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/902 , Y10S526/906
摘要： There is disclosed a process for the stereoregular polymerization of alpha olefins or mixtures thereof with ethylene conducted in the presence of highly active and stereospecific new catalysts. The catalysts are obtained from the reaction of a particular Al-alkyl compound which is at least in part in the form of a complex and/or a substitution reaction product with an electron-donor compound free from ester groups of oxygenated organic and inorganic acids, with a supported component characterized by having surface area exceeding certain values or by showing a particular X-rays spectrum and which is obtained by contacting a halogenated Ti compound, preferably in the form of a complex with an electron-donor compound, with a support comprising a Mg or Mn dihalide in an active state. In the catalysts the ratio between the Ti compound expressed in Ti g-atoms and the g-moles of the electron donor compounds is lower than 0.3.
摘要翻译：公开了在高活性和立体特异性新型催化剂存在下，α-烯烃或其与乙烯的混合物的立构规整聚合方法。催化剂是由至少部分为配合物和/或取代反应产物形式的特定的Al-烷基化合物与不含氧化的有机和无机酸的酯基的电子给体化合物的反应获得的，其特征在于具有超过某些值的表面积或通过显示特定的X射线光谱，并且其通过使配合物形式的卤化Ti化合物与电子给体化合物接触而获得，所述载体包含处于活性状态的Mg或Mn二卤化物。在催化剂中，Ti原子表示的Ti化合物与电子给体化合物的g-摩尔比为0.3以下。

10. 发明授权

US4156063A Process for the stereoregular polymerization of alpha olefins 失效
标题翻译： α-烯烃的立构规整聚合方法
公开(公告)号：US4156063A
公开(公告)日：1979-05-22
申请号：US845947
申请日：1977-10-27
申请人： Umberto Giannini , Antonio Cassata , Paolo Longi , Romano Mazzocchi
发明人： Umberto Giannini , Antonio Cassata , Paolo Longi , Romano Mazzocchi
IPC分类号： C08F4/02 , C08F10/00 , C08F10/06
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： There is disclosed a process for the stereoregular polymerization of alpha olefins or mixtures thereof with ethylene, conducted in the presence of highly active and stereospecific new catalysts. The catalysts are obtained from the reaction of a particular Al-alkyl compound which is at least in part in the form of a complex and/or a substitution reaction product with an ester of an oxygenated organic or inorganic acid, with a supported component characterized by having surface area exceeding certain values or by showing a particular X-rays spectrum, and obtained by contacting a Ti halogenated compound, preferably in the form of a complex with an electron-donor compound, with a support comprising a Mg or Mn bihalide.In the catalysts the ratio between the Ti compound, expressed in Ti g-atoms, and the g moles of the ester and the electron-donor compound, when present, is lower than 0.3.
摘要翻译：公开了在高活性和立体特异性新催化剂存在下进行的α-烯烃或其与乙烯的混合物的立构规整聚合的方法。催化剂是由至少部分以络合物和/或取代反应产物形式的特定的Al-烷基化合物与含氧有机或无机酸的酯与负载的组分的反应获得的，其表面积超过某些值或通过显示特定的X射线光谱，并且通过使优选以络合物形式的电子给体化合物的Ti卤化化合物与包含Mg或Mn二卤化物的载体接触而获得。

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