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1. 发明授权

US4315836A Catalysts for polymerizing alpha-olefins 失效
标题翻译：用于聚合α-烯烃的催化剂
公开(公告)号：US4315836A
公开(公告)日：1982-02-16
申请号：US137256
申请日：1980-04-04
申请人： Enrico Albizzati , Enzo Giannetti
发明人： Enrico Albizzati , Enzo Giannetti
IPC分类号： C08F4/00 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/64 , C08F4/659 , C08F10/00 , C08F210/00
CPC分类号： C08F4/022 , C08F10/00
摘要： New and improved catalysts for polymerizing alpha-olefins of formula CH.sub.2 .dbd.CHR in which R is a C.sub.1 to C.sub.6 alkyl, more particularly propylene, mixtures of the alpha-olefins, and mixtures thereof with ethylene are disclosed. The catalysts are prepared from Al alkyl compounds and a solid product including a Mg dihalide and reaction products of said halide with at least one Ti compound and an electron donor compound which is an ester of an organic or inorganic oxygenated acid.The improvement consists in providing catalysts prepared from components (a) and (b) as defined infra and component (b) of which includes an alkyl Al compound as defined in (b) in amounts equal to molar ratios between the alkyl Al compound and the Ti compound of component (a) in the range of from 1 to 30, preferably from 2 to 20, and in which if the alkyl Al compound is complexed with an electron donor compound, the latter is used in reduced amounts such that at least 85% of the alkyl Al compound is in a form not combined with an electron donor compound, i.e., catalysts which are highly active and highly stereospecific but which involve a lower consumption of alkyl Al compound with respect to the Ti compound than has been required in the case of various prior art catalysts and which make it possible to use a lower amount of electron-donor compound complexed with the Al alkyl compound.
摘要翻译：公开了用于聚合式CH 2 = CHR的α-烯烃的新的和改进的催化剂，其中R是C1至C6烷基，更特别是丙烯，α-烯烃的混合物及其与乙烯的混合物。催化剂由Al烷基化合物和包含二卤化镁的固体产物和所述卤化物与至少一种Ti化合物和作为有机或无机氧化酸的酯的电子给体化合物的反应产物制备。改进之处在于提供由下文定义的组分（a）和（b）制备的催化剂，组分（b）包括如（b）中所定义的烷基铝化合物，其量等于烷基铝化合物与组分（a）的Ti化合物在1至30，优选2至20的范围内，并且其中如果烷基Al化合物与电子给体化合物络合，则后者以减少的量使用，使得至少85 烷基铝化合物的％为不与电子给体化合物组合的形式，即，高活性和高立体特异性但涉及相对于Ti化合物的烷基Al化合物的消耗量低于在各种现有技术催化剂的情况，并且可以使用较少量的与Al烷基化合物络合的电子给体化合物。

2. 发明授权

US4472315A Components of catalysts and catalysts for (Co) polymerizing olefins and process for preparing said components, said components being based on particular chlorinated compounds of trivalent vanadium 失效
标题翻译：用于（Co）聚合烯烃的催化剂和催化剂的组分和用于制备所述组分的方法，所述组分基于三价钒的特定氯化化合物
公开(公告)号：US4472315A
公开(公告)日：1984-09-18
申请号：US223851
申请日：1981-01-09
申请人： Enrico Albizzati , Enzo Giannetti
发明人： Enrico Albizzati , Enzo Giannetti
IPC分类号： C08F4/68 , C08F10/00 , C07F9/00
CPC分类号： C08F10/00
摘要： Components of catalysts for polymerizing olefins having the general formula:VCl.sub.n (OR).sub.min which R=a hydrocarbon radical having 1-18 C; or R.sub.p.sup.1 Si(OH).sub.3-p, in which R.sup.1 =a hydrocarbon radical, 1.ltoreq.p.ltoreq.3; 1.5.ltoreq.n.ltoreq.3, m=3-n; with X-ray powder spectrum, in which maximum intensity diffraction lines, which in the spectrum of normal VCl.sub.3 appear at d=5.75 .ANG., d=2.67 .ANG. and d=1.74 .ANG., exhibit a broadening of the half peak breath of at least three times for the diffraction line at d=5.75 .ANG. and of at least four times for the diffraction lines appearing at d=2.67 .ANG. and d=1.74 .ANG., or said diffraction lines disappear.
摘要翻译：用于聚合具有以下通式的烯烃的催化剂的组分：VCln（OR）m，其中R =具有1-18个碳原子的烃基; 或Rp1Si（OH）3-p，其中R1 =烃基，1 = 3; 1.5

3. 发明授权

US4464478A Catalyst components and catalysts for polymerizing olefins 失效
标题翻译：用于聚合烯烃的催化剂组分和催化剂
公开(公告)号：US4464478A
公开(公告)日：1984-08-07
申请号：US428976
申请日：1982-09-30
申请人： Umberto Scata , Enrico Albizzati , Enzo Giannetti
发明人： Umberto Scata , Enrico Albizzati , Enzo Giannetti
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022
摘要： Catalyst-forming components are prepared from(a) a halogenated Ti compound containing at least a Ti-halogen bond;(b) an electron-donor compound free of active hydrogen atoms;and(c) the solid product of the reaction between at least one electron-donor compound containing active hydrogen atoms and a Mg dihalide or a complex thereof with an electron-donor compound free of active hydrogen atoms, obtained by decomposing organic Mg compounds containing at least one Mg-R or Mg-OR group, in which R is an alkyl, aryl, cycloalkyl or alkenyl radical having 1 to 20 carbon atoms, by means of a halogenating agent different from (a).Catalysts for polymerizing olefins and prepared by mixing the aforesaid catalyst-forming components with an organometallic compound of Al are also disclosed.
摘要翻译：催化剂形成成分由（a）至少含有Ti-卤素键的卤化Ti化合物制备; （b）不含活性氢原子的电子给体化合物; 和（c）包含活性氢原子的至少一种电子给体化合物与二卤化镁或其配合物与不含活性氢原子的电子给体化合物之间的反应的固体产物，通过分解含有至少一个Mg-R或Mg-OR基团，其中R是具有1至20个碳原子的烷基，芳基，环烷基或烯基，通过不同于（a）的卤化剂。还公开了用于聚合烯烃并通过将上述催化剂形成组分与Al的有机金属化合物混合制备的催化剂。

4. 发明授权

US4399054A Catalyst components and catalysts for the polymerization of alpha-olefins 失效
标题翻译：用于α-烯烃聚合的催化剂组分和催化剂
公开(公告)号：US4399054A
公开(公告)日：1983-08-16
申请号：US226837
申请日：1981-01-21
申请人： Mario Ferraris , Francesco Rosati , Sandro Parodi , Enzo Giannetti , Giuseppe Motroni , Enrico Albizzati
发明人： Mario Ferraris , Francesco Rosati , Sandro Parodi , Enzo Giannetti , Giuseppe Motroni , Enrico Albizzati
IPC分类号： C08F4/00 , B01J31/38 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/65 , C08F4/654 , C08F10/00
CPC分类号： C08F4/022 , C08F10/00
摘要： Catalyst components which comprise the reaction product of a Ti compound and a Mg dihalide and which are in the form of spherical particles having an average diameter of 1 to 100 microns, a surface area of 300 to 500 m.sup.2 /g, and a porosity of 0.3 to 0.4 cc/g are disclosed, as are catalysts also in the form of spherical particles prepared therefrom and useful in the polymerization of ethylene and of alpha-olefins CH.sub.2 .dbd.CHR in which R is alkyl radical having from 1 to 6 carbon atoms, and the polymerization of the alpha-olefins therewith.
摘要翻译：催化剂组分包括Ti化合物和二卤化镁的反应产物，其呈球形颗粒形式，平均直径为1至100微米，表面积为300至500m 2 / g，孔隙率为0.3 公开了0.4cc / g，作为由其制备的球形颗粒形式的催化剂也可用于乙烯和其中R为具有1至6个碳原子的烷基的α-烯烃CH 2 = CHR的聚合，以及 α-烯烃的聚合反应。

5. 发明授权

US4789717A Process for the polymerization in aqueous dispersion of fluorinated monomers 失效
标题翻译：氟化单体的水性分散体中的聚合方法
公开(公告)号：US4789717A
公开(公告)日：1988-12-06
申请号：US41527
申请日：1987-04-23
申请人： Enzo Giannetti , Angelo Rotasperti , Enrico Marchese
发明人： Enzo Giannetti , Angelo Rotasperti , Enrico Marchese
IPC分类号： C08F2/16 , B01F17/42 , C08F2/00 , C08F2/18 , C08F2/22 , C08F2/30 , C08F14/18 , C08F214/26
CPC分类号： C08F214/262 , C08F14/18
摘要： A process for polymerizing or copolymerizing fluorinated monomers, in an aqueous dispersion, by the use of radicalic starters and of fluorinated surfactants, characterized in that it is operated in the presence of perfluoropolyether having neutral end groups, being liquid under the polymerization conditions and in the form of an aqueous emulsions, in order to increase the polymerization rate.

6. 发明授权

US4864006A Process for the polymerization in aqueous dispersion of fluorinated monomers 失效
标题翻译：氟化单体的水性分散体中的聚合方法
公开(公告)号：US4864006A
公开(公告)日：1989-09-05
申请号：US41525
申请日：1987-04-23
申请人： Enzo Giannetti , Mario Visca
发明人： Enzo Giannetti , Mario Visca
IPC分类号： C08F2/16 , B01F17/42 , C08F2/00 , C08F2/18 , C08F2/22 , C08F2/30 , C08F14/18 , C08F214/26
CPC分类号： C08F14/18
摘要： A process for polymerizing or copolymerizing fluorinated monomers, in an aqueous dispersion, by using radicalic-type starters and fluorinated surfactants, characterized in that it is operated in the presence of a perfluoropolyether having neutral end groups and prepared in the form of an aqueous microemulsion, in order to increase the polymerization rate, to increase the process reproducibility and to minimize the consumption of said perfluoropolyether.

7. 发明申请

US20120264887A1 Curable composition 有权
标题翻译：可固化组合物
公开(公告)号：US20120264887A1
公开(公告)日：2012-10-18
申请号：US13517239
申请日：2010-12-16
申请人： Enzo Giannetti , Aldo Sanguineti , Ivan Wlassics , Giuseppe Marchionni
发明人： Enzo Giannetti , Aldo Sanguineti , Ivan Wlassics , Giuseppe Marchionni
IPC分类号： C07C22/04 , C08L27/16 , C08F214/26 , C07C43/285 , C07C15/48 , C07C22/08 , C07C15/24 , C08L27/18 , C08F214/22
CPC分类号： C08K5/01 , C08K5/0025 , C08K5/02 , C08K5/5475
摘要： The invention relates to the use of 1,5-enediyne compounds of formula (I) as curing agents in polymeric systems. In particular the invention relates to a curable composition comprising a curing agent of formula (I) and a polymer suitable to be cross-linked and to the cured article obtained therefrom.
摘要翻译：本发明涉及式（I）的1,5-戊二烯化合物作为聚合体系中的固化剂的用途。特别地，本发明涉及包含式（I）的固化剂和适于交联的聚合物和由其获得的固化制品的可固化组合物。

8. 发明授权

US5219964A Fluoroelastomers endowed with improved processability and process for preparing them 失效
标题翻译：氟弹性体具有改进的加工性和制备它们的方法
公开(公告)号：US5219964A
公开(公告)日：1993-06-15
申请号：US925845
申请日：1992-08-07
申请人： Margherita Albano , Giulio Brinati , Vincenzo Arcella , Enzo Giannetti
发明人： Margherita Albano , Giulio Brinati , Vincenzo Arcella , Enzo Giannetti
IPC分类号： C08F4/08 , C08F214/22 , C08F214/26
CPC分类号： C08F214/22 , C08F214/26
摘要： Fluoroelastomers characterized by the presence of iodine or bromine atoms at the end of the polymeric chain in an amount equal to or lower than 1 iodine or bromine atom per polymeric chain, and by a bromine content in the chain ranging from 0.05 to 2% by weight referred to the total weight of the monomeric units.Said fluoroelastomers exhibit improved characteristics of processability, particularly as regards the utilization in injection molding processes and the detaching from the molds, as well as of stability to heat.A process for preparing fluoroelastomers containing iodine or bromine atoms at the ends of the polymeric chain, in an amount equal to or lower than 1 iodine or bromine atom per polymeric chain, which process comprises polymerizing mixes of fluorinated monomers (VDF, TFE, HFP, FVE) in bulk, in suspension, in aqueous emulsion, or in solution of organic solvents by means of radical starters, in the presence of compounds capable of providing I.sup.- or Br.sup.- ions in the polymerization medium and conditions.
摘要翻译：其特征在于聚合物链末端存在碘或溴原子，其量为每个聚合物链等于或低于1个碘或溴原子，并且链中的溴含量为0.05-2重量％指单体单元的总重量。所述含氟弹性体表现出改进的加工性能，特别是关于注射成型工艺的利用和从模具的分离以及对热的稳定性。在聚合物链的末端制备含有碘或溴原子的含氟弹性体的方法，其量等于或低于每个聚合物链1个碘或溴原子，该方法包括将氟化单体（VDF，TFE，HFP， FVE）在悬浮液中，在水性乳液中，或在有机溶剂的溶液中，通过自由基引发剂在能够在聚合介质和条件下提供I-或Br离子的化合物存在下进行。

9. 发明授权

US4395360A Catalyst components and catalysts for the polymerization of alpha-olefins 失效
标题翻译：用于α-烯烃聚合的催化剂组分和催化剂
公开(公告)号：US4395360A
公开(公告)日：1983-07-26
申请号：US256235
申请日：1981-04-21
申请人： Enrico Albizatti , Enzo Giannetti , Umberto Scata
发明人： Enrico Albizatti , Enzo Giannetti , Umberto Scata
IPC分类号： C08F4/02 , C08F4/60 , C08F4/64 , C08F4/642 , C08F10/00
CPC分类号： C08F10/00
摘要： Catalyst components for the polymerization of olefins are disclosed. Said components comprise the solid product of the reaction of a halogenated Ti compound and of an electron-donor compound not containing active H atoms with the solid product of the reaction between an electron-donor compound containing active H atoms and a Mg dihalide obtained by decomposition, with halogenating agents other than the above halogenated Ti compound, of product (d) obtained from the reaction between an organometallic Mg compound of formula R.sub.m MgX.sub.n is which R is a hydrocarbon or --OR group, X is halogen or a group R, OR, or COX' (X' being halogen), 0
摘要翻译：公开了用于烯烃聚合的催化剂组分。所述组分包括卤化Ti化合物和不含活性H原子的电子给体化合物与含有活性H原子的电子给体化合物与通过分解获得的二卤化镁之间的反应的固体产物的反应的固体产物使用得自式RmMgXn的有机金属Mg化合物之间的反应得到的产物（d），其中R是烃或-OR基团，X是卤素或基团R，OR，或COX'（X'为卤素），0

10. 发明授权

US09458307B2 Curable composition 有权
公开(公告)号：US09458307B2
公开(公告)日：2016-10-04
申请号：US13517239
申请日：2010-12-16
申请人： Enzo Giannetti , Aldo Sanguineti , Ivan Wlassics , Giuseppe Marchionni
发明人： Enzo Giannetti , Aldo Sanguineti , Ivan Wlassics , Giuseppe Marchionni
IPC分类号： C08K5/02 , C08K5/01 , C08K5/00 , C08K5/5475
CPC分类号： C08K5/01 , C08K5/0025 , C08K5/02 , C08K5/5475
摘要： The invention relates to the use of 1,5-enediyne compounds of formula (I) as curing agents in polymeric systems. In particular the invention relates to a curable composition comprising a curing agent of formula (I) and a polymer suitable to be cross-linked and to the cured article obtained therefrom.

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