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    • 2. 发明授权
    • Coating compositions
    • 涂料组合物
    • US5277709A
    • 1994-01-11
    • US822446
    • 1992-01-16
    • William P. ArmstrongEmyr Phillips
    • William P. ArmstrongEmyr Phillips
    • C09D5/00C07C59/185C07C59/347C07C59/80C07C59/84C07C59/90C07C61/22C07C62/30C07C65/34C07C69/738C07F9/38C09D5/08C09D5/44C09D7/12C04B9/02
    • C09D5/448C07C59/185C07C59/347C07C59/80C07C59/84C07C59/90C07C61/22C07C62/30C07C65/34C07C69/738C07F9/3808C07F9/3882C09D5/086
    • A coating composition comprising a) an organic film-forming binder; and b) a corrosion-inhibiting amount of a substantially water-insoluble mono- or poly-basic salt of:i) a ketoacid having the formula I: ##STR1## in which m and n, independently, are 0 or an integer from 1 to 10 provided that the sum of m and n is at least 1; A is C.sub.1 -C.sub.15 alkyl, C.sub.2 -C.sub.15 alkenyl, optionally substituted C.sub.3 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.15 alkyl interrupted by one or more O-, N- or S-atoms, optionally substituted C.sub.6 -C.sub.10 aryl, optionally substituted C.sub.7 -C.sub.12 aralkyl, optionally substituted C.sub.7 -C.sub.12 aralkenyl, a heterocyclic residue or a ferrocenyl residue; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each is a substituent A, hydrogen, OH, O-C.sub.1 -C.sub.15 alkyl, NH.sub.2, NH(C.sub.1 -C.sub.15 alkyl), N(C.sub.1 -C.sub.15 alkyl).sub.2, CO.sub.2 H, CO.sub.2 (C.sub.1 -C.sub.15 alkyl), SO.sub.3 H, P(O) (OH).sub.2 P(O)(OH)(O-C.sub.1 -C.sub.15 alkyl), P(O) (O-C.sub.1 -C.sub.15 alkyl).sub.2, SH, S(C.sub.1 -C.sub.15 alkyl), nitro, cyano, halogen or two of R.sub.1, R.sub.2 R.sub.3 and R.sub.4, together with the carbon atoms to which they are attached, form a C.sub.3 -C.sub.12 cycloalkyl ring or C.sub.6 - or C.sub.10 aryl ring, or one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 together with the carbon atom to which it is attached, and with the group A--C(.dbd.O)--, forms a ring, or R.sub.1 and R.sub.2, R.sub.3 and R.sub.4 form a carbonyl group or a C.dbd.C double bond, provided that A is not optionally substituted C.sub.6 -C.sub.10 aryl when R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are simultaneously hydrogen and provided that R.sub.1 and R.sub.2, or R.sub.3 and R.sub.4, respectively, are not simultaneously both OH or both NH.sub.2 ; and ii) a base selected from a) a cation of Group Ia, Ib, IIa, IIb, IIIa, IIIb, IVa, IVb, Va, VIa, VIIa or VIIIa of the Periodic Table of Elements;b) an amine of formula II which is specified herein.
    • 一种涂料组合物,其包含a)有机成膜粘合剂; 和b)基本上不溶于水的不溶性单碱金属或多碱性盐的腐蚀抑制量:i)具有式I的酮酸:(*化学结构*)I,其中m和n独立地为0或 1到10的整数,只要m和n之和至少为1; A是C 1 -C 15烷基,C 2 -C 15烯基,任选取代的C 3 -C 12环烷基,被一个或多个O-,N-或S-原子间隔的C 2 -C 15烷基,任选取代的C 6 -C 10芳基,任选取代的C 7 -C 12 芳烷基,任选取代的C 7 -C 12芳烯基,杂环残基或二茂铁基残基; R 1,R 2,R 3和R 4相同或不同,各自为取代基A,氢,OH,O-C 1 -C 15烷基,NH 2,NH(C 1 -C 15烷基),N(C 1 -C 15烷基)2,CO 2 H ,CO(C 1 -C 15烷基),SO 3 H,P(O)(OH)2 P(O)(OH)(O-C 1 -C 15烷基),P(O)(O-C 1 -C 15烷基) ,S(C 1 -C 15烷基),硝基,氰基,卤素或R 2,R 3,R 3和R 4中的两个与它们所连接的碳原子一起形成C 3 -C 12环烷基环或C 6 - 或C 10芳环, 或R 1,R 2,R 3和R 4中的一个与其所连接的碳原子一起,并与基团AC(= O) - 形成环,或者R 1和R 2,R 3和R 4形成羰基或 C = C双键,条件是当R 1,R 2,R 3和R 4同时为氢时,A不是任选取代的C 6 -C 10芳基,条件是R 1和R 2或R 3和R 4分别不同时为OH或NH 2 ; 和ii)选自a)元素周期表的Ia,Ib,IIa,IIb,IIIa,IIIb,IVa,IVb,Va,VIa,VIIa或VIIIa族的阳离子的碱; b)本文所述的式II的胺。
    • 4. 发明授权
    • Solar powered relatively balanced pumping system
    • 太阳能供电相对平衡的泵送系统
    • US5336061A
    • 1994-08-09
    • US006646
    • 1993-01-21
    • William P. Armstrong
    • William P. Armstrong
    • F04B9/06F04B17/00F04B47/14F04B35/04
    • F04B9/06F04B17/006F04B47/14
    • A solar powered pumping system has a ground level walking beam pumping unit and a downhole pump unit which pump liquids during daylight hours. The walking beam pumping unit has a solar powered electric motor which drives a flywheel through drive wheels and a centrifugal clutch to pivot a fulcrum beam having counterweights at one end. The other end of the fulcrum beam is connected by a lift wire to the downhole pump. The downhole pump has a pump housing with a stationary check valve at its upper end connected to a supply conduit extending to the surface. A traveling check valve/piston inside the pump housing is moved on the up stroke by a lift rod slidably mounted on the exterior of the housing which has a top end connected to the lift wire and a lower end connected to the traveling check valve/piston through a longitudinal slot in the lower housing. The traveling check valve/piston is returned on the down stroke by a tension return spring connected between the traveling check valve/piston and the pump housing. On the down stroke the traveling check valve opens and the stationary check valve at the top of the pump housing closes allowing liquid to enter. On the up stroke the traveling check valve closes, the stationary check valve opens, and the traveling check valve/piston lifts or pushes the liquid through the stationary check valve and subsequently to the surface. The return spring and counterweights produce a relatively balanced load condition to reduce power consumption and increase operating efficiency.
    • 太阳能泵送系统具有地平面步进式排水装置和井下泵装置,其在白天用于泵送液体。 步进式射束单元具有太阳能驱动的电动机,其通过驱动轮驱动飞轮和离心离合器,以在一端枢转具有配重的支点梁。 支点梁的另一端通过升降线连接到井下泵。 井下泵具有在其上端连接有延伸到表面的供应管道的固定止回阀的泵壳体。 泵壳体内的行进止回阀/活塞通过可滑动地安装在壳体外部的提升杆在上行程上移动,该提升杆具有连接到提升线的顶端,并且下端连接到行进止回阀/活塞 通过下壳体中的纵向狭槽。 行程止回阀/活塞通过连接在行进止回阀/活塞和泵壳体之间的张力复位弹簧在下行程中返回。 在下冲行程中,行驶止回阀打开,泵壳顶部的固定止回阀关闭,允许液体进入。 在行程上,行驶止回阀关闭,静止止回阀打开,行驶止回阀/活塞提升或推动液体通过静止止回阀并随后到达表面。 复位弹簧和配重产生相对平衡的负载条件,以降低功耗并提高运行效率。
    • 6. 发明授权
    • Alkaline earth metal salts, transition metal salts and transition metal
complexes of ketocarboxylic acids as corrosion inhibitors
    • 碱土金属盐,过渡金属盐和酮羧酸的过渡金属络合物作为腐蚀抑制剂
    • US5458678A
    • 1995-10-17
    • US222766
    • 1994-04-04
    • William P. ArmstrongAdalbert BraigMarkus FreyAndreas Kramer
    • William P. ArmstrongAdalbert BraigMarkus FreyAndreas Kramer
    • C07C51/41C07C59/84C07C59/88C07C59/90C07C205/56C09D5/08C09K15/06C23F11/00C09D5/00C07C51/00
    • C07C59/84C07C205/56C07C59/88C07C59/90C09D5/086
    • There are described novel alkaline earth metal salts, transition metal salts and transition metal complexes of compounds of the formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are, independently of one another, hydrogen, halogen, nitro, cyano, CF.sub.3, C.sub.1 -C.sub.15 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.15 alkenyl, C.sub.1 -C.sub.12 haloalkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl; C.sub.6 -C.sub.10 aryloxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl; C.sub.7 -C.sub.12 arylalkyl which is unsubstituted or substituted on the aryl radical by from 1 to 3 C.sub.1 -C.sub.4 alkyl groups; --CO.sub.2 R.sub.6, --COR.sub.6 or ##STR2## where at least one of the radicals R.sub.1 to R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.15 alkyl, in addition the radicals R.sub.1 and R.sub.2, R2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 form, together with the carbon atoms to which they are bound, a benzo or cyclohexenyl ring,R.sub.6 is C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkyl interrupted by oxygen, sulfur or >N--R.sub.9 ; C.sub.7 -C.sub.12 arylalkyl which is unsubstituted or substituted on the aryl radical by from 1 to 3 C.sub.1 -C.sub.4 alkyl groups, R.sub.7 and R.sub.8 are, independently of one another, hydrogen, C.sub.1 -C.sub.24 alkyl or C.sub.2 -C.sub.24 alkyl interrupted by oxygen, sulfur or >N--R.sub.9,R.sub.9 is hydrogen or C.sub.1 -C.sub.8 alkyl, andn is an integer in the range from 1 to 10 for use, as corrosion inhibitors in coating compositions for protecting metal surfaces.
    • 描述了式I(I)化合物的新型碱土金属盐,过渡金属盐和过渡金属络合物,其中R 1,R 2,R 3,R 4和R 5彼此独立地为氢,卤素, 硝基,氰基,CF 3,C 1 -C 15烷基,C 5 -C 12环烷基,C 2 -C 15烯基,C 1 -C 12卤代烷基,C 1 -C 12烷氧基,C 1 -C 12烷硫基,未被C 1 -C 4烷基取代的C 6 -C 10芳基; 未取代或被C 1 -C 4烷基取代的C 6 -C 10芳氧基; 未取代或在芳基上被1至3个C 1 -C 4烷基取代的C 7 -C 12芳基烷基; -CO 2 R 6,-COR 6或其中基团R 1至R 5中的至少一个为氢,卤素或C 1 -C 15烷基,此外基团R 1和R 2,R 2和R 3,R 3和R 4或R 4和R 5一起形成 与其结合的碳原子,苯并或环己烯基环,R 6是C 1 -C 20烷基,被氧,硫或> N-R 9中断的C 2 -C 20烷基; 未取代或在芳基上被1至3个C 1 -C 4烷基取代的C 7 -C 12芳基烷基,R 7和R 8彼此独立地为氢,C 1 -C 24烷基或C 2 -C 24烷基,其被氧,硫或> N- R9,R9为氢或C1-C8烷基,n为1〜10的整数,用作保护金属表面的涂料组合物中的腐蚀抑制剂。
    • 8. 发明授权
    • Slurry pipeline leaching method
    • 泥浆管道浸出法
    • US5709731A
    • 1998-01-20
    • US676853
    • 1996-07-08
    • William P. Armstrong
    • William P. Armstrong
    • B65G53/30C22B1/00C22B3/04C22B3/08
    • C22B1/00C22B3/04Y02P10/234
    • A method for concurrently transporting and leaching metal values from an ore or concentrate containing said metal values from an originating site such as an elevated site to a delivery site comprising the steps of crushing and/or grinding the ore or concentrate to form a particulate having a size range suitable for transport by gravity or a combination of pumping and gravity as a solid constituent in an aqueous slurry, forming an aqueous slurry of from about 30 to about 70 percent by weight of said particulate in an aqueous medium, and adjusting said aqueous slurry to contain an effective amount of a lixiviant for dissolution of said metal values into the aqueous medium. The aqueous slurry with lixiviant is transported in an elongated pipeline under a static pressure and for a residence time sufficient for dissolution of a substantial portion of the metal values, and the aqueous medium with the metal values is separated from the solids constituent of the slurry by a hydrocone, settling tank, thickener, lagoon, pond or heap, or counter-current decantation or washing circuit for recovery of values therefrom. The ore or concentrate may contain metal oxides, metal sulphides, native metal or a combination thereof, such as for example, a copper oxide concentrate or an ore, and the lixiviant may be sulphuric acid.
    • 将来自含有所述金属值的矿石或浓缩物的金属值同时输送和浸出的方法,所述金属或浓缩物从起始位点如高架位置输送到输送位置,包括以下步骤:粉碎和/或研磨矿石或浓缩物以形成具有 尺寸范围适合于通过重力或泵送和重力的组合作为固体成分在水性浆料中的运输,在水性介质中形成约30至约70重量%的所述颗粒的水性浆料,并调节所述含水浆料 以含有有效量的用于将所述金属值溶解到水性介质中的浸渍剂。 具有浸渍剂的含水浆料在静态压力下在细长的管线中运输,并且足以溶解大部分金属值的停留时间,并且将金属值的水性介质与浆料的固体成分分离, 水龙头,沉淀池,增稠器,泻湖,池塘或堆,或用于从其中回收值的逆流倾析或洗涤回路。 矿石或浓缩物可以含有金属氧化物,金属硫化物,天然金属或其组合,例如氧化铜浓缩物或矿石,并且浸出剂可以是硫酸。