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1. 发明申请

US20080269459A1 Process for the Preparation of a Dicarboxylic Acid 审中-公开
标题翻译：二羧酸的制备方法
公开(公告)号：US20080269459A1
公开(公告)日：2008-10-30
申请号：US11884113
申请日：2006-02-10
申请人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
发明人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
IPC分类号： C07C57/13 , C08G73/00
CPC分类号： C07C51/14 , B01J31/24 , B01J2531/824 , C07C57/03 , C07C55/14
摘要： A process for the preparation of a saturated dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water to obtain a mixture containing an ethylenically unsaturated acid product and one or more reversible adducts of the conjugated diene and the ethylenically unsaturated acid; and (b) reacting the ethylenically unsaturated acid product further with carbon monoxide and water to obtain the dicarboxylic acid, wherein step (a) and (b) are performed in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, and wherein in step (a) the water concentration is maintained at a range of from 0.001 to less than 3% by weight of water, calculated on the overall weight of the liquid reaction medium, and wherein in step (b) the water concentration is maintained at a range of from 3% to 50% by weight of water, calculated on the overall weight of the liquid reaction medium.
摘要翻译：一种制备饱和二羧酸的方法，包括以下步骤：（a）使共轭二烯与一氧化碳和水接触，以获得含有烯属不饱和酸产物和一种或多种可共轭二烯的可逆加合物和烯键式不饱和酸和（b）使烯属不饱和酸产物进一步与一氧化碳和水反应以获得二羧酸，其中步骤（a）和（b）在催化剂体系存在下进行，所述催化剂体系包括钯源，阴离子和二齿膦配体，并且其中在步骤（a）中，水浓度保持在0.001至小于3重量％的水的范围内，以液体反应介质的总重计算，并且其中在步骤（b）根据液体反应介质的总重量，水浓度保持在3重量％至50重量％的水的范围内。

2. 发明申请

US20080269433A1 Process for the Carbonylation of a Conjugated Diene 审中-公开
标题翻译：共轭二烯的羰基化方法
公开(公告)号：US20080269433A1
公开(公告)日：2008-10-30
申请号：US11884107
申请日：2006-02-10
申请人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom , Timothy Michael Nisbet
发明人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom , Timothy Michael Nisbet
IPC分类号： C08F2/60
CPC分类号： C07C51/14 , C07C57/03
摘要： A process for the carbonylation of a conjugated diene to an ethylenically unsaturated acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid and a reversible diene adduct comprising alkenyl ester of the conjugated diene with the ethylenically unsaturated acid; (b) separating the obtained reaction mixture into a gaseous stream comprising unreacted conjugated diene and carbon monoxide, a first liquid product stream comprising at least part of the ethylenically unsaturated acid and the reversible diene adducts, and a second liquid stream comprising the catalyst system in admixture with the ethylenically unsaturated acid; (c) separating the first liquid product stream obtained in step (b) into a stream comprising the ethylenically unsaturated acid and a stream comprising the reversible diene adducts; and (d) recycling the stream comprising the reversible diene adducts to step (a), or converting the reversible diene adducts back to the conjugated diene and the ethylenically unsaturated acid and recycling the thus obtained conjugated diene to step (a).
摘要翻译：一种将共轭二烯羰基化成烯属不饱和酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和/或其盐的催化剂体系存在下使共轭二烯与一氧化碳和水接触，二次膦配体，以获得包含烯键式不饱和酸和包含共轭二烯烯基酯与烯键式不饱和酸的可逆二烯加合物的混合物; （b）将获得的反应混合物分离成包含未反应的共轭二烯和一氧化碳的气流，包含至少部分烯键式不饱和酸和可逆二烯加合物的第一液体产物流和包含催化剂体系的第二液体流与烯属不饱和酸的混合物; （c）将步骤（b）中获得的第一液体产物流分离成包含烯属不饱和酸的物流和包含可逆二烯加成物的物流; 和（d）将包含可逆二烯加合物的料流再循环到步骤（a）中，或将可逆二烯加合物转化回共轭二烯和烯属不饱和酸，并将由此得到的共轭二烯再循环到步骤（a）。

3. 发明申请

US20090131630A1 Process For the Preparation of a Dicarboxylic Acid 审中-公开
标题翻译：二羧酸的制备方法
公开(公告)号：US20090131630A1
公开(公告)日：2009-05-21
申请号：US11884081
申请日：2006-02-10
申请人： Johannes Adrianus Maria Van Broekhoven , Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
发明人： Johannes Adrianus Maria Van Broekhoven , Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom
IPC分类号： C07C51/44 , C08G69/26
CPC分类号： C07C51/14 , C07C55/14
摘要： A process for the preparation of a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture containing an ethylenically unsaturated acid and one or more reversible adduct of the conjugated diene and the ethylenically unsaturated acid; and (b) removing unreacted conjugated diene, and the reversible adducts of the conjugated diene from the reaction mixture; and (c) reacting the mixture obtained in step (b) containing the ethylenically unsaturated acid further with carbon monoxide and water to obtain the dicarboxylic acid.
摘要翻译：一种制备二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和二齿膦配体的催化剂体系的存在下，使共轭二烯与一氧化碳和水接触，以获得含有烯属不饱和酸和共轭二烯和烯键式不饱和酸的一种或多种可逆加合物的混合物; 和（b）从反应混合物中除去未反应的共轭二烯和共轭二烯的可逆加合物; 和（c）使含有烯属不饱和酸的步骤（b）中获得的混合物与一氧化碳和水进一步反应，得到二羧酸。

4. 发明申请

US20080269520A1 Process for the Carbonylation of a Conjugated Diene to a Dicarboxylic Acid 审中-公开
标题翻译：共轭二烯羰基化成二羧酸的方法
公开(公告)号：US20080269520A1
公开(公告)日：2008-10-30
申请号：US11884103
申请日：2006-02-10
申请人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom , Timothy Michael Nisbet
发明人： Eit Drent , Rene Ernst , Willem Wabe Jager , Cornelia Alida Krom , Timothy Michael Nisbet
IPC分类号： C07C51/14
CPC分类号： C07C51/14 , C07C55/14
摘要： A process for the carbonylation of a conjugated diene to a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid and reversible diene adducts; (b) separating the obtained reaction mixture into a gaseous stream comprising unreacted conjugated diene and carbon monoxide, a first normally liquid stream comprising at least part of the ethylenically unsaturated acid and the reversible diene adducts, and a second normally liquid stream comprising the catalyst system in admixture with the ethylenically unsaturated acid; (c) recycling the second liquid stream obtained in step (b) to step (a); (d) separating the first liquid product stream obtained in step (b) into a stream comprising the ethylenically unsaturated acid and a stream comprising the reversible diene adducts; and (e) contacting the stream comprising the ethylenically unsaturated acid obtained in step (d) with carbon monoxide and water in the presence of a second catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand.
摘要翻译：一种将共轭二烯羰基化成二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和阴离子的催化剂体系的存在下使共轭二烯与一氧化碳和水接触二次膦配体，以获得包含烯属不饱和酸和可逆二烯加成物的混合物; （b）将获得的反应混合物分离成包含未反应的共轭二烯和一氧化碳的气流，包含至少部分烯属不饱和酸和可逆二烯加合物的第一常规液体流，以及包含催化剂体系的第二常规液流与烯属不饱和酸的混合物; （c）将步骤（b）中获得的第二液体流循环到步骤（a）; （d）将步骤（b）中获得的第一液体产物流分离成包含烯属不饱和酸的物流和包含可逆二烯加成物的物流; 和（e）在包含钯源，阴离子源和二齿膦配体的第二催化剂体系的存在下，将包含步骤（d）中获得的烯属不饱和酸的物流与一氧化碳和水接触。

5. 发明申请

US20080194870A1 Process for the Preparation of a Dicarboxylic Acid 审中-公开
标题翻译：二羧酸的制备方法
公开(公告)号：US20080194870A1
公开(公告)日：2008-08-14
申请号：US11884079
申请日：2006-02-10
申请人： Eit Drent , Rene Ernst , Willem Wade Jager , Cornelia Alida Krom
发明人： Eit Drent , Rene Ernst , Willem Wade Jager , Cornelia Alida Krom
IPC分类号： C07C51/14
CPC分类号： C08G69/28 , C07C51/14 , C07C51/43 , Y02P20/584 , C07C55/14
摘要： A process for the preparation of a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid product; (b) reacting the mixture obtained in step (a) further with carbon monoxide and water to obtain the dicarboxylic acid in admixture with the ethylenically unsaturated acid; (c) separating the dicarboxylic acid from a liquid filtrate comprising the catalyst system; and (d) recycling at least part of the obtained liquid filtrate to step (a).
摘要翻译：一种制备二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和二齿膦配体的催化剂体系的存在下，使共轭二烯与一氧化碳和水接触，以获得包含烯属不饱和酸产物的混合物; （b）使步骤（a）中得到的混合物进一步与一氧化碳和水反应，得到与烯属不饱和酸混合的二羧酸; （c）从包含催化剂体系的液体滤液中分离二羧酸; 和（d）将至少部分获得的液体滤液再循环到步骤（a）。

6. 发明授权

US07767862B2 Ligand, catalyst and process for hydroformylation 有权
标题翻译：配体，催化剂和加氢甲酰化方法
公开(公告)号：US07767862B2
公开(公告)日：2010-08-03
申请号：US12538524
申请日：2009-08-10
申请人： Marijke De Boer-Wildschut , Manutsavin Charernsuk , Cornelia Alida Krom , Monica Carreira Mendez , Wilhelmus Petrus Mul , Paul Gerard Pringle
发明人： Marijke De Boer-Wildschut , Manutsavin Charernsuk , Cornelia Alida Krom , Monica Carreira Mendez , Wilhelmus Petrus Mul , Paul Gerard Pringle
IPC分类号： C07F9/02 , C07C45/50 , B01J31/00
CPC分类号： C07F9/65683
摘要： According to the present invention, there is provided an organophosphine ligand comprising a phosphabicyclohydrocarbyl group in which the phosphorus atom is further substituted with a hydrocarbyl or heterohydrocarbyl moiety containing at least one branch at the β-carbon position. The present invention also provides a catalytic composition for the hydroformylation of an ethylenically unsaturated compound, said catalytic composition comprising i) a source of Group VIII metal cations; and ii) the above ligand. Furthermore, the present invention also provides a process for the hydroformylation of an ethylenically unsaturated compound, said process comprising contacting the ethylenically unsaturated compound with carbon monoxide and hydrogen in the presence the above catalytic composition.
摘要翻译：根据本发明，提供了包含磷杂双环烃基的有机膦配体，其中磷原子进一步被烃基或杂烃基部分取代，所述烃基或杂烃基部分在碳位置包含至少一个分支。本发明还提供了用于烯键式不饱和化合物的加氢甲酰基化的催化组合物，所述催化组合物包含i）VIII族金属阳离子源; 和ii）上述配体。此外，本发明还提供了烯键式不饱和化合物的加氢甲酰基化方法，所述方法包括在上述催化剂组合物存在下使烯属不饱和化合物与一氧化碳和氢气接触。

7. 发明申请

US20100036171A1 LIGAND, CATALYST AND PROCESS FOR HYDROFORMYLATION 有权
标题翻译：配体，催化剂和氢化方法
公开(公告)号：US20100036171A1
公开(公告)日：2010-02-11
申请号：US12538524
申请日：2009-08-10
申请人： Marijke De Boer-Wildschut , Manutsavin Charernsuk , Cornelia Alida Krom , Monica Carreira Mendez , Wilhelmus Petrus Mul , Paul Gerard Pringle
发明人： Marijke De Boer-Wildschut , Manutsavin Charernsuk , Cornelia Alida Krom , Monica Carreira Mendez , Wilhelmus Petrus Mul , Paul Gerard Pringle
IPC分类号： C07C45/34 , C07F9/6568 , B01J27/185
CPC分类号： C07F9/65683
摘要： According to the present invention, there is provided an organophosphine ligand comprising a phosphabicyclohydrocarbyl group in which the phosphorus atom is further substituted with a hydrocarbyl or heterohydrocarbyl moiety containing at least one branch at the β-carbon position. The present invention also provides a catalytic composition for the hydroformylation of an ethylenically unsaturated compound, said catalytic composition comprising i) a source of Group VIII metal cations; and ii) the above ligand. Furthermore, the present invention also provides a process for the hydroformylation of an ethylenically unsaturated compound, said process comprising contacting the ethylenically unsaturated compound with carbon monoxide and hydrogen in the presence the above catalytic composition.
摘要翻译：根据本发明，提供了一种含有磷杂双环烃基的有机膦配体，其中磷原子进一步被含有至少一个在β-碳位的分支的烃基或杂烃基部分取代。本发明还提供了用于烯键式不饱和化合物的加氢甲酰基化的催化组合物，所述催化组合物包含i）VIII族金属阳离子源; 和ii）上述配体。此外，本发明还提供了烯键式不饱和化合物的加氢甲酰基化方法，所述方法包括在上述催化剂组合物存在下使烯属不饱和化合物与一氧化碳和氢气接触。

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