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    • 2. 发明授权
    • Distyrylbiphenyls
    • 二苯乙烯基联苯
    • US4602087A
    • 1986-07-22
    • US611819
    • 1984-05-18
    • Christian LuthiHans R. MeyerKurt Weber
    • Christian LuthiHans R. MeyerKurt Weber
    • C07C63/66C07D213/20C07D213/30C07D295/092C07D303/24C07C141/02C07C93/02C07D207/06C07D211/00
    • C07D213/20C07C63/66C07D213/30C07D295/088C07D303/24C09B23/148
    • The distyrylbiphenyls of the formula ##STR1## in which X and X' independently of one another are a direct bond, oxygen, sulfur, --O--C.sub.1-3 -alkylene-CON(R.sub.4)--CON(R.sub.4)--, --O--C.sub.1-3 alkylene-COO--, OCO or --COO--, with the proviso that if n+n'=O, X and X' may not be --CON(R.sub.4)-- or O--C.sub.1-3 -alkylene-CON(R.sub.4)--, and if n+n'=2 and X and X' are --CON(R.sub.4)-- or --COO--, A.sup..crclbar. may not be a phosphite or phosphonate anion, and Y and Y' independently of one another are C.sub.1-20 -alkyene, R.sub.1 and R.sub.1 ' independently of one another are unsubstituted or substituted C.sub.1-8 -alkyl or C.sub.3-4 -alkenyl, R.sub.1 together with R.sub.2, or R.sub.1 ' together with R.sub.2 ', is a heterocyclic ring, R.sub.2 and R.sub.2 ' independently of one another are unsubstituted or substituted C.sub.1-8 -alkyl or C.sub.3-4 -alkenyl, or R.sub.2 together with R.sub.1, or R.sub.2 ' together with R.sub.1 ', is a heterocyclic ring, or R.sub.1 and R.sub.2, or R.sub.1 ' and R.sub.2 ', together with R.sub.3 are a pyridine or picoline ring, R.sub.3 is hydrogen, unsubstituted or substituted C.sub.1-4 -alkyl or C.sub.3-4 -alkenyl or together with R.sub.1 and R.sub.2, or with R.sub.1 ' and R.sub.2 ', is a pyridine or picoline ring, R.sub.4 is hydrogen or unsubstituted or substituted C.sub.1-6 -alkyl, A.sup..crclbar. is a colorless anion and n and n' independently of one another are the number 0 or 1, and the benzene nuclei B and C can also be substituted by non-chromophoric substituents, can be prepared by reacting a correspondingly substituted benzaldehyde with a biphenyl phosphonate and then alkylating or protonating the distryrylbiphenyldiamine formed. The distyrylbiphenyls are fluorescent brightening agents for organic materials. They are particularly suitable for use as additives for textile and laundry after-treatment agents which contain cationic textile softeners.
    • 其中X和X'彼此独立的式“IMAGE”(n + n')(+)(n + n')(+)(+)(n + n')A( - )的二苯乙烯基联苯是氧键, -3-亚烷基-CON(R 4)-CON(R 4) - , - O-C 1-3亚烷基-COO - ,OCO或-COO-,条件是如果n + n'= O,X和X' 是-CON(R4) - 或O-C1-3 - 亚烷基-CON(R4) - ,如果n + n'= 2,X和X'是-CON(R4) - 或-COO-,则A( - )可以不是亚磷酸酯或膦酸根阴离子,Y和Y'彼此独立地是C 1-20 - 烷基,R 1和R''彼此独立地是未取代的或取代的C 1-8 - 烷基或C 3-8 - 烯基, R1与R2一起或R 1'与R 2'一起为杂环,R 2和R 2'彼此独立地为未取代或取代的C 1-8 - 烷基或C 3-8 - 烯基,或R 2与R 1或R 2一起 与R 1'一起为杂环,R 1和R 2或R 1'和R 2'与R 3一起为吡啶或甲基吡啶环,R 3为氢,未取代或取代的C 1-4 - 烷基或C 3-4 - 烯基或与R1 a一起 d R2或R1'和R2'是吡啶或甲基吡啶环,R4是氢或未取代或取代的C1-6烷基,A( - )是无色阴离子,n和n'彼此独立地是 0或1,苯核B和C也可以被非发色取代基取代,可以通过相应地取代的苯甲醛与联苯基膦酸酯反应,然后使所形成的二苯基二苯基二胺进行烷基化或质子化来制备。 二苯乙烯基联苯是有机材料的荧光增白剂。 它们特别适合用作含有阳离子纺织软化剂的纺织品和洗衣后处理剂的添加剂。
    • 5. 发明授权
    • Distyrylbiphenyls
    • 二苯乙烯基联苯
    • US4339393A
    • 1982-07-13
    • US137147
    • 1980-04-04
    • Christian LuthiHans R. MeyerKurt Weber
    • Christian LuthiHans R. MeyerKurt Weber
    • C07C63/66C07D213/20C07D213/30C07D295/092C07D303/24C07C141/02C07C93/02C07D207/06C07D211/00
    • C07D213/20C07C63/66C07D213/30C07D295/088C07D303/24C09B23/148
    • The distyrylbiphenyls of the formula ##STR1## in which X and X' independently of one another are a direct bond, oxygen, sulfur, --O--C.sub.1--3 --alkylene--CON(R.sub.4)--, --CON(R.sub.4)--,--O--C.sub.1--3 --alkylene--COO--, OCO or --COO--, with the proviso that if n+n'=O, X and X' may not be --CON(R.sub.4)--or O--C.sub.1--3 --alkylene--CON(R.sub.4)--, and if n+n'=2 and X and X' are --CON(R.sub.4)--or --COO--, A.crclbar. may not be a phosphite or phosphonate anion, and Y and Y' independently of one another are C.sub.1--20 --alkylene, R.sub.1 and R.sub.1' independently of one another are unsubstituted or substituted C.sub.1--8 --alkyl or C.sub.3--4 --alkenyl, or R.sub.1 together with R.sub.2, or R.sub.1' together with R.sub.2', is a heterocyclic ring, R.sub.2 and R.sub.2' independently of one another are unsubstituted or substituted C.sub.1--8 --alkyl or C.sub.3--4 -- alkenyl, or R.sub.2 together with R.sub.1, or R.sub.2' together with R.sub.1', is a heterocyclic ring, or R.sub.1 and R.sub.2, or R.sub.1' and R.sub.2', together with R.sub.3 are a pyridine or picoline ring, R.sub.3 is hydrogen, unsubstituted or substituted C.sub.1--4 --alkyl or C.sub.3--4 --alkenyl or together with R.sub.1 and R.sub.2, or with R.sub.1' and R.sub.2', is a pyridine or picoline ring, R.sub.4 is hydrogen or unsubstituted or substituted C.sub.1--6 --alkyl, A.crclbar. is a colorless anion and n and n' independently of one another are the number 0 or 1, and the benzene nuclei B and C can also be substituted by non-chromophoric substituents, can be prepared by reacting a correspondingly substituted benzaldehyde with a biphenyl phosphonate and then alkylating or protonating the distyrylbiphenyldiamine formed. The distyrylbiphenyls are fluorescent brightening agents for organic materials. They are particularly suitable for use as additives for textile and laundry after-treatment agents which contain cationic textile softeners.
    • 其中X和X'彼此独立的式“IMAGE”+ TR 的二苯乙烯基联苯是直接键,氧,硫,-O-C 1-3 - 亚烷基-CON(R 4) - , - CON R4) - , - O-C1-3 - 亚烷基-COO-,OCO或-COO-,条件是如果n + n'= O,X和X'可能不是-CON(R4) - 或O- C 3 - 亚烷基-CON(R 4) - ,如果n + n'= 2且X和X'为-CON(R 4) - 或-COO-,则A( - )可以不是亚磷酸酯或膦酸根阴离子, 并且Y和Y'彼此独立地是C 1-20 - 亚烷基,R 1和R''彼此独立地是未取代或取代的C 1-8 - 烷基或C 3-8 - 烯基,或R 1与R 2或R 1'一起 R2'是杂环,R2和R2'彼此独立地是未取代的或取代的C 1-8 - 烷基或C 3-4 - 烯基,或者R 2与R 1或R 2'连同R 1'是杂环的 R 1和R 2,或R 1和R 2,或R 1'和R 2'与R 3一起为吡啶或甲基吡啶环,R 3为氢,未取代或取代的C 1-4 - 烷基或C 3-4 - 烯基或与R 1和R 2一起, R1'和R2'是吡啶或甲基吡啶环,R4是氢或未取代的或取代的C1-6烷基,A( - )是无色阴离子,n和n'彼此独立地是0或1 ,苯核B和C也可以被非发色取代基取代,可以通过相应地取代的苯甲醛与联苯基膦酸酯反应,然后使形成的二苯乙烯基联苯基二胺进行烷基化或质子化来制备。 二苯乙烯基联苯是有机材料的荧光增白剂。 它们特别适合用作含有阳离子纺织软化剂的纺织品和洗衣后处理剂的添加剂。
    • 8. 发明授权
    • Distyrylbiphenyls
    • 二苯乙烯基联苯
    • US4468352A
    • 1984-08-28
    • US372779
    • 1982-04-28
    • Christian LuthiHans R. MeyerKurt Weber
    • Christian LuthiHans R. MeyerKurt Weber
    • C07C63/66C07D213/20C07D213/30C07D295/092C07D303/24C07C141/02C07C93/02C07D207/06C07D211/00
    • C07D213/20C07C63/66C07D213/30C07D295/088C07D303/24C09B23/148
    • The distyrylbiphenyls of the formula ##STR1## in which X and X' independently of one another are a direct bond, oxygen, sulfur, --O--C.sub.1-3 -alkylene-CON(R.sub.4)----CON(R.sub.4)--, --O--C.sub.1-3 -alkylene-COO--, OCO or --COO--, with the proviso that if n+n'=O, X and Y' may not be --CON(R.sub.4)-- or O--C.sub.1-3 -alkylene-CON(R.sub.4)--, and if n+n'=2 and X and X' are --CON(R.sub.4)-- or --COO--, A.sup..crclbar. may not be a phosphite or phosphonate anion, and Y and Y' independently of one another are C.sub.1-20 -alkylene, R.sub.1 and R.sub.1 ' independently of one another are unsubstituted or substituted C.sub.1-8 -alkyl or C.sub.3-4 -alkenyl, or R.sub.1 together with R.sub.2, or R.sub.1 ' together with R.sub.2 ', is a heterocyclic ring, R.sub.2 and R.sub.2 ' independently of one another are unsubstituted or substituted C.sub.1-8 -alkyl or C.sub.3-4 -alkenyl, or R.sub.2 together with R.sub.1, or R.sub.2 ' together with R.sub.1 ', is a heterocyclic ring, or R.sub.1 and R.sub.2, or R.sub.1 ' and R.sub.2 ', together with R.sub.3 are a pyridine or picoline ring, R.sub.3 is hydrogen, unsubstituted or substituted C.sub.1-4 -alkyl or C.sub.3-4 -alkenyl or together with R.sub.1 and R.sub.2, or with R.sub.1 ' and R.sub.2 ', is a pyridine or picoline ring, R.sub.4 is hydrogen or unsubstituted or substituted C.sub.1-6 -alkyl, A.sup..crclbar. is a colorless anion and n and n' independently of one another are the number 0 or 1, and the benzene nuclei B and C can also be substituted by non-chromophoric substituents, can be prepared by reacting a correspondingly substituted benzaldehyde with a biphenyl phosphonate and then alkylating or protonating the distyrylbiphenyldiamine formed. The distyrylbiphenyls are fluorescent brightening agents for organic materials. They are particularly suitable for use as additives for textile and laundry after-treatment agents which contain cationic textile softeners.
    • 其中X和X'彼此独立的式“IMAGE”+ TR 的二苯乙烯基联苯是直接键,氧,硫,-O-C 1-3亚烷基-CON(R 4)-CON ) - ,-O-C 1-3 - 亚烷基-COO-,OCO或-COO-,条件是如果n + n'= O,X和Y'可以不是-CON(R 4) - 或O-C1 -3-亚烷基-CON(R 4) - ,如果n + n'= 2且X和X'是-CON(R 4) - 或-COO-,则A( - )可以不是亚磷酸酯或膦酸根阴离子, Y和Y'彼此独立地是C 1-20亚烷基,R 1和R 1'彼此独立地是未取代或取代的C 1-8 - 烷基或C 3-8 - 烯基,或者R 1与R 2或R 1'连同 R 2'是杂环,R 2和R 2'彼此独立地是未取代或取代的C 1-8 - 烷基或C 3-8 - 烯基,或者R 2与R 1或R 2'与R 1'一起是杂环 ,或R 1和R 2,或R 1'和R 2'与R 3一起为吡啶或甲基吡啶环,R 3为氢,未取代或取代的C 1-4 - 烷基或C 3-4 - 烯基或与R 1和R 2一起,或 R1'和R2'是吡啶或甲基吡啶环,R4是氢或未取代的或取代的C1-6烷基,A( - )是无色阴离子,n和n'彼此独立地是0或1 ,苯核B和C也可以被非发色取代基取代,可以通过相应地取代的苯甲醛与联苯基膦酸酯反应,然后使形成的二苯乙烯基联苯基二胺进行烷基化或质子化来制备。 二苯乙烯基联苯是有机材料的荧光增白剂。 它们特别适合用作含有阳离子纺织软化剂的纺织品和洗衣后处理剂的添加剂。