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    • 3. 发明授权
    • Thermofix process for the dyeing of polyester fibers
    • 聚酯纤维染色的Thermofix工艺
    • US3989451A
    • 1976-11-02
    • US442827
    • 1974-02-15
    • Edgar Earl RenfrewDominic Andrew Zanella
    • Edgar Earl RenfrewDominic Andrew Zanella
    • C09B29/08D06P1/18D06P1/39
    • D06P1/18C09B29/0802Y10S8/922
    • Polyester is dyed through thermofixation in fast shades with azo dyestuffs of the formula ##SPC1##WhereinR.sub.1 is hydrogen, chlorine, bromine, lower alkyl, or lower alkoxy;R.sub.2 is hydrogen, chlorine, bromine, lower alkyl, lower alkoxy, R.sub.7 CONH-- or R.sub.7 SO.sub.2 NH--;R.sub.3 is hydrogen, lower alkyl, hydroxy(lower alkyl), lower alkoxy(lower alkyl), cyano(lower alkyl), chloro(lower alkyl), bromo(lower alkyl) or ##EQU1## R.sub.4 is hydrogen, lower alkyl, hydroxy(lower alkyl), lower alkoxy(lower alkyl), cyano(lower alkyl), chloro(lower alkyl), bromo(lower alkyl), benzyl, chlorobenzyl, bromobenzyl, nitrobenzyl or ##EQU2## one of R.sub.5 and R.sub.6 is hydrogen or methyl; AND THE OTHER R.sub.5 and R.sub.6 is hydrogen;Each R.sub.7 is independently lower alkyl, chloro(lower alkyl) bromo(lower alkyl), cyano(lower alkyl), phenyl, chlorophenyl, bromophenyl, lower alkylphenyl, lower alkoxyphenyl or cyanophenyl;X is hydrogen, chlorine, bromine, lower alkyl, lower alkoxy, hydroxy(lower alkyl) or lower alkoxy(lower alkoxy);Y is hydrogen, chlorine, or bromine; andZ is methylene or carbonyl.
    • 聚酯经快速色调通过热固性染色,与下式的偶氮染料,其中R1是氢,氯,溴,低级烷基或低级烷氧基; R2是氢,氯,溴,低级烷基,低级烷氧基,R7CONH-或R7SO2NH-; R3是氢,低级烷基,羟基(低级烷基),低级烷氧基(低级烷基),氰基(低级烷基),氯(低级烷基),溴(低级烷基)或-CHCHOCR7; ||并行R5R6O R4是氢,低级烷基,羟基(低级烷基),低级烷氧基(低级烷基),氰基(低级烷基),氯(低级烷基),溴(低级烷基),苄基,氯苄基,溴苄基,硝基苄基或 -CHCHOCR7; R 5和R 6中的一个是氢或甲基; 而其他的R5和R6是氢; 每个R 7独立地是低级烷基,氯(低级烷基)溴(低级烷基),氰基(低级烷基),苯基,氯苯基,溴苯基,低级烷基苯基,低级烷氧基苯基或氰基苯基; X是氢,氯,溴,低级烷基,低级烷氧基,羟基(低级烷基)或低级烷氧基(低级烷氧基); Y是氢,氯或溴; Z是亚甲基或羰基。