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1. 发明公开

US20240101846A1 METHOD OF CONTINUOUS INKJET PRINTING FLUORESCENT INK 审中-公开
公开(公告)号：US20240101846A1
公开(公告)日：2024-03-28
申请号：US17944448
申请日：2022-09-14
申请人： Eastman Kodak Company
发明人： Barbara Boland Lussier , Douglas Eugene Bugner , Mark Edward Irving
IPC分类号： C09D11/50 , B41J2/02 , B41M3/06 , B41M3/14 , C09D11/324 , C09D11/328 , C09D11/40 , C09K11/06
CPC分类号： C09D11/50 , B41J2/02 , B41M3/06 , B41M3/144 , C09D11/324 , C09D11/328 , C09D11/40 , C09K11/06 , C09K2211/1007
摘要： An aqueous colored pigment-based ink that is capable of fluorescence, has a pigment colorant in an amount of 1-7 weight %; a non-polymeric fluorophore that when excited by fluorescence-exciting radiation having a peak of at least 200 nm and up to and including 400 nm, exhibits an emission peak of at least 400 nm and up to and including 750 nm, and which non-polymeric fluorophore is present in an amount of 0.1-2 weight %; and an aqueous medium comprising water. This aqueous colored pigment-based ink can be included in an ink set that also includes one or more aqueous colored pigment-based inks that are non-fluorescent. All of these inks can be applied using continuous inkjet (CIJ) printing, onto non-UV fluorescent substrates to provide images that can be detected when excited as noted above, which images can be provided on articles such as security documents, currency, and lottery tickets.

2. 发明授权

US11813882B2 Inkjet printed articles and method of making 有权
公开(公告)号：US11813882B2
公开(公告)日：2023-11-14
申请号：US17324394
申请日：2021-05-19
申请人： Eastman Kodak Company
发明人： Mark Edward Irving , Douglas Eugene Bugner , David D. Putnam
IPC分类号： B41M5/50 , C09D11/38 , C09D11/322 , C09D11/106 , C09D139/06 , C09D129/04 , B41M5/00 , C09D139/02 , C08K3/22
CPC分类号： B41M5/502 , B41M5/0023 , C09D11/106 , C09D11/322 , C09D11/38 , C09D129/04 , C09D139/02 , C09D139/06 , C08K3/22 , C08K2003/2241
摘要： An aqueous composition can be used for pre-treating a substrate prior to inkjet printing to provide a white opaque background for inkjet-printed images. This aqueous composition includes: (a) one or more water-soluble salts of a multivalent metal cation at 5-30 weight %; (b) a nonionic or cationic water-soluble or water-dispersible polymeric binder material at 5-30 weight %; and (c) surface-treated visible light-scattering particles having a D50 (median) particle size of at least 0.04 μm and up to and including 2 μm in an amount of 5-60 weight % based on the total aqueous composition weight. The pre-treated substrate is useful as an inkjet receiving medium that can be readily inkjet-printed particularly with anionically-stabilized aqueous pigment-based inks.

3. 发明申请

US20210062028A1 METHOD OF PREPARING LAMINATED ARTICLE 有权
公开(公告)号：US20210062028A1
公开(公告)日：2021-03-04
申请号：US16551942
申请日：2019-08-27
申请人： Eastman Kodak Company
发明人： David D. Putnam , Mark Edward Irving , Douglas Eugene Bugner , Todd Russell Griffin , Barbara Boland Lussier , Allan Francis Sowinski
IPC分类号： C09D11/54 , C09J7/32 , C09J7/30 , C09J7/21 , C09J7/29 , C09J7/22 , C09D11/322 , C09J5/00 , C09D11/03 , C09D11/107 , B41J3/407 , B41M5/00
摘要： A flexible inkjet-printed article is prepared by: A′) providing an ink receptive medium having a substrate and an aqueous-based ink-receptive layer. This layer has: (a) a water-soluble salt of a multivalent metal cation; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. At least one aqueous pigment-based ink is deposited directly on the aqueous-based ink-receptive layer, each having: a) an anionically-stabilized pigment colorant; and b) a water-miscible humectant at 1-20 weight %, each having a carbon to oxygen atom ratio of ≥1.0:1.0 and only two hydroxy groups. After drying, a functional layer with adhesive composition is formed on the inkjet-printed image and a flexible material is laminated to the functional layer, to form a flexible inkjet printed article.

4. 发明授权

US10926565B1 Article prepared by inkjet printing 有权
公开(公告)号：US10926565B1
公开(公告)日：2021-02-23
申请号：US16551908
申请日：2019-08-27
申请人： Eastman Kodak Company
发明人： Mark Edward Irving , David D. Putnam , Allan Francis Sowinski , Barbara Boland Lussier , Todd Russell Griffin , Douglas Eugene Bugner
IPC分类号： B41M5/50 , B41M5/52
摘要： An inkjet-printed article has an ink receptive medium with a substrate and an aqueous-based ink-receptive layer disposed thereon. The aqueous-based ink-receptive layer includes: (a) a water-soluble salt of a multivalent metal cation at 0.6-49 weight %; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent or (d) silica particles. The article also has an inkjet-printed image disposed on the aqueous-based ink-receptive layer, provided from one or more aqueous pigment-based inks, each of which has a) an anionically-stabilized pigment colorant; b) one or more water-miscible humectants at a total amount of 1-20 weight %, each of which has a carbon atom to oxygen atom ratio of at least 1.0:1.0 and only two hydroxy groups.

5. 发明申请

US20150125787A1 ELECTROLESS PLATING METHOD USING BLEACHING 有权
标题翻译：使用漂白的电镀方法
公开(公告)号：US20150125787A1
公开(公告)日：2015-05-07
申请号：US14071951
申请日：2013-11-05
申请人： EASTMAN KODAK COMPANY
发明人： Mark Edward Irving , Thomas B. Brust
IPC分类号： G03F7/16
CPC分类号： G03F7/16 , C23C18/1603 , C23C18/1608 , C23C18/1612 , C23C18/166 , C23C18/204 , C23C18/2086 , G03F7/038 , G03F7/0392 , G03F7/265 , G03F7/405
摘要： A conductive pattern can be formed a reactive polymer comprising pendant tertiary alkyl ester groups, (b) a compound that provides an acid upon exposure to radiation, (c) a crosslinking agent that is capable of reacting in the presence of the acid, and (d) optionally, a photosensitizer. The polymeric layer is patternwise exposed to provide non-exposed regions and exposed regions comprising a polymer comprising carboxylic acid groups. Both the non-exposed regions and the exposed regions of the polymeric layer are contacted with a reducing agent, bleached to remove surface amounts of the reducing agent in both non-exposed and exposed regions of the polymeric layer, and contacted with electroless seed metal ions to oxidize the reducing agent and to form corresponding electroless seed metal nuclei in the exposed regions. The corresponding electroless seed metal nuclei are then electrolessly plated with a conductive metal.
摘要翻译：可以形成导电图案，该反应性聚合物包括叔烷基酯基团，（b）暴露于辐射时提供酸的化合物，（c）能够在酸存在下反应的交联剂和（ d）任选的光敏剂。聚合物层被图案化地暴露以提供非暴露区域和包含包含羧酸基团的聚合物的暴露区域。未曝光区域和聚合物层的暴露区域与还原剂接触，漂白以除去聚合物层的未曝光和暴露区域中的表面量的还原剂，并与无电晶种金属离子以在曝光区域中氧化还原剂并形成相应的无电子种子金属核。然后将相应的无电子种子金属核用导电金属无电镀。

6. 发明授权

US10730331B2 Method for providing inkjet receiving media 有权
公开(公告)号：US10730331B2
公开(公告)日：2020-08-04
申请号：US16106040
申请日：2018-08-21
申请人： Eastman Kodak Company
发明人： Thomas Joseph Dannhauser , Mark Edward Irving
IPC分类号： B41J2/01 , B41M5/00 , B41M5/52 , C09D11/38
摘要： Inkjet receiving medium are prepared by disposing an aqueous composition onto at least one surface of a substrate to provide a topcoat layer. The aqueous composition has: (a) one or more water-soluble salts of a multivalent metal cation; and (b) composite particles having a Rockwell Hardness of less than or equal to R90 and each of the composite particles comprising domains of a (i) first organic polymer and domains of a (ii) second organic polymer. The domains of the (ii) second organic polymer are dispersed within the domains of the (i) first organic polymer. The melting point of the (i) first organic polymer is lower than the melting point of the (ii) second organic polymer. The weight ratio of the (i) first organic polymer to the (ii) second organic polymer is chosen such that the (b) composite particles have a density of 1.0-1.5 g/ml.

7. 发明公开

US20240101841A1 FLUORESCENT INK AND INK SETS CONTAINING SAME 审中-公开
公开(公告)号：US20240101841A1
公开(公告)日：2024-03-28
申请号：US17944354
申请日：2022-09-14
申请人： Eastman Kodak Company
发明人： Barbara Boland Lussier , Douglas Eugene Bugner , Mark Edward Irving
IPC分类号： C09D11/108 , C09D11/102
CPC分类号： C09D11/108 , C09D11/102
摘要： An aqueous colored pigment-based ink that is capable of fluorescence, has a pigment colorant in an amount of 1-7 weight %; a non-polymeric fluorophore that when excited by fluorescence-exciting radiation having a peak of at least 200 nm and up to and including 400 nm, exhibits an emission peak of at least 400 nm and up to and including 750 nm, and which non-polymeric fluorophore is present in an amount of 0.1-2 weight %; and an aqueous medium comprising water. This aqueous colored pigment-based ink can be included in an ink set that also includes one or more aqueous colored pigment-based inks that are non-fluorescent. All of these inks can be inkjet printed on non-UV fluorescent substrates to provide images that can be detected when excited as noted above, which images can be provided on documents, lottery tickets, and other security papers.

8. 发明申请

US20220379646A1 INKJET PRINTED ARTICLES AND METHOD OF MAKING 有权
公开(公告)号：US20220379646A1
公开(公告)日：2022-12-01
申请号：US17324394
申请日：2021-05-19
申请人： Eastman Kodak Company
发明人： Mark Edward Irving , Douglas Eugene Bugner , David D. Putnam
IPC分类号： B41M5/50 , C09D11/38 , C09D11/322 , C09D11/106 , C09D139/02 , C09D139/06 , C09D129/04 , B41M5/00
摘要： An aqueous composition can be used for pre-treating a substrate prior to inkjet printing to provide a white opaque background for inkjet-printed images. This aqueous composition includes: (a) one or more water-soluble salts of a multivalent metal cation at 5-30 weight %; (b) a nonionic or cationic water-soluble or water-dispersible polymeric binder material at 5-30 weight %; and (c) surface-treated visible light-scattering particles having a D50 (median) particle size of at least 0.04 μm and up to and including 2 μm in an amount of 5-60 weight % based on the total aqueous composition weight. The pre-treated substrate is useful as an inkjet receiving medium that can be readily inkjet-printed particularly with anionically-stabilized aqueous pigment-based inks.

9. 发明授权

US11155076B2 Method for inkjet printing 有权
公开(公告)号：US11155076B2
公开(公告)日：2021-10-26
申请号：US16551890
申请日：2019-08-27
申请人： Eastman Kodak Company
发明人： Barbara Boland Lussier , Allan Francis Sowinski , Mark Edward Irving , David D. Putnam , Todd Russell Griffin , Douglas Eugene Bugner
IPC分类号： C09D11/322 , B41J2/005 , B41J2/21 , B41J2/01
摘要： Inkjet printing is carried out to provide monochrome or polychrome inkjet-printed images. An ink-receptive medium is provided with a substrate with an aqueous-based ink-receptive layer disposed thereon. The aqueous-based ink-receptive layer has: (a) one or more water-soluble salts of a multivalent metal cation in an amount of 0.6-49 weight %; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer of a vinyl alcohol and vinyl amine) in a total amount of 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. One or more aqueous pigment-based inks are inkjet printed onto this aqueous-based ink-receptive layer, each ink comprising: a) one or more anionically-stabilized pigment colorants; b) one or more water-miscible humectants that are present in a total amount of 1-20 weight % and each having a carbon atom to oxygen atom ratio of at least 1.0:1.0 and only two hydroxy groups.

10. 发明授权

US10894437B1 Laminated article 有权
公开(公告)号：US10894437B1
公开(公告)日：2021-01-19
申请号：US16551924
申请日：2019-08-27
申请人： Eastman Kodak Company
发明人： David D. Putnam , Mark Edward Irving , Douglas Eugene Bugner , Allan Francis Sowinski , Todd Russell Griffin , Barbara Boland Lussier
IPC分类号： B41M5/50 , B41M5/52
摘要： A flexible inkjet printed article includes an ink receptive medium comprising a substrate and an aqueous-based ink-receptive layer. The aqueous-based ink-receptive layer has: (a) a water-soluble salt of a multivalent metal cation; (b) one or more of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent or (d) silica particles. An inkjet-printed image is disposed on the ink-receptive layer, provided from one or more aqueous pigment-based inks, each having: a) one or more anionically-stabilized pigment colorants; b) one or more water-miscible humectants at 1-20 weight %, each of which has a carbon atom to oxygen atom ratio of at least 1.0:1.0 and only two hydroxy groups. A functional layer comprising an adhesive composition disposed on the inkjet-printed image; and a flexible polymeric film or paper adhered to the functional layer.

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