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    • 5. 发明申请
    • SILVER CARBOXYLATE NANOPARTICLE COMPOSITIONS WITH PHOSPHORIC ACID ESTER SURFACE MODIFIERS
    • 带有磷酸酯表面改性剂的银羧酸纳米复合物组合物
    • WO0159519A3
    • 2002-03-14
    • PCT/US0103896
    • 2001-02-07
    • EASTMAN KODAK CO
    • LELENTAL MARKDICKINSON DAVID AWAKLEY JAMES LOREM MICHAEL WGHYZEL PETER J
    • B41M5/323G03C1/498
    • G03C1/498G03C1/49809G03C1/4989
    • There is disclosed an oxidation-reduction imaging forming composition comprising an aqueous based dispersion of (i) nanoparticulate silver carboxylate particles having on the surface of the particles a surface modifier which is a phosphoric acid ester and (ii) an organic reducing agent. In particular, the surface modifiers can be mixtures of mono- and di-esters of orthophosphoric acid and hydroxyl-terminated, oxyethylated long-chain alcohols or oxyethylated alkyl phenols or derivatives thereof. Also disclosed are various compositions including the dispersions including oxidation-reduction imaging forming compositions, thermographic elements and photothermographic compositions and elements. The preferred carboxylate is a silver salt of a long chain fatty acid such as silver behenate. A media milling method and a controlled precipitation method of making the dispersions are also disclosed.
    • 公开了一种氧化还原成像组合物,其包含(i)纳米颗粒状羧酸银颗粒的水性分散体,所述颗粒在颗粒表面上具有作为磷酸酯的表面改性剂和(ii)有机还原剂。 特别地,表面改性剂可以是正磷酸和羟基封端的羟乙基化长链醇或羟乙基化烷基酚或其衍生物的单酯和二酯的混合物。 还公开了包括包括氧化还原成像组合物,热成像元件和光热成像组合物和元素的分散体的各种组合物。 优选的羧酸酯是长链脂肪酸的银盐,例如山嵛酸银。 还公开了制备分散体的介质研磨方法和受控沉淀法。