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1. 发明申请

WO2014042865A1 METHOD FOR CONTROLLING AND OPTIMIZING THE MANUFACTURE OF GASOLINE BLENDSTOCKS FOR BLENDING WITH AN ALCOHOL AS AN OXYGENATE 审中-公开
标题翻译：控制和优化汽油混合物的制造方法，用于与作为氧化剂的酒精混合
公开(公告)号：WO2014042865A1
公开(公告)日：2014-03-20
申请号：PCT/US2013/056760
申请日：2013-08-27
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： KELLY, Francis, X.
IPC分类号： C10L1/02 , C10L1/182 , C10L10/10
CPC分类号： C10L10/10 , C10L1/023 , C10L2290/24 , C10L2290/562 , C10L2290/58
摘要： A method for manufacturing an oxygenated gasoline-blend by blending a hydrocarbon Basestock for Oxygenate Blending (BOB) with an alcohol such as ethanol to a required octane specification first blends the BOB to an octane number, (RON+MON)/2 based on the octane sensitivity (RON-MON) of the BOB and the proportion of alcohol to be added to the BOB, such that when the BOB is blended with the specification proportion of alcohol to form the oxygenated gasoline blend, this blend will have the required octane specification. The blending of the BOB with the alcohol will typically be done at a location remote from that where the BOB is blended, e.g. at the product distribution terminal after being transported from the refinery by pipeline or tank car.
摘要翻译：通过将含氧混合物（BOB）的碳氢化合物基料与乙醇（例如乙醇）混合至所需的辛烷法制备氧化汽油混合物的方法首先将BOB与辛烷值（RON + MON）/ 2基于 BOB的辛烷值灵敏度（RON-MON）和加入到BOB中的醇的比例，使得当BOB与醇的规格比例混合以形成含氧汽油共混物时，该共混物将具有所需的辛烷值。 BOB与醇的混合通常在远离BOB混合的位置进行，例如，在通过管道或油罐车从炼油厂运输后的产品分销终端。

2. 发明申请

WO2012151374A1 QUALITY CERTIFICATION OF OXYGENATED GASOLINE 审中-公开
标题翻译：氧化汽油的质量认证
公开(公告)号：WO2012151374A1
公开(公告)日：2012-11-08
申请号：PCT/US2012/036277
申请日：2012-05-03
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , KELLY, Francis, X. , LAU, Tian, Chong
发明人： KELLY, Francis, X. , LAU, Tian, Chong
IPC分类号： C10L1/02 , G01N33/28 , G05D21/00
CPC分类号： C10L1/023 , G01N33/22 , G01N33/2829 , G05D21/02
摘要： A method for controlling the manufacture and certification of an oxygenated gasoline product is carried out by manufacturing a gasoline Basestock for Oxygenate Blending (BOB) at a refinery site in accordance with an empirical relationship, valid for at that site under typical manufacturing conditions, between (i) a property value of the BOB stream such as octane as determined by an on-site online process analyzer and (ii) the corresponding instantaneous value or FPAPV property value as determined by the test method mandated by the product specification for the final gasoline stream when blended with the required proportion of oxygenate. The quality of fit of this empirical relationship is calculated according to the standard deviation of the residuals of the relationship and a confidence level is fixed so that the final oxygenated gasoline formulated with the BOB will meet the required property specification when measured by the test method mandated by the specification. The final oxygenated gasoline blend is certified as having a property value conforming to the required specification based on the predicted property value for the finished gasoline.
摘要翻译：用于控制含氧汽油产品的制造和认证的方法通过根据经验关系在炼油厂位置制造用于氧化剂混合的汽油Bases（BOB）来进行，该经验关系在典型制造条件下在（ i）由现场在线过程分析仪确定的BOB流的属性值（例如辛烷值），以及（ii）由最终汽油流的产品规格要求的测试方法确定的相应瞬时值或FPAPV属性值当与所需比例的含氧化合物混合时。这种经验关系的拟合质量根据关系残差的标准偏差来计算，置信水平是固定的，使得用BOB配制的最终含氧汽油将满足所要求的性能规格，按规格。最终的含氧汽油混合物被认证为具有符合所需规格的性能值，基于成品汽油的预测性能值。

3. 发明申请

WO2018093472A1 SYSTEMS AND METHODS FOR GENERATING A PETROLEUM MODEL OF COMPOSITION USING TWO-DIMENSIONAL GAS CHROMATOGRAPHY 审中-公开
公开(公告)号：WO2018093472A1
公开(公告)日：2018-05-24
申请号：PCT/US2017/054855
申请日：2017-10-03
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： WANG, Frank, Cheng-yu , PAEK, Changyub , QIAN, Kuangnan , KELLY, Francis, X.
IPC分类号： G01N30/88 , G01N30/86 , G01N30/46 , G01N30/78 , G01N33/28
摘要： Methods to generate a model of composition for a petroleum sample can include providing a petroleum sample to a two-dimensional gas chromatograph coupled with at least one detector. The chromatograph can have first and second columns. The chromatograph can be adapted to output data for each detector representing first and second dimension retention times corresponding to the first and second columns, respectively. The data representing the first and second dimension retention times for each detector based on the petroleum sample can be obtained from the chromatograph. Molecular components of the petroleum sample can be identified based at least in part on the first and second dimension retention times for each detector. The identified molecular components of the petroleum sample can be quantified based at least in part on integrated peaks of the first and second dimension retention times for each detector to generate a model of composition of the petroleum sample.

4. 发明公开

EP2895581A1 METHOD FOR CONTROLLING AND OPTIMIZING THE MANUFACTURE OF GASOLINE BLENDSTOCKS FOR BLENDING WITH AN ALCOHOL AS AN OXYGENATE 审中-公开
标题翻译：方法用于控制和汽油混合物的生产优化与酒精混合成一个氧合
公开(公告)号：EP2895581A1
公开(公告)日：2015-07-22
申请号：EP13762635.4
申请日：2013-08-27
申请人： ExxonMobil Research and Engineering Company
发明人： KELLY, Francis, X.
IPC分类号： C10L1/02 , C10L1/182 , C10L10/10
CPC分类号： C10L10/10 , C10L1/023 , C10L2290/24 , C10L2290/562 , C10L2290/58
摘要： A method for manufacturing an oxygenated gasoline-blend by blending a hydrocarbon Basestock for Oxygenate Blending (BOB) with an alcohol such as ethanol to a required octane specification first blends the BOB to an octane number, (RON+MON)/2 based on the octane sensitivity (RON-MON) of the BOB and the proportion of alcohol to be added to the BOB, such that when the BOB is blended with the specification proportion of alcohol to form the oxygenated gasoline blend, this blend will have the required octane specification. The blending of the BOB with the alcohol will typically be done at a location remote from that where the BOB is blended, e.g. at the product distribution terminal after being transported from the refinery by pipeline or tank car.

5. 发明公开

EP2705123A1 QUALITY CERTIFICATION OF OXYGENATED GASOLINE 审中-公开
标题翻译：含氧汽油质量认证
公开(公告)号：EP2705123A1
公开(公告)日：2014-03-12
申请号：EP12721100.1
申请日：2012-05-03
申请人： ExxonMobil Research and Engineering Company
发明人： KELLY, Francis, X. , LAU, Tian, Chong
IPC分类号： C10L1/02 , G01N33/28 , G05D21/00
CPC分类号： C10L1/023 , G01N33/22 , G01N33/2829 , G05D21/02
摘要： A method for controlling the manufacture and certification of an oxygenated gasoline product is carried out by manufacturing a gasoline Basestock for Oxygenate Blending (BOB) at a refinery site in accordance with an empirical relationship, valid for at that site under typical manufacturing conditions, between (i) a property value of the BOB stream such as octane as determined by an on-site online process analyzer and (ii) the corresponding instantaneous value or FPAPV property value as determined by the test method mandated by the product specification for the final gasoline stream when blended with the required proportion of oxygenate. The quality of fit of this empirical relationship is calculated according to the standard deviation of the residuals of the relationship and a confidence level is fixed so that the final oxygenated gasoline formulated with the BOB will meet the required property specification when measured by the test method mandated by the specification. The final oxygenated gasoline blend is certified as having a property value conforming to the required specification based on the predicted property value for the finished gasoline.

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