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1. 发明申请

WO2012006054A1 INTEGRATED HYDROCRACKING AND DEWAXING OF HYDROCARBONS 审中-公开
标题翻译：烃的综合加氢和脱水
公开(公告)号：WO2012006054A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/042106
申请日：2011-06-28
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , PRENTICE, Krista, M. , DAAGE, Michel, A. , DANDEKAR, Ajit, B. , OLIVERI, Christopher, G. , VIJAY, Rohit , MCCARTHY, Stephen, J. , LAI, Frank, Wenyih , FINGLAND, Bradley, R.
发明人： PRENTICE, Krista, M. , DAAGE, Michel, A. , DANDEKAR, Ajit, B. , OLIVERI, Christopher, G. , VIJAY, Rohit , MCCARTHY, Stephen, J. , LAI, Frank, Wenyih , FINGLAND, Bradley, R.
IPC分类号： C10G45/00
CPC分类号： C10G67/02 , B01J29/7461 , B01J35/026 , B01J2229/36 , B01J2229/42 , C10G45/64 , C10G65/043 , C10G65/12 , C10G2300/202 , C10G2300/302 , C10G2300/4018 , C10G2300/4081 , C10G2400/02 , C10G2400/04 , C10G2400/10 , C10L1/08 , C10L2200/0446 , C10L2270/026 , C10L2290/543 , C10M101/02
摘要： An integrated process for producing naphtha fuel, diesel fuel and/or lubricant base oils from feedstocks under sour conditions is provided. The integrated process includes an initial dewaxing of a feed under sour conditions, optional hydrocracking of the dewaxed feed, and a separation to form a first diesel product and a bottoms fraction. The bottoms fraction is then exposed to additional hydrocracking and dewaxing to form a second diesel product and optionally a lubricant base oil product. Alternatively, a feedstock can be hydrotreated, fractionated, dewaxed, and then hydrocracked to form a diesel fuel and a dewaxed, hydrocracked bottoms fraction that is optionally suitable for use as a lubricant base oil.
摘要翻译：提供了一种在酸性条件下从原料生产石脑油燃料，柴油和/或润滑油基础油的综合方法。一体化方法包括在酸性条件下进料的初始脱蜡，脱蜡进料的任选加氢裂化和分离以形成第一柴油产物和塔底馏分。然后将底部馏分暴露于额外的加氢裂化和脱蜡以形成第二柴油产品和任选的润滑剂基础油产品。或者，可以将原料加氢处理，分馏，脱蜡，然后进行加氢裂化，以形成任选适合用作润滑剂基础油的柴油燃料和脱蜡加氢裂化塔底馏分。

2. 发明申请

WO2017172576A1 LUBRICANT BASESTOCK PRODUCTION WITH ENHANCED AROMATIC SATURATION 审中-公开
标题翻译：增强芳香族饱和度润滑剂基础油生产
公开(公告)号：WO2017172576A1
公开(公告)日：2017-10-05
申请号：PCT/US2017/024242
申请日：2017-03-27
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： DANDEKAR, Ajit, B. , FINGLAND, Bradley, R. , FRUCHEY, Kendall, S. , WEIGEL, Scott, J.
IPC分类号： C10G47/18 , C10G65/12
摘要： Systems and methods are provided for producing lubricant basestocks having a reduced or minimized aromatics content. A first processing stage can perform an initial amount of hydrotreating and/or hydrocracking. A first separation stage can then be used to remove fuels boiling range (and lower boiling range) compounds. The remaining lubricant boiling range fraction can then be exposed under hydrocracking conditions to a USY catalyst including a supported noble metal, such as Pt and/or Pd. The USY catalyst can have a desirable combination of catalyst properties, such as a unit cell size of 24.30 or less (or 24.24 or less), a silica to alumina ratio of at least 50 (or at least 80), and an alpha value of 20 or less (or 10 or less). In some aspects, the effluent from the second (hydrocracking) stage can be dewaxed without further separation. In such aspects, a portion of the dewaxed effluent can be used as a recycle quench stream to cool the hydrocracking effluent prior to entering the dewaxing reactor.
摘要翻译：提供了用于生产具有降低或最小化的芳族化合物含量的润滑剂基础油料的系统和方法。第一处理阶段可以执行初始量的加氢处理和/或加氢裂化。然后可以使用第一分离阶段来除去燃料沸程（和较低沸程）的化合物。然后可以将剩余的润滑剂沸程馏分在加氢裂化条件下暴露于包含负载型贵金属（例如Pt和/或Pd）的USY催化剂。 USY催化剂可以具有催化剂性质的理想组合，例如24.30或更小（或24.24或更小）的单位晶胞尺寸，至少50（或至少80）的二氧化硅与氧化铝之比，以及α值 20或更少（或10或更少）。在一些方面，来自第二（加氢裂化）阶段的流出物可以脱蜡而无需进一步分离。在这些方面中，一部分脱蜡的流出物可以用作循环骤冷物流，以在进入脱蜡反应器之前冷却加氢裂化流出物。

3. 发明申请

WO2014175952A1 HIGH VISCOSITY HIGH QUALITY GROUP II LUBE BASE STOCKS 审中-公开
标题翻译：高粘度高品质组II LUBE基座
公开(公告)号：WO2014175952A1
公开(公告)日：2014-10-30
申请号：PCT/US2014/017918
申请日：2014-02-24
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： HOLTZER, Gretchen, L. , DANDEKAR, Ajit, B. , BAKER, Charles, Lambert, Jr. , FINGLAND, Bradley, R. , HAGEE, Bryan, E. , YUNG, Cathleen , WANG, Frank, Cheng-Yu , SANCHEZ, Eugenio , PATHARE, Rugved, Prakash
IPC分类号： C10M101/02 , C10G67/02
CPC分类号： C10M101/02 , C10G45/64 , C10G65/043 , C10G65/12 , C10G2300/302 , C10G2400/04 , C10G2400/10 , C10M2203/1025 , C10N2220/02 , C10N2220/021 , C10N2230/02 , C10N2230/74 , C10N2240/14
摘要： Provided are high viscosity high quality Group II lube base stocks with improved properties produced by an integrated hydrocracking and dewaxing process. In one form, the Group II lube base stock includes greater than or equal to 90 wt.% saturates, and less than 10 wt.% aromatics, and has an aromatic performance ratio between 1.0 and 5.0. Also provided are lubricant formulations including the high viscosity high quality Group II lube base stock.
摘要翻译：提供了通过一体化加氢裂化和脱蜡过程产生的具有改进性能的高粘度高品质II组润滑油基础油料。在一种形式中，II组润滑油基料包含大于或等于90重量％的饱和物和小于10重量％的芳族化合物，并且具有1.0至5.0的芳族性能比。还提供润滑剂配方，包括高粘度高质量的II组润滑油基础油。

4. 发明申请

WO2014025598A1 CO-PRODUCTION OF HEAVY AND LIGHT BASE OILS 审中-公开
标题翻译：重油和轻油基油的生产
公开(公告)号：WO2014025598A1
公开(公告)日：2014-02-13
申请号：PCT/US2013/053123
申请日：2013-08-01
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： DAAGE, Michel , CALLA, Jason, T. , DANDEKAR, Ajit, B. , PRENTICE, Krista, M.
IPC分类号： C10G53/00 , C10G53/06 , C10G65/04 , C10G65/12 , C10G67/00
CPC分类号： C10G65/12 , C10G21/003 , C10G47/00 , C10G53/06 , C10G67/16 , C10G2400/04 , C10G2400/10 , C10M101/02 , C10M177/00
摘要： A suitable feedstock for forming lubricant base oils is separated into at least a lower boiling portion and a higher boiling portion. The lower boiling portion is combined with a feed suitable for use as a fuels hydrocracking feed. The combined feed is hvdrocracked and catalylicallv devvaxed in order to form fuels and Group II, Group ]]+, or Group I II light neutral basestocks. The higher boilmg portion of the feedstock is solvent processed in order to form Group I heavy neutral base oils and/or Group I brightstock base oils. The higher boiling portion of the feedstock can correspond to both a bottoms fraction and one or more additional fractions boiling above a fractionation cut point.
摘要翻译：用于形成润滑剂基础油的合适原料被分离成至少较低沸点部分和较高沸点部分。低沸点部分与适合用作燃料加氢裂化原料的进料组合。组合的饲料被氢化和催化灭活以形成燃料和组II，组]] +或组I II轻质中性基础油。原料的较高沸点部分进行溶剂处理，以形成I组重质中性基础油和/或I类亮片基础油。原料的较高沸点部分可对应于塔底馏分和高于分馏馏分沸点的一个或多个另外的馏分。

5. 发明申请

WO2020036727A1 OLIGOMERIZATION OF OLEFINS DERIVED FROM OXYGENATES 审中-公开
公开(公告)号：WO2020036727A1
公开(公告)日：2020-02-20
申请号：PCT/US2019/043863
申请日：2019-07-29
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： DEIMUND, Mark, A. , O'NEILL, Brandon, J. , DANDEKAR, Ajit, B.
IPC分类号： C07C2/24 , B01J23/755 , C10G3/00 , C10G50/00
摘要： Systems and methods are provided for conversion of oxygenate feeds to lubricant and/or distillate boiling range compounds with desirable properties by first selectively converting oxygenates to light olefins and then converting the light olefins to distillate and lubricant boiling range compounds with beneficial properties. The distillate boiling range products can have an unexpectedly high cetane, while the lubricant boiling range products can have an unexpectedly high viscosity index. The ability to form the distillate boiling range products and lubricant boiling range products is facilitated by using a Ni-enhanced oligomerization catalyst.

6. 发明申请

WO2018136242A1 CONVERSION OF OXYGENATES TO HYDROCARBONS WITH VARIABLE CATALYST COMPOSITION 审中-公开
公开(公告)号：WO2018136242A1
公开(公告)日：2018-07-26
申请号：PCT/US2018/012502
申请日：2018-01-05
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： O'NEILL, Brandon, J. , MCCARTHY, Stephen, J. , DEIMUND, Mark, A. , DANDEKAR, Ajit, B.
IPC分类号： C10G3/00 , C07C1/20 , C07C31/04 , B01J27/14 , B01J29/06 , B01J35/10
摘要： Systems and methods are provided for modifying the composition of the conversion catalyst in a reactor for oxygenate conversion during conversion of an oxygenate feed to allow for adjustment of the slate of conversion products. The modification of the conversion catalyst can be performed by introducing a substantial portion (relative to the amount of catalyst inventory in the reaction system) of make-up catalyst having a distinct composition relative to the conversion catalyst in the reaction system. Introducing the distinct composition of make-up catalyst can modify the composition of the conversion catalyst in the reactor to allow for changes in the resulting product slate. By introducing the distinct catalyst composition, the conversion catalyst in the reactor can correspond to a different composition of catalyst than the overall average catalyst composition within the catalyst inventory in the reaction system.

7. 发明申请

WO2018071169A1 LUBRICANT BASESTOCK PRODUCTION WITH ENHANCED AROMATIC SATURATION 审中-公开
标题翻译：增强芳香族饱和度润滑剂基础油生产
公开(公告)号：WO2018071169A1
公开(公告)日：2018-04-19
申请号：PCT/US2017/053401
申请日：2017-09-26
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： CALLA, Jason, T. , DANDEKAR, Ajit, B. , WEIGEL, Scott, J. , LACY, Darryl, D. , LAI, Wenyih, F. , YOHE, Sara, L.
IPC分类号： C10G65/08 , B01J29/03 , B01J29/04 , C10G65/12
摘要： Systems and methods are provided for producing lubricant basestocks using a process flow that includes a conversion catalyst that can provide a desired improvement in viscosity index at a reduced or minimized amount of feed conversion. An initial processing stage can be used to produce a lubricant boiling range fraction with a reduced or minimized heteroatom content. After a separation, at least a portion of the lubricant boiling range portion can be exposed to a conversion catalyst that has an effective pore size of at least 8.0 Angstroms, a total surface area of at least 200 m 2 /g, and/or an Alpha value of 20 or less, where the conversion catalyst includes a supported Group 8 - 10 noble metal. The methods can allow for increased yields of high viscosity index lubricant boiling range products from a process flow for lubricant base stock and/or blend stock production.
摘要翻译：提供了使用包括转化催化剂的工艺流程生产润滑剂基础油料的系统和方法，该转化催化剂可以在降低或最小化的原料转化量下提供期望的粘度指数改进。初始加工阶段可用于产生具有降低或最小化的杂原子含量的润滑剂沸程馏分。分离后，至少一部分润滑剂沸程部分可以暴露于转化催化剂，该转化催化剂的有效孔径至少为8.0埃，总表面积至少为200m 2 / / g和/或α值为20或更小，其中转化催化剂包含负载的第8-10族贵金属。该方法可以允许从用于润滑剂基料和/或共混料生产的工艺流程中提高高粘度指数润滑剂沸程产品的收率。

8. 发明申请

WO2017117176A1 INTEGRATED RESID DEASPHALTING AND GASIFICATION 审中-公开
标题翻译：集成化学脱硫和气化
公开(公告)号：WO2017117176A1
公开(公告)日：2017-07-06
申请号：PCT/US2016/068801
申请日：2016-12-28
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： FRUCHEY, Kendall, S. , GREEN, Sara, K. , KOVVALI, Anjaneya, S. , HILBERT, Timothy, L. , CARROLL, Michael, B. , DANDEKAR, Ajit, B. , YOHE, Sara, L. , BROWN, Stephen, H. , OWENS, Tracie, L. , ROSS, April, D. , SENZER, Eric, B. , PYL, Steven
IPC分类号： C10G55/02 , C10G67/04 , C10G65/04 , C10K1/00 , C10K3/04
CPC分类号： C10G67/049 , C01B3/48 , C01B2203/0283 , C01B2203/065 , C10G55/02 , C10G65/043 , C10G67/04 , C10G67/0418 , C10G67/0445 , C10G67/0454 , C10G67/0463 , C10G67/0481 , C10G2300/1077 , C10G2300/202 , C10G2300/206 , C10G2300/301 , C10G2300/304 , C10G2400/10 , C10J3/82 , C10J2300/0906 , C10J2300/0913 , C10J2300/1618 , C10K1/004 , C10K3/04 , C10M101/02 , C10M2203/1006 , C10M2203/1085 , C10N2220/022 , C10N2220/023 , C10N2230/02
摘要： Systems and methods are provided for integration of use deasphalted resid as a feed for fuels and/or lubricant base stock production with use of the corresponding deasphalter rock for gasification to generate hydrogen and/or fuel for the fuels and/or lubncant production process. The integration can include using hydrogen generated during gasification as a fuel to provide heat for solvent processing and/or using the hydrogen for hydroprocessing of deasphalted oil.
摘要翻译：提供了系统和方法，用于将使用脱沥青渣油作为燃料和/或润滑剂基础原料生产的进料的集成，其中使用相应的脱沥青石来气化以生成燃料的氢和/或燃料和/或润滑油生产过程。整合可以包括使用气化过程中产生的氢气作为燃料来为溶剂处理提供热量和/或使用氢气来加氢处理脱沥青油。

9. 发明申请

WO2017117166A1 BRIGHT STOCK PRODUCTION FROM LOW SEVERITY RESID DEASPHALTING 审中-公开
标题翻译：从低浓度DEASPHALTING生产明亮的股票
公开(公告)号：WO2017117166A1
公开(公告)日：2017-07-06
申请号：PCT/US2016/068786
申请日：2016-12-28
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： HILBERT, Timothy, L. , CARROLL, Michael, B. , DANDEKAR, Ajit, B. , YOHE, Sara, L. , BROWN, Stephen, H. , OWENS, Tracie, L. , ROSS, April, D. , SENZER, Eric, B. , PYL, Steven , PATHARE, Rugved, P. , YEH, Lisa, I-Ching , FINGLAND, Bradley, R. , ALDOUS, Keith, K. , KOVVALI, Anjaneya, S. , FRUCHEY, Kendall, S. , GREEN, Sara, K. , HENDERSON, Camden, N.
IPC分类号： C10G67/04
CPC分类号： C10G67/049 , C01B3/48 , C01B2203/0283 , C01B2203/065 , C10G55/02 , C10G65/043 , C10G67/04 , C10G67/0418 , C10G67/0445 , C10G67/0454 , C10G67/0463 , C10G67/0481 , C10G2300/1077 , C10G2300/202 , C10G2300/206 , C10G2300/301 , C10G2300/304 , C10G2400/10 , C10J3/82 , C10J2300/0906 , C10J2300/0913 , C10J2300/1618 , C10K1/004 , C10K3/04 , C10M101/02 , C10M2203/1006 , C10M2203/1085 , C10N2220/022 , C10N2220/023 , C10N2230/02
摘要： Methods are provided for forming lubricant base stocks from feeds such as vacuum resid or other 510°C+ feeds. A feed can be deasphalted and then catalyticaliy and/or solvent processed to form lubricant base stocks, including bright stocks that are resistant to haze formation.
摘要翻译：提供了从诸如减压渣油或其他510℃+进料的原料形成润滑剂基础原料的方法。进料可脱沥青，然后催化处理和/或溶剂处理形成润滑剂基础油料，包括抗雾霾形成的明亮油料。

10. 发明申请

WO2016081216A1 HYDROPROCESSING FOR LUBRICANT BASES TOCK PRODUCTION 审中-公开
标题翻译：润滑油基础油生产的氢化方法
公开(公告)号：WO2016081216A1
公开(公告)日：2016-05-26
申请号：PCT/US2015/059813
申请日：2015-11-10
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
发明人： XU, Xiaochun , FINGLAND, Bradley, R. , WILSON, Keith , LEVIN, Doron , SOLED, Stuart, L. , MISEO, Sabato , BAUMGARTNER, Joseph, E. , DANDEKAR, Ajit, B.
IPC分类号： C10G65/08 , C10G65/04 , C10G45/50 , C10G45/08 , C10G21/16 , C10G21/27 , C10G47/06 , C10G65/12 , C10G67/04
CPC分类号： C10G45/50 , B01J23/882 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J37/20 , C10G35/06 , C10G45/08 , C10G47/06 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G67/04 , C10G69/02 , C10G69/08 , C10G2300/1048 , C10G2300/202 , C10G2300/301 , C10G2400/00 , C10M101/02
摘要： Methods are provided for hydroprocessing a feed (such as hydrotreating, hydrocracking, or hydrofining a feed) to generate a product with a reduced or minimized aromatics content relative to the severity of the hydroprocessing conditions. In some types of hydroprocessing applications, it can be desirable to select the severity of hydroprocessing conditions to achieve a desired level of removal for sulfur, a desired level for removal of nitrogen, and/or a desired level for increasing the viscosity index of a feed. The severity for heteroatom removal and/or viscosity index uplift can also correspond to an amount of conversion of a feed to lower boiling point products, so the lowest severity conditions suitable for achieving a product quality can be desirable. By improving the aromatics saturation during hydroprocessing, the severity of subsequent aromatics saturation processes can be reduced.
摘要翻译：提供用于加氢处理饲料（例如加氢处理，加氢裂化或加氢精制饲料）以产生相对于加氢处理条件的严重性降低或最小化芳烃含量的产物。在一些类型的加氢处理应用中，可以期望选择加氢处理条件的严重性以达到期望的硫去除水平，除去氮的所需水平和/或用于提高进料粘度指数的期望水平。杂原子除去和/或粘度指数提升的严重程度也可以对应于进料到低沸点产物的转化量，因此适合于获得产品质量的最低苛刻度条件是可取的。通过改善加氢处理过程中的芳族化合物饱和度，可以降低随后的芳烃饱和过程的严重性。

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