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1. 发明申请

WO2011112189A1 ALKYLATED AROMATICS PRODUCTION 审中-公开
标题翻译：碱性芳香族生产
公开(公告)号：WO2011112189A1
公开(公告)日：2011-09-15
申请号：PCT/US2010/026844
申请日：2010-03-10
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , STONE & WEBSTER, INC. , VINCENT, Matthew, J. , NANDA, Vijay , BHANDARKAR, Maruti , MAERZ, Brain , HELTON, Terry, E.
发明人： VINCENT, Matthew, J. , NANDA, Vijay , BHANDARKAR, Maruti , MAERZ, Brain , HELTON, Terry, E.
IPC分类号： C07C2/66 , C07C15/00 , C07C7/00 , B01J29/70 , B01J29/08
CPC分类号： B01J29/60 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/50 , B01J29/65 , B01J29/7038 , B01J29/80 , C07C2/66 , C07C7/13 , C07C15/073 , C07C15/085 , C07C2529/08 , C07C2529/70 , Y02P20/52 , C07C15/04
摘要： Disclosed is a process for the production of alkylated aromatics by contacting a feed stream comprising an alkylatable aromatic, an alkylating agent and trace amounts of water and impurities in the presence of first and second alkylation catalysts wherein the water and impurities are removed in order to improve the cycle length of such alkylation catalysts. Water and a portion of impurities are removed in a dehydration zone. A first alkylation zone having a first alkylation catalyst which, in some embodiments is a large pore molecular sieve, acts to remove a larger portion of impurities, such as nitrogenous and other species, and to alkylate a smaller portion of the alkylatable aromatic compound. A second alkylation zone, which in some embodiments is a medium pore molecular sieve, acts to remove a smaller portion of impurities, and to alkylate a larger portion of the alkylatable aromatic compound.
摘要翻译：公开了通过在第一和第二烷基化催化剂存在下使包含可烷基化芳族化合物，烷基化剂和痕量水和杂质的进料流接触来生产烷基化芳族化合物的方法，其中除去水和杂质以改进这种烷基化催化剂的循环长度。在脱水区中除去水和一部分杂质。具有第一烷基化催化剂的第一烷基化区，在一些实施方案中为大孔分子筛，用于除去较大部分杂质如氮和其它物质，并将较小部分的可烷基化芳族化合物烷基化。在一些实施方案中，第二烷基化区是中孔分子筛，其作用是除去较小部分杂质，并使大部分可烷基化芳族化合物烷基化。

2. 发明申请

WO2010021795A1 A NOVEL MOLECULAR SIEVE COMPOSITION EMM-12, A METHOD OF MAKING AND A PROCESS OF USING THE SAME 审中-公开
标题翻译：新型分子筛组合物EMM-12，其制备方法及其使用方法
公开(公告)号：WO2010021795A1
公开(公告)日：2010-02-25
申请号：PCT/US2009/050729
申请日：2009-07-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ROTH, Wieslaw, J. , DORSET, Douglas, L. , KENNEDY, Gordon, J. , YORKE, Thomas , HELTON, Terry, E.
发明人： ROTH, Wieslaw, J. , DORSET, Douglas, L. , KENNEDY, Gordon, J. , YORKE, Thomas , HELTON, Terry, E.
IPC分类号： C01B39/46 , C01B39/48 , B01J29/06
CPC分类号： B01J29/70 , B01J29/7038 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C2/66 , C07C6/123 , C07C6/126 , C07C29/36 , C07C37/11 , C07C37/20 , C07C41/06 , C07C45/53 , C07C51/235 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/14 , C07C2523/02 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C15/107 , C07C33/20 , C07C39/06 , C07C39/16 , C07C43/04 , C07C49/10 , C07C57/30
摘要： This disclosure relates to an EMM- 12 molecular sieve having, in its as-synthesized form and in calcined form, an X-ray diffraction pattern including peaks having a d-spacing maximum in the range of 14.17 to 12.57 Angstroms, a d-spacing maximum in the range of 12.1 to 12.56 Angstroms, and non-discrete scattering between about 8.85 to 11.05 Angstroms or exhibit a valley in between the peaks having a d-spacing maximum in the range of 10.14 to 12.0 Angstroms and a d-spacing maximum in the range from 8.66 to 10.13 Angstroms with measured intensity corrected for background at the lowest point being not less than 50 % of the point at the same XRD d-spacing on the line connecting maxima in the range of 10.14 to 12.0 Angstroms and in the range from 8.66 to 10.13 Angstroms.
摘要翻译：本公开涉及具有其合成形式和煅烧形式的EMM-12分子筛，其X射线衍射图包括d-间距最大值在14.17至12.57埃范围内的峰，d-间距在12.1至12.56埃的范围内的最大值，以及在约8.85至11.05埃之间的非离散散射，或在具有10.14至12.0埃范围内的d间距最大值的峰之间呈现出谷值，在最低点处校正背景的测量强度的8.66至10.13埃的范围不小于连接最大值在10.14至12.0埃范围内的线上的相同XRD d间距处的点的50％从8.66到10.13埃。

3. 发明申请

WO2008070297A2 PROCESS FOR DECREASING BROMINE-REACTIVE CONTAMINANTS IN HYDROCARBON FEEDS 审中-公开
标题翻译：降低碳氢化合物反应性污染物的方法
公开(公告)号：WO2008070297A2
公开(公告)日：2008-06-12
申请号：PCT/US2007/081665
申请日：2007-10-17
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , BROWN, Stephen, H. , SANTIESTEBAN, Jose, G. , SUNBERG, Bryson, J. , HELTON, Terry, E. , LISSY, Daria, N. , BEECKMAN, Jean, W. , WERNER, Arthur, P.
发明人： BROWN, Stephen, H. , SANTIESTEBAN, Jose, G. , SUNBERG, Bryson, J. , HELTON, Terry, E. , LISSY, Daria, N. , BEECKMAN, Jean, W. , WERNER, Arthur, P.
IPC分类号： C10G29/02 , B01J35/02
CPC分类号： C10G29/02 , B01J29/7007 , B01J29/7038 , B01J35/023 , B01J35/026 , C10G2300/1096 , C10G2300/4018
摘要： A process for reducing the Bromine Index of a hydrocarbon feed containing bromine -reactive contaminants that has improved cycle length and utilizes a crystalline molecular sieve catalyst. The process is carried out by contacting the hydrocarbon feed under conversion conditions with a catalyst shaped in the form of an elongated aggregate comprising a crystalline molecular sieve having a MWW or *BEA framework type. The shortest cross-sectional dimension of the elongated aggregate is less about 1/10 inch (2.54 millimeters).
摘要翻译：一种降低含溴反应性污染物的烃进料的溴指数的方法，其具有改善的循环长度并且使用结晶分子筛催化剂。该方法通过在转化条件下使烃进料与包含具有MWW或* BEA骨架类型的结晶分子筛的细长骨料形式的催化剂接触来进行。细长骨料的最短横截面尺寸较小约为1/10英寸（2.54毫米）。

4. 发明申请

WO2012050751A1 ACTIVATION AND USE OF HYDROALKYLATION CATALYSTS 审中-公开
标题翻译：氢化催化剂的活化和应用
公开(公告)号：WO2012050751A1
公开(公告)日：2012-04-19
申请号：PCT/US2011/052241
申请日：2011-09-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , XU, Teng , LEMON, Edward, A. , HELTON, Terry, E. , CHEN, Tan-Jen , SMITH, Charles, M.
发明人： XU, Teng , LEMON, Edward, A. , HELTON, Terry, E. , CHEN, Tan-Jen , SMITH, Charles, M.
IPC分类号： B01J29/74 , B01J29/70 , B01J29/76 , B01J37/18 , C07C2/74 , C07C13/18
CPC分类号： B01J29/7476 , B01J29/061 , B01J29/064 , B01J29/068 , B01J29/072 , B01J29/7088 , B01J29/7276 , B01J29/7676 , B01J37/088 , B01J37/18 , B01J2229/20 , B01J2229/40 , B01J2229/42 , C07C2/74 , C07C2529/70 , C07C2529/74 , C07C2529/76 , C07C2601/14 , Y02P20/52 , C07C13/28
摘要： A hydroalkylation catalyst comprising a molecular sieve and a compound of a hydrogenation metal is activated by treating the catalyst at a temperature of less than about 250°C in the presence of hydrogen.
摘要翻译：包含分子筛和氢化金属化合物的加氢烷基化催化剂通过在氢存在下在小于约250℃的温度下处理催化剂来活化。

5. 发明申请

WO2010014404A1 PROCESS OF MAKING ALKYLAROMATICS USING EMM-13 审中-公开
标题翻译：使用EMM-13制备碱性物质的方法
公开(公告)号：WO2010014404A1
公开(公告)日：2010-02-04
申请号：PCT/US2009/050724
申请日：2009-07-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HELTON, Terry, E.
发明人： HELTON, Terry, E.
IPC分类号： C01B39/46 , C01B39/48 , B01J29/00
CPC分类号： B01J29/7038 , B01J29/70 , C01B39/46 , C01B39/48 , C07C2/66 , C07C2529/70 , Y02P20/52 , C07C15/085 , C07C15/073
摘要： This disclosure relates to a process for manufacturing a mono-alkylaromatic aromatic compound, said process comprising contacting a feedstock comprising an alkylatable aromatic compound and an alkylating agent under alkylation reaction conditions with a catalyst comprising EMM-13, wherein said EMM-13 is a molecular sieve comprising a framework of tetrahedral atoms bridged by oxygen atoms, the tetrahedral atom framework being defined by a unit cell with atomic coordinates in nanometers shown in Table 3.
摘要翻译：本公开涉及一种制备单烷基芳族化合物的方法，所述方法包括在烷基化反应条件下将包含可烷基化芳族化合物和烷基化剂的原料与包含EMM-13的催化剂接触，其中所述EMM-13是分子筛，其包含由氧原子桥接的四面体原子的框架，四面体原子框架由具有如表3所示的纳米的原子坐标的晶胞定义。

6. 发明申请

WO2009134516A1 PROCESS FOR PRODUCING CYCLOHEXYLBENZENE 审中-公开
标题翻译：生产环己烷苯的方法
公开(公告)号：WO2009134516A1
公开(公告)日：2009-11-05
申请号：PCT/US2009/034823
申请日：2009-02-23
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CHEN, Tan-Jen , CHENG, Jane, C. , BENITEZ, Francisco, M. , HELTON, Terry, E. , STANAT, Jon, E.
发明人： CHEN, Tan-Jen , CHENG, Jane, C. , BENITEZ, Francisco, M. , HELTON, Terry, E. , STANAT, Jon, E.
IPC分类号： C07C2/74 , C07C45/53 , C07C13/28 , C07C49/403
CPC分类号： C07C37/06 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt% of said hydrogenation metal is supported on the inorganic oxide and the inorganic oxide has an average particle size less than 40 μm (microns).
摘要翻译：在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50重量％的所述氢化金属负载在无机氧化物上，无机氧化物具有平均粒度小于40μm（微米）。

7. 发明申请

WO2009079136A1 HYDROCARBON CONVERSION PROCESS USING EMM-10 FAMILY MOLECULAR SIEVE 审中-公开
标题翻译：使用EMM-10系列分子筛的碳氢转化方法
公开(公告)号：WO2009079136A1
公开(公告)日：2009-06-25
申请号：PCT/US2008/083627
申请日：2008-11-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ROTH, Wieslaw, J. , CHENG, Jane, C. , KALYANARAMAN, Mohan , KERBY, Michael, C. , HELTON, Terry, E.
发明人： ROTH, Wieslaw, J. , CHENG, Jane, C. , KALYANARAMAN, Mohan , KERBY, Michael, C. , HELTON, Terry, E.
IPC分类号： B01J29/70 , C01B39/48 , C07C2/66 , C07C6/00
CPC分类号： C07C2/66 , B01J29/70 , B01J37/0009 , B01J2229/42 , Y02P20/52 , C07C15/073 , C07C15/02 , C07C15/085 , C07C15/08
摘要： This disclosure relates to a process for hydrocarbon conversion comprising contacting, under conversion conditions, a feedstock suitable for hydrocarbon conversion with a catalyst comprising an EMM- 10 family molecular sieve.
摘要翻译：本公开涉及一种烃转化方法，其包括在转化条件下将适于烃转化的原料与包含EMM-10族分子筛的催化剂接触。

8. 发明申请

WO2011146189A2 IMPROVED ALKYLATION PROCESS 审中-公开
标题翻译：改进的碱化过程
公开(公告)号：WO2011146189A2
公开(公告)日：2011-11-24
申请号：PCT/US2011/032661
申请日：2011-04-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VINCENT, Matthew, J. , NANDA, Vijay , HELTON, Terry, E.
发明人： VINCENT, Matthew, J. , NANDA, Vijay , HELTON, Terry, E.
CPC分类号： C07C2/66 , C07C7/12 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , Y02P20/52 , C07C15/02 , C07C15/073 , C07C15/085 , C07C15/04
摘要： The present invention provides an improved process for producing an alkylated aromatic compound from an at least partially untreated alkylatable aromatic compound having catalyst poisons and an alkylating agent, wherein said alkylatable aromatic compound stream is treated to reduce catalyst poisons with a treatment composition having a surface area/surface volume ratio of greater than or equal to 30 in -1 (76 cm -1 ) in a treatment zone separate from an alkylation reaction zone under treatment conditions including a temperature of from about 30°C to about 300°C to form an effluent comprising said treated alkylatable aromatic compound.
摘要翻译：本发明提供了一种由至少部分未经处理的具有催化剂毒素和烷基化剂的可烷化芳族化合物制备烷基化芳族化合物的改进方法，其中用具有表面积的处理组合物处理所述可烷基化芳族化合物流以减少催化剂毒物 /表面体积比大于或等于30in -1（76cm -1），在处理区域与烷基化反应区分离，在包括温度为约30℃至约300℃的处理条件下形成流出物包含所述处理的可烷基化芳族化合物。

9. 发明申请

WO2010014405A1 PROCESS OF MAKING ALKYLAROMATICS USING EMM-12 审中-公开
标题翻译：使用EMM-12制造碱性物质的方法
公开(公告)号：WO2010014405A1
公开(公告)日：2010-02-04
申请号：PCT/US2009/050727
申请日：2009-07-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HELTON, Terry, E.
发明人： HELTON, Terry, E.
IPC分类号： C01B39/46 , C01B39/48 , B01J29/00
CPC分类号： B01J29/70 , B01J29/7038 , B01J2229/42 , C01B39/46 , C01B39/48 , C07C2/66 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2521/14 , C07C2523/02 , C07C2529/70 , Y02P20/52 , C07C15/073 , C07C15/085 , C07C15/02
摘要： This disclosure relates to a process for manufacturing a mono-alkylaromatic compound, said process comprising contacting a feedstock comprising an alkylatable aromatic compound and an alkylating agent under alkylation reaction conditions with a catalyst comprising EMM- 12, wherein said EMM- 12 is a molecular sieve having, in its as- synthesized form and in calcined form, an X-ray diffraction pattern including peaks having a d-spacing maximum in the range of 14.17 to 12.57 Angstroms, a d-spacing maximum in the range of 12.1 to 12.56 Angstroms, and non-discrete scattering between about 8.85 to 11.05 Angstroms or exhibit a valley in between the peaks having a d-spacing maximum in the range of 10.14 to 12.0 Angstroms and a d-spacing maximum in the range from 8.66 to 10.13 Angstroms with measured intensity corrected for background at the lowest point being not less than 50 % of the point at the same XRD d-spacing on the line connecting maxima in the range of 10.14 to 12.0 Angstroms and in the range from 8.66 to 10.13 Angstroms.
摘要翻译：本公开涉及一种制备单烷基芳族化合物的方法，所述方法包括在烷基化反应条件下将包含可烷基化芳族化合物和烷基化剂的原料与包含EMM-12的催化剂接触，其中所述EMM-12是分子筛具有其合成形式和煅烧形式的X射线衍射图，其包括在14.17至12.57埃范围内具有d间距最大值的峰，在12.1至12.56埃范围内的d间距最大值，和在约8.85至11.05埃之间的非离散散射或在具有10.14至12.0埃范围内的d间距最大值的峰之间或在具有测量强度的8.66至10.13埃的范围内的d间距最大值之间呈现谷底在最低点处校正的背景不小于在连接最大值在10.14至12.0埃和t的范围内的线上相同XRD d间距处的点的50％他的范围从8.66到10.13埃。

10. 发明申请

WO2010014401A1 HYDROALKYLATION OF AROMATIC COMPOUNDS USING EMM-13 审中-公开
标题翻译：使用EMM-13的芳族化合物的水解
公开(公告)号：WO2010014401A1
公开(公告)日：2010-02-04
申请号：PCT/US2009/050717
申请日：2009-07-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ROTH, Wieslaw, J. , HELTON, Terry, E. , CHENG, Jane, C. , BRENNAN, Michael, J.
发明人： ROTH, Wieslaw, J. , HELTON, Terry, E. , CHENG, Jane, C. , BRENNAN, Michael, J.
IPC分类号： C01B39/46 , C01B39/48 , B01J29/00
CPC分类号： B01J29/7038 , B01J29/7276 , B01J29/7476 , B01J29/7676 , C01B39/46 , C01B39/48 , C07C2/74 , C07C2601/14 , C07C13/28
摘要： This disclosure relates to a process for manufacturing a mono-cycloalkyl-substituted aromatic compound, said process comprising contacting a feedstock comprising an aromatic compound and hydrogen under hydroalkylation reaction conditions with a catalyst system comprising a molecular sieve, wherein said molecular sieve comprises a framework of tetrahedral atoms bridged by oxygen atoms, the tetrahedral atom framework being defined by a unit cell with atomic coordinates in nanometers shown in Table 2.
摘要翻译：本公开涉及制备单环烷基取代的芳族化合物的方法，所述方法包括在加氢烷基化反应条件下将包含芳族化合物和氢的原料与包含分子筛的催化剂体系接触，其中所述分子筛包括由氧原子桥接的四面体原子，四面体原子框架由具有如表2所示的纳米的原子坐标的单元电池定义。

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