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1. 发明申请

WO2012134718A3 AMINE FUNCTIONALIZED POLYOLEFIN AND METHODS FOR PREPARATION THEREOF 审中-公开
公开(公告)号：WO2012134718A3
公开(公告)日：2012-10-04
申请号：PCT/US2012/027683
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , CROWTHER, Donna, J. , GANESH, Renuka, N. , BRANT, Patrick
发明人： HAGADORN, John, R. , CROWTHER, Donna, J. , GANESH, Renuka, N. , BRANT, Patrick
IPC分类号： C08F8/32 , C08F10/06 , C08F4/64 , C08L23/36
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.

2. 发明申请

WO2012134722A2 DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
标题翻译：由交叉METASESIS制备的二嵌段共聚物
公开(公告)号：WO2012134722A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027691
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , RUFF, Charles, J. , GANESH, Renuka, N. , BRANT, Patrick
发明人： HAGADORN, John, R. , RUFF, Charles, J. , GANESH, Renuka, N. , BRANT, Patrick
IPC分类号： C08F10/00 , C08F297/08 , C08F4/64 , C08L23/02 , C08L53/00
CPC分类号： C08G61/08 , C08F297/083 , C08G61/04 , C08G2261/418 , C08L53/00 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R 11 )(R 12 )-C(R 13 )=C(R 14 )-C(R 15 )(R 16 )-PO*, or isomers thereof, wherein R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 , are each independently a substituted or unsubstituted C 1 through C 4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C 20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13 C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13 C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1 H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由下式表示的多嵌段聚烯烃：PO-C（R11）（R12）-C（R13）= C（R14）-C（R15）（R16）-PO * 其中R11，R12，R13，R14，R15和R16各自独立地为取代或未取代的C1至C4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9至4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13 C NMR所示的内部不饱和度在约128至约132ppm之间的峰; 2）Mn比“Z”= 0.1〜10，其中Z为Mn（通过13 C NMR测定）除以Mn（根据使用聚苯乙烯标准品的凝胶渗透色谱法测定）; 和3）任选地，通过1 H NMR光谱确定的每1000个碳的0.3（J）和0.75（J）内部不饱和度，其中J是成为PO和PO的乙烯基封端的聚烯烃的混合物的每1000个碳的反应性数 *，在它们通过烯烃复分解催化剂偶合之前。

3. 发明申请

WO2012134717A2 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译：乙烯基封端的高级烯烃聚合物及其制备方法
公开(公告)号：WO2012134717A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027682
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CROWTHER, Donna, J. , HOLTCAMP, Matthew, W. , HAGADORN, John, R. , RUFF, Charles, J. , RODRIGUEZ, George , BRANT, Patrick
发明人： CROWTHER, Donna, J. , HOLTCAMP, Matthew, W. , HAGADORN, John, R. , RUFF, Charles, J. , RODRIGUEZ, George , BRANT, Patrick
IPC分类号： C08F210/14 , C08F210/06 , C08L23/18 , C08F4/64 , C10M107/10
CPC分类号： C10M107/10 , C08F4/65908 , C08F4/65925 , C08F4/65927 , C08F210/06 , C08F210/14 , C08L2314/06 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/028 , C10N2270/00 , C08F2500/17
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1 H NMR) comprising: (i) from about 20 to about 99.9 mol% of at least one C 5 to C 40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol% of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7: 1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20 至约99.9摩尔％的至少一种C≡5至C≡40高级烯烃单体; 和（ii）约0.1至约80摩尔％的丙烯; 其中高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物还可具有小于0.7：1的异丁基链端与烯丙基链端部比例和/或大于2：1的烯丙基链端部与乙烯叉基链端部比率。

4. 发明申请

WO2012134721A2 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译：乙烯基封端的高级烯烃聚合物及其制备方法
公开(公告)号：WO2012134721A2
公开(公告)日：2012-10-04
申请号：PCT/US2012/027690
申请日：2012-03-05
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HOLTCAMP, Matthew, W. , RUFF, Charles, J. , CROWTHER, Donna, J. , HAGADORN, John, R. , BRANT, Patrick
发明人： HOLTCAMP, Matthew, W. , RUFF, Charles, J. , CROWTHER, Donna, J. , HAGADORN, John, R. , BRANT, Patrick
IPC分类号： C08F10/14 , C08F210/16 , C08F4/64 , C08F4/6592
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65912 , C08F210/14 , C08F4/65925 , C08F4/65927 , C08F2500/02
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by lR NMR) including of one or more C4 to C4Q higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端的聚合物，其包括一种或多种C 4 -C 40高级烯烃衍生的单元，其中高级烯烃乙烯基封端的聚合物基本不含丙烯衍生的单元并且其中高级烯烃聚合物具有至少5％的烯丙基链端和用于其生产的方法。这些乙烯基封端的高级烯烃聚合物可以任选地包括乙烯衍生的单元。

5. 发明申请

WO2012134613A3 PYRIDYLDIAMIDO TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
公开(公告)号：WO2012134613A3
公开(公告)日：2012-10-04
申请号：PCT/US2012/022473
申请日：2012-01-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , GANESH, Renuka, N. , UBORSKY, Dmitry, V. , BORISOV, Iiya, S. , PRUSS, Ivan, V. , VOSKOBOYNIKOV, Alexander, Z.
发明人： HAGADORN, John, R. , GANESH, Renuka, N. , UBORSKY, Dmitry, V. , BORISOV, Iiya, S. , PRUSS, Ivan, V. , VOSKOBOYNIKOV, Alexander, Z.
IPC分类号： C07F7/28 , C07F7/00 , C07F3/00 , C07F9/00 , C07F11/00 , C07F13/00
摘要： Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization.

6. 发明申请

WO2012134614A1 PYRIDYLDIAMIDO TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
标题翻译： PYRIDYLDIAMIDO过渡金属复合物，生产和使用
公开(公告)号：WO2012134614A1
公开(公告)日：2012-10-04
申请号：PCT/US2012/022475
申请日：2012-01-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , GANESH, Renuka, N.
发明人： HAGADORN, John, R. , GANESH, Renuka, N.
IPC分类号： C07F7/28 , C07F7/00 , C07F5/00 , C07F9/00 , C08F4/16 , C08F10/06
CPC分类号： C07D213/38 , B01J31/1815 , B01J31/183 , B01J2531/48 , B01J2531/49 , C07D213/48 , C07D213/53 , C07F7/00 , C07F7/006 , C08F10/00 , C08F110/06 , C08F210/16 , C08F2500/03 , C08F2500/05 , C08F210/14 , C08F4/64144 , C08F4/64148 , C08F4/64151
摘要： Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization to produce multimodal polyolefins.
摘要翻译：公开了用于烯烃聚合以制备多峰聚烯烃的吡啶基二酰氨基过渡金属络合物。

7. 发明申请

WO2011056884A3 CARBENE COMPLEXES OF LITHIUM AND/OR MAGNESIUM METAL SALTS, AND USES THEREOF 审中-公开
公开(公告)号：WO2011056884A3
公开(公告)日：2011-05-12
申请号：PCT/US2010/055313
申请日：2010-11-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , HOLTCAMP, Matthew, W. , BEDOYA, Matthew, S. , GANESH, Renuka, N.
发明人： HAGADORN, John, R. , HOLTCAMP, Matthew, W. , BEDOYA, Matthew, S. , GANESH, Renuka, N.
IPC分类号： C07F1/02 , C07F3/02 , B01J31/22 , C07C2/34 , C07C11/00
摘要： This invention relates to a carbene complex of metal salt represented by the formula: [T-M(R) c ] n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23°C for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L 0 ) q (L 1- ) s (L 2- ) t ] g , where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L 0 is a neutral ligand, L 1- is a monoanionic ligand, L 2- is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3,or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.

8. 发明申请

WO2009155517A2 OLEFIN FUNCTIONALIZATION BY METATHESIS REACTION 审中-公开
标题翻译：烯烃反应的烯烃功能化
公开(公告)号：WO2009155517A2
公开(公告)日：2009-12-23
申请号：PCT/US2009/047953
申请日：2009-06-19
申请人： ExxonMobil Chemical Patent Inc. , HAGADORN, John, R. , HOLTCAMP, Matthew, W. , NARVAEZ, Andrew, G. , CROWTHER, Donna, J. , BRANT, Patrick
发明人： HAGADORN, John, R. , HOLTCAMP, Matthew, W. , NARVAEZ, Andrew, G. , CROWTHER, Donna, J. , BRANT, Patrick
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol% propylene and 10 to 90 mol% of ethylene, wherein the oligomer has at least X% allyl chain ends, where: 1) X = (-0.94 (mole% ethylene incorporated) + 100), when 10 to 60 mole% ethylene is present in the co-oligomer, and 2) X = 45, when greater than 60 and less than 70 mole% ethylene is present in the co-oligomer, and 3) X = (1.83* (mole% ethylene incorporated) -83), when 70 to 90 mole% ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8: 1 to 1.2: 1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中所述低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（摩尔％乙烯掺入）+ 100），当共聚物中存在10至60摩尔％的乙烯时 - 低聚物，和2）X = 45，当共聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83 *（摩尔％乙烯加入）-83），当70〜共聚低聚物中存在90摩尔％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

9. 发明申请

WO2013006353A1 POLYALKYLENE CARBOXYLIC ACID POLYAMINE ADDITIVES FOR FOULING MITIGATION IN HYDROCARBON REFINING PROCESSES 审中-公开
标题翻译：用于在油精炼工艺中减缓的聚亚烷基羧酸聚酰胺添加剂
公开(公告)号：WO2013006353A1
公开(公告)日：2013-01-10
申请号：PCT/US2012/044492
申请日：2012-06-28
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , NG, Man, Kit , BRONS, Glen, Barry , FERRUGHELLI, David, Thomas , CHEN, Hong , MALLORY, Kevin , ULYSSE, Emmanuel , HAGADORN, John, R. , CROWTHER, Donna, J. , BRANT, Patrick
发明人： NG, Man, Kit , BRONS, Glen, Barry , FERRUGHELLI, David, Thomas , CHEN, Hong , MALLORY, Kevin , ULYSSE, Emmanuel , HAGADORN, John, R. , CROWTHER, Donna, J. , BRANT, Patrick
IPC分类号： C08F8/32 , C10G75/04 , C08F10/06 , C10L1/2383
CPC分类号： C08F8/32 , C08F8/04 , C10G75/04 , C10L1/224 , C10L1/2383 , C10L10/00 , C08F10/06
摘要： Methods and systems for reducing fouling, including particuiate-induced fouling, in a hydrocarbon refining process including the steps of providing a crude hydrocarbon for a refining process and adding an antifouling agent containing a polymer base unit and a polyamine group to the crude hydrocarbon are provided. The antifouling agent can be obtained by convertmg a vinyl terminated polymer, such as polypropylene or poiy(ethylene- co-propylene), to a terminal acyl containing functional group, followed by reacting the terminal acyl containing functional group with a polyamine compound.
摘要翻译：提供了一种用于在烃精炼方法中减少污染的方法和系统，包括颗粒物引起的结垢，包括以下步骤：提供用于精制方法的粗制烃，并向粗制烃中加入含有聚合物基础单元和多胺基团的防污剂。防污剂可以通过将乙烯基封端的聚合物如聚丙烯或聚（乙烯 - 共 - 丙烯）转化为末端酰基官能团，然后使含末端酰基官能团与多胺化合物反应而获得。

10. 发明申请

WO2011056881A2 METATHESIS CATALYST AND PROCESS FOR USE THEREOF 审中-公开
标题翻译： METATHESIS催化剂及其使用方法
公开(公告)号：WO2011056881A2
公开(公告)日：2011-05-12
申请号：PCT/US2010/055309
申请日：2010-11-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , HOLTCAMP, Matthew, W. , BEDOYA, Matthew, S.
发明人： HAGADORN, John, R. , HOLTCAMP, Matthew, W. , BEDOYA, Matthew, S.
IPC分类号： B01J31/22 , C07C1/213 , C07C11/00 , C07F15/00
CPC分类号： C07F15/0046 , B01J31/2226 , B01J31/2291 , B01J31/2295 , B01J2231/49 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C2531/22 , C11C3/14 , Y02E50/13 , C07C11/02 , C07C69/533
摘要： This invention relates to a catalyst compound comprising a combination of a cyclic alkyl amino carbene ligand and a benzylidene both attached to a Group 8 metal, preferably ruthenium atom. This invention also relates to a process to make linear alpha-olefms comprising contacting a feed material and an optional alkene (such as ethylene) with the catalyst described above, wherein the feed material is a triacylglyceride, fatty acid, fatty acid alkyl ester, and/or fatty acid ester, typically derived from seed oil (e.g., biodiesel).
摘要翻译：本发明涉及包含环烷基氨基卡宾配体和亚苄基的组合的催化剂化合物，它们都附着在第8族金属，优选钌原子上。本发明还涉及制备线性α-烯烃的方法，包括使进料和任选的烯烃（如乙烯）与上述催化剂接触，其中进料是甘油三酯，脂肪酸，脂肪酸烷基酯和 /或脂肪酸酯，通常衍生自种子油（例如，生物柴油）。

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