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    • 10. 发明公开
    • MOLECULAR SIEVE CATALYST COMPOSITION, ITS MAKING AND USE IN CONVERSION PROCESSES
    • 分子筛催化剂组合物及其制备和在转化过程中的用途
    • EP1680221A2
    • 2006-07-19
    • EP04781264.9
    • 2004-08-16
    • ExxonMobil Chemical Patents, Inc.
    • CHANG, Yun-FengVAUGHN, Stephen, N.CLEM, Kenneth, R.MARTENS, Luc, R., M.HU, Weiguo
    • B01J29/00
    • B01J37/0045B01J29/06B01J29/84B01J29/85B01J35/002B01J37/0009C07C1/20C07C2521/04C07C2521/06C07C2521/16C07C2529/85Y02P30/20Y02P30/42Y10S502/504C07C11/02
    • This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27 Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry. The catalyst compositions obtained by the methods of the present invention have improved attrition resistance, and are particularly useful in hydrocarbon conversion processes.
    • 本发明提供了制备分子筛催化剂颗粒的方法,可用于这种方法的分子筛浆料,分子筛催化剂组合物及其在催化烃转化过程中的用途。 在其一个方面中,本发明提供制备分子筛催化剂颗粒的方法,所述方法包括以下步骤:a)提供含铝无机氧化物前体在液体介质中的溶液或悬浮液; b)将含铝无机氧化物前体的溶液或悬浮液与分子筛以及任选的其他配制剂结合以形成催化剂配制料浆; c)使所述催化剂配制浆料老化,以在所述浆料中产生具有在62-63ppm处的尖锐27 Al NMR峰的低聚物形式的所述含铝前体的铝原子百分比或所述浆料中存在的百分比增加 ; 和d)由催化剂配制浆料形成分子筛催化剂颗粒。 通过本发明的方法获得的催化剂组合物具有改善的耐磨耗性,并且特别用于烃转化过程。