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1. 发明申请

WO2017105635A1 CATALYSTS FOR PRODUCING POLYMERS WITH ENHANCED PROPERTIES 审中-公开
标题翻译：用于生产具有增强性能的聚合物的催化剂
公开(公告)号：WO2017105635A1
公开(公告)日：2017-06-22
申请号：PCT/US2016/058699
申请日：2016-10-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： CANICH, Jo Ann M. , STEWART, Ian C. , BORISOV, Ilya S. , GUZEEV, Bogdan A. , UBORSKY, Dmitry V. , VOSKOBOYNIKOV, Alexander Z.
IPC分类号： C08F4/6592 , C08F4/656 , C08F10/06 , C08F2/44
CPC分类号： C08F10/06 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F2500/01 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F2500/04 , C08F110/06 , C08F2500/16 , C08F210/06 , C08F10/00 , C08F4/65927 , C08F210/02 , C08F236/20 , C08F2500/25
摘要： Disclosed are novel hafnium-based metallocene catalyst compounds with the following characteristics: 1) 4,5-dialkyl substitutions on a fluorenyl ligand, and optionally additional substitutions, 2) a cyclopentadienyl ligand, optionally with substitutions, and 3) a bridging group from group 14 of the Periodic Table. Also disclosed are catalyst systems comprising such catalyst compounds and their uses thereof, and polymers produced using such catalyst systems.
摘要翻译：公开了具有以下特征的新型铪基茂金属催化剂化合物：1）在芴基配体上的4,5-二烷基取代，和任选另外的取代，2）任选具有取代基的环戊二烯基配体，和3）周期表第14族的桥接基团。还公开了包含这种催化剂化合物的催化剂体系及其用途，以及使用这种催化剂体系生产的聚合物。

2. 发明申请

WO2015009474A1 ETHYLENE-PROPYLENE COPOLYMERIC COMPOSITIONS WITH LONG METHYLENE SEQUENCE LENGTHS 审中-公开
标题翻译：乙烯 - 丙烯共聚物长链长度
公开(公告)号：WO2015009474A1
公开(公告)日：2015-01-22
申请号：PCT/US2014/045542
申请日：2014-07-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： TSE, Mun Fu , CANICH, Jo Ann M. , RUFF, Charles J. , BILBAO, Daniel , DEGRACIA, Carlos U. , STEWART, Ian C.
IPC分类号： C08F255/04 , C08F210/16 , C08F4/64
CPC分类号： C08F4/65908 , C08F255/04 , C08F210/16 , C08F4/65927
摘要： This invention relates to methods to prepare and compositions pertaining to branched ethylene-propylene copolymers that include at least 50% ethylene content by weight as determined by FTIR; a g' vis of less than 0.95; a M w of 150,000 to 250,000; a methylene sequence length of 6 or greater as determined by 13 C NMR, wherein the percentage of sequences of the length of 6 or greater is more than 32%; and can have greater than 50% vinyl chain end functionality.
摘要翻译：本发明涉及制备方法和涉及支链乙烯 - 丙烯共聚物的组合物，其包括通过FTIR测定的至少50重量％的乙烯含量; 小于0.95的g'vis; Mw为15万至25万; 通过13 C NMR确定的6或更大的亚甲基序列长度，其中长度为6或更大的序列的百分比大于32％; 并且可以具有大于50％的乙烯基链末端官能度。

3. 发明授权

EP3126419B1 FREE RADICAL GRAFTING OF FUNCTIONALIZED RESINS FOR TIRES 有权
公开(公告)号：EP3126419B1
公开(公告)日：2020-01-22
申请号：EP15711371.3
申请日：2015-03-06
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , HARRIS, David T. , STEWART, Ian C.
IPC分类号： C08F279/00 , C08F291/02 , C08L51/04 , B60C1/00 , C08K5/00 , C08L21/00 , C08L9/06 , C08F8/42 , C08K3/00

4. 发明授权

EP3209506B1 CHAIN END FUNCTIONALIZED POLYOLEFINS FOR IMPROVING WET TRACTION AND ROLLING RESISTANCE OF TIRE TREADS 有权
公开(公告)号：EP3209506B1
公开(公告)日：2020-03-25
申请号：EP15866554.7
申请日：2015-10-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , YANG, Yong , ZHANG, Jingwen , STEWART, Ian C. , LUO, Shuji , TSOU, Andy H.
IPC分类号： B60C1/00 , C08F8/42 , C08L9/00 , C08L15/00

5. 发明公开

EP3077433A1 FUNCTIONALIZED RESINS FOR HIGH PERFORMANCE TIRES 有权
标题翻译：用于高性能轮胎的功能化树脂
公开(公告)号：EP3077433A1
公开(公告)日：2016-10-12
申请号：EP14867356.9
申请日：2014-08-11
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , STEWART, Ian C. , DIAS, Anthony J. , CHEN, Yuan-ju
IPC分类号： C08F279/02 , C08L9/00 , C08L51/04 , C08F4/60 , C08K3/36 , B60C1/00
CPC分类号： C08F132/08 , B60C1/0016 , C08K5/5425 , C08L9/00 , C08L9/06
摘要： This invention relates to a dicyclopentadiene (DCPD)-based resin functionalized with groups capable of reacting with silica or carbon black for use in high performance tires and a preferred method of preparing the functionalized resin comprising ruthenium-catalyzed ring- opening cross metathesis. The functionalized resin may comprise the reaction product obtained by contacting a polymer comprising units derived from (DCPD) and a vinyl monomer or vinylene monomer in the presence of a metathesis catalyst, wherein the vinyl monomer or vinylene monomer comprises at least one of the following functional groups: a silyl group, a siloxy group, or an alkoxysilyl group. This invention further relates to a tire tread composition comprising the functionalized resin and which exhibits enhanced durability, traction, handling, and extractability properties.
摘要翻译：本发明涉及基于双环戊二烯（DCPD）的树脂，该树脂用能够与二氧化硅或炭黑反应的基团官能化以用于高性能轮胎，以及制备包含钌催化的开环交叉复分解的官能化树脂的优选方法。官能化树脂可以包含在易位催化剂存在下通过使包含衍生自（DCPD）的单元的聚合物与乙烯基单体或亚乙烯基单体接触而获得的反应产物，其中所述乙烯基单体或亚乙烯基单体包含至少一种以下官能团基团：甲硅烷基，甲硅烷氧基或烷氧基甲硅烷基。本发明进一步涉及包含官能化树脂并且表现出增强的耐久性，牵引力，处理性和可萃取性的轮胎胎面组合物。

6. 发明公开

EP3209506A2 CHAIN END FUNCTIONALIZED POLYOLEFINS FOR IMPROVING WET TRACTION AND ROLLING RESISTANCE OF TIRE TREADS 有权
标题翻译：链端功能化聚烯烃，用于改善轮胎胎纹的湿牵引和抗滚动性
公开(公告)号：EP3209506A2
公开(公告)日：2017-08-30
申请号：EP15866554.7
申请日：2015-10-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , YANG, Yong , ZHANG, Jingwen , STEWART, Ian C. , LUO, Shuji , TSOU, Andy H.
IPC分类号： B60C1/00 , C08F8/42 , C08L9/00 , C08L15/00
CPC分类号： C08L9/00 , B60C1/0016 , C08F8/42 , C08K3/36 , C08L15/00 , Y02T10/862 , C08F10/02 , C08F10/04
摘要： A functionalized polyolefin and a tire tread composition comprising the functionalized polyolefin is described. The functionalized polyolefin comprises a vinyl/vinylidene-terminated polyolefin in which the vinyl/vinylidene terminus is functionalized with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality. The invention is also directed to the synthesis of vinyl/vinylidene-terminated polyolefins, functionalization at the vinyl/vinylidene terminus with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality.
摘要翻译：描述了包含官能化聚烯烃的官能化聚烯烃和轮胎胎面组合物。官能化聚烯烃包含乙烯基/亚乙烯基封端的聚烯烃，其中乙烯基/亚乙烯基末端用烷氧基硅烷或烷基硅烷官能化并任选具有醚，羟基和/或胺官能团。本发明还涉及乙烯基/亚乙烯基封端的聚烯烃的合成，其在乙烯基/亚乙烯基末端用烷氧基硅烷或烷基硅烷进行官能化并任选具有醚，羟基和/或胺官能团。

7. 发明公开

EP3126419A1 FREE RADICAL GRAFTING OF FUNCTIONALIZED RESINS FOR TIRES 有权
标题翻译： FREIES RADIKALISCHES PFROPFEN VON FUNKTIONALISIERTEN HARZENFÜRREIFEN
公开(公告)号：EP3126419A1
公开(公告)日：2017-02-08
申请号：EP15711371.3
申请日：2015-03-06
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , HARRIS, David T. , STEWART, Ian C.
IPC分类号： C08F279/00 , C08F291/02 , C08L9/00 , C08L51/04 , B60C1/00 , C08K5/00 , C08L21/00
摘要： This invention relates to a process for the preparation of a silane-functionalized resin composition comprising the steps of mixing a polymer backbone, a silane, and a free radical initiator; and producing a silane-functionalized resin composition. The polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof.
摘要翻译：本发明涉及一种制备硅烷官能化树脂组合物的方法，包括混合聚合物骨架，硅烷和自由基引发剂的步骤; 并制备硅烷官能化树脂组合物。聚合物主链选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂，C9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂，及其组合。

8. 发明公开

EP3689638A1 CHAIN END FUNCTIONALIZED POLYOLEFINS FOR IMPROVING WET TRACTION AND ROLLING RESISTANCE OF TIRE TREADS 有权
公开(公告)号：EP3689638A1
公开(公告)日：2020-08-05
申请号：EP20157852.3
申请日：2015-10-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , YANG, Yong , ZHANG, Jingwen , STEWART, Ian C. , LUO, Shuji , TSOU, Andy H.
IPC分类号： B60C1/00 , C08F8/42 , C08L9/00 , C08L15/00
摘要： A functionalized polyolefin and a tire tread composition comprising the functionalized polyolefin is described. The functionalized polyolefin comprises a vinyl/vinylidene-terminated polyolefin in which the vinyl/vinylidene terminus is functionalized with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality. The invention is also directed to the synthesis of vinyl/vinylidene-terminated polyolefins, functionalization at the vinyl/vinylidene terminus with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality.

9. 发明公开

EP3126407A2 SPACER GROUPS FOR FUNCTIONALIZED RESINS IN TIRES 有权
标题翻译： SPACER-GRUPPENFÜRFUNKTIONALISIERTE HARZE IN REIFEN
公开(公告)号：EP3126407A2
公开(公告)日：2017-02-08
申请号：EP15711616.1
申请日：2015-03-06
申请人： ExxonMobil Chemical Patents Inc.
发明人： BLOK, Edward J. , HARRIS, David T. , STEWART, Ian C.
IPC分类号： C08F8/42
CPC分类号： C08F8/42 , B60C1/0016 , C08F2810/30 , C08F2810/40 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L45/00 , C08L2205/025 , C08F132/08
摘要： This invention relates to a functionalized resin composition having the formula P—S—X where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, and X is a silane.
摘要翻译：本发明涉及具有式P-S-X的官能化树脂组合物，其中S是选自C 2 -C 40直链和支链烷基，C 6 -C 40芳烃，丁二烯，异戊二烯及其组合中的至少一种的间隔基，P 是选自基于二环戊二烯（DCPD）的聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂，C 9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂，及其组合，X为硅烷。

10. 发明公开

EP3126453A2 SILICA TREATING OF FUNCTIONALIZED RESINS IN TIRES 有权
标题翻译： KIESELSÄUREBEHANDLUNGVON FUNKTIONALISIERTEN HARENEN REIFEN
公开(公告)号：EP3126453A2
公开(公告)日：2017-02-08
申请号：EP15711617.9
申请日：2015-03-06
申请人： ExxonMobil Chemical Patents Inc.
发明人： HARRIS, David T. , STEWART, Ian C. , GEORJON, Olivier J.F. , BLOK, Edward J.
IPC分类号： C09C1/30 , C09C3/10 , C08G83/00 , C08F8/42 , C08C19/25 , C08G77/442 , C08F8/04 , C08K9/08 , C08L101/02 , C08L9/00 , B60C1/00
CPC分类号： C08K3/36 , B60C1/0016 , C08F8/42 , C08F2810/40 , C08G61/02 , C08G83/001 , C08G2261/3325 , C08G2261/726 , C08K3/06 , C08K3/22 , C08K5/09 , C08K5/18 , C08K5/31 , C08K5/47 , C08K9/06 , C08K9/08 , C08K9/10 , C08K2003/2296 , C08L9/00 , C08L9/06 , C08L45/00 , C08L91/00 , C09C1/3072 , C09C1/3081 , C09C1/309 , Y02T10/862 , C08F132/08
摘要： This invention relates to a process for the preparation of a silica-treated functionalized resin composition comprising the steps of reacting a polymer backbone with a hydrosilylation agent to produce a silane-functionalized resin composition, wherein the polymer backbone is selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof; and mixing the silane-functionalized resin composition with a silica to produce a silica-treated functionalized resin composition.
摘要翻译：本发明涉及一种制备二氧化硅处理的官能化树脂组合物的方法，其包括以下步骤：使聚合物主链与氢化硅烷化剂反应以产生硅烷官能化的树脂组合物，其中聚合物主链选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂，C9均聚物和共聚物树脂， C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂，及其组合; 并将硅烷官能化的树脂组合物与二氧化硅混合以制备二氧化硅处理的官能化树脂组合物。

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