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1. 发明申请

WO2010098916A3 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010098916A3
公开(公告)日：2010-10-21
申请号：PCT/US2010021949
申请日：2010-01-25
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , BENITEZ FRANCISCO M , LATTNER JAMES R , DAKKA JIHAD M , MOZELESKI EDMUND J , ZUSHMA STEPHEN
发明人： WANG KUN , BENITEZ FRANCISCO M , LATTNER JAMES R , DAKKA JIHAD M , MOZELESKI EDMUND J , ZUSHMA STEPHEN
IPC分类号： C07C37/08 , C07C45/53 , C07C407/00
CPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C49/403 , C07C49/10 , C07C49/395 , C07C49/08 , C07C39/04
摘要： Disclosed is a process for producing phenol or a substituted phenol and a co-product comprising the steps of (i) contacting a first stream comprising an alkylaromatic compound with a second stream comprising an oxygen-containing gas in the presence of a first catalyst comprising a cyclic imide under conditions to convert at least a portion of said alkylaromatic compound to an alkylaromatic hydroperoxide, (ii) producing an effluent stream comprising said cyclic imide, said alkylaromatic hydroperoxide, and said alkylaromatic compound wherein said effluent stream has an alkylaromatic hydroperoxide concentration of from 10 to 40 wt%; and (iii) contacting in a second reactor at least a portion of said effluent stream with a second catalyst to convert said alkylaromatic hydroperoxide to a product stream comprising phenol and said co-product.
摘要翻译：公开了一种生产苯酚或取代苯酚和副产物的方法，包括以下步骤：（i）在包含含氧气体的第一催化剂的存在下，将包含烷基芳族化合物的第一物流与包含含氧气体的第二物流接触，所述第一催化剂包含环状酰亚胺在将至少一部分所述烷基芳族化合物转化为烷基芳香族氢过氧化物的条件下，（ii）产生包含所述环状酰亚胺，所述烷基芳族氢过氧化物和所述烷基芳族化合物的流出物流，其中所述流出物流具有烷基芳香族氢过氧化物浓度 10〜40重量％和（iii）在第二反应器中将至少一部分所述流出物流与第二催化剂接触，以将所述烷基芳香族氢过氧化物转化成包含苯酚和所述副产物的产物流。

2. 发明申请

WO2011031374A3 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：氢氧化物
公开(公告)号：WO2011031374A3
公开(公告)日：2011-05-05
申请号：PCT/US2010041801
申请日：2010-07-13
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , DAKKA JIHAD M , ZUSHMA STEPHEN
发明人： WANG KUN , DAKKA JIHAD M , ZUSHMA STEPHEN
IPC分类号： C07C407/00 , C07C409/08 , C07C409/14
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen- containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R1 and R2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO3H, NH2, OH and NO2, or from the atoms H, F, Cl, Br and I provided that R1 and R2 can be linked to one another via a covalent bond; each of Q1 and Q2 is independently selected from C, CH, N and CR3; each of X and Z is independently selected from C, S, CH2, N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is O, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R3 can be any of the entities listed for R1. The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with at least one solid sorbent chosen from alkali metal carbonates, alkali metal bicarbonates, alkali metal hydroxides, alkali metal hydroxide-carbonate complexes, alkaline earth metal carbonates, alkaline earth metal bicarbonates, alkaline earth metal hydroxides and alkaline earth metal hydroxide-carbonate complexes to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，烃在含有通式（I）的环状酰亚胺的催化剂存在下与含氧气体接触：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k是O，1或2; 1是0,1或2; m为1至3，R3可为R1列出的任何实体。接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，流出物用至少一种选自碱金属碳酸盐，碱金属碳酸氢盐，碱金属氢氧化物，碱金属氢氧化物 - 碳酸盐的固体吸附剂处理络合物，碱土金属碳酸盐，碱土金属碳酸氢盐，碱土金属氢氧化物和碱土金属氢氧化物 - 碳酸盐络合物，以除去至少部分未反应的酰亚胺催化剂，并产生包含所述氧化烃产物的处理流出物。然后可以回收有机相。

3. 发明申请

WO2012145028A3 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2012145028A3
公开(公告)日：2013-03-14
申请号：PCT/US2011065056
申请日：2011-12-15
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , GARCIA ROBERTO , DAKKA JIHAD M , MOZELESKI EDMUND J
发明人： WANG KUN , GARCIA ROBERTO , DAKKA JIHAD M , MOZELESKI EDMUND J
IPC分类号： B01J29/08 , B01J29/90 , C07C2/66 , C07C2/74 , C07C13/28 , C07C15/04 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403 , C07C409/16
CPC分类号： C07C37/08 , B01J29/06 , B01J29/08 , B01J29/90 , C07C2/74 , C07C45/53 , C07C51/31 , C07C249/08 , C07C407/00 , C07C2601/14 , Y02P20/52 , Y02P20/584 , C07C39/04 , C07C49/403 , C07C55/14 , C07C409/14 , C07C251/44 , C07C13/28
摘要： In a process for producing phenol, cyclohexylbenzene is contacted with an oxygen- containing compound in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to produce a product comprising cyclohexylbenzene hydroperoxide and unreacted cyclic imide catalyst. Without removing all the unreacted cyclic imide catalyst, at least a portion of the product is contacted with an acidic molecular sieve under conditions effective to adsorb at least a portion of the unreacted cyclic imide and to convert at least part of the cyclohexylbenzene hydroperoxide in the product portion into phenol and cyclohexanone.
摘要翻译：在生产苯酚的方法中，在有效产生包含环己基苯氢过氧化物和未反应的环状酰亚胺催化剂的产物的氧化条件下，环己基苯在含有环状酰亚胺的氧化催化剂的存在下与含氧化合物接触。在不除去所有未反应的环状酰亚胺催化剂的情况下，至少一部分产物在有效吸附至少一部分未反应的环状酰亚胺的条件下与酸性分子筛接触，并将至少部分环己基苯氢过氧化物转化成产物部分成苯酚和环己酮。

4. 发明申请

WO2012145029A3 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2012145029A3
公开(公告)日：2013-04-18
申请号：PCT/US2011065058
申请日：2011-12-15
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , DAKKA JIHAD M
发明人： WANG KUN , DAKKA JIHAD M
IPC分类号： B01J29/08 , B01J29/90 , C07C2/66 , C07C2/74 , C07C13/28 , C07C15/04 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403 , C07C409/16
CPC分类号： C07C37/50 , B01J29/08 , B01J29/90 , B01J31/0244 , C07C37/08 , C07C45/53 , C07C51/31 , C07C407/00 , C07C2601/14 , Y02P20/52 , Y02P20/584 , C07C39/04 , C07C49/403 , C07C55/14 , C07C409/14
摘要： In a process for producing phenol, cyclohexylbenzene is contacted with oxygen in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to produce a product comprising cyclohexylbenzene hydroperoxide and unreacted cyclic imide catalyst. At least a portion of the product is contacted with a cleavage catalyst under conditions effective to convert at least a portion of the cyclohexylbenzene hydroperoxide into a second product comprising further unreacted cyclic imide catalyst, phenol, and cyclohexanone. A portion of the further unreacted cyclic imide catalyst may then be removed from the second product and optionally recycled back to the oxidation step.
摘要翻译：在生产苯酚的方法中，在有效产生包含环己基苯氢过氧化物和未反应的环状酰亚胺催化剂的产物的氧化条件下，环己基苯在含有环状酰亚胺的氧化催化剂存在下与氧气接触。至少一部分产物在有效将至少一部分环己基苯氢过氧化物转化为第二产物的条件下与裂解催化剂接触，该第二产物包含另外未反应的环状酰亚胺催化剂，苯酚和环己酮。然后可以从第二产物中除去部分未反应的环状酰亚胺催化剂，并任选地再循环回氧化步骤。

5. 发明申请

WO2012082232A8 PROCESS FOR PRODUCING CYCLOALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：生产环烷基化合物的方法
公开(公告)号：WO2012082232A8
公开(公告)日：2012-09-07
申请号：PCT/US2011057598
申请日：2011-10-25
申请人： EXXONMOBIL CHEMICAL PATENST INC , WANG KUN , DAKKA JIHAD M , ZUSHMA STEPHEN , LATTNER JAMES R , BECKER CHRISTOPHER L , CHEN TAN-JEN
发明人： WANG KUN , DAKKA JIHAD M , ZUSHMA STEPHEN , LATTNER JAMES R , BECKER CHRISTOPHER L , CHEN TAN-JEN
IPC分类号： C07C37/08 , C07C2/74 , C07C6/12 , C07C13/28 , C07C39/04 , C07C45/53 , C07C409/14
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： In a process for producing a cycloalkylaromatic compound, an aromatic compound and a cyclic olefin are contacted with a first catalyst under conditions effective to produce a reaction product comprising the cycloalkylaromatic compound and at least one non-fused bicyclic by-product. The at least one non-fused bicyclic by-product is then contacted with a second catalyst under conditions effective to convert at least a portion of the at least one non- fused bicyclic by-product to a converted by-product.
摘要翻译：在制备环烷基芳族化合物的方法中，芳族化合物和环状烯烃在有效产生包含环烷基芳族化合物和至少一种非稠合双环副产物的反应产物的条件下与第一催化剂接触。然后在有效将至少一部分非稠合双环副产物转化成转化的副产物的条件下，将至少一种非稠合双环副产物与第二催化剂接触。

6. 发明申请

WO2012018969A2 METHOD OF MAKING 6-HYDROXYHEXANOPHENONE AND 5-BENZOYLPENTANOIC ACID AND MONO OR DIESTERS THEREOF 审中-公开
标题翻译：制备6-羟基喜树碱及5-苯甲酰戊酸及其单或二酯的方法
公开(公告)号：WO2012018969A2
公开(公告)日：2012-02-09
申请号：PCT/US2011046526
申请日：2011-08-04
申请人： EXXONMOBIL RES & ENG CO , WANG KUN , DAKKA JIHAD M , MOZELESKI EDMUND J , BENITEZ FRANCISCO M , BAUGH LISA S , GODWIN ALLEN D , SMIRNOVA DIANA , ZUSHMA STEPHEN
发明人： WANG KUN , DAKKA JIHAD M , MOZELESKI EDMUND J , BENITEZ FRANCISCO M , BAUGH LISA S , GODWIN ALLEN D , SMIRNOVA DIANA , ZUSHMA STEPHEN
IPC分类号： C08K5/12 , C07C45/28 , C07C67/08 , C07C67/40 , C07C69/612 , C07C69/716 , C08K5/101
CPC分类号： C07C45/53 , C07C51/235 , C07C67/08 , C07C67/29 , C07C67/31 , C07C69/24 , C07C69/738 , C07C407/00 , C07C2601/14 , C08K5/10 , C07C49/82 , C07C409/14 , C07C59/84 , C07C69/732 , C07C69/73 , C07C69/28
摘要： Mono- or diester plasticizers of the formula (I): wherein A is either -OC(0)R' or =0, and X is either -COC(0)R or -C(0)OR, and R and R' are C3 to C13 alkyl, which are the same or different, formed from cyclohexylbenzene and processes of making them.
摘要翻译：式（I）的单酯或二酯增塑剂：其中A是-OC（O）R'或= O，并且X是-COC（O）R或-C（O）OR，并且R和R' 是由环己基苯形成的相同或不同的C3至C13烷基及其制备方法。

7. 发明申请

WO2010042261A8 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010042261A8
公开(公告)日：2011-03-17
申请号：PCT/US2009050489
申请日：2009-07-14
申请人： EXXONMOBIL CHEMICAL COMPANY , DAKKA JIHAD M , WANG KUN , MOZELESKI EDMUND J , ZUSHMA STEPHEN
发明人： DAKKA JIHAD M , WANG KUN , MOZELESKI EDMUND J , ZUSHMA STEPHEN
IPC分类号： C07C37/08 , C07C45/53 , C07C409/08 , C07C409/14
CPC分类号： B01J23/002 , B01J21/066 , B01J23/28 , B01J23/30 , B01J23/888 , B01J31/0247 , B01J31/38 , B01J37/031 , B01J37/10 , B01J2523/00 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C2601/18 , Y02P20/52 , C07C39/04 , C07C49/10 , C07C49/403 , B01J2523/17 , B01J2523/48 , B01J2523/69 , B01J2523/842 , B01J2523/68
摘要： In a process for producing phenol or a substituted phenol, an alkylaromatic hydroperoxide having a general Formula: (I) in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with a catalyst comprising an oxide of at least one metal from Groups 3 to 5 and Groups 7 to 14 of the Periodic Table of the Elements and an oxide of at least one metal from Group 6 of the Periodic Table of the Elements.
摘要翻译：在制备苯酚或取代苯酚的方法中，具有通式（I）的烷基芳香族氢过氧化物，其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基，条件是R 1和R 2可以连接到形成具有4至10个碳原子的环状基团，所述环状基团任选被取代，并且R 3表示氢，具有1至4个碳原子的一个或多个烷基或环己基与包含以下化合物的催化剂接触：元素周期表第3至5族和第7至14族中的至少一种金属和至少一种元素周期表第6族金属的氧化物。

8. 发明申请

WO2013052217A3 TERNARY MIXED METAL OXIDE CATALYSTS CONSISTING OF ZR- W- AND CE- OXIDES AND USE THEREOF 审中-公开
标题翻译：包含ZR-W和CE-氧化物的三元混合金属氧化物催化剂及其用途
公开(公告)号：WO2013052217A3
公开(公告)日：2013-08-15
申请号：PCT/US2012052878
申请日：2012-08-29
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , GARCIA ROBERTO , SMITH CHARLES M , LEVIN DORON , VARTULI JAMES C
发明人： WANG KUN , GARCIA ROBERTO , SMITH CHARLES M , LEVIN DORON , VARTULI JAMES C
IPC分类号： B01J23/30 , B01J21/06 , B01J23/00 , B01J37/00 , B01J37/03 , B01J37/06 , C07C39/04
CPC分类号： C07C37/08 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/30 , B01J37/009 , B01J37/036 , B01J37/06 , C07C2/66 , C07C45/53 , C07C407/00 , C07C2529/70 , Y02P20/52 , C07C39/04 , C07C49/403
摘要： Disclosed herein are catalyst compositions useful in selective decomposition of organic oxygenates. A feed comprising an organic oxygenate may be contacted with a catalyst comprising (a) at least 0.1 wt% of an oxide of an element selected from Group 3 of the Periodic Table of Elements, wherein Group 3 includes the Lanthanide series; (b) at least 0.1 wt% of an oxide of an element selected trom Group 6 of the Periodic Table of Elements; and (c) at least 0.1 wt.% of an oxide of at least one element selected from Group 4 of the Periodic Table of Elements, wherein the wt%s are based upon the total combined weight of the oxides in (a) through (c) and excludes any other components.
摘要翻译：本文公开了可用于选择性分解有机含氧化合物的催化剂组合物。包含有机含氧化合物的进料可以与催化剂接触，所述催化剂包含（a）至少0.1重量％的选自元素周期表第3族元素的氧化物，其中第3族包括镧系; （b）至少0.1重量％的选自元素周期表第6族元素的元素的氧化物; 和（c）至少0.1重量％的选自元素周期表第4族中的至少一种元素的氧化物，其中wt％基于（a）至（a）中的氧化物的总重量， c）并排除任何其他组成部分。

9. 发明申请

WO2010138248A3 TRANSALKYLATION OF POLYCYCLOHEXYLBENZENES 审中-公开
标题翻译：多环戊二烯的交联
公开(公告)号：WO2010138248A3
公开(公告)日：2011-01-20
申请号：PCT/US2010031029
申请日：2010-04-14
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , CHENG JANE C , HELTON TERRY EUGENE
发明人： WANG KUN , CHENG JANE C , HELTON TERRY EUGENE
IPC分类号： C07C4/18 , C07C2/74 , C07C13/28 , C07C37/08 , C07C39/04
CPC分类号： C07C409/14 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2521/04 , C07C2521/06 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for the transalkylation of polycyclohexylbenzenes, a feed containing at least one polycyclohexylbenzene is contacted with benzene under transalkylation conditions with a catalyst comprising a zeolite USY having a silica to alumina molar ratio in excess of 10 to convert at least part of said polycyclohexylbenzene to cyclohexylbenzene.
摘要翻译：在多环己基苯的烷基转移方法中，将含有至少一种聚环己基苯的进料在烷基转移条件下与苯接触，其中催化剂包含二氧化硅与氧化铝摩尔比超过10的沸石USY，以将至少部分所述多环己基苯转化为环己基苯。

10. 发明申请

WO2012145031A3 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2012145031A3
公开(公告)日：2013-03-28
申请号：PCT/US2011065062
申请日：2011-12-15
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , GARCIA ROBERTO , KISS GABOR
发明人： WANG KUN , GARCIA ROBERTO , KISS GABOR
IPC分类号： B01J29/08 , B01J29/90 , C07C2/66 , C07C2/74 , C07C13/28 , C07C15/04 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403 , C07C409/16
CPC分类号： C07C37/08 , B01J29/06 , B01J29/08 , B01J29/90 , C07C2/74 , C07C45/53 , C07C51/31 , C07C249/08 , C07C407/00 , C07C2529/89 , C07C2601/14 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C55/14 , C07C39/04 , C07C49/403 , C07C13/28 , C07C409/14 , C07C251/44
摘要： A process for producing phenol is described in which a feed comprising cyclohexylbenzene hydroperoxide is contacted with a cleavage catalyst comprising an aluminosilicate zeolite of the FAU type having a unit cell size less than 24.50 A under cleavage conditions effective to convert at least part of the cyclohexylbenzene hydroperoxide into phenol and cyclohexanone.
摘要翻译：描述了一种生产苯酚的方法，其中包含环己基苯氢过氧化物的进料与裂解催化剂接触，所述裂解催化剂包含具有小于24.50A的晶胞尺寸的单元电池尺寸小于24.50A的FAA型铝硅酸盐沸石，该有效转化至少部分环己基苯氢过氧化物转化成苯酚和环己酮。

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