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1. 发明申请

WO2006009949A2 LOW FOULING AND HIGH ACTIVITY POLYMERIZATION PROCESS 审中-公开
标题翻译：低熔点和高活性聚合方法
公开(公告)号：WO2006009949A2
公开(公告)日：2006-01-26
申请号：PCT/US2005021652
申请日：2005-06-20
申请人： EXXONMOBIL CHEM PATENTS INC , STAVENS KEVIN B , HAGERTY ROBERT O , LAIRD RANDALL B , LIN ZERONG , RISCH MICHAEL A , IACCINO LARRY L
发明人： STAVENS KEVIN B , HAGERTY ROBERT O , LAIRD RANDALL B , LIN ZERONG , RISCH MICHAEL A , IACCINO LARRY L
IPC分类号： C08F210/16 , C08F4/642 , C08F4/649 , C08F4/69 , C08F110/02
CPC分类号： C08F210/16 , C07C17/389 , C07C19/08 , C07C19/10 , C07C21/18 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F2410/01 , C08F2410/02 , Y02P20/127 , Y10S526/912 , C08F4/69 , C08F2/06 , C08F4/6493 , C08F4/6555 , C08F4/651 , C08F4/65912 , C08F2/14 , C08F210/08 , C08F210/14
摘要： This invention is directed to a polymerization process that is carried out at relatively high productivity levels and with relatively low fouling. The process includes mixing together a catalyst system, at least one monomer and a hydrofluorocarbon to produce the polymer. The reaction is carried out such that little to no chlorine containing hydrocarbons are present.
摘要翻译：本发明涉及一种聚合方法，其以较高的生产率和较低的结垢进行。该方法包括将催化剂体系，至少一种单体和氢氟烃混合在一起以产生聚合物。进行反应，使得存在少至不含氯的烃。

2. 发明申请

WO2006009944A3 POLYMERIZATION PROCESS 审中-公开
标题翻译：聚合工艺
公开(公告)号：WO2006009944A3
公开(公告)日：2006-06-01
申请号：PCT/US2005021647
申请日：2005-06-20
申请人： EXXONMOBIL CHEM PATENTS INC , HAGERTY ROBERT O , CHEE CHIA S , LAIRD RANDALL B , RISCH MICHAEL A , SHIRODKAR PRADEEP P , LIN ZERONG , IACCINO LARRY L
发明人： HAGERTY ROBERT O , CHEE CHIA S , LAIRD RANDALL B , RISCH MICHAEL A , SHIRODKAR PRADEEP P , LIN ZERONG , IACCINO LARRY L
IPC分类号： C08F210/16 , C08F4/69
CPC分类号： C08F210/16 , C08F110/02 , C08F2410/01 , C08F2/06 , C08F2/14 , C08F4/69 , C08F2/002 , C08F2500/20 , C08F2500/12 , C08F210/14
摘要： This invention is directed to processes of making polymer in the presence of a hydrofluorocarbon or perfluorocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and provide polymer products that can be manufactured to relatively low densities. The invention is particularly beneficial in the production of ethylene based polymers using chromium catalyst systems.
摘要翻译：本发明涉及在氢氟烃或全氟化碳存在下制备聚合物并回收聚合物的方法。所提供的方法能够使聚合过程在反应体系中污染最小的情况下实施，并且提供可以制造成相对低密度的聚合物产品。本发明在使用铬催化剂体系生产基于乙烯的聚合物中特别有利。

3. 发明申请

WO2006009946A3 POLYMERIZATION PROCESS 审中-公开
标题翻译：聚合工艺
公开(公告)号：WO2006009946A3
公开(公告)日：2006-04-27
申请号：PCT/US2005021649
申请日：2005-06-20
申请人： EXXONMOBIL CHEM PATENTS INC , HAGERTY ROBERT O , CHEE CHIA S , LAIRD RANDALL B , RISCH MICHAEL A , SHIRODKAR PRADEEP P , LIN ZERONG , IACCINO LARRY L
发明人： HAGERTY ROBERT O , CHEE CHIA S , LAIRD RANDALL B , RISCH MICHAEL A , SHIRODKAR PRADEEP P , LIN ZERONG , IACCINO LARRY L
IPC分类号： C08F210/16 , C08F4/642
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , Y10S526/912 , Y10S526/943 , C08F2/06 , C08F2/14 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/03 , C08F210/08
摘要： This invention is directed to processes of making polymer in the presence of a hydrofluorocarbon or perfluorocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and to the recovery of the hydrofluorocarbon and other hydrocarbons such as hydrocarbons for reuse in the process or hydrocarbon by-products from the polymerization process. The invention is particularly beneficial in the production of ethylene based polymers using bulky ligand metallocene-type catalyst systems.
摘要翻译：本发明涉及在氢氟碳化合物或全氟化碳存在下制备聚合物并回收聚合物的方法。所提供的方法使聚合方法能够在反应体系中以最小的结垢进行聚合反应，以及回收氢氟烃和其它烃，例如在该方法中重新使用的烃或来自聚合方法的烃副产物。本发明在使用大体积配体茂金属型催化剂体系的乙烯基聚合物的生产中特别有益。

4. 发明申请

WO2006068814A3 PRODUCTION OF AROMATIC HYDROCARBONS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳烃
公开(公告)号：WO2006068814A3
公开(公告)日：2006-08-31
申请号：PCT/US2005044042
申请日：2005-12-02
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , FENG XIAOBING , VINCENT MATTHEW J , STAVENS ELIZABETH L
发明人： IACCINO LARRY L , FENG XIAOBING , VINCENT MATTHEW J , STAVENS ELIZABETH L
IPC分类号： C07C2/76 , C10G50/00
CPC分类号： C07C2/76 , C07C15/02
摘要： In a process for converting methane to higher hydrocarbons including aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst under conditions effective to convert said methane to aromatic hydrocarbons and produce a first effluent stream comprising aromatic hydrocarbons and hydrogen, wherein said first effluent stream comprises at least 5 wt % more aromatic hydrocarbons than said feed. At least part of the hydrogen from said first effluent stream is then reacted with an oxygen-containing species, such as carbon dioxide, to produce a second effluent stream having a reduced hydrogen content compared with said first effluent stream.
摘要翻译：在将甲烷转化成包括芳烃的高级烃的方法中，将含甲烷的进料与脱氢环化催化剂在有效将所述甲烷转化成芳烃并产生包含芳烃和氢的第一流出物流的条件下接触，其中所述第一流出物流包含比所述进料多至少5wt％的芳烃。然后将来自所述第一流出物流的氢的至少一部分与含氧物质例如二氧化碳反应，以产生与所述第一流出物流相比具有降低的氢含量的第二流出物流。

5. 发明申请

WO2012078373A8 METHOD AND APPARATUS FOR OBTAINING AROMATICS FROM DIVERSE FEEDSTOCK 审中-公开
标题翻译：用于从多种原料获取芳香剂的方法和设备
公开(公告)号：WO2012078373A8
公开(公告)日：2013-03-21
申请号：PCT/US2011062064
申请日：2011-11-23
申请人： EXXONMOBIL CHEM PATENTS INC , ELLRICH JUSTIN M , STRACK ROBERT D , REBECK JOHN W , GAWLIK A SCOTT , IACCINO LARRY L , WOOD GLENN C , BROWN STEPHEN H
发明人： ELLRICH JUSTIN M , STRACK ROBERT D , REBECK JOHN W , GAWLIK A SCOTT , IACCINO LARRY L , WOOD GLENN C , BROWN STEPHEN H
IPC分类号： C07C2/66 , B01J19/24 , C07C2/08 , C07C2/12 , C07C7/13 , C07C15/08
CPC分类号： C07C2/864 , B01J2219/00006 , C07C5/2729 , C07C5/2767 , C10G55/04 , C10G55/06 , C10G57/005 , C10G2400/30 , C07C15/08
摘要： The process relates to the use of any naphtha-range stream containing a portion of C8+ aromatics combined with benzene, toluene, and other non-aromatics in the same boiling range to produce toluene. By feeding the A8+ containing stream to a dealkylation/transalkylation/cracking reactor to increase the concentration of toluene in the stream, a more suitable feedstock for the methylation reaction can be produced. This stream can be obtained from a variety of sources, including the pygas stream from a steam cracker, "cat naphtha" from a fluid catalytic cracker, or the heavier portion of reformate.
摘要翻译：该方法涉及使用含有一部分C 8+芳族化合物与相同沸程的苯，甲苯和其它非芳族化合物结合的任何石脑油馏分物流来生产甲苯。通过将含有A8 +的物流进料到脱烷基化/烷基转移/裂化反应器中以增加物流中甲苯的浓度，可以产生更适合甲基化反应的原料。该料流可以从各种来源获得，包括来自蒸汽裂化器的热解气流，来自流化催化裂化器的“催化裂化汽油”或重整油的较重部分。

6. 发明申请

WO2012021256A3 METHANE CONVERSION PROCESS 审中-公开
标题翻译：甲烷转化过程
公开(公告)号：WO2012021256A3
公开(公告)日：2012-05-10
申请号：PCT/US2011044359
申请日：2011-07-18
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , DENTON ROBERT D , NORMAN GARTH M , LATTNER JAMES R
发明人： IACCINO LARRY L , DENTON ROBERT D , NORMAN GARTH M , LATTNER JAMES R
IPC分类号： C07C2/84 , C07C2/86 , C07C15/08 , C10L3/06
CPC分类号： C07C2/76 , C07C2529/69 , C10L3/08 , F25J3/0209 , F25J3/0223 , F25J3/0233 , F25J3/0252 , F25J2210/62 , F25J2215/04 , F25J2270/904 , Y02P20/125 , C07C15/04 , C07C15/24
摘要： A process for converting a gaseous hydrocarbon feed comprising methane to an aromatic hydrocarbon is integrated with liquefied natural gas (LNG) and/or pipeline gas production. In the integrated process, the gaseous hydrocarbon feed is supplied to a conversion zone comprising at least one dehydroaromatization catalyst and is contacted with the catalyst under conversion conditions to produce a gaseous effluent stream comprising at least one aromatic compound, unreacted methane and H2. The gaseous effluent stream is then separated into a first product stream comprising said at least one aromatic compound and a second product stream comprising unreacted methane and H2. The second product stream is further separated into a methane-rich stream and a hydrogen-rich stream and at least part of the methane-rich stream is passed to LNG and/or pipeline gas production. The gaseous hydrocarbon feed supplied to the conversion zone has at least one of the following properties: (i) a sulfur level of at least 25 ppm by volume; (ii) a C02 level of at least 50 ppm by volume; and (iii) a dew point of at least 203°K.
摘要翻译：将包含甲烷的气态烃进料转化成芳烃的方法与液化天然气（LNG）和/或管道气生产相结合。在一体化方法中，将气态烃进料供给至包含至少一种脱氢芳烃化催化剂的转化区，并在转化条件下与催化剂接触以产生包含至少一种芳族化合物，未反应甲烷和H 2的气态流出物流。然后将气态流出物流分离成包含所述至少一种芳族化合物的第一产物流和包含未反应的甲烷和H 2的第二产物流。第二产物流进一步分离成富甲烷流和富氢流，至少部分富甲烷流被送到LNG和/或管道气生产。供应到转化区的气态烃进料具有以下特性中的至少一个：（i）至少25ppm体积的硫含量; （ii）至少50ppm体积的CO 2水平; 和（iii）露点至少为203°K。

7. 发明申请

WO2007123977A2 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2007123977A2
公开(公告)日：2007-11-01
申请号：PCT/US2007009538
申请日：2007-04-18
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L , PATT JEREMY J
发明人： IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L , PATT JEREMY J
CPC分类号： C07C2/76 , C07C2529/48 , C10G45/44 , Y02P20/142 , Y02P20/52 , Y10S585/943 , C07C15/04 , C07C15/02
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is supplied to one or more reaction zone(s) containing catalytic material operating under reaction conditions effective to convert at least a portion of the methane to aromatic hydrocarbons; the reaction zone(s) being operated with an inverse temperature profile.
摘要翻译：在将甲烷转化为芳族烃的方法中，含有甲烷的进料被供应到一个或多个反应区，该反应区含有在有效将甲烷的至少一部分转化为芳烃的反应条件下运行的催化材料; 反应区域以反向温度曲线运行。

8. 发明申请

WO2012047401A2 REGENERATION OF METAL-CONTAINING CATALYSTS 审中-公开
标题翻译：含金属催化剂的再生
公开(公告)号：WO2012047401A2
公开(公告)日：2012-04-12
申请号：PCT/US2011049269
申请日：2011-08-26
申请人： EXXONMOBIL CHEM PATENTS INC , CLEM KENNETH R , IACCINO LARRY L , AFEWORKI MOBAE , HENAO JUAN D , SANGAR NEERAJ , ZHENG XIAOBO , DECAUL LORENZO C
发明人： CLEM KENNETH R , IACCINO LARRY L , AFEWORKI MOBAE , HENAO JUAN D , SANGAR NEERAJ , ZHENG XIAOBO , DECAUL LORENZO C
IPC分类号： B01J38/04 , B01J27/28 , B01J29/90 , B01J38/10 , C07C2/86
CPC分类号： C07C2/76 , B01J29/48 , B01J29/90 , B01J38/02 , B01J38/10 , C07C1/12 , C07C2/66 , C07C2/864 , C07C2/865 , C07C5/10 , C07C5/11 , C07C2521/06 , C07C2523/02 , C07C2523/06 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/14 , C07C2523/16 , C07C2523/18 , C07C2523/20 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2527/22 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/60 , C07C2529/65 , C07C2529/70 , C07C2601/14 , C07C2601/16 , C07C2602/26 , C07C2602/28 , C10G50/00 , C10G2300/708 , C10G2400/30 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/24 , C07C11/04 , C07C9/04 , C07C9/06 , C07C15/073 , C07C15/08 , C07C13/18 , C07C13/50 , C07C13/20 , C07C13/48
摘要： In a process for the regeneration of a coked metal-containing catalyst, the coked catalyst is contacted in a regeneration zone with an atmosphere which contains carbon dioxide and carbon monoxide at a temperature of at least 400 °C.
摘要翻译：在用于再生焦化含金属催化剂的方法中，焦化催化剂在再生区与含有二氧化碳和一氧化碳的气氛在至少400℃的温度下接触。

9. 发明申请

WO2008027181A3 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2008027181A3
公开(公告)日：2008-04-24
申请号：PCT/US2007017918
申请日：2007-08-13
申请人： EXXONMOBIL CHEM PATENTS INC , SANGAR NEERAJ , IACCINO LARRY L , JONES JEFFREY P
发明人： SANGAR NEERAJ , IACCINO LARRY L , JONES JEFFREY P
IPC分类号： C07C2/76
CPC分类号： C07C2/76 , C07C2521/04 , C07C2521/08 , C07C2523/06 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2529/40 , C10G50/00 , C10G2300/1025 , C10G2400/30
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions effective to convert the methane to aromatic hydrocarbons. The reaction zone is contained within a reactor and the reactor or an internal component of the reactor has at least one surface that is chemically exposed to the feed and is formed from a refractory material that exhibits a carbon uptake (mass of carbon absorbed per unit of exposed metal surface area) of less than 25 g/m 2 when exposed to mixture of 50vol% methane and 50vol% H 2 at 9000C for 168 hours.
摘要翻译：在将甲烷转化为芳族烃的方法中，在有效将甲烷转化为芳烃的条件下，含有甲烷的进料在反应区中与脱氢环化催化剂接触。反应区包含在反应器内，并且反应器或反应器的内部组分具有化学暴露于进料的至少一个表面，并且由表现出碳吸收的耐火材料形成（每单位面积吸收的碳的质量暴露的金属表面积）当暴露于50体积％甲烷和50体积％H 2 O 3的混合物在900℃下168小时时小于25g / m 2。

10. 发明申请

WO2007127026A3 PRODUCTION OF AROMATICS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳族化合物
公开(公告)号：WO2007127026A3
公开(公告)日：2008-01-17
申请号：PCT/US2007008393
申请日：2007-04-05
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L
发明人： IACCINO LARRY L , SANGAR NEERAJ , STAVENS ELIZABETH L
IPC分类号： C07C2/84
CPC分类号： C07C2/84 , C07C2/76 , C07C2529/48 , Y02P20/584 , Y10S585/943 , C07C15/02 , C07C15/04
摘要： In a process for converting methane to aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst in a reaction zone under conditions including a first maximum temperature effective to convert the methane to aromatic hydrocarbons and generate coke on the catalyst. A portion of the coked catalyst is transferred from the reaction zone to a separate regeneration zone, where the catalyst portion is contacted with a regeneration gas under conditions including a second maximum temperature less than or equal to the first maximum temperature and effective to at least partially remove coke from the catalyst portion. Before being returned to the reaction zone, the regenerated catalyst portion is contacted with a carburizing gas in a catalyst treatment zone separate from the reaction zone at a third maximum temperature less than the first maximum temperature.
摘要翻译：在将甲烷转化为芳烃的方法中，在包括有效将甲烷转化为芳族烃并在催化剂上产生焦炭的第一最高温度的条件下，将含甲烷的进料在反应区中与脱氢环化催化剂接触。焦化催化剂的一部分从反应区转移到单独的再生区，其中催化剂部分在包括第二最高温度小于或等于第一最高温度的条件下与再生气体接触，并有效至少部分地从催化剂部分除去焦炭。在返回到反应区之前，再生的催化剂部分在与反应区分开的催化剂处理区中的渗碳气体在低于第一最高温度的第三最高温度下接触。

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