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1. 发明申请

WO2007092136A2 PROCESS FOR GENERATING ALPHA OLEFIN COMONOMERS 审中-公开
标题翻译：生产α-烯烃共聚物的方法
公开(公告)号：WO2007092136A2
公开(公告)日：2007-08-16
申请号：PCT/US2007001200
申请日：2007-01-17
申请人： EXXONMOBIL CHEM PATENTS INC , LATTNER JAMES R , REIMERS JAY L , WALZER JOHN F JR , BUCHANAN JOHN S , SHAFFER TIMOTHY D , SANKARANARAYANAN KRISHNAN , AJINKYA MILIND B , WOOD STEPHEN M , SKOULIDAS ANASTASIOS
发明人： LATTNER JAMES R , REIMERS JAY L , WALZER JOHN F JR , BUCHANAN JOHN S , SHAFFER TIMOTHY D , SANKARANARAYANAN KRISHNAN , AJINKYA MILIND B , WOOD STEPHEN M , SKOULIDAS ANASTASIOS
IPC分类号： C07F11/00 , C07C2/36 , C08F10/00
CPC分类号： C07C2/32 , C07C2/36 , C07C2531/22 , C07C2531/24 , Y02P20/52 , C07C11/02
摘要： The present invention relates to a method for preparing olefin comonomers from ethylene. The comonomer generated can be used in a subsequent process, such as a polyethylene polymerization reactor. The comonomer generated can be transported, optionally without isolation or storage, to a polyethylene polymerization reactor. One method includes the steps of: feeding ethylene and a catalyst in a solvent/diluent to one or more comonomer synthesis reactors; reacting the ethylene and the catalyst under reaction conditions sufficient to produce an effluent comprising a desired comonomer; forming a gas stream comprising unreacted ethylene, and a liquid/bottoms stream comprising the comonomer, optionally by passing the effluent to one or more downstream gas/liquid phase separators; and purifying at least a portion of said liquid/bottoms stream by removing at least one of solid polymer, catalyst, and undesirable olefins therefrom.
摘要翻译：本发明涉及由乙烯制备烯烃共聚单体的方法。所产生的共聚单体可用于后续工艺，如聚乙烯聚合反应器。产生的共聚单体可以任选地在不分离或储存的情况下输送到聚乙烯聚合反应器中。一种方法包括以下步骤：将乙烯和催化剂在溶剂/稀释剂中加入到一个或多个共聚单体合成反应器中; 在足以产生包含所需共聚单体的流出物的反应条件下使乙烯和催化剂反应; 形成包含未反应乙烯的气流和包含共聚单体的液体/底部料流，任选地使流出物通过一个或多个下游气/液相分离器; 和通过从中除去固体聚合物，催化剂和不希望的烯烃中的至少一种来纯化至少一部分所述液体/塔底物流。

2. 发明申请

WO2011049765A3 PRODUCTION OF PARA-XYLENE BY THE METHYLATION OF BENZENE AND/OR TOLUENE 审中-公开
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：WO2011049765A3
公开(公告)日：2011-09-29
申请号：PCT/US2010052066
申请日：2010-10-08
申请人： EXXONMOBIL CHEM PATENTS INC , LATTNER JAMES R , HAGEMEISTER MARK P , SMALLEY CHRISTOPHER G , STANAT JON E R , BENDER TIMOTHY P , SUGITA MASAAKI , DAVULURI RATHNA P , HAN LU
发明人： LATTNER JAMES R , HAGEMEISTER MARK P , SMALLEY CHRISTOPHER G , STANAT JON E R , BENDER TIMOTHY P , SUGITA MASAAKI , DAVULURI RATHNA P , HAN LU
IPC分类号： C07C2/86 , C07C7/09 , C07C15/08
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, an aromatic feedstock comprising toluene and/or benzene is reacted with methanol under alkylation conditions in a reactor in the presence of a fluidized bed of solid catalyst particles to produce a vapor phase effluent comprising para-xylene, water, unreacted toluene and/or benzene and solid catalyst fines. The vapor phase effluent is contacted with a liquid hydrocarbon quench stream under conditions to condense a minor portion of the vapor phase effluent and produce a condensate which contains at least some of the catalyst fines and which is substantially free of an aqueous phase. The condensate containing said catalyst fines is then separated from the remainder of the vapor phase effluent.
摘要翻译：在生产对二甲苯的方法中，包含甲苯和/或苯的芳族原料在烷基化条件下在反应器中在固体催化剂颗粒的流化床的存在下与甲醇反应，以产生气相流出物，二甲苯，水，未反应的甲苯和/或苯和固体催化剂细粒。使气相流出物在一定条件下与液态烃急冷物流接触，以冷凝小部分气相流出物并产生含有至少一些催化剂细粒并基本上不含水相的冷凝物。然后将含有所述催化剂细粉的冷凝物与剩余的气相流出物分离。

3. 发明申请

WO2007142739A3 SYNTHESIS GAS PRODUCTION AND USE 审中-公开
标题翻译：合成气生产和使用
公开(公告)号：WO2007142739A3
公开(公告)日：2013-08-29
申请号：PCT/US2007009256
申请日：2007-04-13
申请人： EXXONMOBIL CHEM PATENTS INC , JENKINS CHRISTOPHER D W , LATTNER JAMES R , VERAA MICHAEL J , KUECHLER KEITH H
发明人： JENKINS CHRISTOPHER D W , LATTNER JAMES R , VERAA MICHAEL J , KUECHLER KEITH H
IPC分类号： C01B3/38 , C01B3/36 , C07C29/151
CPC分类号： C07C29/1518 , C01B3/36 , C01B3/382 , C01B2203/0244 , C01B2203/025 , C01B2203/061 , C01B2203/063 , C01B2203/0844 , C01B2203/142 , C01B2203/82 , C07C31/04
摘要： A method of producing synthesis gas for methanol synthesis (7) that comprises the steps of: (a) obtaining a hydrogen stream that has greater than 5 mol% methane from an external process; (b) feeding into a reforming reactor (4): (i) a feed gas that comprises methane(l), (ii) water (2) in a specified amount, (Hi) oxygen (3) in a specified amount, and (iv) the hydrogen stream in a specified amount; (c) reacting the feed gas, water, oxygen and the hydrogen stream in the reactor; and (d) withdrawing from the reactor the synthesis gas (5) that is at a specific temperature, has less than 3 mol% methane, and has a stoichiometric number of from 1.9 to 2.3.
摘要翻译：一种生产用于甲醇合成的合成气的方法（7），其包括以下步骤：（a）从外部工艺获得具有大于5mol％甲烷的氢气流; （b）进料到重整反应器（4）中：（i）包含甲烷（1），（ii）规定量的水（2），（ⅰ）规定量的氧（3））的原料气，以及（iv）规定量的氢气流; （c）使反应器中的进料气体，水，氧气和氢气流反应; 和（d）从反应器中排出处于特定温度的合成气（5）具有小于3mol％的甲烷，化学计量数为1.9-2.3。

4. 发明申请

WO2013052216A8 PROCESS FOR PRODUCING PHENOL FROM CYCLOHEXYLBENZENE HYDROPEROXIDE 审中-公开
标题翻译：由环己基苯甲醛氢过氧化物生产苯酚的方法
公开(公告)号：WO2013052216A8
公开(公告)日：2014-01-23
申请号：PCT/US2012052876
申请日：2012-08-29
申请人： EXXONMOBIL CHEM PATENTS INC , KUECHLER KEITH H , LATTNER JAMES R , BECKER CHRISTOPHER L
发明人： KUECHLER KEITH H , LATTNER JAMES R , BECKER CHRISTOPHER L
IPC分类号： C07C37/08 , C07C2/74 , C07C13/28 , C07C37/07 , C07C37/74 , C07C39/04 , C07C45/53 , C07C45/82 , C07C49/403 , C07C409/14
CPC分类号： C07C37/07 , C07C2/74 , C07C37/08 , C07C45/53 , C07C49/403 , C07C407/00 , C07C2529/70 , C07C2601/14 , C07C13/28 , C07C409/14 , C07C39/04
摘要： In a process for producing phenol, cyclohexylbenzene hydroperoxide is cleaved to produce a cleavage effluent stream comprising phenol and cyclohexanone and at least a portion of the cleavage effluent stream is fractionated to produce a first fraction richer in cyclohexanone than the cleavage effluent stream portion and a second fraction richer in phenol and depleted in cyclohexanone as compared with said cleavage effluent stream portion. At least a portion of the second fraction is then contacted with a dehydrogenation catalyst in a dehydrogenation reaction zone under dehydrogenation conditions effective to convert at least a portion of the cyclohexanone in said second fraction portion into phenol and cyclohexanol. In another embodiment, a composition of cyclohexanone (>99 wt%) and impurities of methylcy-clopentanone, cyclohexenol, cyclohexanedione or hydroxycyclohex-anone and cyclohexanol is claimed.
摘要翻译：在生产苯酚的方法中，将环己基苯氢过氧化物切割以产生包含苯酚和环己酮的裂解流出料流，并将至少一部分裂解流出物流分馏以产生比裂解流出物流部分富含环己酮的第一馏分，第二馏分与所述裂解流出物流部分相比，苯酚中的馏分比较富含，耗尽环己酮。然后在有效将至少一部分所述第二级分部分中的环己酮转化成苯酚和环己醇的脱氢条件下，在脱氢反应区中至少一部分第二馏分与脱氢催化剂接触。在另一个实施方案中，要求保护环己酮（> 99重量％）和甲基环戊烯酮，环己烯醇，环己二酮或环己烷酮的杂质的组合物。

5. 发明申请

WO2012036826A3 PROCESSES FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的过程
公开(公告)号：WO2012036826A3
公开(公告)日：2012-05-03
申请号：PCT/US2011047845
申请日：2011-08-16
申请人： EXXONMOBIL CHEM PATENTS INC , KUECHLER KEITH H , BENITEZ FRANCISCO M , WANG KUN , LATTNER JAMES R , BECKER CHRISTOPHER L
发明人： KUECHLER KEITH H , BENITEZ FRANCISCO M , WANG KUN , LATTNER JAMES R , BECKER CHRISTOPHER L
IPC分类号： C07C37/08 , C07C37/88 , C07C39/04 , C07C45/53 , C07C45/86 , C07C49/403 , C07C409/14
CPC分类号： C07C31/08 , C07C2/74 , C07C37/08 , C07C37/86 , C07C45/53 , C07C45/85 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C409/14 , C07C39/04 , C07C49/403
摘要： Disclosed herein are processes for producing phenol. The processes include oxidizing cyclohexylbenzene to produce an oxidation composition comprising cyclohexyl-1 -phenyl- 1- hydroperoxide. The cyclohexyl-1 -phenyl- 1 -hydroperoxide in the oxidation composition may undergo a cleavage reaction to produce a cleavage reaction mixture comprising phenol, cyclohexanone and at least one contaminant. The cleavage reaction mixture may be contacted with a basic material to convert at least a portion of the contaminant to a converted contaminant, thereby producing a modified reaction mixture.
摘要翻译：本文公开了生产苯酚的方法。该方法包括氧化环己基苯以产生包含环己基-1-苯基-1-氢过氧化物的氧化组合物。氧化组合物中的环己基-1-苯基-1-氢过氧化物可经历裂解反应以产生包含苯酚，环己酮和至少一种污染物的裂解反应混合物。裂解反应混合物可以与碱性物质接触以将至少一部分污染物转化为转化的污染物，从而产生改性的反应混合物。

6. 发明申请

WO2011049734A3 PRODUCTION OF PARA-XYLENE BY THE METHYLATION OF BENZENE AND/OR TOLUENE 审中-公开
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：WO2011049734A3
公开(公告)日：2011-08-11
申请号：PCT/US2010051275
申请日：2010-10-04
申请人： EXXONMOBIL CHEM PATENTS INC , LATTNER JAMES R , HAGEMEISTER MARK P , STANAT JON E R , OU JOHN DI-YI , ZHENG XIAOBO , HAN LU
发明人： LATTNER JAMES R , HAGEMEISTER MARK P , STANAT JON E R , OU JOHN DI-YI , ZHENG XIAOBO , HAN LU
IPC分类号： C07C2/86 , B01J8/18 , C07C15/08
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译：在生产对二甲苯的方法中，将甲醇预热至第一温度，将包含甲苯和/或苯的芳族原料预热至第二温度，并将预热的甲醇和芳族原料在第一甲醇与芳香族原料的摩尔比。预热的芳族原料在催化剂存在下在烷基化条件下与预热的甲醇接触，使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。在反应过程中，在反应器内测量温度并与预定的最佳温度进行比较。然后以减少反应器中测量的和预定的最佳温度之间的差异的方式调节甲醇与芳族原料的摩尔比。

7. 发明申请

WO2012082409A8 PROCESS OF PRODUCING CYCLOHEXYLBENZENE 审中-公开
标题翻译：生产环己基苯的方法
公开(公告)号：WO2012082409A8
公开(公告)日：2012-09-13
申请号：PCT/US2011063119
申请日：2011-12-02
申请人： EXXONMOBIL CHEM PATENTS INC , KUECHLER KEITH H , LATTNER JAMES R , BECKER CHRISTOPHER L , DAKKA JIHAD M , CHEN TAN-JEN
发明人： KUECHLER KEITH H , LATTNER JAMES R , BECKER CHRISTOPHER L , DAKKA JIHAD M , CHEN TAN-JEN
IPC分类号： C07C2/74 , C07C5/367 , C07C7/163 , C07C13/28 , C07C15/04
CPC分类号： C07C2/74 , C07C5/367 , C07C6/126 , C07C2521/08 , C07C2523/14 , C07C2523/42 , C07C2601/08 , C07C2601/14 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.
摘要翻译：在生产环己基苯的方法中，苯在加氢烷基化条件下与氢接触，有效形成包含环己基苯，环己烷，甲基环戊烷和未反应的苯的第一流出物料流。至少一部分第一流出物流在脱氢条件下与脱氢催化剂接触以将至少一部分环己烷转化成苯，从而形成第二流出物流。第二流出物流中甲基环戊烷的量相差不超过第一流出物流部分总量的65％，所述量以重量计。从第一或第二流出物流中除去含甲基环戊烷的物流，并将至少一部分含苯的第二流出物物流循环至加氢烷基化步骤。

8. 发明申请

WO2010024975A8 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010024975A8
公开(公告)日：2010-11-18
申请号：PCT/US2009050497
申请日：2009-07-14
申请人： EXXONMOBIL CHEM PATENTS INC , BUCHANAN JOHN SCOTT , STANAT JON E R , CHEN TAN-JEN , DAKKA JIHAD M , LATTNER JAMES R
发明人： BUCHANAN JOHN SCOTT , STANAT JON E R , CHEN TAN-JEN , DAKKA JIHAD M , LATTNER JAMES R
IPC分类号： C07C37/06 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403 , C07C409/08 , C07C409/14
CPC分类号： C07C37/06 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要： In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.
摘要翻译：在生产苯酚的方法中，将环己基苯氧化生产环己基苯氢过氧化物，然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。然后将至少一部分流出物流送入至少一个脱氢反应区，其中流出物流部分与脱氢催化剂在有效地将流出物部分中的至少一部分环己酮转化为酚和氢的条件下接触。

9. 发明申请

WO2008002343A3 PRODUCTION OF AROMATIC HYDROCARBONS AND SYNGAS FROM METHANE 审中-公开
标题翻译：从甲烷生产芳香烃和合成气
公开(公告)号：WO2008002343A3
公开(公告)日：2008-02-14
申请号：PCT/US2007010217
申请日：2007-04-26
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , LATTNER JAMES R
发明人： IACCINO LARRY L , LATTNER JAMES R
IPC分类号： C07C2/76
CPC分类号： C01B3/38 , C01B2203/0233 , C01B2203/062 , C07C2/76 , Y02P20/132 , Y02P20/52 , Y10S585/943 , C07C15/02
摘要： In a process for converting methane to syngas and aromatic hydrocarbons, a feed containing methane is contacted with a dehydrocyclization catalyst under conditions effective to convert said methane to aromatic hydrocarbons and produce a first effluent comprising aromatic hydrocarbons and H 2 , wherein said first effluent comprises at least 5 wt% more aromatic hydrocarbons than said feed. At least part of the H 2 from said first effluent is then reacted with an oxygen- containing species, such as carbon dioxide, to produce a second effluent having an increased H 2 and CO content compared with said first effluent.
摘要翻译：在将甲烷转化成合成气和芳香烃的方法中，使含甲烷的进料与脱氢环化催化剂在有效将所述甲烷转化成芳香烃的条件下接触并产生包含芳香烃和H 2 SO 4的第一流出物，其中所述第一流出物包含比所述进料多至少5重量％的芳烃。然后将来自所述第一流出物的至少一部分H 2与含氧物质例如二氧化碳反应以产生具有增加的H 2 SUB的第二流出物，和CO含量与所述第一流出物相比较。

10. 发明申请

WO2012021256A3 METHANE CONVERSION PROCESS 审中-公开
标题翻译：甲烷转化过程
公开(公告)号：WO2012021256A3
公开(公告)日：2012-05-10
申请号：PCT/US2011044359
申请日：2011-07-18
申请人： EXXONMOBIL CHEM PATENTS INC , IACCINO LARRY L , DENTON ROBERT D , NORMAN GARTH M , LATTNER JAMES R
发明人： IACCINO LARRY L , DENTON ROBERT D , NORMAN GARTH M , LATTNER JAMES R
IPC分类号： C07C2/84 , C07C2/86 , C07C15/08 , C10L3/06
CPC分类号： C07C2/76 , C07C2529/69 , C10L3/08 , F25J3/0209 , F25J3/0223 , F25J3/0233 , F25J3/0252 , F25J2210/62 , F25J2215/04 , F25J2270/904 , Y02P20/125 , C07C15/04 , C07C15/24
摘要： A process for converting a gaseous hydrocarbon feed comprising methane to an aromatic hydrocarbon is integrated with liquefied natural gas (LNG) and/or pipeline gas production. In the integrated process, the gaseous hydrocarbon feed is supplied to a conversion zone comprising at least one dehydroaromatization catalyst and is contacted with the catalyst under conversion conditions to produce a gaseous effluent stream comprising at least one aromatic compound, unreacted methane and H2. The gaseous effluent stream is then separated into a first product stream comprising said at least one aromatic compound and a second product stream comprising unreacted methane and H2. The second product stream is further separated into a methane-rich stream and a hydrogen-rich stream and at least part of the methane-rich stream is passed to LNG and/or pipeline gas production. The gaseous hydrocarbon feed supplied to the conversion zone has at least one of the following properties: (i) a sulfur level of at least 25 ppm by volume; (ii) a C02 level of at least 50 ppm by volume; and (iii) a dew point of at least 203°K.
摘要翻译：将包含甲烷的气态烃进料转化成芳烃的方法与液化天然气（LNG）和/或管道气生产相结合。在一体化方法中，将气态烃进料供给至包含至少一种脱氢芳烃化催化剂的转化区，并在转化条件下与催化剂接触以产生包含至少一种芳族化合物，未反应甲烷和H 2的气态流出物流。然后将气态流出物流分离成包含所述至少一种芳族化合物的第一产物流和包含未反应的甲烷和H 2的第二产物流。第二产物流进一步分离成富甲烷流和富氢流，至少部分富甲烷流被送到LNG和/或管道气生产。供应到转化区的气态烃进料具有以下特性中的至少一个：（i）至少25ppm体积的硫含量; （ii）至少50ppm体积的CO 2水平; 和（iii）露点至少为203°K。

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