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1. 发明申请

WO2012134717A3 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译： VINYL终止的高烯烃聚合物及其生产方法
公开(公告)号：WO2012134717A3
公开(公告)日：2012-11-22
申请号：PCT/US2012027682
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , HOLTCAMP MATTHEW W , HAGADORN JOHN R , RUFF CHARLES J , RODRIGUEZ GEORGE , BRANT PATRICK
发明人： CROWTHER DONNA J , HOLTCAMP MATTHEW W , HAGADORN JOHN R , RUFF CHARLES J , RODRIGUEZ GEORGE , BRANT PATRICK
IPC分类号： C08F210/14 , C08F4/64 , C08F210/06 , C08L23/18 , C10M107/10
CPC分类号： C10M107/10 , C08F4/65908 , C08F4/65925 , C08F4/65927 , C08F210/06 , C08F210/14 , C08L2314/06 , C10M2205/0245 , C10M2205/0265 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/028 , C10N2270/00 , C08F2500/17
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol% of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol% of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7: 1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol以上（通过1 H NMR测定）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

2. 发明申请

WO2012134721A3 VINYL TERMINATED HIGHER OLEFIN POLYMERS AND METHODS TO PRODUCE THEREOF 审中-公开
标题翻译： VINYL终止的高烯烃聚合物及其生产方法
公开(公告)号：WO2012134721A3
公开(公告)日：2012-11-29
申请号：PCT/US2012027690
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HOLTCAMP MATTHEW W , RUFF CHARLES J , CROWTHER DONNA J , HAGADORN JOHN R , BRANT PATRICK
发明人： HOLTCAMP MATTHEW W , RUFF CHARLES J , CROWTHER DONNA J , HAGADORN JOHN R , BRANT PATRICK
IPC分类号： C08F10/14 , C08F4/64 , C08F4/6592 , C08F210/16
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65912 , C08F210/14 , C08F4/65925 , C08F4/65927 , C08F2500/02
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by lR NMR) including of one or more C4 to C4Q higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1MRI测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C4-C4Q高级烯烃衍生单元，其中较高级烯烃乙烯基封端的聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

3. 发明申请

WO2009155517A8 OLEFIN FUNCTIONALIZATION BY METATHESIS REACTION 审中-公开
标题翻译：烯烃反应的烯烃功能化
公开(公告)号：WO2009155517A8
公开(公告)日：2011-03-24
申请号：PCT/US2009047953
申请日：2009-06-19
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , HOLTCAMP MATTHEW W , NARVAEZ ANDREW G , CROWTHER DONNA J , BRANT PATRICK
发明人： HAGADORN JOHN R , HOLTCAMP MATTHEW W , NARVAEZ ANDREW G , CROWTHER DONNA J , BRANT PATRICK
IPC分类号： C08F10/06 , C08F4/64 , C08F10/02
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol% propylene and 10 to 90 mol% of ethylene, wherein the oligomer has at least X% allyl chain ends, where: 1) X = (-0.94 (mole% ethylene incorporated) + 100), when 10 to 60 mole% ethylene is present in the co-oligomer, and 2) X = 45, when greater than 60 and less than 70 mole% ethylene is present in the co-oligomer, and 3) X = (1.83* (mole% ethylene incorporated) -83), when 70 to 90 mole% ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8: 1 to 1.2: 1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中所述低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（摩尔％乙烯掺入）+ 100），当共聚物中存在10至60摩尔％的乙烯 - 低聚物，和2）X = 45，当共聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83 *（摩尔％乙烯加入）-83），当70〜共聚低聚物中存在90摩尔％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

4. 发明申请

WO2012134718A2 AMINE FUNCTIONALIZED POLYOLEFIN AND METHODS FOR PREPARATION THEREOF 审中-公开
标题翻译：胺官能化聚烯烃及其制备方法
公开(公告)号：WO2012134718A2
公开(公告)日：2012-10-04
申请号：PCT/US2012027683
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
发明人： HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F8/32 , C08F4/64 , C08F10/06 , C08L23/36
CPC分类号： C08F8/32 , C08F110/14 , C08F210/06 , C08L23/36 , C08F210/16
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，其包括使过渡金属氨化物催化剂与胺（优选仲胺）和一种或多种乙烯基封端的材料，优选一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制得的胺官能化聚烯烃。

5. 发明申请

WO2009155517A3 OLEFIN FUNCTIONALIZATION BY METATHESIS REACTION 审中-公开
标题翻译：烯烃反应的烯烃功能化
公开(公告)号：WO2009155517A3
公开(公告)日：2010-08-12
申请号：PCT/US2009047953
申请日：2009-06-19
申请人： EXXONMOBIL CHEMICAL PATENT INC , HAGADORN JOHN R , HOLTCAMP MATTHEW W , NARVAEZ ANDREW G , CROWTHER DONNA J , BRANT PATRICK
发明人： HAGADORN JOHN R , HOLTCAMP MATTHEW W , NARVAEZ ANDREW G , CROWTHER DONNA J , BRANT PATRICK
IPC分类号： C08F10/06 , C08F4/64 , C08F10/02
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol% propylene and 10 to 90 mol% of ethylene, wherein the oligomer has at least X% allyl chain ends, where: 1) X = (-0.94 (mole% ethylene incorporated) + 100), when 10 to 60 mole% ethylene is present in the co-oligomer, and 2) X = 45, when greater than 60 and less than 70 mole% ethylene is present in the co-oligomer, and 3) X = (1.83* (mole% ethylene incorporated) -83), when 70 to 90 mole% ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8: 1 to 1.2: 1.0, and less than 100 ppm aluminum.
摘要翻译：本发明涉及官能化丙烯共聚低聚物的方法，包括使烯烃复分解催化剂与含杂原子的烯烃接触，以及丙烯，共聚低聚物，其Mn为300至30,000g / mol，包含10至90mol％的丙烯和10 至90mol％的乙烯，其中所述低聚物具有至少X％的烯丙基链端，其中：1）X =（ - 0.94（摩尔％乙烯掺入）+ 100），当共聚物中存在10至60摩尔％的乙烯时 - 低聚物，和2）X = 45，当共聚物中存在大于60且小于70摩尔％的乙烯时，和3）X =（1.83 *（摩尔％乙烯加入）-83），当70〜共聚低聚物中存在90摩尔％的乙烯。本发明还涉及使丙烯均聚物低聚物官能化的方法，包括使烯烃复分解催化剂与含杂原子的烯烃和包含丙烯的丙烯均聚物接触，其中低聚物具有：至少93％的烯丙基链端，Mn 约500至约20,000g / mol，异丁基链端至烯丙基乙烯基的比例为0.8:1至1.2:1.0，低于100ppm的铝。

6. 发明申请

WO2012134722A3 DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
标题翻译：用交叉法制备的二嵌段共聚物
公开(公告)号：WO2012134722A3
公开(公告)日：2012-12-27
申请号：PCT/US2012027691
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
发明人： HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F10/00 , C08F4/64 , C08F297/08 , C08L23/02 , C08L53/00
CPC分类号： C08G61/08 , C08F297/083 , C08G61/04 , C08G2261/418 , C08L53/00 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R11)(R12)-C(R13)=C(R14)-C(R15)(R16)-PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由下式表示的多嵌段聚烯烃：PO-C（R11）（R12）-C（R13）= C（R14）-C（R15）（R16）-PO *或其异构体，其中R 11，R 12，R 13，R 14，R 15和R 16各自独立地为取代或未取代的C 1至C 4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9-4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13C NMR所示的内不饱和度在约128和约132ppm之间的峰值; 2）Mn比率“Z”= 0.1-10，其中Z是Mn（通过13C NMR测定）除以Mn（根据凝胶渗透色谱法使用聚苯乙烯标准测定）; 和3）任选地，通过1 H NMR谱测定，每1000个碳原子有0.3（J）和0.75（J）的内部不饱和度，其中J是乙烯基封端的聚烯烃混合物每1000个碳原子的反应基团数量，其变为PO和PO *，在它们通过烯烃复分解催化剂偶联之前。

7. 发明申请

WO2012134716A8 BLOCK COPOLYMERS FROM SILYLATED VINYL TERMINATED MACROMERS 审中-公开
标题翻译：苯乙烯封端的MACROMERS嵌段共聚物
公开(公告)号：WO2012134716A8
公开(公告)日：2013-10-03
申请号：PCT/US2012027677
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
发明人： CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
IPC分类号： C08F8/00 , B01J31/12 , C07F7/00 , C08F10/00
CPC分类号： C08F8/42 , C08F299/00 , C08F2810/40 , C08F10/00
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a metallocene catalyst with a difunctional diblock hydrosilane, and one or more vinyl terminated polyolefins. This invention further relates to the diblock hydrosilane-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，包括使茂金属催化剂与双官能二嵌段氢化硅烷和一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制备的二嵌段氢硅烷官能化的聚烯烃。

8. 发明申请

WO2012134719A3 NOVEL CATALYSTS AND METHODS OF USE THEREOF TO PRODUCE VINYL TERMINATED POLYMERS 审中-公开
标题翻译：新型催化剂及其制备乙烯基终端聚合物的方法
公开(公告)号：WO2012134719A3
公开(公告)日：2012-11-22
申请号：PCT/US2012027685
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , BRANT PATRICK , DE GRACIA CARLOS U , LOVELL JACQUELINE A
发明人： CROWTHER DONNA J , BRANT PATRICK , DE GRACIA CARLOS U , LOVELL JACQUELINE A
IPC分类号： C08F4/6592 , C08F10/06 , C08L23/10
CPC分类号： C08F10/06 , C08F4/65908 , C08L2314/06 , C08F210/06 , C08F210/16 , C08F2500/03 , C08F4/65927
摘要： This invention relates to a homogenous process for making a vinyl terminated propylene polymer, wherein the process comprises: contacting, propylene, under polymerization conditions, with a catalyst system comprising an activator and at least one metallocene compound, where the metallocene compound is represented by the formula (I) where: M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, dienes, amines, phosphines, ethers, and a combination thereof, (two X's may form a part of a fused ring or a ring system); each R1 is, independently, a C1 Cto C10 alkyl group; each R2 is, independently, a C1 to C10 alkyl group; each R3 is, independently, hydrogen; each R4, R5, and R6, is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, a heteroatom or heteroatom containing group; T is a bridging group; each R7 is, independently, hydrogen, halogen, or a C1 to C20 hydrocarbyl, and two R7 can form a cyclic structure including aromatic, partially saturated, or saturated cyclic or fused ring system; and further provided that any of adjacent R4, R5, and R6 groups may form a fused ring or multicenter fused ring system where the rings may be aromatic, partially saturated or saturated.
摘要翻译：本发明涉及一种用于制备乙烯基封端的丙烯聚合物的均匀方法，其中该方法包括：在聚合条件下使丙烯与包含活化剂和至少一种金属茂化合物的催化剂体系接触，其中茂金属化合物由式（I）其中：M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤化物，二烯，胺，膦，醚及其组合（两个X的可形成稠环或环系的一部分）; 每个R 1独立地为C 1 -C 10烷基; 每个R 2独立地为C 1至C 10烷基; 每个R 3独立地是氢; 每个R 4，R 5和R 6独立地是氢或取代或未取代的烃基，含杂原子或杂原子的基团; T是一个桥接组; 每个R 7独立地是氢，卤素或C 1至C 20烃基，并且两个R 7可以形成包括芳族，部分饱和或饱和的环状或稠环体系的环状结构; 并且进一步规定相邻的R 4，R 5和R 6基团中的任何一个可以形成稠合环或多中心稠环体系，其中所述环可以是芳族的，部分饱和的或饱和的。

9. 发明申请

WO2012134719A8 NOVEL CATALYSTS AND METHODS OF USE THEREOF TO PRODUCE VINYL TERMINATED POLYMERS 审中-公开
标题翻译：新型催化剂及其制备乙烯基终端聚合物的方法
公开(公告)号：WO2012134719A8
公开(公告)日：2014-03-27
申请号：PCT/US2012027685
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , BRANT PATRICK , DE GRACIA CARLOS U , LOVELL JACQUELINE A
发明人： CROWTHER DONNA J , BRANT PATRICK , DE GRACIA CARLOS U , LOVELL JACQUELINE A
IPC分类号： C08F4/6592 , C08F10/06 , C08L23/10
CPC分类号： C08F10/06 , C08F4/65908 , C08L2314/06 , C08F210/06 , C08F210/16 , C08F2500/03 , C08F4/65927
摘要： This invention relates to a homogenous process for making a vinyl terminated propylene polymer, wherein the process comprises: contacting, propylene, under polymerization conditions, with a catalyst system comprising an activator and at least one metallocene compound, where the metallocene compound is represented by the formula (I) where: M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halides, dienes, amines, phosphines, ethers, and a combination thereof, (two X's may form a part of a fused ring or a ring system); each R1 is, independently, a C1 Cto C10 alkyl group; each R2 is, independently, a C1 to C10 alkyl group; each R3 is, independently, hydrogen; each R4, R5, and R6, is, independently, hydrogen or a substituted or unsubstituted hydrocarbyl group, a heteroatom or heteroatom containing group; T is a bridging group; each R7 is, independently, hydrogen, halogen, or a C1 to C20 hydrocarbyl, and two R7 can form a cyclic structure including aromatic, partially saturated, or saturated cyclic or fused ring system; and further provided that any of adjacent R4, R5, and R6 groups may form a fused ring or multicenter fused ring system where the rings may be aromatic, partially saturated or saturated.
摘要翻译：本发明涉及一种用于制备乙烯基封端的丙烯聚合物的均匀方法，其中该方法包括：在聚合条件下使丙烯与包含活化剂和至少一种金属茂化合物的催化剂体系接触，其中茂金属化合物由式（I）其中：M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤化物，二烯，胺，膦，醚及其组合（两个X的可形成稠环或环系的一部分）; 每个R 1独立地为C 1 -C 10烷基; 每个R 2独立地为C 1至C 10烷基; 每个R 3独立地是氢; 每个R 4，R 5和R 6独立地是氢或取代或未取代的烃基，含杂原子或杂原子的基团; T是一个桥接组; 每个R 7独立地是氢，卤素或C 1至C 20烃基，并且两个R 7可以形成包括芳族，部分饱和或饱和的环状或稠环体系的环状结构; 并且进一步规定相邻的R 4，R 5和R 6基团中的任何一个可以形成稠合环或多中心稠环体系，其中所述环可以是芳族的，部分饱和的或饱和的。

10. 发明申请

WO2012134726A3 HYDROSILYATION OF VINYL MACROMERS WITH METALLOCENES 审中-公开
标题翻译：用金属离子水解乙烯基大分子
公开(公告)号：WO2012134726A3
公开(公告)日：2012-11-22
申请号：PCT/US2012027710
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
发明人： CROWTHER DONNA J , LOVELL JACQUELINE A , BRANT PATRICK
IPC分类号： C08F8/00 , C08F4/656 , C08F8/42 , C08F10/00 , C08L23/26
CPC分类号： C08F8/00 , C08F4/65908 , C08F4/65927 , C08F8/42 , C08F10/00 , C08L23/26
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a metallocene catalyst with a hydrosilane, and one or more vinyl terminated polyolefins. This invention further relates to the hydrosilane- functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，其包括使茂金属催化剂与氢硅烷和一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制得的氢硅烷官能化聚烯烃。

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