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1. 发明申请

WO2012134720A3 ENHANCED CATALYST PERFORMANCE FOR PRODUCTION OF VINYL TERMINATED PROPYLENE AND ETHYLENE/PROPYLENE MACROMERS 审中-公开
标题翻译：生产乙烯终端丙烯和乙烯/丙烯大型催化剂的催化剂性能增强
公开(公告)号：WO2012134720A3
公开(公告)日：2012-11-22
申请号：PCT/US2012027688
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , CROWTHER DONNA J , GANESH RENUKA N , NARVAEZ ANDREW G JR , BRANT PATRICK
发明人： CROWTHER DONNA J , GANESH RENUKA N , NARVAEZ ANDREW G JR , BRANT PATRICK
IPC分类号： C08F8/00 , B01J31/12 , C07F7/00 , C08F10/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F210/06 , C08F210/16 , C08F2500/03 , C08F4/65925
摘要： This invention relates to a transition metal catalyst compound represented by structure (A); wherein M is hafnium or zirconium; each X is, independently, selected from the group consisting of hydrocarbyl radicals having from 1 to 20 carbon atoms, hydrides, amides, alkoxides, sulfides, phosphides, halogens, dienes, amines, phosphines, ethers, or a combination thereof; each R1 and R3 are, independently, a C1 to C8 alkyl group; and each R2, R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, and R14 are, independently, hydrogen, or a substituted or unsubstituted hydrocarbyl group having from 1 to 8 carbon atoms, provided however that at least three of the R10-R14 groups are not hydrogen, compositions thereof and methods of use thereof to prepare polymers.
摘要翻译：本发明涉及由结构（A）表示的过渡金属催化剂化合物; 其中M是铪或锆; 每个X独立地选自具有1至20个碳原子的烃基，氢化物，酰胺，醇盐，硫化物，磷化物，卤素，二烯，胺，膦，醚或其组合; 每个R 1和R 3独立地为C 1 -C 8烷基; 并且每个R 2，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11，R 12，R 13和R 14独立地为氢或具有1至8个碳原子的取代或未取代的烃基，至少三个R10-R14基团不是氢，其组合物及其用于制备聚合物的方法。

2. 发明申请

WO2012134718A2 AMINE FUNCTIONALIZED POLYOLEFIN AND METHODS FOR PREPARATION THEREOF 审中-公开
标题翻译：胺官能化聚烯烃及其制备方法
公开(公告)号：WO2012134718A2
公开(公告)日：2012-10-04
申请号：PCT/US2012027683
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
发明人： HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F8/32 , C08F4/64 , C08F10/06 , C08L23/36
CPC分类号： C08F8/32 , C08F110/14 , C08F210/06 , C08L23/36 , C08F210/16
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及使聚烯烃官能化的方法，其包括使过渡金属氨化物催化剂与胺（优选仲胺）和一种或多种乙烯基封端的材料，优选一种或多种乙烯基封端的聚烯烃接触。本发明还涉及由此制得的胺官能化聚烯烃。

3. 发明申请

WO2012134722A3 DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
标题翻译：用交叉法制备的二嵌段共聚物
公开(公告)号：WO2012134722A3
公开(公告)日：2012-12-27
申请号：PCT/US2012027691
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
发明人： HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F10/00 , C08F4/64 , C08F297/08 , C08L23/02 , C08L53/00
CPC分类号： C08G61/08 , C08F297/083 , C08G61/04 , C08G2261/418 , C08L53/00 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R11)(R12)-C(R13)=C(R14)-C(R15)(R16)-PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.
摘要翻译：本发明涉及一种组合物，其包含由下式表示的多嵌段聚烯烃：PO-C（R11）（R12）-C（R13）= C（R14）-C（R15）（R16）-PO *或其异构体，其中R 11，R 12，R 13，R 14，R 15和R 16各自独立地为取代或未取代的C 1至C 4烃基或氢; PO和PO *是聚烯烃; PO和PO *各自独立地为具有9-4000个碳原子的取代或未取代的烃基，条件是PO和PO *中的至少一个为C20或更大，所述聚烯烃具有：1）如13C NMR所示的内不饱和度在约128和约132ppm之间的峰值; 2）Mn比率“Z”= 0.1-10，其中Z是Mn（通过13C NMR测定）除以Mn（根据凝胶渗透色谱法使用聚苯乙烯标准测定）; 和3）任选地，通过1 H NMR谱测定，每1000个碳原子有0.3（J）和0.75（J）的内部不饱和度，其中J是乙烯基封端的聚烯烃混合物每1000个碳原子的反应基团数量，其变为PO和PO *，在它们通过烯烃复分解催化剂偶联之前。

4. 发明申请

WO2011056884A2 CARBENE COMPLEXES OF LITHIUM AND/OR MAGNESIUM METAL SALTS, AND USES THEREOF 审中-公开
标题翻译：锂和/或镁金属盐的碳复合物及其用途
公开(公告)号：WO2011056884A2
公开(公告)日：2011-05-12
申请号：PCT/US2010055313
申请日：2010-11-03
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , HOLTCAMP MATTHEW W , BEDOYA MATTHEW S , GANESH RENUKA N
发明人： HAGADORN JOHN R , HOLTCAMP MATTHEW W , BEDOYA MATTHEW S , GANESH RENUKA N
IPC分类号： C07F1/02 , B01J31/22 , C07C2/34 , C07C11/00 , C07F3/02
CPC分类号： C07F15/0046 , B01J31/2269 , B01J31/2273 , B01J31/2278 , B01J2231/543 , B01J2531/0205 , B01J2531/11 , B01J2531/22 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C2531/22 , C07C11/02 , C07C69/533
摘要： This invention relates to a carbene complex of metal salt represented by the formula: [T-M(R)c]n wherein, R is a monoanionic group; c is 1 or 2; M is a Li or Mg; T is a cyclic carbene ligand; and n is selected from the group of integers comprising 1 to 24 wherein the complex has 50% or less decomposition when stored in 0.01 molar benzene at 23°C for a period of 1 hour. This invention also relates to transition-metal-carbene complexes prepared from such carbene complexes of metal salts, where the transition-metal-carbene complex is represented by the formula: [M*(T)(L0)q(L1-)s(L2-)t]g, where M* is a transition metal from Group 6, 7, 8, 9, 10, 11 or 12, T is a cyclic carbene ligand, L0 is a neutral ligand, L1- is a monoanionic ligand, L2- is a dianionic ligand, q is 0, 1, 2, 3 or 4, s is 0, 1, 2, 3, or 4, t is 0, 1, 2, 3,or 4, g is the overall charge of the molecule. The transition-metal-carbene complexes may be used for synthesis reactions, including metathesis of olefins.
摘要翻译：本发明涉及由式[T-M（R）c] n表示的金属盐的卡宾络合物，其中R是单阴离子基团; c为1或2; M是Li或Mg; T是环卡宾配体; 并且n选自包含1至24的整数组，其中当在23℃下在0.01摩尔苯中储存1小时时，所述络合物具有50％或更少的分解。本发明还涉及由金属盐的这种卡宾络合物制备的过渡金属 - 卡宾络合物，其中过渡金属 - 卡宾络合物由下式表示：[M *（T）（L0）q（L1-）s L2-）t] g，其中M *是第6,7,8,9,10,11或12族的过渡金属，T是环卡宾配体，L 0是中性配体，L1-是单阴离子配体， L2-是二阴离子配体，q是0,1,2,3或4，s是0,1,2,3或4，t是0,1,2,3或4，g是总电荷的分子。过渡金属 - 卡宾络合物可用于合成反应，包括烯烃的复分解。

5. 发明申请

WO2012134613A2 PYRIDYLDIAMIDO TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
标题翻译： PYRIDYLDIAMIDO过渡金属复合物，生产和使用
公开(公告)号：WO2012134613A2
公开(公告)日：2012-10-04
申请号：PCT/US2012022473
申请日：2012-01-25
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , GANESH RENUKA N , UBORSKY DMITRY V , BORISOV IIYA S , PRUSS IVAN V , VOSKOBOYNIKOV ALEXANDER Z
发明人： HAGADORN JOHN R , GANESH RENUKA N , UBORSKY DMITRY V , BORISOV IIYA S , PRUSS IVAN V , VOSKOBOYNIKOV ALEXANDER Z
IPC分类号： C07F7/28 , C07F3/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F13/00
CPC分类号： C07F7/006 , B01J31/143 , B01J31/146 , B01J31/1815 , B01J31/183 , B01J2531/0241 , B01J2531/0297 , B01J2531/48 , B01J2531/49 , C07D213/38 , C07D213/48 , C07D213/53 , C07F7/00 , C07F7/003 , C08F10/00 , C08F110/06 , C08F210/16 , C08F2500/03 , C08F210/14 , C08F4/64148 , C08F4/64144
摘要： Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization.
摘要翻译：公开了用于烯烃聚合的吡啶基二酰氨基过渡金属络合物。

6. 发明申请

WO2009061678A8 HALOGEN SUBSTITUTED HETEROCYCLIC HETEROATOM CONTAINING LIGANDS-ALUMOXANE ACTIVATION OF METALLOCENES 审中-公开
标题翻译：含卤素 - 金属氧化物的卤化物取代的杂环异构体
公开(公告)号：WO2009061678A8
公开(公告)日：2010-07-29
申请号：PCT/US2008082066
申请日：2008-10-31
申请人： EXXONMOBIL CHEM PATENTS INC , HOLTCAMP MATTHEW W , GANESH RENUKA N
发明人： HOLTCAMP MATTHEW W , GANESH RENUKA N
IPC分类号： C08F4/659 , C08F4/602 , C08F110/06
CPC分类号： C08F10/06 , C08F110/06 , C08F4/65912 , C08F2500/03 , C08F2500/15 , C08F2500/12
摘要： This invention relates to an activator, catalyst system, and the use thereof. In one aspect, the catalyst system includes one or more polymerization catalysts and at least one activator. The activator comprises one or more heterocyclic heteroatom containing ligands coordinated to an alumoxane, wherein the activator is a reaction product of one or more alumoxanes and one or more heterocyclic heteroatom containing compounds, the one or more heterocyclic heteroatom containing ligands represented by the formula: where Y is O, S, PH or NH; wherein each substituent X2, X3, X4, X5, X6, and X7 is independently selected from the group consisting of hydrogen, chlorine, fluorine, iodine, and bromine, provided at least one of X2, X3, X4, X5, X6 and X7 is not hydrogen when Y is NH; and wherein the ratio of the heterocyclic heteroatom containing ligand to aluminum is between about 0.01 and about 10 molar equivalents. The catalyst system may be supported or non-supported.
摘要翻译：本发明涉及一种活化剂，催化剂体系及其用途。一方面，催化剂体系包括一种或多种聚合催化剂和至少一种活化剂。活化剂包含一个或多个与铝氧烷配位的杂环杂原子的配位体，其中活化剂是一种或多种铝氧烷和一种或多种含杂环杂原子的化合物的反应产物，一种或多种含杂原子的含有配体由下式表示：其中 Y是O，S，PH或NH; 其中每个取代基X 2，X 3，X 4，X 5，X 6和X 7独立地选自氢，氯，氟，碘和溴，条件是X 2，X 3，X 4，X 5，X 6和X 7中的至少一个当Y为NH时不是氢; 并且其中所述含杂原子的配体与铝的比例在约0.01至约10摩尔当量之间。催化剂体系可以被支持或不支持。

8. 发明公开

EP2688921A4 DIBLOCK COPOLYMERS PREPARED BY CROSS METATHESIS 审中-公开
标题翻译：通过交叉复分解生产的二嵌段
公开(公告)号：EP2688921A4
公开(公告)日：2015-02-25
申请号：EP12764240
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC
发明人： HAGADORN JOHN R , RUFF CHARLES J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F299/00 , C08G81/02
CPC分类号： C08G61/08 , C08F297/083 , C08G61/04 , C08G2261/418 , C08L53/00 , C08L65/00
摘要： This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO-C(R11)(R12)-C(R13)=C(R14)-C(R15)(R16)-PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio "Z" = 0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.75(J) internal unsaturations per 1000 carbons as determined by 1H NMR spectroscopy, where J is the number of reactive groups per 1000 carbons for the mixture of vinyl terminated polyolefins that become PO and PO*, before they are coupled by an alkene metathesis catalyst.

9. 发明公开

EP2688918A4 ENHANCED CATALYST PERFORMANCE FOR PRODUCTION OF VINYL TERMINATED PROPYLENE AND ETHYLENE/PROPYLENE MACROMERS 失效
标题翻译：改进的性能催化剂的乙烯基封端的丙烯和乙烯/ PROPYLENMAKROMEREN的制造
公开(公告)号：EP2688918A4
公开(公告)日：2014-12-10
申请号：EP12763722
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC
发明人： CROWTHER DONNA J , GANESH RENUKA N , NARVAEZ ANDREW G JR , BRANT PATRICK
IPC分类号： C08F4/6592 , C08F10/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F210/06 , C08F210/16 , C08F2500/03 , C08F4/65925

10. 发明公开

EP2688920A4 AMINE FUNCTIONALIZED POLYOLEFIN AND METHODS FOR PREPARATION THEREOF 有权
标题翻译：胺用于生产功能化聚烯烃和过程
公开(公告)号：EP2688920A4
公开(公告)日：2015-03-04
申请号：EP12765215
申请日：2012-03-05
申请人： EXXONMOBIL CHEM PATENTS INC
发明人： HAGADORN JOHN R , CROWTHER DONNA J , GANESH RENUKA N , BRANT PATRICK
IPC分类号： C08F8/32 , C08C19/22
CPC分类号： C08F8/32 , C08F110/14 , C08F210/06 , C08L23/36 , C08F210/16
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.

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