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1. 发明申请

WO2009067331A2 CATALYST REGENERATION PROCESS 审中-公开
标题翻译：催化再生过程
公开(公告)号：WO2009067331A2
公开(公告)日：2009-05-28
申请号：PCT/US2008082352
申请日：2008-11-04
申请人： EXXONMOBIL CHEM PATENTS INC , LEVIN DORON , BEECH JAMES H , KWOK SELMA , STEINHEIDER JULIA E
发明人： LEVIN DORON , BEECH JAMES H , KWOK SELMA , STEINHEIDER JULIA E
IPC分类号： B01J29/00 , B01J29/90
CPC分类号： B01J29/90 , B01J29/06 , B01J29/7034 , B01J29/74 , B01J29/78 , B01J38/20 , B01J2229/42
摘要： This disclosure relates to a process for regenerating a catalyst composition, wherein the catalyst composition comprising a molecular sieve and at least 10 wt.% coke having a C/H ratio in the range of 0.26 to 5, the process comprising (a) contacting the catalyst composition with a first oxidative medium having oxygen and water at first conditions sufficient to form a first regenerated catalyst composition having at least 50 wt.% less coke than the catalyst composition; and then (b) contacting at least a portion of the first regenerated catalyst composition with a second oxidative medium having oxygen, and optionally water, at second conditions sufficient to form a second regenerated catalyst composition having at least 50 wt% less coke than the first regenerated catalyst composition, wherein the catalyst composition in step (a) and the first regenerated catalyst in step (b) have contacted total amount of water in the range of 1 to 50 weight water per weight of the second regenerated catalyst composition.
摘要翻译：本公开涉及一种用于再生催化剂组合物的方法，其中所述催化剂组合物包含分子筛和至少10重量％的C / H比在0.26至5的范围内的焦炭，所述方法包括（a）使催化剂组合物，其具有在第一条件下具有氧和水的第一氧化介质，足以形成具有比催化剂组合物少至少50重量％的焦炭的第一再生催化剂组合物; 然后（b）在足以形成第二再生催化剂组合物的第二条件下使至少一部分第一再生催化剂组合物与具有氧的第二氧化介质和任选的水接触，所述第二再生催化剂组合物的焦炭比第一再生催化剂组合物少至少50重量％再生催化剂组合物，其中步骤（a）中的催化剂组合物和步骤（b）中的第一再生催化剂已经接触每重量第二再生催化剂组合物的1至50重量％水的总量。

2. 发明申请

WO2013052217A3 TERNARY MIXED METAL OXIDE CATALYSTS CONSISTING OF ZR- W- AND CE- OXIDES AND USE THEREOF 审中-公开
标题翻译：包含ZR-W和CE-氧化物的三元混合金属氧化物催化剂及其用途
公开(公告)号：WO2013052217A3
公开(公告)日：2013-08-15
申请号：PCT/US2012052878
申请日：2012-08-29
申请人： EXXONMOBIL CHEM PATENTS INC , WANG KUN , GARCIA ROBERTO , SMITH CHARLES M , LEVIN DORON , VARTULI JAMES C
发明人： WANG KUN , GARCIA ROBERTO , SMITH CHARLES M , LEVIN DORON , VARTULI JAMES C
IPC分类号： B01J23/30 , B01J21/06 , B01J23/00 , B01J37/00 , B01J37/03 , B01J37/06 , C07C39/04
CPC分类号： C07C37/08 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/30 , B01J37/009 , B01J37/036 , B01J37/06 , C07C2/66 , C07C45/53 , C07C407/00 , C07C2529/70 , Y02P20/52 , C07C39/04 , C07C49/403
摘要： Disclosed herein are catalyst compositions useful in selective decomposition of organic oxygenates. A feed comprising an organic oxygenate may be contacted with a catalyst comprising (a) at least 0.1 wt% of an oxide of an element selected from Group 3 of the Periodic Table of Elements, wherein Group 3 includes the Lanthanide series; (b) at least 0.1 wt% of an oxide of an element selected trom Group 6 of the Periodic Table of Elements; and (c) at least 0.1 wt.% of an oxide of at least one element selected from Group 4 of the Periodic Table of Elements, wherein the wt%s are based upon the total combined weight of the oxides in (a) through (c) and excludes any other components.
摘要翻译：本文公开了可用于选择性分解有机含氧化合物的催化剂组合物。包含有机含氧化合物的进料可以与催化剂接触，所述催化剂包含（a）至少0.1重量％的选自元素周期表第3族元素的氧化物，其中第3族包括镧系; （b）至少0.1重量％的选自元素周期表第6族元素的元素的氧化物; 和（c）至少0.1重量％的选自元素周期表第4族中的至少一种元素的氧化物，其中wt％基于（a）至（a）中的氧化物的总重量， c）并排除任何其他组成部分。

3. 发明申请

WO2011133326A2 XYLENES ISOMERIZATION PROCESS AND CATALYST THEREFOR 审中-公开
标题翻译： XYLENES异构化方法及其催化剂
公开(公告)号：WO2011133326A2
公开(公告)日：2011-10-27
申请号：PCT/US2011031445
申请日：2011-04-06
申请人： EXXONMOBIL CHEM PATENTS INC , OU JOHN D Y , ROSS APRIL D , LEVIN DORON , KALYANARAMAN MOHAN , LAI WENYIH F
发明人： OU JOHN D Y , ROSS APRIL D , LEVIN DORON , KALYANARAMAN MOHAN , LAI WENYIH F
IPC分类号： C07C5/27 , B01J29/40 , B01J29/70 , C07C15/08
CPC分类号： B01J29/40 , B01J29/70 , B01J29/90 , B01J38/10 , C07C5/2737 , C07C2529/40 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/08
摘要： The invention concerns a xylenes isomerization process for the production of equilibrium or near-equilibrium xylenes. The process utilizes a catalyst comprising HZSM-5 or MCM-49 and process conditions including a temperature of less than 295°C and a pressure sufficient to maintain the xylenes in liquid phase. In embodiments, the process can be operated in a continuous mode with ppm levels of dissolved H2 in the feed and in other embodiments in a cyclic mode without the H2 in feed but with periodic regenerations using a feed having low ppm levels of H2.
摘要翻译：本发明涉及用于产生平衡或近平衡二甲苯的二甲苯异构化方法。该方法使用包含HZSM-5或MCM-49的催化剂和包括低于295℃的温度和足以将二甲苯保持在液相中的压力的工艺条件。在实施方案中，该方法可以在进料中的ppm水平的溶解的H 2以及其它实施方案中以循环模式以不含进料中的H 2的连续模式操作，而是使用具有低ppm水平的H 2的进料进行周期性再生。

4. 发明申请

WO2011097003A3 TRANSALKYLATION OF HEAVY AROMATIC HYDROCARBON FEEDSTOCKS 审中-公开
标题翻译：重质芳烃烃原料的转移
公开(公告)号：WO2011097003A3
公开(公告)日：2011-10-27
申请号：PCT/US2010061308
申请日：2010-12-20
申请人： EXXONMOBIL CHEM PATENTS INC , LEVIN DORON , ROSS APRIL D , BEECH JAMES H
发明人： LEVIN DORON , ROSS APRIL D , BEECH JAMES H
IPC分类号： C07C6/12 , B01J29/40 , B01J29/65 , C07C15/08
CPC分类号： B01J8/04 , B01J29/064 , B01J29/072 , B01J29/076 , B01J29/44 , B01J29/46 , B01J29/7034 , B01J29/7669 , B01J35/0006 , B01J35/023 , B01J37/0009 , B01J37/20 , B01J2229/42 , C07C6/12 , C07C2529/42 , Y02P20/52 , C07C15/08
摘要： In a process for producing xylene by transalkylation of a C9+ aromatic hydrocarbon feedstock with a C6 and/or C7 aromatic hydrocarbon, the C9+ aromatic hydrocarbon feedstock, at least one C6 and/or C7 aromatic hydrocarbon and hydrogen are contacted with a first catalyst comprising (i) a first molecular sieve having a Constraint Index in the range of about 3 to about 12 and (ii) at least first and second different metals or compounds thereof of Groups 6 to 12 of the Periodic Table of the Elements. Contacting with the first catalyst is conducted under conditions effective to dealkylate aromatic hydrocarbons in the feedstock containing C2+ alkyl groups and to saturate C2+ olefins formed so as to produce a first effluent. At least a portion of the first effluent is then contacted with a second catalyst comprising a second molecular sieve having a Constraint Index less than 3 under conditions effective to transalkylate C9+ aromatic hydrocarbons with said at least one C6-C7 aromatic hydrocarbon to form a second effluent comprising xylene.
摘要翻译：在通过用C 6和/或C 7芳烃对C 9+芳烃原料进行烷基转移来制备二甲苯的方法中，使C 9+芳烃原料，至少一种C 6和/或C 7芳烃和氢气与包含 i）具有约3至约12的约束指数的第一分子筛和（ii）元素周期表第6-12族的至少第一和第二不同金属或其化合物。与第一催化剂的接触在有效使含C2 +烷基的原料中的芳烃脱烷基化并使所形成的C2 +烯烃饱和以产生第一流出物的条件下进行。然后使至少一部分第一流出物与第二催化剂接触，所述第二催化剂包含约束指数小于3的第二分子筛，在有效使C 9+芳族烃与所述至少一种C 6 -C 7芳族烃进行烷基转移的条件下形成第二流出物包含二甲苯。

5. 发明申请

WO2008018972A3 PROCESS FOR OXIDIZING ALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：氧化烷基化合物的方法
公开(公告)号：WO2008018972A3
公开(公告)日：2008-03-27
申请号：PCT/US2007016042
申请日：2007-07-13
申请人： EXXONMOBIL CHEM PATENTS INC , DAKKA JIHAD M , LEVIN DORON , BUCHANAN JOHN S , STANAT JON E
发明人： DAKKA JIHAD M , LEVIN DORON , BUCHANAN JOHN S , STANAT JON E
IPC分类号： C07C409/08 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/04 , C07C49/10 , C07C407/00
CPC分类号： C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/10 , C07C49/04 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing alkylaromatic compounds to the corresponding hydroperoxide, an alkylaromatic compound of general formula (I): in which R 1 and R 2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R 1 and R 2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R 3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of an added catalyst comprising tert-butyl hydroperoxide and in the absence of any other catalyst, to produce a hydroperoxide of general formula (II): in which R 1 , R 2 and R 3 have the same meaning as in formula (I). The hydroperoxide may then be converted into a phenol and a ketone of the general formula R 1 COCH2R 2 (III), in which R 1 and R 2 have the same meaning as in formula (I).
摘要翻译：在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有如果R 1和R 2可以连接形成具有4至10个碳原子的环状基团，则所述环状基团任选被取代，R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基与氧在含叔丁基过氧化氢的加成催化剂存在下与氧接触，不存在任何其它催化剂，以产生通式（II）的氢过氧化物：其中R 1，R 2和R 3 3具有与式（I）中相同的含义。然后将氢过氧化物转化为酚和通式为R 1 COCH 2 R 2（III）的酮，其中R 1和 R 2具有与式（I）中相同的含义。

6. 发明申请

WO2004045762A8 MULTI-COMPONENT MOLECULAR SIEVE CATALYST COMPOSITIONS, THEIR PREPARATION AND THEIR USE IN ALKYLATION REACTIONS 审中-公开
标题翻译：多组分分子筛催化剂组合物，其制备及其在烷基化反应中的应用
公开(公告)号：WO2004045762A8
公开(公告)日：2005-03-24
申请号：PCT/US0332894
申请日：2003-10-17
申请人： EXXONMOBIL CHEM PATENTS INC , DAKKA JIHAD , VARTULI JAMES C , BUCHANAN JOHN S , SANTIESTEBAN JOSE G , LEVIN DORON
发明人： DAKKA JIHAD , VARTULI JAMES C , BUCHANAN JOHN S , SANTIESTEBAN JOSE G , LEVIN DORON
IPC分类号： B01J21/06 , B01J23/10 , B01J29/06 , B01J29/40 , B01J29/82 , B01J35/00 , B01J37/00 , B01J37/03 , C07C2/86 , B01J23/02 , C07C2/66
CPC分类号： B01J37/0009 , B01J21/06 , B01J21/066 , B01J23/10 , B01J29/06 , B01J29/40 , B01J29/82 , B01J35/0006 , B01J35/002 , B01J37/03 , B01J2229/20 , B01J2229/32 , B01J2229/36 , B01J2229/42 , C07C2/864 , C07C2521/06 , C07C2523/10 , Y02P20/52 , C07C15/08
摘要： The invention relates to a process for producing alkylated aromatic hydrocarbons, preferably with an oxygen or sulfur containing alkylating agent, in the presence of a multi-component molecular sieve catalyst composition that includes a molecular sieve and an active non-acidic metal oxide preferably a mixed oxide of zirconium and lanthanum. The invention is also directed to methods of making and formulating the multi-component molecular sieve catalyst composition useful in producing alkylated aromatics.
摘要翻译：本发明涉及在多组分分子筛催化剂组合物存在下，优选用含氧或含硫烷基化剂制备烷基化芳烃的方法，该组合物包括分子筛和活性非酸性金属氧化物，优选混合锆和镧的氧化物。本发明还涉及制备和配制用于制备烷基化芳族化合物的多组分分子筛催化剂组合物的方法。

7. 发明申请

WO03074177A2 CATALYST COMPOSITIONS COMPRISING MOLECULAR SIEVES, THEIR PREPARATION AND USE IN CONVERSION PROCESSES 审中-公开
标题翻译：包含分子筛的催化剂组合物，其在转化过程中的制备和使用
公开(公告)号：WO03074177A2
公开(公告)日：2003-09-12
申请号：PCT/US0304169
申请日：2003-02-10
申请人： EXXONMOBIL CHEM PATENTS INC
发明人： LEVIN DORON , VARTULI JAMES C
IPC分类号： B01J21/10 , B01J23/02 , B01J23/10 , B01J29/85 , B01J35/00 , B01J35/10 , B01J37/00 , B01J37/03 , B01J37/04 , B01J37/08 , C07B61/00 , C07C1/20 , C07C2/84 , C07C11/04 , C07C11/06 , C10G3/00 , C10G11/05 , C10G35/095 , C10G45/54 , C10G45/64 , C10G47/20 , C10G49/08 , C10G50/00 , C10G50/02 , B01J29/00
CPC分类号： C10G50/02 , B01J21/10 , B01J23/02 , B01J23/10 , B01J29/85 , B01J35/0006 , B01J35/10 , B01J37/0009 , B01J2229/42 , C07C1/20 , C07C2521/06 , C07C2521/10 , C07C2523/08 , C07C2529/00 , C07C2529/83 , C07C2529/85 , C10G3/44 , C10G3/49 , C10G11/05 , C10G35/095 , C10G45/54 , C10G45/64 , C10G47/20 , C10G49/08 , C10G50/00 , C10G2400/20 , Y02P30/42 , C07C11/02
摘要： The invention relates to a catalyst composition, a method of making the same and its use in the conversion of a feedstock, preferably an oxygenated feedstock, into one or more olefin(s), preferably ethylene and/or propylene. The catalyst composition comprises a molecular sieve and at least one oxide of a metal selected from Group 3 of the Periodic Table of Elements, the Lanthanide series of elements and the Actinide series of elements.
摘要翻译：本发明涉及一种催化剂组合物，其制备方法及其在原料（优选氧化原料）转化为一种或多种烯烃，优选乙烯和/或丙烯中的用途。催化剂组合物包含分子筛和至少一种选自元素周期表第3族的金属，元素的镧系元素和锕系元素的至少一种。

8. 发明申请

WO2012027034A2 CATALYST REGENERATION PROCESS 审中-公开
标题翻译：催化再生过程
公开(公告)号：WO2012027034A2
公开(公告)日：2012-03-01
申请号：PCT/US2011044634
申请日：2011-07-20
申请人： EXXONMOBIL CHEM PATENTS INC , BEECH JAMES H JR , STEINHEIDER JULIA E , LEVIN DORON , LAWRENCE SELMA S
发明人： BEECH JAMES H JR , STEINHEIDER JULIA E , LEVIN DORON , LAWRENCE SELMA S
IPC分类号： C07C2/72 , B01J38/02 , B01J38/06 , C07C5/22 , C07C15/08
CPC分类号： C07C2/12 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/7034 , B01J29/7038 , B01J29/7042 , B01J29/7046 , B01J29/90 , B01J37/18 , B01J37/20 , B01J38/14 , B01J38/16 , B01J38/20 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/40 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/08
摘要： This disclosure relates to a process for regenerating a catalyst composition to improve the aging rate in subsequent cycles.
摘要翻译：本公开涉及一种用于再生催化剂组合物以改善随后循环中的老化速率的方法。

9. 发明申请

WO2007120405A9 HIGH PRESSURE AND HIGH CAPACITY OXYGENATE CONVERSION WITH CATALYST EXPOSURE CYCLE 审中-公开
标题翻译：高压和高容量氧气转化与催化剂暴露周期
公开(公告)号：WO2007120405A9
公开(公告)日：2008-01-10
申请号：PCT/US2007005427
申请日：2007-03-01
申请人： EXXONMOBIL CHEM PATENTS INC , KUECHLER KEITH H , BEECH JAMES H , LEVIN DORON , VAUGHN STEPHEN N , BROWN STEPHEN H
发明人： KUECHLER KEITH H , BEECH JAMES H , LEVIN DORON , VAUGHN STEPHEN N , BROWN STEPHEN H
IPC分类号： C07C1/20 , C10G3/00
CPC分类号： C07C1/20 , B01J29/90 , B01J38/06 , C07C2529/85 , C08F10/00 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/308 , C10G2300/4012 , C10G2300/4018 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C08F2/00
摘要： A gas-solids reaction system is provided for improving product recovery in a multiple reactor reaction system. An oxygenate feedstock, desirably of high concentration in oxygenate, is reacted with a catalyst having a low to modest acidity and a Si/Al 2 ratio of from 0.10 to 0.32. The reaction occurs in a reaction zone of a fluidized bed reactor at an oxygenate partial pressure of at least 45 psia and a reactor gas superficial velocity of at least 10 ft/s, conveying catalyst through the reaction zone to a circulation zone. The catalyst undergoes displacement with an inert gas in the circulation zone at a displacement gas superficial velocity of at least 0.03 m/s, after which at least a portion, preferably a large portion is returned to the reaction zone. The catalyst has a residence time in the circulation zone of at least twice that of the residence time of catalyst in the reaction zone. Extraordinary catalyst activity at high olefin selectivity results despite insignificant changes in coke on catalyst and coke yield when compared to lower pressure operations.
摘要翻译：提供了一种气体 - 固体反应系统，用于改善多反应器反应系统中的产物回收。含氧化合物的含氧化合物原料，优选在含氧化合物中的高浓度与具有低至适度酸度和0.10 / 0.32的Si / Al 2 O比的催化剂反应。反应在流化床反应器的反应区中发生，氧化分压至少为45psia，反应器气体表观速度为至少10ft / s，将催化剂通过反应区输送到循环区。催化剂在循环区中以惰性气体置换，位移气体空速为至少0.03m / s，此后至少一部分，优选大部分返回到反应区。催化剂在循环区中的停留时间至少是催化剂在反应区中的停留时间的两倍。尽管与较低压力操作相比，尽管催化剂上的焦炭和焦炭产量都没有显着变化，但是在高烯烃选择性下仍然具有特殊的催化剂活性。

10. 发明公开

EP2560936A4 XYLENES ISOMERIZATION PROCESS AND CATALYST THEREFOR 无效
标题翻译： XYLENISERIZATION过程和催化剂这个
公开(公告)号：EP2560936A4
公开(公告)日：2014-08-06
申请号：EP11772422
申请日：2011-04-06
申请人： EXXONMOBIL CHEM PATENTS INC
发明人： OU JOHN D Y , ROSS APRIL D , LEVIN DORON , KALYANARAMAN MOHAN , LAI WENYIH F
IPC分类号： C07C5/27 , B01J29/40 , B01J29/70 , C07C15/08
CPC分类号： B01J29/40 , B01J29/70 , B01J29/90 , B01J38/10 , C07C5/2737 , C07C2529/40 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/08

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