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1. 发明申请

WO2010046181A3 DEFOAMING AGENT FOR DEFOAMING LACQUERS 审中-公开
标题翻译：消泡剂消泡油漆
公开(公告)号：WO2010046181A3
公开(公告)日：2010-07-01
申请号：PCT/EP2009061838
申请日：2009-09-14
申请人： EVONIK GOLDSCHMIDT GMBH , CAVALEIRO PEDRO , FAVRESSE PHILIPPE , DE GANS BEREND-JAN , SCHWAN MICHAEL , VOLKMER STEFANIE
发明人： CAVALEIRO PEDRO , FAVRESSE PHILIPPE , DE GANS BEREND-JAN , SCHWAN MICHAEL , VOLKMER STEFANIE
IPC分类号： B01D19/04 , B41J2/19 , C07C273/18 , C07C275/14 , C09D7/12 , C10M171/00
CPC分类号： B01D19/0413 , B01D19/0404 , C07C275/14 , C08K5/21 , C09D7/63 , C10M133/20 , C10M171/004 , C10M173/02 , C10M2203/1006 , C10M2209/102 , C10M2209/106 , C10M2215/102 , C10N2230/18 , C10N2240/40 , C10N2250/12
摘要： The invention relates to substances for defoaming aqueous media. Said substances contain urea derivatives of formula (I) in the form of solid particles as defoaming agents. In formula (I), R1 is a hydrocarbon group comprising 4 to 30 carbon atoms, a hydrocarbon group comprising 4 to 24 carbon atoms and a nitrogen atom, or a hydrocarbon group comprising 4 to 30 carbon atoms and a carbonyl group, R2 is a hydrogen atom or a hydrocarbon group comprising 1 to 24 carbon atoms, R3 is a hydrogen atom or a hydrocarbon group comprising 1 to 24 carbon atoms, R4 is an organic group comprising 2 to 30 carbon atoms, and n is a number between 0 and 5. The urea derivatives are obtained by reacting isocyanates with amines in a carrier medium. The invention is characterized in that the reaction is carried out in the presence of a monovalent alcohol of formula (VI) R8-OH, in which R8 is a linear or branched, preferably branched, alkyl group comprising 6 to 10 carbon atoms.
摘要翻译：本发明涉及一种试剂为消泡含水介质，作为式消泡剂脲衍生物（I）其中R1是具有4至30个碳原子或具有4至24个碳原子和一个氮原子，或碳原子数4〜30的烃基和羰基的烃基的烃基， R2是氢原子或烃基，其具有碳原子数为1〜24，R 3是一个氢原子或具有碳原子数为1〜24的烃基，R 4为有机基团的碳原子数2〜30，并且n为0至5被包含在固体颗粒的形式，其中，由所述尿素衍生物异氰酸酯的反应与在载体介质中的胺得到的，其特征在于在式一元醇（VI）R8-OH =直链或支链的存在下进行反应，优选支链的碳原子数为6〜10的烷基，与R 8进行。

2. 发明专利

AT483748T 未知
公开(公告)号：AT483748T
公开(公告)日：2010-10-15
申请号：AT07787893
申请日：2007-07-25
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： LANDERS RUEDIGER , DE GANS BEREND-JAN
IPC分类号： C08J9/00 , C08K5/00 , C08L83/12
摘要： The subject matter of the present invention relates to a low-viscosity aqueous hot-cure flexible polyurethane foam stabilizer solution which can be used in the production of hot-cure flexible polyurethane foams, wherein the low-viscosity aqueous hot-cure flexible polyurethane foam stabilizer solution comprises the following components: ≧40% to ≦̸70% by weight of polyethersiloxane, ≧0.5% to ≦̸20% by weight of organic surfactant, ≧10% by weight of water, ≧0% by weight of organic solvent additions, in which the polyethersiloxane has the following formula (I) —R1—Si(CH3)2O—[Si(CH3)(OSi(CH3)2R0)O—]u—[Si(OSi(CH3)2R0)2O—]v—[Si(CH3)2O—]w—[SiCH3R2O—]x—[SiCH3R3O—]y—[SiCH3R4O]z—[SiR3R4O]t—Si(CH3)2—R5 (I).

3. 发明专利

CA2652706A1 NEW TYPES OF COMPATIBILISING AGENTS FOR IMPROVING THE STORAGE STABILITY OF POLYOL MIXTURES 未知
公开(公告)号：CA2652706A1
公开(公告)日：2009-08-06
申请号：CA2652706
申请日：2009-02-05
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： DE GANS BEREND-JAN , FERENZ MICHAEL , GLOS MARTIN
IPC分类号： C08G18/48 , C08G18/10 , C08G18/72
摘要： The invention relates to polyethers containing urethane or urea groups as compatibilising agents, their preparation and use, obtained by the reaction of A. at least one di- and/or polyisocyanate with B. (a) at least one hydrophilic polyether which randomly carries at least one OH and/or NH2 and/or NH function and (b) at least one hydrophobic polyether which randomly comprises at least one OH and/or NH2 and/or NH function and (c) optionally further compounds which carry at least one OH and/or NH2 and/or NH function and/or other isocyanate-reactive groups such as carboxylic acid or epoxide functions, and with the proviso that at least one isocyanate A is difunctional or multifunctional.

4. 发明专利

ES2353139T3 UTILIZACION DE SOLUCIONES ACUOSAS DE BAJA VISCOSIDAD ESTABILIZADORAS DE ESPUMAS FLEXIBLES DE POLIURETANO DE CURADO EN CALIENTE QUE CONTIENEN POLIETERSILOXANOS PARA LA PRODUCCION DE ESPUMAS FLEXIBLES DE POLIURETANO DE CURADO EN CALIENTE. 未知
公开(公告)号：ES2353139T3
公开(公告)日：2011-02-25
申请号：ES07787893
申请日：2007-07-25
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： LANDERS RUDIGER , DE GANS BEREND-JAN
IPC分类号： C08J9/00 , C08K5/00 , C08L83/12
摘要： Solución acuosa de baja viscosidad estabilizadora de las espumas flexibles de poliu-retano de curado en caliente que tiene una viscosidad = 40% en peso hasta = 0,5% hasta = 10% en peso de agua, >= 0% en peso de aditivos disolventes orgánicos, en la cual el polietersiloxano tiene la fórmula (I) siguiente: R1-Si(CH3)2O-[Si(CH3)(OSi(CH3)2R0)O-]u-[Si(OSi(CH3)2R0)2O-]v-[Si(CH3)2O-]w-[SiCH3R2O]x-[SiCH3R3O-]y-[SiCH3R4O]z-[SiR3R4O]t-Si(CH3)2-R5 en la cual son: R0=-O-[Si(CH3)2O-]w-[SiCH3R2O-]x-[SiCH3R3O-]y-[SiCH3R4O]z-Si(CH3)2-R R1, R2, R3, R4 y R5, iguales o diferentes unos de otros en cada caso, un resto alquilo o arilo de 1 a 12 átomos de carbono o en cada caso -CH2-R6 o -CH2-CH2-R6 o po (óxido de alquileno)-poliéter de la fórmu -CmH2mO(C2H4O)a(C3H6O)b(C4H8O)c(C6H5-C2H3O)d(C12H24O)gR7 (II), = H, -C6H5, -CN, -alquilo con C1 a C10, -CH-CH2O (anillo epóxido), alquil-OH, -aril-OH, -Cl, -OH, -R8-O-R9, -R8-O-CO-R9 o un eslabón puente divalente para un resto si-loxano adicional seleccionado del grupo alquile R8-, -R8-COO-R9-OOC-R8-, -R8-OOC-R9-COO-R8-, R7 = resto H, alquilo, acilo, acetilo o arilo, grupo alquil- o aril-uretano o un eslabón puente divalente para un resto siloxano adicional seleccionado del grupo alquileno, -R COR9, - R8-O-R9-O-R R8 = alquilo o arilo, R9= alquilo o ar u = 0 hasta 5, v = 0 hasta 5, t = 0 hasta 15, w = 15 hasta 130, x = 0 hasta 15, y = 0 hasta 15, z = 0 hasta 15, m = 0 hasta 4, a = >= 0 hasta = 0 hasta = 0 hasta = 0 hasta = 0 hasta = 10, con la condición de que x+y+z+t >= 3, y que al menos un sustituyente R1, R2, R3, R4, R5 es un poliéter de acuerdo con la fórmula II, donde la proporción en peso de los componentes mencionados anteriormente se selecciona de tal modo que la proporción total en peso de los componentes no sobrepasa 100% en peso, referida espas flexibles de poliuretano de curado en caliente.

5. 发明专利

DE102008043032A1 未知
公开(公告)号：DE102008043032A1
公开(公告)日：2010-04-29
申请号：DE102008043032
申请日：2008-10-22
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： CAVALEIRO PEDRO , FAVRESSE PHILIPPE , DE GANS BEREND-JAN , SCHWAN MICHAEL , VOLKMER STEFANIE
IPC分类号： B01D19/04 , C08K5/21 , C09D7/12 , C09K23/42 , C09K23/52 , C10M133/20 , C10N40/30
摘要： The invention relates to substances for defoaming aqueous media. Said substances contain urea derivatives of formula (I) in the form of solid particles as defoaming agents. In formula (I), R1 is a hydrocarbon group comprising 4 to 30 carbon atoms, a hydrocarbon group comprising 4 to 24 carbon atoms and a nitrogen atom, or a hydrocarbon group comprising 4 to 30 carbon atoms and a carbonyl group, R2 is a hydrogen atom or a hydrocarbon group comprising 1 to 24 carbon atoms, R3 is a hydrogen atom or a hydrocarbon group comprising 1 to 24 carbon atoms, R4 is an organic group comprising 2 to 30 carbon atoms, and n is a number between 0 and 5. The urea derivatives are obtained by reacting isocyanates with amines in a carrier medium. The invention is characterized in that the reaction is carried out in the presence of a monovalent alcohol of formula (VI) R8-OH, in which R8 is a linear or branched, preferably branched, alkyl group comprising 6 to 10 carbon atoms.

6. 发明专利

CA2688022C PROCESS FOR MODIFYING SURFACES USING CURABLE HYDROXYL-CONTAINING SILYL POLYETHERS 未知
公开(公告)号：CA2688022C
公开(公告)日：2016-09-13
申请号：CA2688022
申请日：2009-12-04
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： EBBRECHT THOMAS , SCHUBERT FRANK , NAUMANN MATTHIAS , KNOTT WILFRIED , LEHMANN KATHRIN , VENZMER JOACHIM , DE GANS BEREND-JAN , SILBER STEFAN , HENNING FRAUKE
IPC分类号： C09D183/12 , C08L83/12
摘要： Use of one or more mixed curable hydroxyl-containing silyl polyethers as a constituent of compositions, as modifiers for surfaces, the silyl polyethers being prepared by DMC-catalysed alkoxylation of epoxy-functional alkoxysilanes.

7. 发明专利

DE502007005283D1 VERWENDUNG NIEDRIGVISKOSER WÄSSRIGER POLYURETHANHEISSWEICHSCHAUMSTABILISATORLÖSUNGEN ENTHALTEND POLYETHERSILOXANE BEI DER HERSTELLUNG VON POLYURETHANHEISSWEICHSCHÄUMEN 未知
公开(公告)号：DE502007005283D1
公开(公告)日：2010-11-18
申请号：DE502007005283
申请日：2007-07-25
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： LANDERS RUEDIGER , DE GANS BEREND-JAN
IPC分类号： C08J9/00 , C08K5/00 , C08L83/12

8. 发明专利

CA2688022A1 PROCESS FOR MODIFYING SURFACES 未知
公开(公告)号：CA2688022A1
公开(公告)日：2010-06-05
申请号：CA2688022
申请日：2009-12-04
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： EBBRECHT THOMAS , SCHUBERT FRANK , NAUMANN MATTHIAS , KNOTT WILFRIED , LEHMANN KATHRIN , VENZMER JOACHIM , DE GANS BEREND-JAN , SILBER STEFAN , HENNING FRAUKE
IPC分类号： C09D183/12 , C08L83/12
摘要： Use of one or more mixed hardenable hydroxyl group containing silylpolyether compound (Q) with at least one non-terminal silyl function as a component of composition as modifying- and/or coating-agent for surfaces, is claimed. Use of one or more mixed hardenable hydroxyl group containing silylpolyether compound (Q) of formula (I), (X 1>-Si(X) 2-O-(Si(X) 2-O) k-(Si(X)(X 2>)-O) l 3-(Si(X)(X 3>)-O) l 4-(Si(X 4>)(O-(Si(X) 2-O) k 1-(Si(X)(X 2>)-O) l 5-(Si(X)(X 3>)-O) l 6-Si(X) 2(X 1>))) o-Si(X) 2(X 1>)) (V), or a linear polyether-siloxane-polyether-triblock copolymer compound of formula (X 7>-O-Si(R1a) 2-(O-Si(R1a) 2) m-O-X 7>) (VI), with at least one non-terminal silyl function as a component of composition as modifying- and/or coating-agent for surfaces, is claimed. a : 1-3; b : 0-2, where the sum of a and b is 3, preferably less than 3; c : 0-22; c1 : 0-24; d : 1-1000, preferably 1-500; e : 0-10000; f, g : 0-1000; h, i, j : 0-500; n : 2-8; R : 1-20C-alkyl or 1-20C-haloalkyl; R 1> : optionally saturated, optionally branched residue, which is bonded over O, or a polyether residue of alkoxy-, arylalkoxy- or alkylarylalkoxy group, in which the carbon chain is optionally interrupted by O, an optionally mono- or polycyclic, annelated aromatic aryloxy group, a silicon containing compound or a siloxane residue optionally substituted by alkyl and/or aryl; R 2>, R 3>, R 5>, R 6> : H or optionally saturated, optionally substituted, optionally mono or polyvalent hydrocarbon, where R 5> or R 6> is similar to monovalent hydrocarbon, the cycloaliphatic hydrocarbon is optionally bridged over the fragment Y 1>, and R 2> are/or R 3> are a residue with 1-20 carbon atoms; Y 1> : CH 3 bridge with 1 or 2 methylene unit, or O; R 4> : 1-24C-alkyl or an aromatic or cycloaliphatic residue optionally containing alkyl group; R 7>, R 8> : H, alkyl-, alkoxy-, aryl- or aralkyl group, which becomes polyether ester copolymer under the ring opening polymerization of crosslinkable alkoxysilane group; R 9>-R 1> 2> : H, alkyl-, alkenyl-, alkoxy-, aryl- or aralkyl group, where the hydrocarbon residue is cycloaliphatically or aromatically bridged over Z; Z : a divalent alkylene and/or alkenylene residue; X : cyclic, aliphatic or aromatic, optionally saturated 1-20C-hydrocarbon optionally containing heteroatoms of O, N, P or S X 1> : X, X 2>, or X 3>; X 2> : an alkoxysilyl group containing OH functional polyoxyalkylene residue of formula (Va), which is optionally ester or carbonate modified; X 3> : a terminally etherified polyoxyalkylene residue of formula (Vb); R2a, R3a : 1-20C-hydrocarbon, which optionally contains halo, OH or glycidyloxypropyl, when Y 1> is O; R4a : 1-18C-alkyl optionally bonded to an aryl or cycloaliphatic residue; R7a, R8a : H, alkyl-, alkoxy-, aryl- or aralkyl group; R 1> 3> : 1-18C-alkyl or monofunctional carboxylic acid with terminal transesterified polyoxyalkylene residue of formula (Vc); R 1> 4> : optionally saturated, aliphatic or aromatic 1-30C-hydrocarbon, which contains OH groups; X 4> : X 1> or a fragment of formula (-O(-Si(X)-O) k 2-(Si(X)(X 2>)-O) l 7-(Si(X)(X 3>)-O) l 8-Si(X) 2-X 1>) (Vd); k, k1, k2 : 0-500; l3-l8 : 0-60; o : 0-10; R1a : optionally saturated 1-20C-alkyl; m : 0-5000; and X 7> : polyether fragment of formula (VIa). Provided that: fragments with the index d-j are freely permutable among one another, i.e. sequences are interchangeable against each other within the polyether chain; fragments with the index k, k1, l2, l3, l4, l5, l6, l7, l8 and o are freely permutable among one another, i.e. sequences are interchangeable against each other within the siloxane chain, and selectively statistically distributed or exist as a block; and X 1> is X 2>, when the sum of l3-l7 is 0 or X 1> is not equal to X 2>, when l3-l7 is at least 1. Independent claims are included for: (1) a composition for surface modification or coating comprising (I); (2) the surface modification of particles or films comprising applying the compositions containing (I) either under mixing, or in the presence of pure crosslinking catalyst, or from suitable organic and/or inorganic solvents on the particle surface or from emulsion, where the compounds react covalently or physically; and (3) the surface modification of particle surfaces comprising modifying the particle or a matrix dispersed particle by adding (Q) under mixing and optionally adding a suitable catalyst. [Image] [Image] [Image] [Image].

9. 发明专利

CA2660403C USE OF AQUEOUS POLYURETHANE HOT SOFT FOAM STABILIZING SOLUTIONS OF LOW VISCOSITY HAVING POLYETHER SILOXANE IN THE PRODUCTION OF POLYURETHANE HOT SOFT FOAMS 未知
公开(公告)号：CA2660403C
公开(公告)日：2014-06-03
申请号：CA2660403
申请日：2007-07-25
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： LANDERS RUEDIGER , DE GANS BEREND-JAN
IPC分类号： C08J9/00 , C08K5/00 , C08L83/12
摘要： The object of the present invention relates to aqueous polyurethane hot soft foam stabilizing solutions of low viscosity that can be used in the production of polyurethane hot soft foams, wherein the aqueous polyurethane hot soft foam stabilizing solution of low viscosity comprises the following components >= 40% by weight to = 0,5% by weight to = 10% by weight water, >= 0% by weight organic solvent additives, wherein the polyurethane siloxane has the following formula (I): R1-Si(CH3)2O-[Si(CH3)(OSi(CH3)2R0)O-]u-[Si(OSi(CH3)2R0)2O-]v-[Si(CH3)2O-]w-[SiCH3R2O- ]x-[SiCH3R3O-] y-[SiCH3R4O]z-[SiR3R4O]t-Si(CH3)2-R5, wherein R0= -O-[Si(CH3)2O-]w-[SiCH3R2O-]x-[SiCH3R3O-] y-[SiCH3R4O]z-Si(CH3)2-R5; R1, R2, R3, R4 and R5 = each represent equally or differently from each other an alkyl or aryl residue of 1 to 12 carbon atoms, or each -CH2-R6 oder -CH2-CH2-R6 or polyalkylene oxide polyether of the formula (II), -CmH2mO(C2H4O)a(C3H6O)b(C4H8O)c(C6H5-C2H3O)d(C12H24O)gR7, R6 = H, -C6H5, -CN, -Alkyl with C1 to C10, -CH-CH2O (epoxy ring), -Alkyl-OH, -Aryl-OH, -Cl, - OH, -R8-O-R9, -R8-O-CO-R9 or a divalent binding link to a further siloxane residue, selected from the group of alkylene, -R8-O-R9-, -R8-COO-R9, - R8-O-R9-O-R8-, - R8-COO-R9-OOC-R8-, -R8-OOC-R9-COO-R8-, R7 = H, alkyl-, acyl-, acetyl- or aryl residue, alkyl- or aryl urethane group, or a divalent binding link to a further siloxane residue, selected from the group of alkylene, -R8- O-R9-, -R8-COO-R9, - R8-O-R9-O-R8-, -R8-COO-R9-OOC-R8-, -R8-OOC-R9-COO-R8-, R8 = alkyl- or aryl-; R9 = alkyl- or aryl-; u = 0 to 5; v = 0 to 5; t = 0 to 15; w = 15 to 130; x = 0 to 15; y = 0 to 15; z = 0 to 15; m = 0 to 4; a = >= 0 to = 0 to = 0 to = 0 to = 0 to =10; provided that x + y + z + t >= 3, and that at least one substituent R1, R2, R3, R4, R5 represents a polyether according to formula (II), wherein the proportion by weight of the above stated components is selected such that the total proportion by weight of the components does not exceed 100% by weight, based on the polyurethane hot soft foam stabilizing solution.

10. 发明专利

BRPI0715694A2 未知
公开(公告)号：BRPI0715694A2
公开(公告)日：2013-08-06
申请号：BRPI0715694
申请日：2007-07-25
申请人： EVONIK GOLDSCHMIDT GMBH
发明人： LANDERS RUEDIGER , DE GANS BEREND-JAN
IPC分类号： C08J9/00 , C08K5/00 , C08L83/12
摘要： The subject matter of the present invention relates to a low-viscosity aqueous hot-cure flexible polyurethane foam stabilizer solution which can be used in the production of hot-cure flexible polyurethane foams, wherein the low-viscosity aqueous hot-cure flexible polyurethane foam stabilizer solution comprises the following components: ≧40% to ≦̸70% by weight of polyethersiloxane, ≧0.5% to ≦̸20% by weight of organic surfactant, ≧10% by weight of water, ≧0% by weight of organic solvent additions, in which the polyethersiloxane has the following formula (I) —R1—Si(CH3)2O—[Si(CH3)(OSi(CH3)2R0)O—]u—[Si(OSi(CH3)2R0)2O—]v—[Si(CH3)2O—]w—[SiCH3R2O—]x—[SiCH3R3O—]y—[SiCH3R4O]z—[SiR3R4O]t—Si(CH3)2—R5 (I).

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