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1. 发明公开

EP3119829A1 CONTROLLED CROSSLINKING OF LATEX POLYMERS WITH POLYFUNCTIONAL AMINES 有权转让
标题翻译： GESTEUERTE VERNETZUNG VON LATEXPOLYMEREN MIT POLYFUNKTIONELLEN AMINEN
公开(公告)号：EP3119829A1
公开(公告)日：2017-01-25
申请号：EP15764165.5
申请日：2015-01-20
申请人： Ennis Paint Inc. , Li, Haibo , Newell, Kevin , Cheek, Jeremy
发明人： LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy
IPC分类号： C08G59/50
摘要： Coating compositions and methods providing a high build, fast drying, fast hardening non-amine containing aqueous latex binders are provided, wherein the coating composition is applied to a substrate at a wet film thickness to about 15 mils that ensure drying times of less than 10 minutes. The binder requires the use of at least one specific coalescent solvent with both anionic and non-anionic surfactants.
摘要翻译：本发明的胶乳聚合物组合物具有潜在的交联性能。聚合物中的潜在交联利用阴离子胶乳电荷与与多官能胺交联剂相关的阳离子电荷之间的快速相互作用。一旦将胶乳涂布在基材上，挥发性碱就蒸发掉，并且基团反应形成具有改善的洗涤性能的交联涂层。

2. 发明申请

WO2017049025A1 CONTROLLED CROSSLINKING OF LATEX POLYMERS WITH POLYFUNCTIONAL AMINES 审中-公开
标题翻译：具有多官能胺的LATEX聚合物的控制交联
公开(公告)号：WO2017049025A1
公开(公告)日：2017-03-23
申请号：PCT/US2016/052041
申请日：2016-09-16
申请人： ENNIS PAINT, INC. , LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy
发明人： LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy
IPC分类号： C08K5/3492 , C07D251/30 , C09D133/12 , C09D121/02 , C09D5/00 , C09D7/12
CPC分类号： C08F226/06 , C07D251/30 , C08F2/24 , C08F2/26 , C08F8/32 , C08G73/0273 , C08G73/0633 , C08G73/0638 , C09D139/04 , C09D179/02 , C09D179/04 , C08F220/14 , C08F2220/1825 , C08F220/06
摘要： The latex polymer compositions of the present invention exhibit latent crosslinking properties. Latent crosslinking in the polymers takes advantage of the fast interaction between the anionic latex charge and the cationic charge associated with polyfunctional amine crosslinkers. Once the latex is coated onto a substrate, the volatile base evaporates and the groups react to form a crosslinked coating with improved wash-off properties.
摘要翻译：本发明的胶乳聚合物组合物具有潜在的交联性能。聚合物中的潜在交联利用阴离子胶乳电荷与与多官能胺交联剂相关的阳离子电荷之间的快速相互作用。一旦将胶乳涂覆到基材上，挥发性基体蒸发，并且基团反应以形成具有改善的冲洗性能的交联涂层。

3. 发明申请

WO2016057526A1 LATEX POLYMERIZATION USING A COMBINATION OF REACTIVE SURFACTANTS FOR TRAFFIC MARKINGS 审中-公开
标题翻译：使用反应性表面活性剂组合使用交联标记的LATEX聚合
公开(公告)号：WO2016057526A1
公开(公告)日：2016-04-14
申请号：PCT/US2015/054260
申请日：2015-10-06
申请人： ENNIS PAINT, INC. , CAI, Jiali , LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy , GREER, Robert, W.
发明人： CAI, Jiali , LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy , GREER, Robert, W.
IPC分类号： C07C43/23 , C07F9/06 , C08K5/06 , C09D4/00 , C09D121/02
CPC分类号： C09D113/02 , C08K3/22 , C08K2003/2241
摘要： The present invention provides latex compositions using a combination of reactive surfactants wherein selected from the group consisting of: where, n=1, 2, x is 1-10 more preferably 1-5 and most preferably 1, z is 4-200 more preferably from about 5 to 60, and most preferably 16; Z - can be either SO 3 - or PO 3 2- and most preferably SO 3 - , and M + is Na + , K + , NH 4 + , or an alkanolamine, and is most preferably NH 4 + , and; Where n=1, 2, x is 1-10 more preferably 1-5 and most preferably 1, y is 0, 1, or 2, z is 4-200 more preferably from about 5 to 60, and most preferably 16; and wherein these reactive surfactants provide only one reactive group to react with the latex.
摘要翻译：本发明提供使用反应性表面活性剂的组合的胶乳组合物，其中选自：其中n = 1,2，x为1-10，更优选为1-5，最优选为1，z为4〜200，更优选为约5至60，最优选16; Z-可以是SO 3 - 或PO 3 2-，最优选为SO 3 - ，M +为Na +，K +，NH 4 +或链烷醇胺，最优选为NH 4 + 其中n = 1,2，x为1-10，更优选为1-5，最优选为1，y为0,1或2，z为4〜200，更优选为约5〜60，最优选为16; 并且其中这些反应性表面活性剂仅提供一个与胶乳反应的反应性基团。

4. 发明申请

WO2015142416A1 CONTROLLED CROSSLINKING OF LATEX POLYMERS WITH POLYFUNCTIONAL AMINES 审中-公开
标题翻译：具有多官能胺的LATEX聚合物的控制交联
公开(公告)号：WO2015142416A1
公开(公告)日：2015-09-24
申请号：PCT/US2015/012052
申请日：2015-01-20
申请人： ENNIS PAINT, INC. , LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy
发明人： LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy
IPC分类号： C08G59/50
CPC分类号： C08K5/3492 , C07C209/68 , C07C215/08 , C07C227/02 , C07C229/16 , C07D251/30 , C07D403/14 , C08F220/14 , C08G59/1477 , C08K5/103 , C08K5/17 , C08K5/175 , C08K5/34924 , C08K5/34926 , C09D5/00 , C09D5/024 , C09D5/14 , C09D7/63 , C09D133/12 , C09D153/02 , E01F9/518 , C08F2220/1825 , C08F220/06
摘要： The latex polymer compositions of the present invention exhibit latent crosslinking properties. Latent crosslinking in the polymers takes advantage of the fast interaction between the anionic latex charge and the cationic charge associated with polyfunctional amine crosslinkers. Once the latex is coated onto a substrate, the volatile base evaporates and the groups react to form a crosslinked coating with improved wash-off properties.
摘要翻译：本发明的胶乳聚合物组合物具有潜在的交联性能。聚合物中的潜在交联利用阴离子胶乳电荷与与多官能胺交联剂相关的阳离子电荷之间的快速相互作用。一旦将胶乳涂覆到基材上，挥发性基体蒸发，并且基团反应以形成具有改善的冲洗性能的交联涂层。

5. 发明申请

WO2017132089A1 TRAFFIC MARKING COMPOSITIONS CONTAINING POLYFUNCTIONAL AMINES 审中-公开
标题翻译：含有多官能胺的交通标志组合物
公开(公告)号：WO2017132089A1
公开(公告)日：2017-08-03
申请号：PCT/US2017/014546
申请日：2017-01-23
申请人： ENNIS PAINT, INC.
发明人： NEWELL, Kevin , LI, Haibo , CHEEK, Jeremy
IPC分类号： C09D179/02
CPC分类号： C09D179/02 , C08G73/0273 , C08G73/0633 , C08G73/0638 , C08L2201/54 , C09D5/004 , C09D5/024 , C09D133/00 , C09D133/02 , C09D179/04 , C08L33/00 , C08K5/17
摘要： Disclosed are aqueous coating compositions containing an anionically stabilized polymer, one or more polyfunctional amines acting as crosslinking agents, and a volatile base. Coating compositions can further include one or more additional copolymers, which may or may not be anionically stabilized, and/or additional additives, including pigments, defoamers, pigment dispersing agents, thickeners, surfactants, and combinations thereof. By incorporating one or more polyfunctional amines, such as those comprising recurring units derived from the reaction of one tri-glycidyl moiety and a single di-, or tri-functional amino monomer, or a combination of mono/bi, mono/tri, mono/tetra, bi/bi, bi/tri, bi/tetra, tri/tri, tri/tetra, and tetra/tetra functional amino monomers with a bi- or tri-glycidyl moiety, water wash-off resistance of the coating compositions which comprise paint formulations, can be increased.
摘要翻译：公开了含有阴离子稳定化聚合物，一种或多种充当交联剂的多官能胺和挥发性碱的水性涂料组合物。涂料组合物可以进一步包含一种或多种可以或不可以阴离子稳定的另外的共聚物和/或另外的添加剂，包括颜料，消泡剂，颜料分散剂，增稠剂，表面活性剂及其组合。通过掺入一种或多种多官能胺，例如那些包含衍生自一个三缩水甘油基部分和单个二官能或三官能氨基单体的反应单元的那些，或者单/双，单/三，单具有双缩水甘油基部分或三缩水甘油基部分的双/三，四/双，双/三，双/四，三/三，三/四和四/四官能氨基单体，其中涂料组合物具有耐水洗性包括油漆配方，可以增加。

6. 发明授权

EP3119829B1 CONTROLLED CROSSLINKING OF LATEX POLYMERS WITH POLYFUNCTIONAL AMINES 有权转让
公开(公告)号：EP3119829B1
公开(公告)日：2020-08-19
申请号：EP15764165.5
申请日：2015-01-20
申请人： Ennis Paint, Inc.
发明人： LI, Haibo , NEWELL, Kevin , CHEEK, Jeremy
IPC分类号： C08G59/50 , C07D403/14 , C07C209/68 , C07C215/08 , C07C227/02 , C07C229/16 , C07D251/30 , C08F220/14 , C09D5/00 , C09D5/02 , C09D5/14 , C09D133/12 , C09D153/02 , C08K5/103 , C08K5/17 , C08K5/3492 , E01F9/518 , C08G59/14 , C08G73/00 , C09D7/63 , C08G73/02

7. 发明申请

WO2014172050A1 FAST DRYING AQUEOUS AMINE FREE COATING COMPOSITION(S) 审中-公开
标题翻译：快干ING US US US US））））））））））））
公开(公告)号：WO2014172050A1
公开(公告)日：2014-10-23
申请号：PCT/US2014/030265
申请日：2014-03-17
申请人： FLINT TRADING, INC. , TENG, George Ganghua , GREER, Robert W. , NEWELL, Kevin
发明人： TENG, George Ganghua , GREER, Robert W. , NEWELL, Kevin
IPC分类号： C09D121/02 , C09D5/00 , C09D7/12
CPC分类号： C08K5/3492 , C07C209/68 , C07C215/08 , C07C227/02 , C07C229/16 , C07D251/30 , C07D403/14 , C08F220/14 , C08G59/1477 , C08K5/103 , C08K5/17 , C08K5/175 , C08K5/34924 , C08K5/34926 , C09D5/00 , C09D5/024 , C09D5/14 , C09D7/63 , C09D133/12 , C09D153/02 , E01F9/518 , C08F2220/1825 , C08F220/06
摘要： Coating compositions and methods providing a high build, fast drying, fast hardening non-amine containing aqueous latex binders are provided, wherein the coating composition is applied to a substrate at a wet film thickness to about 15 mils that ensure drying times of less than 10 minutes. The binder requires the use of at least one specific coalescent solvent with both anionic and non-anionic surfactants.
摘要翻译：提供了涂料组合物和提供高构建，快速干燥，快速硬化非胺含水胶乳粘合剂的组合物和方法，其中将涂料组合物以湿膜厚度施加至基材至约15密耳，确保干燥时间小于10 分钟。粘合剂需要使用具有阴离子和非阴离子表面活性剂的至少一种特定的聚结剂溶剂。

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