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1. 发明授权

US11930705B2 Diaryloxybenzoheterodiazole compounds di-substituted with thienothiophenic groups 有权
公开(公告)号：US11930705B2
公开(公告)日：2024-03-12
申请号：US17775900
申请日：2020-11-12
申请人： ENI S.P.A.
发明人： Giuliana Schimperna , Luigi Abbondanza , Antonio Alfonso Proto , Stefano Zanardi
IPC分类号： H10K85/60 , C07D495/04 , H10K30/87
CPC分类号： H10K85/6576 , C07D495/04 , H10K30/87 , H10K85/657
摘要： There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia):

The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.

2. 发明申请

US20220399509A1 DIARYLOXYBENZOHETERODIAZOLE COMPOUNDS DI-SUBSTITUTED WITH THIENOTHIOPHENIC GROUPS 有权
公开(公告)号：US20220399509A1
公开(公告)日：2022-12-15
申请号：US17775900
申请日：2020-11-12
申请人： ENI S.P.A.
发明人： Giuliana Schimperna , Luigi Abbondanza , Antonio Alfonso Proto , Stefano Zanardi
IPC分类号： H01L51/00 , C07D495/04 , H01L51/44
摘要： There is a diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia): The diaryloxybenzoheterodiazole compound di-substituted with thienothiophenic groups having general formula (Ia) can be advantageously used as a spectrum converter in luminescent solar concentrators (LSCS) capable, in turn, of improving the performance of photovoltaic devices (or solar devices), selected for example, between photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support. More particularly, said photovoltaic devices (or solar devices) can be advantageously used in the construction of greenhouses.

3. 发明申请

US20220165959A1 DISUBSTITUTED FLUOROARYLOXYBENZOHETERODIAZOLE COMPOUNDS 有权
公开(公告)号：US20220165959A1
公开(公告)日：2022-05-26
申请号：US17441513
申请日：2020-03-19
申请人： ENI S.P.A.
发明人： Luigi Abbondanza , Antonio Alfonso Proto , Giuliana Schimperna
IPC分类号： H01L51/00 , C07D417/14
摘要： Disubstituted fluoroaryloxybenzoheterodiazole compound having general formula (I): Said disubstituted fluoroaryloxybenzoheterodiazole compound having general formula (I) may be advantageously used as a spectrum converter in luminescent solar concentrators (LSCs) capable, in turn, of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), either on a rigid support, or on a flexible support.

4. 发明申请

US20210320262A1 LUMINESCENT SOLAR CONCENTRATOR COMPRISING DITHIENYLPYRIDINETHIADIOAZOLE COMPOUNDS 有权
公开(公告)号：US20210320262A1
公开(公告)日：2021-10-14
申请号：US17414549
申请日：2019-12-20
申请人： ENI S.P.A.
发明人： Luigi Abbondanza , Antonio Alfonso Proto , Giuliana Schimperna
IPC分类号： H01L51/00 , C09K11/06 , C07D513/04 , H01L51/44
摘要： Luminescent solar concentrator (LSC) having at least one dithienylpyridinethiadiazole compound having general formula (I) or (II): Said luminescent solar concentrator (LSC) can be advantageously used in the construction of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), both on rigid support, and on flexible support.

5. 发明授权

US11856806B2 Disubstituted dl aryloxybenzoh eterodi azole compounds 有权
公开(公告)号：US11856806B2
公开(公告)日：2023-12-26
申请号：US17286621
申请日：2019-10-18
申请人： ENI S.P.A.
发明人： Luigi Abbondanza , Antonio Alfonso Proto , Giuliana Schimperna
IPC分类号： H02S40/22 , C09K11/06 , C07D417/14 , H10K30/87 , H10K85/60
CPC分类号： H10K30/87 , C07D417/14 , C09K11/06 , H02S40/22 , H10K85/655 , H10K85/657 , C09K2211/1007 , C09K2211/1018
摘要： There is a disubstituted diaryloxybenzoheterodiazole compound having general formula (I):

This disubstituted diaryloxybenzoheterodiazole compound having general formula (I) may advantageously be used as a spectrum converter in luminescent solar concentrators (“Luminescent Solar Concentrators”—LSCs) which, in turn, are capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on either a rigid or flexible support.

6. 发明授权

US11706979B2 Disubstituted diaryloxybenzoheterodiazole compounds 有权
公开(公告)号：US11706979B2
公开(公告)日：2023-07-18
申请号：US17380967
申请日：2021-07-20
申请人： ENI S.P.A.
发明人： Luigi Abbondanza , Andrea Alessi , Antonio Alfonso Proto , Giuliana Schimperna , Liliana Gila
IPC分类号： H10K85/60 , C07D417/14 , C09K11/06 , H02S40/22 , H10K30/87 , H10K30/00 , H10K39/10 , H10K85/10 , C09K11/02 , H01L31/0232 , H01L27/146
CPC分类号： H10K85/657 , C07D417/14 , C09K11/02 , C09K11/06 , H02S40/22 , H10K30/451 , H10K30/87 , H10K39/10 , H10K85/141 , H10K85/626 , H10K85/655 , C09K2211/1007 , C09K2211/1011 , C09K2211/1051 , C09K2211/1092 , H01L27/14663 , H01L31/02322 , Y02E10/52
摘要： Disubstituted diaryloxybenzoheterodiazole compound of general formula (I):

in which:

Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, or from optionally substituted aryl groups;
R1, R2, R3 and R4 are as defined in the claims. The disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.

7. 发明授权

US10312395B2 Luminescent solar concentrator comprising disubstituted benzoheterodiazole compounds 有权
公开(公告)号：US10312395B2
公开(公告)日：2019-06-04
申请号：US15514393
申请日：2015-09-24
申请人： ENI S.p.A.
发明人： Luigi Abbondanza , Antonio Alfonso Proto , Giuliana Schimperna , Liliana Gila
IPC分类号： H01L31/055 , C07D417/14 , C07D413/14 , C09K11/06
摘要： Luminescent solar concentrator (LSC) comprising at least one disubstituted benzoheterodiazole compound of general formula (I), in which: —Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR6 group in which R6 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups; —R1, R2 and R3, which are the same or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxyl groups, optionally substituted phenoxyl groups, or —COOR7 groups or —OCOR7 groups in which R7 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or is a cyano group, provided that when the substituents R1 represents a hydrogen atom, at least one of the substituents R2 and R3 represents an optionally substituted aryl group or an optionally substituted phenoxyl group; —or R1 and R2, can optionally be linked together so as to form, together with the carbon atoms to which they are linked, a saturated, unsaturated or aromatic cyclic ring or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; —or R2 and R3 can optionally be linked together so as to form, together with the carbon atoms to which they are linked, a saturated, unsaturated or aromatic cyclic ring or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorus, selenium; —R4 and R5, which are the same or different, represent a hydrogen atom; or are selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, optionally containing heteroatoms, optionally substituted cycloalkyl groups, optionally substituted aryl groups, optionally substituted linear or branched C1-C20, preferably C1-C8, alkoxyl groups, —COOR7 groups or —OCOR7 groups in which R7 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or is a cyano group; or R4 and R5, can optionally be linked together so as to form, together with the carbon atoms to which they are linked, a saturated, unsaturated, or aromatic cyclic ring or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, containing one or more heteroatoms such as, for example, sulfur, nitrogen, silicon, phosphorus, selenium.

8. 发明申请

US20210367176A1 DISUBSTITUTED DL ARYLOXYBENZOH ETERODI AZOLE COMPOUNDS 有权
公开(公告)号：US20210367176A1
公开(公告)日：2021-11-25
申请号：US17286621
申请日：2019-10-18
申请人： ENI S.P.A.
发明人： Luigi Abbondanza , Antonio Alfonso Proto , Giuliana Schimperna
IPC分类号： H01L51/44 , C07D417/14 , C09K11/06 , H01L51/00 , H02S40/22
摘要： A disubstituted diaryloxybenzoheterodiazole compound having general formula (I): wherein: R1, R2 and R3, which are the same as or different from each other, represent a hydrogen atom; or represent a halogen atom such as, for example, chlorine, bromine, fluorine, iodine, preferably fluorine; or are selected from optionally halogenated linear or branched C1-C12, preferably C1-C8, alkyl groups, optionally substituted phenoxy groups, provided that at least one of R1, R2 and R3 is an optionally substituted phenoxy group and, if R3 is an optionally substituted phenoxy group, at least one of R1, R2 is different from hydrogen; R4, which are the same as or different from each other, represent a hydrogen atom; or are selected from —COOR groups wherein R is selected from linear or branched C1-C8, preferably C1-C4, alkyl groups. This disubstituted diaryloxybenzoheterodiazole compound having general formula (I) may advantageously be used as a spectrum converter in luminescent solar concentrators (“Luminescent Solar Concentrators”—LSCs) which, in turn, are capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on either a rigid or flexible support.

9. 发明授权

US11133474B2 Disubstituted diaryloxybenzoheterodiazole compounds 有权
公开(公告)号：US11133474B2
公开(公告)日：2021-09-28
申请号：US15514412
申请日：2015-09-24
申请人： ENI S.P.A.
发明人： Luigi Abbondanza , Andrea Alessi , Antonio Alfonso Proto , Giuliana Schimperna , Liliana Gila
IPC分类号： H01L51/00 , C07D417/14 , C09K11/06 , H02S40/22 , C09K11/02 , H01L27/30 , H01L51/42 , H01L51/44 , H01L31/0232 , H01L27/146
摘要： Disubstituted diaryloxybenzoheterodiazole compound of general formula (1): in which:—Z represents a sulfur atom, an oxygen atom, a selenium atom; or an NR5 group in which R5 is selected from linear or branched C1-C20, preferably C1-C8, alkyl groups, or from optionally substituted aryl groups;—R1, R2 and R3 are as defined in the claims. The said disubstituted diaryloxybenzoheterodiazole compound of general formula (I) can advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules) on either a rigid substrate or a flexible substrate.

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