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1. 发明申请

WO2011070432A1 PROCESS FOR THE PRODUCTION OF BIO-OIL FROM PHOTOTROPHIC AND HETEROTROPHIC ALGAE 审中-公开
标题翻译：生物油生产过程从光热和异位酸生产
公开(公告)号：WO2011070432A1
公开(公告)日：2011-06-16
申请号：PCT/IB2010/003179
申请日：2010-12-07
申请人： ENI S.P.A. , D'ADDARIO, Ezio, Nicola , DE FERRA, Francesca , CAPUANO, Federico , MIGLIO, Roberta , BOSETTI, Aldo , CARNELLI, Lino
发明人： D'ADDARIO, Ezio, Nicola , DE FERRA, Francesca , CAPUANO, Federico , MIGLIO, Roberta , BOSETTI, Aldo , CARNELLI, Lino
IPC分类号： C12P7/64
CPC分类号： C12P7/649 , Y02E50/13
摘要： A process for the production of bio -oil from phototrophic and heterotrophic algae comprising: cultivating at least one phototrophic alga, under photoautotrophic conditions, in order to obtain a first aqueous suspension of algal biomass; - cultivating at least one heterotrophic alga, under heterotrophic conditions, in order to obtain a second aqueous suspension of algal biomass; - subjecting said first aqueous suspension of algal biomass to concentration in order to obtain a first concentrated aqueous suspension of algal biomass; - combining said first concentrated aqueous suspension of algal biomass with said second aqueous suspension of algal biomass obtaining a third aqueous suspension of algal biomass; - subjecting said third aqueous suspension of algal biomass to concentration in order to obtain a second concentrated aqueous suspension of algal biomass; - subjecting said second concentrated aqueous suspension of algal biomass to thermal treatment in order to obtain an oily phase comprising bio-oil and an aqueous phase comprising organic compounds.
摘要翻译：一种从光养和异养藻类生产生物油的方法，包括：在光自养条件下培养至少一种光营养藻，以获得藻类生物质的第一含水悬浮液; - 在异养条件下培养至少一种异养藻，以获得藻类生物质的第二水性悬浮液; - 对藻类生物质的所述第一水性悬浮液进行浓缩，以获得藻类生物质的第一浓缩水悬浮液; 将藻类生物质的所述第一浓缩水性悬浮液与藻类生物质的所述第二水性悬浮液相组合，得到藻类生物质的第三水性悬浮液; - 使藻类生物质的所述第三水性悬浮液浓缩，以获得藻类生物质的第二浓缩水悬浮液; - 将藻类生物质的所述第二浓缩水悬浮液经受热处理，以获得包含生物油和含有机化合物的水相的油相。

2. 发明申请

WO2010140037A1 PROCESS FOR THE DRYING OF ALGAL BIOMASS 审中-公开
标题翻译： ALGAL生物质干燥的方法
公开(公告)号：WO2010140037A1
公开(公告)日：2010-12-09
申请号：PCT/IB2010/001230
申请日：2010-05-18
申请人： ENI S.P.A. , PANDOLFI, Gianni , MIGLIO, Roberta , CARNELLI, Lino
发明人： PANDOLFI, Gianni , MIGLIO, Roberta , CARNELLI, Lino
IPC分类号： C12N1/00 , C12N1/12 , C12P7/64
CPC分类号： C12N1/005 , C12N1/12 , C12P7/6463 , C12P7/649 , Y02E50/13 , Y02P20/134
摘要： A process for the drying of algal biomass, comprising: - producing an aqueous suspension of algal biomass; concentrating said aqueous suspension of algal biomass in order to obtain a concentrated aqueous suspension of algal biomass; depositing a layer of said concentrated aqueous suspension of algal biomass on a hydrophobic surface, in order to obtain a layer having a thickness lower than or equal to 1 cm, preferably ranging from 0.2 to 0.6 cm,- putting this layer in contact with hot air, said hot air being at a temperature ranging from 40°C to 110°C, preferably ranging from 60°C to 9O°C in order to obtain a layer of dried algal biomass. The dried algal biomass obtained by means of the above-mentioned process can be advantageously used for the production of lipids. Said lipids can be used, in turn, for the production of biodiesel or green diesel. Alternatively, said dried algal biomass can be advantageously used for the production of bio-oil or bio- crude. Alternatively, said dried algal biomass can be advantageously used for the production of energy through thermal treatments such as, for example, combustion or gasification.
摘要翻译：一种用于干燥藻类生物质的方法，包括： - 产生藻类生物质的水悬浮液; 浓缩所述藻类生物质的水悬浮液以获得藻类生物质的浓缩水悬浮液; 将一层所述浓缩的藻类生物质的水性悬浮液沉积在疏水表面上，以获得厚度小于或等于1cm，优选为0.2至0.6cm的层，将该层与热空气接触所述热空气的温度范围为40℃至110℃，优选为60℃至90℃，以获得一层干燥的藻类生物质。通过上述方法获得的干藻类生物质可有利地用于生产脂质。所述脂质又可用于生产生物柴油或绿色柴油。或者，所述干燥的藻类生物质可有利地用于生产生物油或生物粗品。或者，所述干燥的藻类生物质可以有利地用于通过热处理例如燃烧或气化来产生能量。

3. 发明申请

WO2009090105A1 PROCESS FOR THE TREATMENT OF THE AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应处理水质流的处理方法
公开(公告)号：WO2009090105A1
公开(公告)日：2009-07-23
申请号：PCT/EP2009/000390
申请日：2009-01-14
申请人： ENI S.P.A. , CARNELLI, Lino , MIGLIO, Roberta , D'OLIMPIO, Paolo
发明人： CARNELLI, Lino , MIGLIO, Roberta , D'OLIMPIO, Paolo
IPC分类号： C02F1/04 , C02F1/44 , C02F1/66 , B01D61/44 , B01D61/02
CPC分类号： C02F1/441 , B01D3/143 , B01D61/025 , C02F1/04 , C02F1/20 , C02F1/4693 , C02F1/66 , C02F2101/322 , C02F2101/34 , C10G2/32 , C10G2300/1022
摘要： The present invention relates to a process for the treatment of the aqueous stream coming from the Fischer- Tropsch reaction, comprising: - feeding the aqueous stream (1) containing organic by- products of the reaction to a distillation or stripping column (10); - collection from the column of a distillate (2) enriched in alcohols having from 1 to 8 carbon atoms and other possible volatile compounds - feeding the aqueous stream leaving the bottom of the column (3) to a reverse osmosis unit (20) and the production of two outgoing streams; - an aqueous stream (4) enriched in organic acids with from 1 to 8 carbon atoms; - a partially purified aqueous stream (5) with a low acid content.
摘要翻译：本发明涉及一种处理来自费 - 托反应的水流的方法，包括： - 将含有反应有机副产物的含水物流（1）加入到蒸馏塔或汽提塔（10）中; - 从富含1至8个碳原子的醇和其他可能的挥发性化合物的馏出物（2）的塔中收集 - 将离开塔（3）底部的水流送入反渗透单元（20）生产两个输出流; 富含有1至8个碳原子的有机酸的含水物流（4）; - 具有低酸含量的部分纯化的水流（5）。

4. 发明申请

WO2010028731A1 PROCESS FOR THE PURIFICATION OF AN AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应中净化水质流的方法
公开(公告)号：WO2010028731A1
公开(公告)日：2010-03-18
申请号：PCT/EP2009/005892
申请日：2009-08-07
申请人： ENI S.P.A. , MIGLIO, Roberta , CARNELLI, Lino , CLERICI, Gabriele, Carlo, Ettore , ZENNARO, Roberto
发明人： MIGLIO, Roberta , CARNELLI, Lino , CLERICI, Gabriele, Carlo, Ettore , ZENNARO, Roberto
IPC分类号： C02F1/44 , B01D61/36 , B01D3/14 , B01D3/36 , C02F1/04
CPC分类号： B01D61/362 , B01D3/14 , B01D3/145 , B01D2311/04 , C02F1/448 , C02F2103/365 , B01D2311/2669
摘要： Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: feeding said aqueous stream containing the organic by products of the reaction to one or more pervaporation units, said one or more pervaporation units comprising at least one polymeric pervaporation membrane, obtaining two outgoing streams: - an aqueous stream (i) enriched in alcohols having from 1 to 8 carbon atoms, preferably from 2 to 4 carbon atoms; - an aqueous stream (ii) enriched in water.
摘要翻译：用于净化来自费 - 托反应的含水物流的方法，其包括：将含有反应产物的含水物流送入一个或多个渗透蒸发单元，所述一个或多个渗透蒸发单元包含至少一个聚合物渗透蒸发膜获得两个输出流： - 富含具有1至8个碳原子，优选2至4个碳原子的醇的含水物流（i） - 富含水的含水物流（ii）。

5. 发明申请

WO2010099882A1 PROCESS FOR THE PURIFICATION OF AN AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应中净化水质流的方法
公开(公告)号：WO2010099882A1
公开(公告)日：2010-09-10
申请号：PCT/EP2010/001098
申请日：2010-02-18
申请人： ENI S.P.A. , FRANZOSI, Giuliana , CESTI, Pietro , PAGLINO, Roberto , CARNELLI, Lino , MIGLIO, Roberta
发明人： FRANZOSI, Giuliana , CESTI, Pietro , PAGLINO, Roberto , CARNELLI, Lino , MIGLIO, Roberta
IPC分类号： C02F1/04 , C02F3/28 , C02F9/00 , C02F101/32 , C02F101/34
CPC分类号： C02F1/04 , C02F1/20 , C02F1/441 , C02F1/444 , C02F1/66 , C02F3/1268 , C02F3/28 , C02F3/2846 , C02F2101/32 , C02F2101/34 , C02F2103/36 , C02F2303/10 , Y02W10/15 , Y02W10/30
摘要： Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises: - feeding said aqueous stream containing the organic by-products of the reaction to a distillation column, obtaining two output streams: - an aqueous stream (i) exiting from the column head, enriched with alcohols having from 1 to 20 carbon atoms, preferably from 1 to 9 carbon atoms, and other optional volatile compounds; an aqueous stream (ii) exiting from the column bottom, enriched with organic acids having from 1 to 10 carbon atoms, preferably from 2 to 6 carbon atoms; - subjecting said aqueous stream (ii) to an anaerobic biological treatment obtaining a purified aqueous stream (iii); wherein said anaerobic biological treatment is carried out with a hydraulic retention time lower than 15 hours, preferably ranging from 4 hours to 10 hours, more preferably ranging from 5 hours to 8 hours.
摘要翻译：净化来自费 - 托反应的含水物流的方法，其包括：将含有反应的有机副产物的所述含水物流送入蒸馏塔，得到两个输出流： - 水流（i）离开富集具有1至20个碳原子，优选1至9个碳原子的醇和其它任选的挥发性化合物; 从塔底出来的含水物流（ii）富含具有1-10个碳原子，优选2-6个碳原子的有机酸; - 对所述含水物流（ii）进行厌氧生物处理，获得纯化的含水物流（iii）; 其中所述厌氧生物处理水力停留时间低于15小时，优选4小时至10小时，更优选5小时至8小时进行。

6. 发明申请

WO2010069581A1 PROCESS FOR THE PURIFICATION OF AN AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应中净化水质流的方法
公开(公告)号：WO2010069581A1
公开(公告)日：2010-06-24
申请号：PCT/EP2009/009107
申请日：2009-12-16
申请人： ENI S.p.A. , CARNELLI, Lino , MIGLIO, Roberta , PISANI, Franca , ZENNARO, Roberto
发明人： CARNELLI, Lino , MIGLIO, Roberta , ZENNARO, Roberto
IPC分类号： C02F1/04 , C02F1/66 , C02F9/00 , C02F101/32 , C02F103/36
CPC分类号： C02F1/04 , B01D3/143 , B01D3/148 , C02F1/048 , C02F1/66 , C02F9/00 , C02F2101/322 , C02F2103/36
摘要： Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises a distillation and/or stripping treatment, a treatment with at least one inorganic base and a treatment with at least one organic base. Said process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer-Tropsch plant for the production of hydrocarbons.
摘要翻译：用于净化来自费 - 托反应的水流的方法，其包括蒸馏和/或汽提处理，用至少一种无机碱处理和用至少一种有机碱处理。所述方法允许来自费 - 托反应的至少一部分水流作为合成气生产设备中的工艺用水，随后送至费 - 托工厂生产碳氢化合物。

7. 发明申请

WO2009090106A1 PROCESS FOR THE TREATMENT OF THE AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应处理水质流的处理方法
公开(公告)号：WO2009090106A1
公开(公告)日：2009-07-23
申请号：PCT/EP2009/000391
申请日：2009-01-14
申请人： ENI S.P.A. , MIGLIO, Roberta , BIGNAZZI, Renzo , CARNELLI, Lino
发明人： MIGLIO, Roberta , BIGNAZZI, Renzo , CARNELLI, Lino
IPC分类号： C02F1/04 , C02F1/469 , B01D61/44
CPC分类号： C02F1/469 , B01D3/143 , B01D61/44 , B01D61/445 , B01D2311/04 , B01D2311/06 , C02F1/4693 , C02F2101/34 , C02F2103/365 , C02F2201/46115 , C02F2201/46125 , C02F2201/46145 , C02F2201/4615 , C02F2201/4618 , C10G2300/1022 , B01D2311/2669
摘要： The present invention relates to a process for the treatment of the aqueous stream coming from the Fischer- Tropsch reaction which comprises: - feeding of the aqueous stream containing organic by-products of the reaction to a distillation or stripping column; - collection from the column of a distillate enriched in alcohols having from 1 to 8 carbon atoms and other possible volatile compounds; feeding of the aqueous stream containing the acids leaving the bottom of the distillation column to an electrodialysis cell and the production of two outgoing streams : - an aqueous stream (i) enriched in organic acids having from 1 to 8 carbon atoms; - a purified aqueous stream (ii) with a low acid content.
摘要翻译：本发明涉及一种处理来自费 - 托反应的含水物流的方法，该方法包括：将含反应有机副产物的含水物流送入蒸馏塔或汽提塔; - 从富含1至8个碳原子的醇和其他可能的挥发性化合物的馏出物塔中收集; 将含有离开蒸馏塔底部的酸的水流进料到电渗析池中并产生两个输出流： - 含有1至8个碳原子的富含有机酸的水流（i） - 具有低酸含量的纯化水流（ii）。

8. 发明申请

WO2012004001A2 PROCESS FOR THE PRODUCTION OF SYNTHESIS GAS BY MEANS OF A FLUID BED GASIFICATION REACTOR FED WITH CARBONACEOUS MATERIAL AND DEVICE SUITABLE FOR THE PURPOSE 审中-公开
标题翻译：用含有碳质材料的流化床气化反应器和适用于该目的的装置生产合成气的方法
公开(公告)号：WO2012004001A2
公开(公告)日：2012-01-12
申请号：PCT/EP2011/003441
申请日：2011-07-04
申请人： ENI S.p.A. , BUA, Letizia , CARNELLI, Lino , CHIODINI, Andrea
发明人： BUA, Letizia , CARNELLI, Lino , CHIODINI, Andrea
IPC分类号： C10J3/52
CPC分类号： C10J3/523 , C10J3/723 , C10J2300/0916 , Y02P20/145
摘要： A process for the production of synthesis gas which comprises : feeding a carbonaceous material having a particle-size lower than or equal to 50 mm, to a gasification reactor; feeding an oxidizing gas to the bottom of the reactor at a flow-rate which is such as to give the solid mass present in the reactor an aspect of a biphasic bed; filtering the solid particles entrained by the gas, in a cyclone filter positioned internally at the top of the reactor; discharging from the cyclone filter a gaseous stream essentially consisting of synthesis gas and unreacted oxidizing gas; and recycling the filtered solid particles, discharged at the base of the cyclone, directly to the biphasic bed, through an inner duct.
摘要翻译：生产合成气的方法，其包括：将粒径小于或等于50mm的碳质材料供给到气化反应器; 以一定的流速将氧化气体供入反应器的底部，以便使反应器中存在的固体物质成为双相床的一个方面; 在内部设置在反应器顶部的旋风过滤器中过滤由气体夹带的固体颗粒; 从旋风过滤器中排出主要由合成气和未反应的氧化气体组成的气流; 并将通过旋风分离器底部排出的过滤的固体颗粒直接通过内导管循环到双相床。

9. 发明申请

WO2011042806A1 PROCESS FOR THE PURIFICATION OF AN AQUEOUS STREAM COMING FROM THE FISCHER TROPSCH REACTION 审中-公开
标题翻译：从FISCHER TROPSCH反应中净化水质流程的过程
公开(公告)号：WO2011042806A1
公开(公告)日：2011-04-14
申请号：PCT/IB2010/002563
申请日：2010-10-06
申请人： ENI S.P.A. , PISANI, Franca , CARNELLI, Lino
发明人： CARNELLI, Lino
IPC分类号： C02F1/04 , C02F101/32 , C02F9/00 , C02F103/36
CPC分类号： B01D3/38 , C02F1/04 , C02F1/20 , C02F1/441 , C02F3/12 , C02F3/28 , C02F9/00 , C02F2101/322 , C02F2103/36 , Y02W10/15
摘要： Process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction, which comprises feeding a part of said aqueous stream to a saturator, feeding a part of said aqueous stream to a distillation and/or stripping column, feeding the aqueous stream leaving the head of said distillation and/ or stripping column to said saturator. Said process allows at least a part of the aqueous stream coming from the Fischer-Tropsch reaction to be used as process water in the synthesis gas production plant, subsequently sent to the Fischer Tropsch plant for the production of hydrocarbons.
摘要翻译：净化来自费 - 托反应的含水物流的方法，其包括将一部分所述水流进料到饱和器中，将一部分所述水流送入蒸馏塔和/或汽提塔，将水流送出所述蒸馏塔和/或汽提塔的头部至所述饱和器。所述方法允许来自费 - 托反应的至少一部分水流作为合成气生产设备中的工艺用水，随后送到费托工厂生产烃。

10. 发明申请

WO2008151742A1 PROCESS FOR THE PURIFICATION OF AN AQUEOUS STREAM COMING FROM THE FISCHER-TROPSCH REACTION 审中-公开
标题翻译：从FISCHER-TROPSCH反应中净化水质流的方法
公开(公告)号：WO2008151742A1
公开(公告)日：2008-12-18
申请号：PCT/EP2008/004397
申请日：2008-05-30
申请人： ENI S.P.A. , CARNELLI, Lino , LAZZARI, Carla , PANDOLFI, Gianni
发明人： CARNELLI, Lino , LAZZARI, Carla , PANDOLFI, Gianni
IPC分类号： C02F1/04 , C02F9/00
CPC分类号： C02F1/04 , C02F1/16 , C02F9/00 , C02F2101/32 , C02F2103/365
摘要： The present invention relates to a process for the purification of an aqueous stream coming from the Fischer-Tropsch reaction which comprises : - feeding of the aqueous stream containing the organic by- products of the reaction to a system consisting of a distillation column equipped with a partial condenser and a total condenser; - partial condensation of the vaporized stream leaving the head of the column and collection of a first distillate enriched in the heavier by-products; - total condensation of the vaporized stream leaving the partial condenser and collection of a liquid stream which is partly sent back to the distillation column as reflux whereas the remaining part is collected as distillate; - extraction of the purified aqueous stream from the bottom of the distillation column.
摘要翻译：本发明涉及一种用于净化来自费 - 托反应的含水物流的方法，该方法包括：将含有该反应的有机副产物的含水物流输送到由装备有部分冷凝器和总冷凝器; - 离开柱头的汽化物流的部分冷凝和收集富含较重副产物的第一馏出物; - 离开部分冷凝器的蒸发物流的总冷凝和收集液态物流，其部分地作为回流送回蒸馏塔，而剩余部分作为馏出物收集; - 从蒸馏塔的底部萃取纯化的含水物流。

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