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1. 发明申请

WO2011072841A1 PROCESS FOR RECOVERING METALS FROM A STREAM RICH IN HYDROCARBONS AND CARBONACEOUS RESIDUES 审中-公开
标题翻译：从碳氢化合物和碳氢化合物中回收金属的方法
公开(公告)号：WO2011072841A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/007627
申请日：2010-12-13
申请人： ENI S.P.A. , BARTOLINI, Andrea , POLLESEL, Paolo , SENTIMENTI, Emilio , CHECCHIN, Michele
发明人： BARTOLINI, Andrea , POLLESEL, Paolo , SENTIMENTI, Emilio , CHECCHIN, Michele
IPC分类号： C22B7/00
CPC分类号： C10G21/06 , C10G21/28 , C10G2300/205 , C22B3/22 , C22B7/008 , C22B7/009 , C22B23/026 , C22B34/225 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234 , Y02W30/54
摘要： A process for recovering metals from a stream rich in hydrocarbons and carbonaceous residues by means of a treatment section characterized in that it comprises the following steps : • sending said stream to an extraction by mixing said stream with a suitable hydrophilizing agent, i.e. being capable of removing the hydrophobic qualities of said stream; • sending the mixture consisting of said stream and said hydrophilizing agent to separation, separating a liquid phase containing most of the hydrophilizing agent and hydrocarbons dissolved from a "solid" phase; • preferably subjecting the "solid" phase separated to drying effected at a maximum temperature of 3500C in order to remove the medium- light hydrocarbon components from the "solid" phase; • sending the "solid" phase separated, preferably dried, to leaching with an alkaline solution in the presence of air and/or oxygen and possibly in the presence of an emulsifying agent or its precursor; • sending the leached mixture to separation, separating the solid residue from the liquor.
摘要翻译：一种通过处理部分从富含烃和碳质残渣的物流中回收金属的方法，其特征在于其包括以下步骤：将所述物流与合适的亲水剂混合，将所述物流与所述物流混合，去除所述流的疏水性质; 将由所述流和所述亲水剂组成的混合物发送到分离，分离含有大部分亲水剂的液相和从“固体”相中溶解的烃; 优选在350℃的最高温度下对分离的“固体”相进行干燥，以从“固体”相除去中轻烃成分; °的“固体”相分离，优选干燥，在空气和/或氧气存在下并可能在乳化剂或其前体存在下用碱性溶液浸出; °将该沥滤混合物送入分离，将固体残渣与液体分离。

2. 发明申请

WO2011047829A1 PROCESS FOR REDUCING THE VISCOSITY OF OIL RESIDUES COMING FROM DISTILLATION AT ATMOSPHERIC PRESSURE OR UNDER VACUUM 审中-公开
标题翻译：降低大气压力下或真空蒸发的油料残留粘度的方法
公开(公告)号：WO2011047829A1
公开(公告)日：2011-04-28
申请号：PCT/EP2010/006371
申请日：2010-10-15
申请人： ENI S.P.A. , D'ELIA, Luigi , RISPOLI, Giacomo Fernando , POLLESEL, Paolo , SENTIMENTI, Emilio
发明人： D'ELIA, Luigi , RISPOLI, Giacomo Fernando , POLLESEL, Paolo , SENTIMENTI, Emilio
IPC分类号： C10G55/04
CPC分类号： C10G55/04 , C10G15/08 , C10G32/02
摘要： A process for reducing the viscosity of oil residues coming from distillation at atmospheric pressure or under vacuum, substantially comprising a visbreaking area, having a coil visbreaker or soaker visbreaker, in which a thermal treatment is effected at temperatures ranging from 350 to 500°C characterized in that further treatment is effected, by irradiation with microwaves (in continuous or in a pulsed mode) operating at temperatures ranging from 100 to 500°C, for a period of time ranging from 1 second to 120 minutes and with frequencies ranging from 0.3 to 300 GHz.
摘要翻译：一种降低来自大气压或真空蒸馏的油残余物的粘度的方法，其基本上包括具有线性破裂剂或均匀破裂剂的减粘裂化区域，其中热处理在350-500℃的温度范围内进行表征在进一步的处理中，通过在从100℃至500℃的温度范围内操作的微波（连续或以脉冲模式）照射1秒至120分钟，频率范围为0.3至 300 GHz。

3. 发明申请

WO2011072804A1 PROCESS FOR REDUCING THE VISCOSITY OF CRUDE OILS 审中-公开
标题翻译：降低原油粘度的方法
公开(公告)号：WO2011072804A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/007284
申请日：2010-11-30
申请人： ENI S.P.A. , D'ELIA, Luigi , SENTIMENTI, Emilio , GUADALUPI, Giuseppe , RISPOLI, Giacomo, Fernando , POLLESEL, Paolo
发明人： D'ELIA, Luigi , SENTIMENTI, Emilio , GUADALUPI, Giuseppe , RISPOLI, Giacomo, Fernando , POLLESEL, Paolo
IPC分类号： C10G15/08 , C10G32/02 , B01J19/12
CPC分类号： C10G15/08 , C10G32/02 , C10G2300/1033 , C10G2300/302
摘要： Process for the reduction of the viscosity of crude oils substantially comprising a separation step of said crude oils (in order to separate a light fraction and a heavy fraction having a residual water content not higher than 1,400 ppm) and a treatment step of said heavy fraction by means of microwave irradiation (in continuous or pulsed mode), operating at temperatures ranging from 50 to 350°C, for a time period of between 1 second and 120 minutes and with frequencies ranging from 0.3 to 300 GHz.
摘要翻译：降低基本上包括所述原油的分离步骤的原油的粘度的方法（以便分离残余水含量不高于1400ppm的轻馏分和重馏分）以及通过微波辐射（以连续或脉冲模式）在50至350℃的温度范围内操作1秒至120分钟的时间段和频率范围为0.3至10℃的所述重馏分的处理步骤 300 GHz。

4. 发明申请

WO2010142397A2 PROCESS FOR RECOVERING METALS FROM A STREAM RICH IN HYDROCARBONS AND CARBONACEOUS RESIDUES 审中-公开
标题翻译：从碳氢化合物和碳氢化合物中回收金属的方法
公开(公告)号：WO2010142397A2
公开(公告)日：2010-12-16
申请号：PCT/EP2010/003345
申请日：2010-06-01
申请人： ENI S.P.A. , BARTOLINI, Andrea , CORNARO, Ugo , POLLESEL, Paolo , OUDENNE, Paul, Dominique
发明人： BARTOLINI, Andrea , CORNARO, Ugo , POLLESEL, Paolo , OUDENNE, Paul, Dominique
IPC分类号： C10G47/26
CPC分类号： C10G47/26 , B01J23/28 , B01J23/92 , B01J38/02 , B01J38/72 , C10G49/12 , C10G49/22 , C10G2300/1025 , C10G2300/205 , C10G2300/301 , C10G2300/4006 , C10G2300/4081 , C22B3/20 , C22B7/001 , Y02P10/214 , Y02P10/234
摘要： A process for recovering metals from a stream rich in hydrocarbons and carbonaceous residues by means of a treatment section, characterized in that it comprises the following steps: sending said stream to a primary treatment, effected in one or more steps, wherein said stream is treated in the presence of a fluxant agent in a suitable apparatus, at a temperature ranging from 80 to 180°C, preferably from 100 to 160°C, and subjected to liquid/solid separation in order to obtain a clarified product essentially consisting of liquids and a cake (oilcake); possibly subjecting the separated cake to drying, in order to remove the hydrocarbon component having a boiling point lower than a temperature ranging from 300 to 350°C from the cake; sending the cake, possibly dried, to a secondary thermal treatment comprising: a flameless pyrolysis of the cake effected between 400 and 800°C, preferably between 500 and 670°C; an oxidation of the pyrolysis residue effected in an oxidizing environment and at temperatures ranging from 400 to 800°C, preferably from 500 to 700°C.
摘要翻译：一种通过处理部分从富含烃和碳质残余物的物流中回收金属的方法，其特征在于其包括以下步骤：将一个或多个步骤中的所述物流送入初级处理，其中所述物流被处理在合适的装置中，在80至180℃，优选100至160℃的温度范围内，存在助剂，并进行液/固分离，以获得基本上由液体和一块蛋糕（油饼）; 可能使分离的饼干经历干燥，以便从饼中除去沸点低于300-350℃的沸点的烃成分; 将可能干燥的蛋糕送到二次热处理中，其包括：在400和800℃之间，优选在500和670℃之间进行无蛋白质的热解; 在氧化环境和400至800℃，优选500至700℃的温度范围内进行热解残留的氧化。

5. 发明申请

WO2013034642A1 CATALYTIC SYSTEM AND PROCESS FOR THE TOTAL HYDROCONVERSION OF HEAVY OILS 审中-公开
标题翻译：催化体系及重油总氢过程
公开(公告)号：WO2013034642A1
公开(公告)日：2013-03-14
申请号：PCT/EP2012/067412
申请日：2012-09-06
申请人： ENI S.P.A. , MOLINARI, Daniele , BELLUSSI, Giuseppe , LANDONI, Alberto , POLLESEL, Paolo
发明人： MOLINARI, Daniele , BELLUSSI, Giuseppe , LANDONI, Alberto , POLLESEL, Paolo
IPC分类号： B01J27/051 , B01J29/78 , C10G45/12
CPC分类号： B01J29/89 , B01J27/051 , B01J29/7876 , C10G45/12 , C10G47/16 , C10G65/12
摘要： A catalytic system characterized in that it comprises: a first catalyst, having a hydrogenating function, consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 μm, containing one or more sulfides of metals of group VI and/or VIII B, possibly prepared starting from an oil- soluble precursor of the same; and a second catalyst, having a cracking function, consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 μm and smaller than 5 mm, containing an amorphous silico- aluminate and/or a crystalline silico-aluminate and/or an alumina, the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst. Said catalytic system can be used in a process for the hydroconversion of heavy oils which comprises sending the heavy oil to a hydroprocessing step carried out in one or more slurry reactors, in the presence of hydrogen or a mixture of hydrogen and H 2 S, obtaining a stream of products in vapour or liquid-vapour phase, and extracting at the bottom, in continuous or discontinuous, a liquid stream containing non-converted products together with the two catalysts of said catalytic system, said liquid stream extracted then being separated into a clarified primary stream containing the first catalyst, which is at least partially recycled to the hydroprocessing step, and a stream rich in the second catalyst, which is regenerated in a regeneration step and at least partially recycled to the hydroprocessing step.
摘要翻译：一种催化体系，其特征在于它包括：具有氢化功能的第一催化剂，其由至少95体积％的当量直径小于20μm的固体颗粒组成，其含有一种或多种第VI族金属的硫化物，和 /或VIII B，可能从其油溶性前体开始制备; 和具有裂化功能的第二催化剂，其由固体颗粒组成，其中至少90体积％的当量直径大于5μm且小于5mm，其含有非晶硅铝酸盐和/或结晶硅铝酸盐和/或氧化铝，所述第二催化剂的固体颗粒的当量平均直径大于所述第一催化剂的固体颗粒的当量平均直径。所述催化体系可用于重油加氢转化的方法，其包括将重油送入在一种或多种淤浆反应器中，在氢气或氢气和H 2 S的混合物存在下进行的加氢处理步骤，获得流的蒸气或液相 - 蒸气相中的产物，并且连续或不连续地将含有未转化产物的液体物流与所述催化体系的两种催化剂一起萃取，然后将所述液体流分离成澄清的初级含有至少部分再循环到加氢处理步骤的第一催化剂的物流和富含第二催化剂的物流，其在再生步骤中再生并且至少部分地循环到加氢处理步骤。

6. 发明申请

WO2006094612A1 PROCESS FOR THE REMOVAL BY OXIDATION, OF MERCAPTANS CONTAINED IN HYDROCARBONS 审中-公开
标题翻译：通过氧化剂除去含有碳氢化合物的梅尔卡普坦的方法
公开(公告)号：WO2006094612A1
公开(公告)日：2006-09-14
申请号：PCT/EP2006/001443
申请日：2006-02-15
申请人： ENI S.P.A. , ENITECNOLOGIE S.P.A. , DE ANGELIS, Alberto , POLLESEL, Paolo
发明人： DE ANGELIS, Alberto , POLLESEL, Paolo
IPC分类号： C10G27/00 , C10G27/04 , C10L3/10 , B01J27/199 , C07C319/24
CPC分类号： C07C319/14 , B01J23/002 , B01J27/199 , B01J2523/00 , C07C319/24 , C10G27/00 , C10L3/10 , C10L3/102 , C07C321/14 , B01J2523/51 , B01J2523/55 , B01J2523/68
摘要： The mercaptans R-SH contained in a hydrocarbon stream are oxidized to the corresponding (di)sulfides by means of a redox system which comprises trivalent iron and a heteropolyacid which allows the complete reoxidation of the reduced iron also with air.
摘要翻译：通过包含三价铁和杂多酸的氧化还原体系将包含在烃流中的硫醇R-SH氧化成相应的（二）硫化物，其允许还用空气完全还原还原铁。

7. 发明申请

WO2009018932A3 INTEGRATED FLUID CATALYTIC CRACKING PROCESS FOR OBTAINING HYDROCARBON BLENDS HAVING A HIGH QUALITY AS FUEL 审中-公开
公开(公告)号：WO2009018932A3
公开(公告)日：2009-02-12
申请号：PCT/EP2008/006176
申请日：2008-07-21
申请人： ENI S.P.A. , RISPOLI, Giacomo , MOGGI, Alberto , FARACI, Giovanni , POLLESEL, Paolo
发明人： RISPOLI, Giacomo , MOGGI, Alberto , FARACI, Giovanni , POLLESEL, Paolo
IPC分类号： B01J21/12 , B01J23/40 , B01J29/74 , C10G11/00 , C10G11/18 , C10G45/62 , C10G69/04
摘要： The present invention relates to an integrated fluid catalytic cracking process (FCC) which allows hydrocarbon blends to be obtained having a high quality as fuel. In particular, it relates to an integrated process comprising a fluid catalytic cracking step wherein hydrocarbon cuts of an oil origin are converted into blends with a high content of light cycle oil (LCO) having a high quality in terms of density and nature of the aromatic products contained, which, after a separation and a hydrotreating step, is subjected to upgrading by treatment with hydrogen and a catalyst comprising one or more metals selected from Pt, Pd, Ir, Ru, Rh and Re and a silicoaluminate of an acidic nature.

8. 发明申请

WO2009086924A2 PROCESS FOR STABILIZING THE PERFORMANCES OF A CATALYST FOR FISCHER TROPSCH REACTION 审中-公开
标题翻译：用于稳定FISCHER TROPSCH反应的催化剂性能的方法
公开(公告)号：WO2009086924A2
公开(公告)日：2009-07-16
申请号：PCT/EP2008/011174
申请日：2008-12-29
申请人： ENI S.P.A , INSTITUT FRANCAIS DU PETROLE , TASSO, Andrea , ROSSINI, Stefano , POLLESEL, Paolo
发明人： TASSO, Andrea , ROSSINI, Stefano , POLLESEL, Paolo
CPC分类号： C10G2/342 , B01J8/22 , B01J23/8476 , B01J23/8913 , B01J35/023 , B01J35/1061 , B01J2219/00162 , C07C1/047 , C10G2/332
摘要： Process for maintaining the stability of performances of a catalyst for Fischer-Tropsch reaction, performed in a slurry bubble column reactor under a triphase system, which comprises gradually increasing the P H20 /P H2 ratio and the P H20 /Z ratio, during the start-up phase, with Z = P0 • (T/T 1 ) 4 • e -(K2/(t •K3)) from 0.4 to 0.8, for a period of time not shorter than 100-150 hrs and not longer than 200-300 hours and, at the end of the start-up phase, maintaining the P H20 /P H2 and P H20 /Z ratios substantially equal to or lower than 0.8.
摘要翻译：在三相体系下在浆液鼓泡塔反应器中维持费 - 托反应催化剂的性能稳定性的方法，其包括在启动阶段逐渐增加PH20 / PH2比和PH20 / Z比，Z = P0（T / T1）4 e-（K2 /（t K3））为0.4〜0.8，时间不低于100-150小时，不超过200-300小时，在启动阶段结束，保持PH20 / PH2和PH20 / Z比基本上等于或低于0.8。

9. 发明申请

WO2007028540A1 PROCESS FOR THE REOXIDATION, WITHOUT THE FORMATION OF NITROGEN OXIDES, OF FERROUS SOLUTIONS COMING FROM THE REMOVAL PROCESS IN CONTINUOUS OF HYDROGEN SULFIDE FROM GASEOUS STREAMS BY MEANS OF THE REDOX METHOD 审中-公开
标题翻译：在氧化还原过程中，无法形成氮氧化物，通过REDOX方法从连续流出的硫酸氢盐中除去过程中的有害溶剂
公开(公告)号：WO2007028540A1
公开(公告)日：2007-03-15
申请号：PCT/EP2006/008524
申请日：2006-08-31
申请人： ENI S.P.A. , BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
发明人： BELLUSSI, Giuseppe , DE ANGELIS, Alberto , POLLESEL, Paolo , MILLI, Marcello
IPC分类号： C10L3/10 , C01B17/05 , B01D53/14 , B01D53/52
CPC分类号： B01D53/1468 , B01D53/1418 , B01D53/1425 , B01D53/1493 , C01B17/05 , C10L3/10
摘要： Process for the reoxidation, without the formation of ni¬ trogen oxides, of ferrous solutions used in the removal process in continuous of hydrogen sulfide from gaseous streams containing them, comprising: a) putting a gas containing H∑S in contact with an oxidiz¬ ing acid aqueous solution of ferric nitrate and containing a heteropolyacid having rjedox properties; b) filtrating and separating the sulfur produced; c) reoxidizing the ferrous nitrate to ferric nitrate with air as such or enriched in oxygen at a pressure higher than atmospheric pressure; d) recycling the solution containing ferric nitrate and the heteropolyacid to the oxidation step (a); and e) discharging the air.
摘要翻译：包括：a）将含有H 2 S的气体与氧化物接触，用于在不含氧化物的情况下，再次氧化从含有它们的气流中连续除去硫化氢中的亚铁溶液，酸式硝酸铁水溶液，含有具有杂聚性质的杂多酸; b）过滤和分离产生的硫; c）将空气中的硝酸亚铁还原为硝酸铁，或在高于大气压的压力下富集氧气; d）将含有硝酸铁和杂多酸的溶液再循环到氧化步骤（a）中; 和e）排出空气。

10. 发明申请

WO2014033762A1 METHOD FOR REVAMPING A CONVENTIONAL MINERAL OILS REFINERY TO A BIOREFINERY 审中-公开
标题翻译：将常规矿物油精炼改造为生物制品的方法
公开(公告)号：WO2014033762A1
公开(公告)日：2014-03-06
申请号：PCT/IT2012/000268
申请日：2012-09-04
申请人： ENI S.p.A , RISPOLI, Giacomo Fernando , PRATI, Claudia , AMOROSO, Andrea , POLLESEL, Paolo
发明人： RISPOLI, Giacomo Fernando , PRATI, Claudia , AMOROSO, Andrea , POLLESEL, Paolo
IPC分类号： C10G65/04 , C10G3/00
CPC分类号： C10G3/50 , C10G3/42 , C10G3/52 , C10G45/58 , C10G65/043 , C10G2300/4056 , C10L1/04 , C10L2290/10 , C10L2290/54 , Y02A50/2327 , Y02E50/13 , Y02P30/20 , Y10T29/49346
摘要： The invention relates to a method for revamping a conventional refinery of mineral oils into a biorefinery, characterized by a production scheme which allows the treatment of raw materials of a biological origin (vegetable oils, animal fats, exhausted cooking oils) for the production of biofuels, prevalently high-quality biodiesel. This method allows the re-use of existing plants, allowing, in particular, the revamping of a refinery containing a system comprising two hydrodesulfurization units, U1 and U2, into a biorefinery containing a production unit of hydrocarbon fractions from mixtures of a biological origin containing fatty acid esters by means of their hydrodeoxygenation and isomerization, wherein each of the hydrodesulfurization units U1 and U2 comprises: a hydrodesulfurization reactor, (Al) for the unit U1 and (A2) for the unit U2, wherein said reactor contains a hydrodesulfurization catalyst; one or more heat exchangers between the feedstock and effluent of the reactor; a heating system of the feedstock upstream of the reactor; an acid gas treatment unit downstream of the reactor, containing an absorbent (B) for H2S, said unit being called Tl in the unit U1 and T2 in the unit U2, and wherein said method comprises: installing a line L between the units U1and U2 which connects them in series; installing a recycling line of the product for the unit U1 and possibly for the unit U2, substituting the hydrodesulfurization catalyst in the reactor Al with a hydrodeoxygenation catalyst; substituting the hydrodesulfurization catalyst in the reactor A2 with an isomerization catalyst; installing a y-pass line X of the acid gas treatment unit T2 of the unit U2; substituting the absorbent (B) in the acid gas treatment unit Tl with a specific absorbent for C02 and H2S. The operative configuration obtained with the method, object of the present invention, also leads to a substantial reduction in emissions of pollutants into the atmosphere, with respect to the original operative mode. The invention also relates to the transformation unit of mixtures of a biological origin obtained with said conversion method and particularly hydrodeoxygenation and isomerization processes.
摘要翻译：本发明涉及一种将常规的矿物油精炼改造成生物精炼厂的方法，其特征在于允许将生物来源的原料（植物油，动物脂肪，耗尽的烹饪油）的原料处理用于生产生物燃料，优质的生物柴油。这种方法允许现有设备的再利用，特别是允许将包含两个加氢脱硫单元U1和U2的系统的炼油厂改造成生物精炼厂，该生物精炼厂含有来自含有脂肪酸酯通过其加氢脱氧和异构化，其中每个加氢脱硫单元U1和U2包括：加氢脱硫反应器，用于单元U1的（A1）和用于单元U2的（A2）的加氢脱硫反应器，其中所述反应器含有加氢脱硫催化剂; 反应器的原料和流出物之间的一个或多个热交换器; 反应器上游的原料的加热系统; 在反应器下游的酸性气体处理单元，其中包含用于H 2 S的吸收剂（B），所述单元在单元U1中被称为T1，在单元U2中被称为T1，并且其中所述方法包括：在单元U1和U2之间安装线路L 连接它们; 为单元U1和可能的单元U2安装产品的回收管线，用加氢脱氧催化剂代替反应器A1中的加氢脱硫催化剂; 用异构化催化剂代替反应器A2中的加氢脱硫催化剂; 安装单元U2的酸性气体处理单元T2的y通道X; 用酸性气体处理单元T1中的吸收剂（B）代替CO 2和H 2 S的特定吸收剂。通过本发明的目的获得的操作结构，相对于原始操作模式，也导致大气中污染物排放的实质性减少。本发明还涉及通过所述转化方法获得的生物来源的混合物的转化单元，特别是加氢脱氧和异构化方法。

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