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    • 2. 发明授权
    • Compounds containing a pentalene unit and process for their preparation
    • US09776984B2
    • 2017-10-03
    • US14890824
    • 2014-07-22
    • ENI S.P.A.
    • Gabriele BianchiGiuliana Schimperna
    • C07D333/16C07D333/18C09K11/06H01L51/00
    • C07D333/16C07D333/18C09K11/06C09K2211/1011C09K2211/1092H01L51/0036H01L51/0054H01L51/0068Y02E10/549
    • Compound containing a pentalene unit having general formula (I) wherein R1 and R2, equal to or different from each other, are selected from: linear or branched C1-C20, preferably C2-C12, alkyl groups, saturated or unsaturated, optionally containing heteroatoms, cycloalkyl groups optionally substituted, linear or branched C1-C20, preferably C2-C12, alkoxyl groups, saturated or unsaturated, optionally substituted; or the groups R1 and R2 can be optionally bound to each other so as to form, together with the carbon atoms to which they are bound, a cycle or a polycyclic system containing from 3 to 14 carbon atoms, preferably from 4 to 6 carbon atoms, saturated, unsaturated, or aromatic, optionally containing one or more heteroatoms such as, for example, oxygen, sulfur, nitrogen, silicon, phosphorous, selenium; R3 is selected from aryl groups optionally substituted, heteroaryl groups optionally substituted; n is 0 or 1; with the proviso that: when n is 0, X represents a covalent bond and Y represents a sulfur atom (S); when n is 1, X is equal to Y, and represents a CH group, or a nitrogen atom (N). Said compound containing a pentalene unit, as such or after suitable functionalization and polymerization, can be advantageously used in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid and flexible supports. Said compound containing a pentalene unit can also be advantageously used as a constitutive unit of luminescent solar concentrators (LSCs). Furthermore, said compound containing a pentalene unit can be advantageously used as precursor of monomeric units in the preparation of semiconductor polymers.
    • 3. 发明授权
    • Process for the preparation of benzohetero [1, 3] diazole compounds disubstituted with heteroaryl groups
    • 用杂芳基二取代的苯并[3,4]二唑化合物的制备方法
    • US09328109B2
    • 2016-05-03
    • US14759328
    • 2014-01-13
    • ENI S.p.A.
    • Gabriele BianchiRiccardo Po'
    • C07D417/14
    • C07D417/14
    • Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentrators”). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductor polymers.
    • 制备用溴化杂芳基二取代的苯并[13]二唑化合物的方法,其包括使至少一种二卤代苯并[1,3]二唑化合物与至少一种溴化杂芳基化合物反应。 用溴化杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用于合成可用于太阳能聚光器(LSCs-“发光太阳能集中器”)的构建中的化合物。 此外,用溴化杂芳基二取代的所述苯并[1,3]二噻唑化合物可有利地用于合成可用于构建光伏器件(或太阳能器件)的光聚合物,例如光伏电池(或太阳能电池 ),光伏模块(或太阳能模块),在刚性或柔性支撑件上。 此外,用溴化杂芳基二取代的所述苯并[1,3]二唑化合物可有利地用作半导体聚合物合成中单体单元的前体。
    • 4. 发明授权
    • Conjugated polymers including an indacen-4-one derivative, procedure for their preparation and photovoltaic devices comprising the same
    • US11430957B2
    • 2022-08-30
    • US17277897
    • 2019-09-18
    • ENI S.P.A.
    • Gabriele Bianchi
    • H01L51/00C08G61/12H01L51/42
    • There is a conjugated polymer having a derivative of indacen-4-one having general formula (I): wherein: R1 and R2, same or different, are selected from C1-C30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; optionally substituted heteroaryl groups; C1-C30 alkoxyl groups, linear or branched; R4—O—[CH2—CH2—O]m— polyoxyethylene groups, wherein R4 is selected from C1-C30 alkyl groups, linear or branched, and m is an integer ranging from 1 to 4; —R5—OR6 groups, wherein R5 is selected from C1-C30 alkylene groups, linear or branched, and R6 represents a hydrogen atom or is selected from C1-C30 alkyl groups, linear or branched, or is selected from R4—[—OCH2—CH2—]p— polyoxyethylene groups, wherein R4 has the same meanings as reported above and p is an integer ranging from 1 to 4; —COR7 groups, wherein R7 is selected from C1-C30 alkyl groups, linear or branched; —COOR8 groups, wherein R8 is selected from C1-C30 alkyl groups, linear or branched; or they represent a —CHO group or a cyano (—CN) group; R3 is selected from C1-C30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; and C1-C30 alkoxyl groups, linear or branched; n is an integer ranging from 10 to 500. There is also a photovoltaic device (or solar device) having a support having the conjugated polymer having a derivative of indacen-4-one.
    • 9. 发明申请
    • CONJUGATED POLYMERS INCLUDING AN INDACEN-4-ONE DERIVATIVE, PROCEDURE FOR THEIR PREPARATION AND PHOTOVOLTAIC DEVICES COMPRISING THE SAME
    • US20210351355A1
    • 2021-11-11
    • US17277897
    • 2019-09-18
    • ENI S.P.A.
    • Gabriele Bianchi
    • H01L51/00C08G61/12
    • There is a conjugated polymer having a derivative of indacen-4-one having general formula (I): wherein: R1 and R2, same or different, are selected from C1-C30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; optionally substituted heteroaryl groups; C1-C30 alkoxyl groups, linear or branched; R4—O—[CH2—CH2—O]m— polyoxyethylene groups, wherein R4 is selected from C1-C30 alkyl groups, linear or branched, and m is an integer ranging from 1 to 4; —R5—OR6 groups, wherein R5 is selected from C1-C30 alkylene groups, linear or branched, and R6 represents a hydrogen atom or is selected from C1-C30 alkyl groups, linear or branched, or is selected from R4—[—OCH2—CH2—]p— polyoxyethylene groups, wherein R4 has the same meanings as reported above and p is an integer ranging from 1 to 4; —COR7 groups, wherein R7 is selected from C1-C30 alkyl groups, linear or branched; —COOR8 groups, wherein R8 is selected from C1-C30 alkyl groups, linear or branched; or they represent a —CHO group or a cyano (—CN) group; R3 is selected from C1-C30 alkyl groups, linear or branched; optionally substituted cycloalkyl groups; optionally substituted aryl groups; and C1-C30 alkoxyl groups, linear or branched; n is an integer ranging from 10 to 500. There is also a photovoltaic device (or solar device) having a support having the conjugated polymer having a derivative of indacen-4-one.