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    • 9. 发明申请
    • METHOD FOR PURIFYING METHANESULPHONYL CHLORIDE
    • 纯化甲磺酰氯的方法
    • WO1997003952A1
    • 1997-02-06
    • PCT/FR1996001099
    • 1996-07-16
    • ELF ATOCHEM S.A.COMMARIEU, AnnieOLLIVIER, Jean
    • ELF ATOCHEM S.A.
    • C07C303/44
    • C07C303/44C07C309/80
    • A method for purifying methanesulphonyl chloride (MSC) and particularly for substantially reducing the amount of sulphuric acid that would otherwise be contained in methanesulphonic acid produced at a later stage by hydrolysing MSC. According to the method, MSC is treated with at least one powdered or shaped solid selected from (1) activated charcoals; (2) substances known to be convertible into water-insoluble SO4 counter-cations; (3) inorganic solids known to be capable of trapping SO4 anions in aqueous media by means of an exchange with other anions in the structures of said solids; (4) anion exchange resins known to be capable of trapping SO4 anions in aqueous media by means of an exchange with other anions in the structures of said resins; and (5) solids known to be capable of interacting with SO4 anions in aqueous media, the purified MSC then being separated from the solid phase with which the sulphates to be removed have combined.
    • 一种用于纯化甲磺酰氯(MSC)的方法,特别是用于基本上减少后续阶段通过水解MSC产生的甲磺酸中所含的硫酸的量。 根据该方法,用至少一种选自(1)活性炭的粉末或成形固体处理MSC; (2)已知可转化为不溶于水的SO4 <2->抗衡阳离子的物质; (3)已知能够通过与所述固体的结构中的其它阴离子的交换在水性介质中捕获SO 4 2-阴离子的无机固体; (4)已知能够通过与所述树脂的结构中的其它阴离子的交换在水性介质中捕获SO 4 2-阴离子的阴离子交换树脂; 已知能够在水性介质中与SO 4 2-阴离子相互作用的固体的固体和(5)固体,然后与待除去的硫酸盐的固相分离。