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    • 5. 发明申请
    • HOMOGENEOUS CATALYST SYSTEM FOR PRODUCING ETHYLENE HOMOPOLYMER OR ETHYLENE COPOLYMERS WITH ALPHA-OLEFINS
    • 用于生产乙烯共聚物或乙酸乙烯共聚物的均相催化剂体系
    • WO2007029986A1
    • 2007-03-15
    • PCT/KR2006/003583
    • 2006-09-08
    • SK CORPORATIONWOO, Tae WooOK, Myung AhnHAHN, Jong SokKANG, Sang OokJUNG, Jae Ho
    • WOO, Tae WooOK, Myung AhnHAHN, Jong SokKANG, Sang OokJUNG, Jae Ho
    • C08F4/64
    • C08F10/00C08F4/65908C08F4/65912C08F210/16C08F4/6592C08F210/14C08F2500/03C08F2/06
    • Disclosed is a homogeneous catalyst system for producing an ethylene homopolymer or an ethylene copolymer with α-olefin. Specifically, this invention pertains to a transition metal catalyst which has stability under high temperature solution polymerization at 120 ~ 250 °C, in which a cyclopentadiene derivative and an electron donating substituent, both of which are bonded to a Group IV transition metal acting as a central metal, are crosslinked through a silyl derivative substituted with a cyclohexyl, to a catalyst system including such a transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and to a method of producing an ethylene homopolymer or an ethylene copolymer with α-olefin, having high molecular weight, using the catalyst system under conditions of high-temperature solution polymerization. The catalyst according to this invention has excellent thermal stability and compatibility with a paraffin hydrocarbon solvent and thus is effective in the production of an ethylene homopolymer or an ethylene copolymer with α-olefm having various properties in commercial polymerization processes.
    • 公开了用于生产乙烯均聚物或与α-烯烃的乙烯共聚物的均相催化剂体系。 具体地说,本发明涉及在120〜250℃的高温溶液聚合中具有稳定性的过渡金属催化剂,其中环戊二烯衍生物和给电子取代基都与作为 中间金属通过由环己基取代的甲硅烷基衍生物交联到包括这种过渡金属催化剂和铝氧烷助催化剂或硼化合物助催化剂的催化剂体系中,以及制备乙烯均聚物或乙烯共聚物的方法, 烯烃,具有高分子量,在高温溶液聚合条件下使用催化剂体系。 根据本发明的催化剂具有优异的热稳定性和与链烷烃溶剂的相容性,因此在商业聚合方法中生产具有各种性质的α-烯烃的乙烯均聚物或乙烯共聚物是有效的。