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    • 4. 发明申请
    • SCUFF RESISTANT COMPOSITIONS COMPRISING ETHYLENE ACID COPOLYMERS AND POLYAMIDES
    • 包含乙烯酸共聚物和聚酰胺的耐冲击组合物
    • WO2004113445A1
    • 2004-12-29
    • PCT/US2004/018238
    • 2004-06-04
    • E.I. DUPONT DE NEMOURS AND COMPANYCHOU, Richard, T.HAUSMANN, Karlheinz
    • CHOU, Richard, T.HAUSMANN, Karlheinz
    • C08L77/00
    • B32B27/08B32B27/20B32B27/308B32B27/32B32B27/34B32B27/36B32B37/153B32B2307/412B32B2307/584B32B2307/756B32B2323/04B32B2333/12B32B2367/00B32B2377/00B32B2419/04B32B2451/00B32B2553/00B32B2571/00C08L23/02C08L23/0876C08L77/00C08L77/02C08L77/06C08L2666/20C08L2666/06
    • Disclosed are compositions of ethylene acid copolymers and polyamides that are useful for fabricating films, sheets and molded articles for scuff and scratch resistant material and their application as decorative and protective films, comprising (1) from about 30 to about 65 weight % of a polyamide; and (2) from about 70 to about 35 weight % of a copolymer of (a) ethylene; (b) from about 5 weight % to about 15 weight % of an &agr;,ß unsaturated C?3#191-C?8#191 carboxylic acid; (c) from about 0.5 weight % to about 12 weight % of at least one comonomer that is an ethylenically unsaturated dicarboxylic acid; and (d) from 0 weight % to about 30 weight % of monomers selected from alkyl acrylate and alkyl methacrylate, wherein the alkyl groups have from one to twelve carbon atoms; at least partially neutralized by one or more alkali metal, transition metal, or alkaline earth metal cations. Articles prepared from these compositions, such as films, show high toughness, good mechanical properties, excellent scratch and scuff resistance and, most importantly, good optical properties. More particularly, the compositions of ethylene copolymers and polyamides of the present invention can be used as protective coatings or layers on scuff- and scratch-exposed objects.
    • 公开了可用于制造用于防刮擦和耐划伤材料的薄膜,片材和模塑制品的乙烯酸共聚物和聚酰胺的组合物,以及它们作为装饰和保护膜的应用,其包含(1)约30至约65重量%的聚酰胺 ; 和(2)约70-约35重量%的(a)乙烯共聚物; (b)约5重量%至约15重量%的α,β不饱和C <3#191-C 8#191羧酸; (c)约0.5重量%至约12重量%的至少一种作为烯属不饱和二羧酸的共聚单体; 和(d)0重量%至约30重量%的选自丙烯酸烷基酯和甲基丙烯酸烷基酯的单体,其中烷基具有1至12个碳原子; 至少部分被一种或多种碱金属,过渡金属或碱土金属阳离子中和。 由这些组合物制备的制品,例如薄膜,显示出高韧性,良好的机械性能,优异的耐划伤性和耐擦伤性,最重要的是具有良好的光学性能。 更具体地,本发明的乙烯共聚物和聚酰胺的组合物可以用作防刮伤和刮擦暴露物体上的保护性涂层或层。