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    • 2. 发明公开
    • POLYPHENYLENE SULFIDE ALLOY COATED WIRE
    • 在带有混纺POLPHENYLEN硫化物包覆丝
    • EP1428229A1
    • 2004-06-16
    • EP02759182.5
    • 2002-07-25
    • E. I. du Pont de Nemours and Company
    • DEAN, David, M.ARHART, Richard, James
    • H01B3/18H01B3/30C08L81/04C08L81/02
    • H01B3/441C08L81/02C08L2205/05H01B3/301Y10T428/2933Y10T428/294Y10T428/2962C08L2666/24C08L2666/04
    • The present invention relates an electrically conductive wire having a metal core and an outer electrically insulative, polymer coating wherein the polymer composition contains polyphenylene sulfide, a polymeric grafting agent and an ethylene copolymer. The polymeric grafting agent is a copolymer of at least about 50% by weight ethylene, about 0.5% to about 15% by weight of a reactive comonomer selected from the group consisting of: (i) an unsaturated epoxide of 4-11 carbon atoms, (ii) an unsaturated isocyanate of 2-11 carbon atoms, (iii) an unsaturated alkoxy silane and/or unsaturated alkyl silane wherein the alkoxy or alkyl group is from 1-12 carbon atoms, and (iv) an oxazoline; and about 0 to about 49% by weight of a third optional comonomer selected from at least one of an alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, where the alkyl and ether groups are of 1-12 carbon atoms. The ethylene copolymer comprises at least about 50% by weight ethylene, about 1% to about 35% by weight of an acid-containing unsaturated mono-carboxylic acid, and about 0 to about 49% by weight of a moiety selected from at least one of alkyl acrylate, alkyl methacrylate, vinyl ether, carbon monoxide, and sulfur dioxide, and further wherein the acid groups are neutralized from 0-100% by a metal ion. Such wire meets SAE J1678 specifications at 125°C or higher at a thickness of polymeric coating of less than 12 mils and/or withstands temperatures as high as 150°C at a thickness of polymeric coating of from 15 mils to 30 mils.