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1. 发明授权

US5693742A Solventless method for making polyarylene ethers 失效
标题翻译：制备聚亚芳基醚的无溶剂方法
公开(公告)号：US5693742A
公开(公告)日：1997-12-02
申请号：US522165
申请日：1995-09-15
申请人： Dwain Montgomery White , Margaret Louise Blohm , David Winfield Woodruff , Sterling Bruce Brown
发明人： Dwain Montgomery White , Margaret Louise Blohm , David Winfield Woodruff , Sterling Bruce Brown
IPC分类号： C08G65/38 , C08G65/44
CPC分类号： C08G65/44
摘要： A method for making polyarylene ethers comprises the step of melt polymerizing phenolic monomers in the presence of oxygen and oxidative coupling catalysts without employing environmentally unfriendly solvents.
摘要翻译：制备聚亚芳基醚的方法包括在氧气和氧化偶合催化剂的存在下熔融聚合酚类单体的步骤，而不使用环境不友好的溶剂。

2. 发明授权

US06559270B1 Weatherable block copolyestercarbonates and blends containing them, and method 有权
标题翻译：耐候性共聚酯碳酸酯和含有它们的混合物，以及方法
公开(公告)号：US06559270B1
公开(公告)日：2003-05-06
申请号：US09416529
申请日：1999-10-12
申请人： Tiberiu Mircea Siclovan , Jimmy Lynn Webb , Sterling Bruce Brown , Donald Joseph Buckley, Jr. , James Edward Pickett , Joseph Anthony Suriano , Paul Dean Sybert , Daniel Joseph Brunelle , Margaret Louise Blohm , Hongyi Zhou , Georgia Dris Fishburn
发明人： Tiberiu Mircea Siclovan , Jimmy Lynn Webb , Sterling Bruce Brown , Donald Joseph Buckley, Jr. , James Edward Pickett , Joseph Anthony Suriano , Paul Dean Sybert , Daniel Joseph Brunelle , Margaret Louise Blohm , Hongyi Zhou , Georgia Dris Fishburn
IPC分类号： C08G6401
CPC分类号： C08L67/00 , C08G63/64 , C08G63/78 , C08G64/18 , C08G2261/126 , C08K3/013 , C08L67/02 , C08L67/03 , C08L69/00 , C08L69/005 , C08L79/08 , F02B61/045
摘要： Block copolyestercarbonates may be prepared by first conducting a reaction between at least one of resorcinol or an alkyl- or haloresorcinol and at least one aromatic dicarboxylic acid dichloride, preferably isophthaloyl dichloride, terephthaloyl dichloride or a mixture thereof, to produce a hydroxy-terminated polyester intermediate, and then conducting a reaction of the intermediate with a carbonate precursor, preferably in the presence of a dihydroxy compound such as bisphenol A. The products have excellent physical properties, including a high degree of weatherability. They may be blended with other polymers such as polycarbonates, poly(alkylene carboxylates), polyarylates, polyetherimides, and addition polymers to improve the weatherability thereof.
摘要翻译：嵌段共聚酯碳酸酯可以通过首先在间苯二酚或烷基 - 或卤代间苯二酚和至少一种芳族二羧酸二氯化物，优选间苯二酰氯，对苯二甲酰氯或其混合物中的至少一种之间进行反应来制备，以产生羟基封端的聚酯中间体，然后进行中间体与碳酸酯前体的反应，优选在二羟基化合物如双酚A的存在下进行。产物具有优异的物理性能，包括高度的耐候性。它们可以与其他聚合物如聚碳酸酯，聚（亚烷基羧酸酯），聚芳酯，聚醚酰亚胺和加成聚合物共混以改善其耐候性。

3. 发明授权

US5837758A Compositions of poly (phenylene ether), poly (arylene sulfide) and ortho ester compounds 失效
标题翻译：聚（亚苯基醚），聚（亚芳基硫醚）和原酸酯化合物的组合物
公开(公告)号：US5837758A
公开(公告)日：1998-11-17
申请号：US687263
申请日：1996-07-25
申请人： Sterling Bruce Brown , Chorng-Fure Robin Hwang , Steven Thomas Rice , James Joseph Scobbo, Jr. , John Bennie Yates, III , Farid F. Khouri
发明人： Sterling Bruce Brown , Chorng-Fure Robin Hwang , Steven Thomas Rice , James Joseph Scobbo, Jr. , John Bennie Yates, III , Farid F. Khouri
IPC分类号： C08K3/34 , C08K5/1565 , C08K7/04 , C08K7/06 , C08K7/14 , C08K7/20 , C08L71/00 , C08L71/12 , C08L81/02
CPC分类号： C08K5/1565 , C08L71/12 , C08L81/02
摘要： Compositions are provided which comprise a poly(phenylene ether) resin, a poly(arylene sulfide) resin and an ortho ester compound. The compositions can further comprise compatibilizing agents and reinforcing fillers to provide compositions that exhibit low flash molding characteristics. Articles molded from these compositions are useful in the electrical connector industry.
摘要翻译：提供了包含聚（苯醚）树脂，聚（亚芳基硫醚）树脂和原酸酯化合物的组合物。组合物还可以包含相容剂和增强填料，以提供显示低闪蒸成型特性的组合物。由这些组合物成型的制品可用于电连接器行业。

4. 发明授权

US5698632A Compatible compositions of poly(phenylene ether) resins and semi-crystalline resins 失效
标题翻译：聚（苯醚）树脂和半结晶树脂的兼容组合物
公开(公告)号：US5698632A
公开(公告)日：1997-12-16
申请号：US582690
申请日：1996-01-04
申请人： Sterling Bruce Brown , Chorng-Fure Robin Hwang , Farid Fouad Khouri , Steven Thomas Rice , James Joseph Scobbo, Jr. , John Bennie Yates
发明人： Sterling Bruce Brown , Chorng-Fure Robin Hwang , Farid Fouad Khouri , Steven Thomas Rice , James Joseph Scobbo, Jr. , John Bennie Yates
IPC分类号： C08K5/05 , C08F8/00 , C08G64/42 , C08G65/48 , C08K5/06 , C08K5/09 , C08K5/092 , C08K5/11 , C08K5/17 , C08K5/20 , C08K5/25 , C08K5/3412 , C08L23/02 , C08L51/08 , C08L67/00 , C08L67/02 , C08L71/00 , C08L71/12 , C08L67/03 , C08L67/04
CPC分类号： C08L67/02 , C08G64/42 , C08G65/48 , C08L71/126 , C08L23/02
摘要： Compatibilized blends of poly(phenylene ether) resins and polyester resins are provided from nucleophile containing poly(phenylene ether) resins and polyester resins and compatibilizer compounds to afford articles having good impact, ductility and tensile properties. The compositions may further comprise impact modifiers, metal salts, reinforcing agents, flame retardants and flow promoters. Articles made from the compositions are useful for automotive components.
摘要翻译：由含有亲核试剂的聚（苯醚）树脂和聚酯树脂和增容剂化合物提供聚（苯醚）树脂和聚酯树脂的相容共混物，以提供具有良好冲击，延展性和拉伸性能的制品。组合物还可以包含抗冲改性剂，金属盐，增强剂，阻燃剂和流动促进剂。由组合物制成的制品可用于汽车部件。

5. 发明授权

US06753365B2 Polyetherimide composition, method, and article 有权
标题翻译：聚醚酰亚胺组合物，方法和制品
公开(公告)号：US06753365B2
公开(公告)日：2004-06-22
申请号：US09683805
申请日：2002-02-19
申请人： Sterling Bruce Brown , Jennifer L. David , Robert Russell Gallucci , Yimin Jin , Martin J. Lindway
发明人： Sterling Bruce Brown , Jennifer L. David , Robert Russell Gallucci , Yimin Jin , Martin J. Lindway
IPC分类号： C08K553
CPC分类号： C08K5/09 , C08K5/1345 , C08K5/49 , C08L67/02 , C08L79/08
摘要： A composition useful in the manufacturing of plastic cookware includes a polyetherimide resin and an acidic additive selected from the group consisting of aliphatic carboxylic acids having a vapor pressure less than one atmosphere at 300° C., aromatic carboxylic acids having a vapor pressure less than one atmosphere at 300° C., and combinations comprising at least one of the foregoing acidic additives. In one embodiment, the composition further comprises an additional resin, such as a polyester resin. The acidic additive is effective in improving the mold release and increasing the melt flow of the composition. Articles including the composition and a method for preparing the composition are also described.
摘要翻译：可用于制造塑料炊具的组合物包括聚乙烯酰亚胺树脂和酸性添加剂，其选自蒸汽压在300℃以下蒸气压小于1个大气的脂族羧酸，蒸气压小于1的芳族羧酸在300℃的气氛，以及包含至少一种前述酸性添加剂的组合。在一个实施方案中，组合物还包含另外的树脂，例如聚酯树脂。酸性添加剂有效地改善了脱模并增加了组合物的熔体流动性。还描述了包括组合物的制品和制备该组合物的方法。

6. 发明授权

US5852085A Transparent blends of polyetherimide resins 失效
标题翻译：聚醚酰亚胺树脂的透明共混物
公开(公告)号：US5852085A
公开(公告)日：1998-12-22
申请号：US775697
申请日：1996-12-31
申请人： Sterling Bruce Brown , Stephen Michael Copper , Brenda A. Giles
发明人： Sterling Bruce Brown , Stephen Michael Copper , Brenda A. Giles
IPC分类号： C08K3/22 , C08G81/00 , C08K5/5313 , C08K5/56 , C08L67/03 , C08L69/00 , C08L79/08 , C08L77/06
CPC分类号： C08L69/005 , C08L67/03 , C08L69/00 , C08L79/08
摘要： Disclosed are transparent blends of a polyetherimide, at least one resin selected from the group consisting of polycarbonate resins, poly(ester-carbonate) resins, and polyarylate resins, and an effective amount of a catalyst to provide transparency to the blends. In addition to being transparent, the blends have good ductility as well as high flexural and tensile properties. The yellowness index of the compositions can be improved with the addition of a phosphite.
摘要翻译：公开了聚醚酰亚胺，选自聚碳酸酯树脂，聚（碳酸酯 - 碳酸酯）树脂和聚芳酯树脂中的至少一种树脂的透明共混物和有效量的催化剂以提供共混物的透明性。除了透明之外，共混物具有良好的延展性以及高弯曲和拉伸性能。通过添加亚磷酸酯可以提高组合物的黄度指数。

7. 发明授权

US06303708B1 Functional poly(phenylene ether)/poly(arylene sulfide)/epoxy function alpha olefin elastomer/elastomeric block copolymer/metal salt compositions and process for making thereof 失效
标题翻译：功能性聚（亚苯基醚）/聚（亚芳基硫醚）/环氧官能α-烯烃弹性体/弹性嵌段共聚物/金属盐组合物及其制备方法
公开(公告)号：US06303708B1
公开(公告)日：2001-10-16
申请号：US08405668
申请日：1995-03-17
申请人： Sterling Bruce Brown , Chorng-Fure Robin Hwang , Hiromi Ishida , James Joseph Scobbo, Jr. , John Bennie Yates, III
发明人： Sterling Bruce Brown , Chorng-Fure Robin Hwang , Hiromi Ishida , James Joseph Scobbo, Jr. , John Bennie Yates, III
IPC分类号： C08L5300
CPC分类号： C08L53/00 , C08G65/485 , C08L71/126 , C08L81/00 , Y10S525/925 , C08L2666/14 , C08L2666/02
摘要： A composition is provided which comprises a functionalized poly(phenylene ether) resin, poly(arylene sulfide) resin, epoxy functional alpha-olefin elastomer, elastomeric block copolymer, and a metal salt. The composition is preferably prepared by premixing a poly(phenylene ether) resin with an organic acid and a vinyl aromatic-diene block copolymer to form a premix, and then compounding the premix with an epoxy functional alpha-olefin elastomer, a poly(arylene sulfide) resin and a metal salt of an organic acid. The composition has enhanced levels of mechanical properties such as impact strength, and is suitable for making molded articles such as vertical automotive body panels.
摘要翻译：提供了一种组合物，其包含官能化的聚（苯醚）树脂，聚（亚芳基硫醚）树脂，环氧官能的α-烯烃弹性体，弹性体嵌段共聚物和金属盐。组合物优选通过将聚苯醚树脂与有机酸和乙烯基芳族 - 二烯嵌段共聚物预混合以制备预混物，然后将预混物与环氧官能α-烯烃弹性体，聚（亚芳基硫醚）树脂和有机酸的金属盐。组合物具有增强的机械性能水平，例如冲击强度，并且适用于制造诸如垂直汽车车身板的模制品。

8. 发明授权

US6150473A Polyetherimide resin/polyester resin blends having improved properties 有权
标题翻译：具有改进性能的聚醚酰亚胺树脂/聚酯树脂共混物
公开(公告)号：US6150473A
公开(公告)日：2000-11-21
申请号：US211304
申请日：1998-12-14
申请人： Sterling Bruce Brown , Yimin Jin , James F. Kelley , Jun Liao , Michael Teruki Takemori , Raymond Lee Utley
发明人： Sterling Bruce Brown , Yimin Jin , James F. Kelley , Jun Liao , Michael Teruki Takemori , Raymond Lee Utley
IPC分类号： C08K5/00 , C08K5/1515 , C08L63/00 , C08L67/02 , C08L79/08
CPC分类号： C08L67/02 , C08K5/005 , C08K5/1515 , C08L79/08
摘要： The present invention is directed to a thermoplastic resin composition comprising one or more polyetherimide resins; one or more polyester resins; at least one epoxy compound having one or more epoxy functional groups per molecule in an amount effective to improve at least one of impact resistance, hydrolytic resistance, and tab-bending performance of a molded specimen of the composition; and optionally, at least one catalyst in an amount effective to improve at least one of impact resistance, hydrolytic resistance, and tab-bending performance of a molded specimen of the composition as compared to the same composition not containing the catalyst. It was unexpectedly found that the compositions exhibited enhanced heat, impact, hydrolytic resistance, and/or enhanced tab-bending performance over other compositions known in the art. In a preferred embodiment, the epoxy compound contains 3,4-epoxycyclohexylmethyl-3,4-epoxycyclohexanecarboxylate and the catalyst contains sodium stearate.
摘要翻译：本发明涉及一种包含一种或多种聚醚酰亚胺树脂的热塑性树脂组合物; 一种或多种聚酯树脂; 至少一种每分子具有一个或多个环氧官能团的环氧化合物，其量可以有效地改善组合物的模制样品的抗冲击性，抗水解性和弯曲弯曲性能中的至少一种; 和任选的至少一种催化剂，其量可以有效地改善与不含催化剂的相同组合物相比，该组合物的模塑试样的耐冲击性，耐水解性和弯曲弯曲性能中的至少一种。意外地发现，与本领域已知的其它组合物相比，组合物显示出增强的热，冲击，抗水解性和/或增强的弯片弯曲性能。在优选的实施方案中，环氧化合物含有3,4-环氧环己基甲基-3,4-环氧环己烷羧酸酯，催化剂含有硬脂酸钠。

9. 发明授权

US07547749B2 Triazine compounds, polymers comprising triazine structural units, and method 有权
标题翻译：三嗪化合物，包含三嗪结构单元的聚合物和方法
公开(公告)号：US07547749B2
公开(公告)日：2009-06-16
申请号：US11766122
申请日：2007-06-21
申请人： Sterling Bruce Brown , Hans-Peter Brack , James Anthony Cella , Dennis Karlik
发明人： Sterling Bruce Brown , Hans-Peter Brack , James Anthony Cella , Dennis Karlik
IPC分类号： C08G64/42 , C08G64/00 , C08G65/48 , C08G65/44
CPC分类号： C07D405/12 , C07D251/26 , C07D251/34 , C07D405/14 , C08G65/485
摘要： In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.
摘要翻译：在各种实施方案中，本发明包含2,4,6-三取代-1,3,5-三嗪封端剂，其包含一个，两个或三个离去基团作为取代基，其中任何残留的取代基基本上与在亲核基团上反应的惰性基团聚合物或单体，或者与聚合物或单体上的亲核基团以比任何离去基团更慢的速率反应。本发明还包括具有用三嗪部分封端的亲核基团的聚合物或单体。本发明的其它实施方案包括在聚合物或单体中封端亲核基团的方法，其包括将聚合物或单体与含三嗪的封端剂混合并使其反应。

10. 发明授权

US07235611B2 Triazine compounds, polymers comprising triazine structural units, and method 有权
标题翻译：三嗪化合物，包含三嗪结构单元的聚合物和方法
公开(公告)号：US07235611B2
公开(公告)日：2007-06-26
申请号：US10672789
申请日：2003-09-26
申请人： Sterling Bruce Brown , Hans Peter Brack , James Anthony Cella , Dennis Karlik
发明人： Sterling Bruce Brown , Hans Peter Brack , James Anthony Cella , Dennis Karlik
IPC分类号： C08G64/14 , C08G65/44
CPC分类号： C07D405/12 , C07D251/26 , C07D251/34 , C07D405/14 , C08G65/485
摘要： In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.
摘要翻译：在各种实施方案中，本发明包含2,4,6-三取代-1,3,5-三嗪封端剂，其包含一个，两个或三个离去基团作为取代基，其中任何残留的取代基基本上与在亲核基团上反应的惰性基团聚合物或单体，或者与聚合物或单体上的亲核基团以比任何离去基团更慢的速率反应。本发明还包括具有用三嗪部分封端的亲核基团的聚合物或单体。本发明的其它实施方案包括在聚合物或单体中封端亲核基团的方法，其包括将聚合物或单体与含三嗪的封端剂混合并使其反应。

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