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1. 发明申请

WO2009126415A1 MULTI-STAGE PROCESS AND APPARATUS FOR RECOVERING DICHLOROHYDRINS 审中-公开
标题翻译：用于回收二氯乙烯的多级处理和装置
公开(公告)号：WO2009126415A1
公开(公告)日：2009-10-15
申请号：PCT/US2009/037487
申请日：2009-03-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , HOOK, Bruce, D. , TIRTOWIDJOJO, Dan , MERENOV, Andrei
发明人： HOOK, Bruce, D. , TIRTOWIDJOJO, Dan , MERENOV, Andrei
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： C07C29/82 , B01D3/14 , B01D3/36 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is distilled or fractionated to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture to form a higher boiling fraction comprising the residue of the distillation or fractionation. The higher boiling fraction is distilled or fractionated to separate remaining dichlorohydrin(s) from the above mixture to form an even higher boiling fraction comprising the residue of the distillation or fractionation. At least some of the lower boiling fraction and the dichlorohydrin(s) are recovered. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, reduced capital investment in recovery equipment, and reduced energy utilization while maintaining the quality of dichlorohydrin product produced and not increasing the amount of undesired byproducts formed.
摘要翻译：一种用于从包含二氯代醇的混合物中回收二氯代醇的方法和装置，一种或多种选自二氯丙醇，一氯代醇和/或其酯的化合物和多羟基化脂族烃化合物和/或其酯的化合物，以及任选的一种或多种包含水的物质，公开了氯化剂，催化剂和/或催化剂的酯。将混合物蒸馏或分馏以从混合物中分离包含二氯丙醇的低沸点馏分以形成包含蒸馏或分馏残余物的较高沸点馏分。将较高沸点馏分蒸馏或分馏以从上述混合物中分离剩余的二氯代醇，以形成包含蒸馏或分馏残余物的更高沸点馏分。回收至少一些较低沸点馏分和二氯代丙醇。优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少了浪费，减少了回收设备的资本投入，并降低了能源利用率，同时保持了生产的二氯丙醇产品的质量并且不增加形成不希望的副产物的量。

2. 发明申请

WO2011043803A1 REDUCING IMPURITIES IN SOLID EPOXY RESIN 审中-公开
标题翻译：降低固体环氧树脂的污染
公开(公告)号：WO2011043803A1
公开(公告)日：2011-04-14
申请号：PCT/US2010/002684
申请日：2010-10-05
申请人： DOW GLOBAL TECHNOLOGIES INC. , NEYER, Jane , GU, Leming , HOOK, Bruce, D. , CARLBERG, Philip, J. , MENEFEE, Charles, L. , RIPPLINGER, Eric, B. , BUROW, David, L. , BROOKS, David, R. , YOUNG, Thomas, C.
发明人： NEYER, Jane , GU, Leming , HOOK, Bruce, D. , CARLBERG, Philip, J. , MENEFEE, Charles, L. , RIPPLINGER, Eric, B. , BUROW, David, L. , BROOKS, David, R. , YOUNG, Thomas, C.
IPC分类号： C08G59/00 , C08G59/06
CPC分类号： C08G59/00 , C08G59/063
摘要： Methods of reducing impurities from a solid epoxy resin in a discrete particulate form. The methods include heating a heterogeneous mixture of the solid epoxy resin, while maintaining the solid epoxy resin in discrete particulate form, and a solution to a predetermined temperature below the solid epoxy resin's softening point temperature. Agitating the heterogeneous mixture at the predetermined temperature for a predetermined time to extract ionic species from the solid epoxy resin into the solution and separating the solid epoxy resin in discrete particulate form from the ionic species in solution. The separated solid epoxy resin having a reduced impurity content relative to the heterogeneous mixture prior to heating.
摘要翻译：以离散的颗粒形式从固体环氧树脂中还原杂质的方法。所述方法包括加热固体环氧树脂的不均匀混合物，同时将固体环氧树脂以离散的颗粒形式保持，并将溶液保持在低于固体环氧树脂的软化点温度的预定温度。在预定温度下将非均匀混合物搅拌预定时间以将离子物质从固体环氧树脂中提取到溶液中，并将离散的颗粒形式的固体环氧树脂与溶液中的离子物质分离。分离的固体环氧树脂在加热前相对于异质混合物具有降低的杂质含量。

3. 发明申请

WO2008128014A1 PROCESS AND APPARATUS FOR VAPOR PHASE PURIFICATION DURING HYDROCHLORINATION OF MULTI-HYDROXYLATED ALIPHATIC HYDROCARBON COMPOUNDS 审中-公开
标题翻译：多羟基化学烃类化合物氢化过程中蒸汽相纯化的工艺和装置
公开(公告)号：WO2008128014A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059980
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , HOOK, Bruce, D. , FORLIN, Anna , MERENOV, Andrei, S. , TIRTOWIDJOJO, Danil , MEHTA, Anil, J. , VERWIJS, Jan, Willem , HENSEN, Wilma
发明人： HOOK, Bruce, D. , FORLIN, Anna , MERENOV, Andrei, S. , TIRTOWIDJOJO, Danil , MEHTA, Anil, J. , VERWIJS, Jan, Willem , HENSEN, Wilma
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： B01D3/38 , B01D3/14 , B01D3/146 , B01D3/36 , C07C29/62 , Y02P20/127 , C07C31/42
摘要： A process for converting multihydroxylated- aliphatic hydrocarbon compound(s) and/or ester(s) thereof to chlorohydrins and/or esters thereof is disclosed in which one or more of multihydroxylated- aliphatic hydrocarbon compound(s) and/or ester(s) thereof and/or monochlorohydrin(s) and/or ester(s) thereof with at least one chlorinating feed stream comprising at least one chlorinating agent and at least one impurity having a boiling point below the boiling point of the chlorohydrin product having the lowest boiling under hydrochlorination conditions, optionally in the presence of water, one or more catalyst(s), and/or one or more heavy byproduct(s) in a reaction vessel under hydrochlorination conditions, wherein the liquid-phase reaction mixture is maintained at a temperature below the boiling point of the chlorohydrin product having the lowest boiling point under hydrochlorination conditions and greater than the boiling point(s) of the at least one impurity and a vapor phase vent stream comprising the at least one impurity is removed from the liquid phase reaction mixture. An apparatus suitable for carrying out the disclosed process is illustrated in Figure 1 of the drawings. The process and apparatus improve conversion rates and/or provide for recovery of chlorinating agent for lower operating costs.
摘要翻译：公开了一种将多羟基化脂族烃化合物和/或其酯转化为氯醇和/或其酯的方法，其中一种或多种多羟基化脂族烃化合物和/或酯，和/或一氯代醇和/或其酯与至少一种氯化进料流一起包含至少一种氯化剂和至少一种沸点低于具有最低沸点的氯代醇产物的沸点的杂质在氢氯化条件下，任选地在氢氯化条件下在反应容器中存在水，一种或多种催化剂和/或一种或多种重质副产物，其中将液相反应混合物保持在温度低于在氢氯化条件下具有最低沸点的氯代醇产物的沸点并且大于至少一种杂质的沸点和气相排出流包括从液相反应混合物中除去至少一种杂质。在附图的图1中示出了适用于执行所公开的处理的装置。该方法和设备提高转化率和/或提供氯化剂的回收以降低运行成本。

4. 发明申请

WO2010014896A1 PROCESS FOR PRODUCING EPOXIDES 审中-公开
标题翻译：生产环氧化物的方法
公开(公告)号：WO2010014896A1
公开(公告)日：2010-02-04
申请号：PCT/US2009/052397
申请日：2009-07-31
申请人： DOW GLOBAL TECHNOLOGIES, INC. , FAN, William, W. , KNEUPPER, Christian, D. , NOORMANN, Sascha, N. , PATRASCU, Renate, P. , HOOK, Bruce, D. , LIPP, Charles, W. , CLOETER, Michael, D. , GROENEWALD, Heinz, G.
发明人： FAN, William, W. , KNEUPPER, Christian, D. , NOORMANN, Sascha, N. , PATRASCU, Renate, P. , HOOK, Bruce, D. , LIPP, Charles, W. , CLOETER, Michael, D. , GROENEWALD, Heinz, G.
IPC分类号： C07D301/26 , C07D303/04 , C07D303/08
CPC分类号： C07D301/26 , C07D303/04 , C07D303/08 , Y02P20/127
摘要： A process for producing epoxide, the process including contacting an organic phase including at least one halohydrin(s) with at least one aqueous phase including a base in a plug-flow mixer/reactor system to disperse the organic phase in the aqueous phase via a mixing device imparting a power-to-mass ratio of at least 0.2 W/kg to convert at least a portion of the at least one halohydrin to an epoxide.
摘要翻译：一种生产环氧化物的方法，该方法包括使包含至少一种卤代醇的有机相与至少一种包含碱的水相在活塞流混合器/反应器系统中接触，以通过经由混合装置赋予至少0.2W / kg的功率质量比以将至少一部分卤代醇转化为环氧化物。

5. 发明申请

WO2009129014A1 CONVERSION OF MULTIHYDROXYLATED-ALIPHATIC HYDROCARBON OR ESTER THEREOF TO A CHLOROHYDRIN 审中-公开
标题翻译：多羟基化二烃或其衍生物转化为氯仿
公开(公告)号：WO2009129014A1
公开(公告)日：2009-10-22
申请号：PCT/US2009/037488
申请日：2009-03-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , BRIGGS, John, R. , HOOK, Bruce, D. , KRUPER, Jr. , MEHTA, Anil , ALVARADO, Robert, M. , NOORMANN, Sascha , BASILE, Perry, S.
发明人： BRIGGS, John, R. , HOOK, Bruce, D. , KRUPER, Jr. , MEHTA, Anil , ALVARADO, Robert, M. , NOORMANN, Sascha , BASILE, Perry, S.
IPC分类号： C07C29/62 , C07C31/42 , B01D3/00
CPC分类号： C07C29/62 , C07C31/42 , C07C31/36
摘要： The present invention relates to a process for converting at least one multihydroxylated-aliphatic hydrocarbon and/or an ester thereof to at least one chlorohydrin and/or an ester thereof, comprising at least one reaction step in which the multihydroxylated-aliphatic hydrocarbon and/or ester thereof is contacted with hydrogen chloride under reaction conditions to produce the chlorohydrin and/or ester thereof, followed by at least one downstream processing step in which the effluents of the reaction step are processed, wherein the downstream processing step is performed in such conditions that the effluents containing the chlorohydrin and/or ester thereof are kept at a temperature of less than 120 0 C. The invention allows to minimize the liberation of hydrogen chloride from the products of the hydrochlorination reaction, hence reducing the corrosion of the downstream equipment and reducing the need to use costly corrosion resistant materials.
摘要翻译：本发明涉及将至少一种多羟基化脂族烃和/或其酯转化成至少一种氯代醇和/或其酯的方法，该方法包括至少一个反应步骤，其中多羟基化脂族烃和/或其酯在反应条件下与氯化氢接触以产生氯醇和/或其酯，随后是至少一个下游处理步骤，其中反应步骤的流出物被处理，其中下游处理步骤在以下条件下进行：含有氯代醇和/或其酯的流出物保持在低于120℃的温度。本发明允许最小化氢氯化反应产物中氯化氢的释放，从而减少下游设备的腐蚀并减少使用昂贵的耐腐蚀材料的需要。

6. 发明申请

WO2008128013A1 PROCESS AND APPARATUS FOR AZEOTROPIC RECOVERY OF DICHLOROHYDRINS 审中-公开
标题翻译：二氯乙烯的AZOOPOPIC恢复的方法和装置
公开(公告)号：WO2008128013A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059979
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHTA, Anil
发明人： TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHTA, Anil
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： B01D3/38 , B01D3/14 , B01D3/146 , B01D3/36 , C07C29/82 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, water, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising chlorinating agents, catalysts and/or esters of catalysts is disclosed. A liquid aqueous phase is recycled to the distillation column while distilling or fractionating the mixture to separate dichlorohydrin(s) and water from the mixture. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译：一种用于从包含二氯代醇，水，一种或多种选自二氯代醇，一氯醇和/或其酯的酯和多羟基化脂族烃化合物和/或其酯的化合物的混合物中回收二氯代醇的方法和装置，以及任选的一种或多种物质公开了氯化剂，催化剂和/或催化剂的酯。将液体水相再循环到蒸馏塔中，同时蒸馏或分馏该混合物以从混合物中分离出二氯丙醇和水。优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少浪费，并减少了回收设备的资本投入。

7. 发明申请

WO2011017401A1 PROCESS FOR PRODUCING AN OXIRANE 审中-公开
标题翻译：生产氧化锡的方法
公开(公告)号：WO2011017401A1
公开(公告)日：2011-02-10
申请号：PCT/US2010/044354
申请日：2010-08-04
申请人： DOW GLOBAL TECHNOLOGIES, INC. , CRAMPTON, Hannah, L. , CARLBERG, Philip, J. , WEST, David, H. , HOOK, Bruce, D. , FAN, William, W. , FORLIN, Anna
发明人： CRAMPTON, Hannah, L. , CARLBERG, Philip, J. , WEST, David, H. , HOOK, Bruce, D. , FAN, William, W. , FORLIN, Anna
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/52
摘要： A multiple liquid phase composition and process for preparing an oxirane product, such as epichlorohydrin, including a reaction mixture of: (a) at least one olefin, wherein the olefin is selected from one of (i) an aliphatic olefin or substituted aliphatic olefin, with the proviso that the aliphatic olefin is not propylene, (ii) a cycloaliphatic olefin, (iii) an aromatic olefin, (iv) a cycloaromatic olefin, and (v) mixtures thereof; (b) at least one peroxide compound, (c) at least one catalyst, and (d) and a solvent mixture; wherein the solvent mixture comprises at least (i) at least one alcohol or a combination of alcohols, and (ii) at least one non-reactive co-solvent; wherein the solvents are mixed at a predetermined concentration; wherein the non-reactive co- solvent has a different boiling point than the oxirane product; and wherein the oxirane product partitions into a high affinity solvent during the reaction. The process of the present invention advantageously produces a waste stream with no significant amount of sodium chloride (NaCl). In one embodiment, the present invention includes a process for preparing epichlorohydrin from allyl chloride and hydrogen peroxide including reacting (a) an allyl chloride with (b) hydrogen peroxide, in the presence of (c) a titanium silicalite-1 (TS-1) catalyst and (d) in the presence of a predetermined amount of a mixed solvent system; wherein the mixed solvent system includes at least (i) methanol and (ii) at least one non-reactive co-solvent.
摘要翻译：一种多液相组合物和用于制备环氧乙烷产物如表氯醇的方法，包括：（a）至少一种烯烃的反应混合物，其中烯烃选自（i）脂族烯烃或取代的脂族烯烃，条件是脂族烯烃不是丙烯，（ii）脂环族烯烃，（iii）芳族烯烃，（iv）环芳族烯烃和（v）它们的混合物; （b）至少一种过氧化物化合物，（c）至少一种催化剂，和（d）和溶剂混合物; 其中所述溶剂混合物至少包含（i）至少一种醇或醇的组合，和（ii）至少一种非反应性助溶剂; 其中所述溶剂以预定浓度混合; 其中所述非反应性助溶剂具有与环氧乙烷产物不同的沸点; 并且其中环氧乙烷产物在反应期间分成高亲和力溶剂。本发明的方法有利地产生没有显着量氯化钠（NaCl）的废物流。在一个实施方案中，本发明包括由烯丙基氯和过氧化氢制备环氧氯丙烷的方法，包括在（c）钛硅沸石-1（TS-1）存在下使（a）烯丙基氯与（b）过氧化氢反应）催化剂和（d）在预定量的混合溶剂体系的存在下; 其中所述混合溶剂系统至少包括（i）甲醇和（ii）至少一种非反应性助溶剂。

8. 发明申请

WO2008128004A1 MULTI-STAGE PROCESS AND APPARATUS FOR RECOVERING DICHLOROHYDRINS 审中-公开
标题翻译：用于回收二氯乙烯的多级处理和装置
公开(公告)号：WO2008128004A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059968
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHRA, Anil
发明人： TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHRA, Anil
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： C07C29/82 , B01D3/14 , B01D3/146 , B01D3/38 , C07C2601/14 , C07C33/46 , C07C31/42 , C07C31/44 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is distilled or fractionated to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture to form a higher boiling fraction comprising the residue of the distillation or fractionation. The higher boiling fraction is stripped to recover remaining dichlorohydrins. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译：一种用于从包含二氯代醇的混合物中回收二氯代醇的方法和装置，一种或多种选自二氯丙醇，一氯代醇和/或其酯的化合物和多羟基化脂族烃化合物和/或其酯的化合物，以及任选的一种或多种包含水的物质，公开了氯化剂，催化剂和/或催化剂的酯。将混合物蒸馏或分馏以从混合物中分离包含二氯丙醇的低沸点馏分以形成包含蒸馏或分馏残余物的较高沸点馏分。汽提高沸点馏分以回收剩余的二氯代醇。优点包括为给定的蒸馏塔更有效地回收二氯代醇，避免了有利于形成重质副产品的条件减少浪费，减少回收设备的资本投入。

9. 发明申请

WO2006020234A1 CONVERSION OF A MULTIHYDROXYLATED-ALIPHATIC HYDROCARBON OR ESTER THEREOF TO A CHLOROHYDRIN 审中-公开
标题翻译：将多羟基化二烃或其酯转化为氯仿的转化
公开(公告)号：WO2006020234A1
公开(公告)日：2006-02-23
申请号：PCT/US2005/025443
申请日：2005-07-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , SCHRECK, David, J. , KRUPER, William, J., Jr. , VARJIAN, Richard, D. , JONES, Mark, E. , CAMPBELL, Robert, M. , KEARNS, Kenneth , HOOK, Bruce, D. , BRIGGS, John, R. , HIPPLER, Jeffrey, G.
发明人： SCHRECK, David, J. , KRUPER, William, J., Jr. , VARJIAN, Richard, D. , JONES, Mark, E. , CAMPBELL, Robert, M. , KEARNS, Kenneth , HOOK, Bruce, D. , BRIGGS, John, R. , HIPPLER, Jeffrey, G.
IPC分类号： C07C29/62 , C07D303/08
CPC分类号： C07D301/24 , C07C29/62 , C07C29/82 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts. In addition, certain catalysts of the present invention may be used in the present process at superatmospheric, atmospheric and subatmospheric pressure conditions with improved results.
摘要翻译：本发明涉及将多羟基化脂肪族烃或其酯转化为氯代醇的方法，该方法是将多羟基化脂族烃或其起始原料与氯化氢的超大气压分压源接触足够的时间和足够的温度，并且其中这种收缩步骤在不显着除去水的情况下进行，以产生所需的氯代醇产物; 其中所需的产物或产物可以高产率制备而不显着形成不需要的过氯化副产物。此外，本发明的某些催化剂可以在超大气压，大气压和低于大气压的条件下用于本方法，并具有改进的结果。

10. 发明申请

WO2011084687A1 PROCESS FOR PREPARING DIVINYLARENE DIOXIDES 审中-公开
标题翻译：制备二硝基二氧化物的方法
公开(公告)号：WO2011084687A1
公开(公告)日：2011-07-14
申请号：PCT/US2010/061019
申请日：2010-12-17
申请人： DOW GLOBAL TECHNOLOGIES INC. , RIPPLINGER, Eric, B. , JEAN, David , BUROW, David, L. , PHAM, Khiet, T. , GULYAS, Gyongyi , HOOK, Bruce, D.
发明人： RIPPLINGER, Eric, B. , JEAN, David , BUROW, David, L. , PHAM, Khiet, T. , GULYAS, Gyongyi , HOOK, Bruce, D.
IPC分类号： C07D301/19 , C07D301/12
CPC分类号： C08G59/22 , C07D301/12 , C07D301/19 , C08G59/027
摘要： A process for preparing a divinylarene dioxide including reacting (a) at least one divinylarene; (b) at least one peroxycarboximidic acid; (c) at least one solvent; and (d) at least one basic compound, under conditions to form a reaction mixture containing a divinylarene dioxide product; and then separating the divinylarene dioxide product from the other reaction mixture components to obtain a purified divinylarene dioxide product.
摘要翻译：一种制备二乙烯基芳烃二氧化物的方法，包括使（a）至少一种二乙烯基芳烃反应; （b）至少一种过氧羧甲酸; （c）至少一种溶剂; 和（d）至少一种碱性化合物，在形成含二乙烯基芳烃二氧化物产物的反应混合物的条件下; 然后将二乙烯基芳烃二氧化物产物与其它反应混合物组分分离，得到纯化的二乙烯基二氧化碳产品。

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