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1. 发明申请

WO2008128014A1 PROCESS AND APPARATUS FOR VAPOR PHASE PURIFICATION DURING HYDROCHLORINATION OF MULTI-HYDROXYLATED ALIPHATIC HYDROCARBON COMPOUNDS 审中-公开
标题翻译：多羟基化学烃类化合物氢化过程中蒸汽相纯化的工艺和装置
公开(公告)号：WO2008128014A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059980
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , HOOK, Bruce, D. , FORLIN, Anna , MERENOV, Andrei, S. , TIRTOWIDJOJO, Danil , MEHTA, Anil, J. , VERWIJS, Jan, Willem , HENSEN, Wilma
发明人： HOOK, Bruce, D. , FORLIN, Anna , MERENOV, Andrei, S. , TIRTOWIDJOJO, Danil , MEHTA, Anil, J. , VERWIJS, Jan, Willem , HENSEN, Wilma
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： B01D3/38 , B01D3/14 , B01D3/146 , B01D3/36 , C07C29/62 , Y02P20/127 , C07C31/42
摘要： A process for converting multihydroxylated- aliphatic hydrocarbon compound(s) and/or ester(s) thereof to chlorohydrins and/or esters thereof is disclosed in which one or more of multihydroxylated- aliphatic hydrocarbon compound(s) and/or ester(s) thereof and/or monochlorohydrin(s) and/or ester(s) thereof with at least one chlorinating feed stream comprising at least one chlorinating agent and at least one impurity having a boiling point below the boiling point of the chlorohydrin product having the lowest boiling under hydrochlorination conditions, optionally in the presence of water, one or more catalyst(s), and/or one or more heavy byproduct(s) in a reaction vessel under hydrochlorination conditions, wherein the liquid-phase reaction mixture is maintained at a temperature below the boiling point of the chlorohydrin product having the lowest boiling point under hydrochlorination conditions and greater than the boiling point(s) of the at least one impurity and a vapor phase vent stream comprising the at least one impurity is removed from the liquid phase reaction mixture. An apparatus suitable for carrying out the disclosed process is illustrated in Figure 1 of the drawings. The process and apparatus improve conversion rates and/or provide for recovery of chlorinating agent for lower operating costs.
摘要翻译：公开了一种将多羟基化脂族烃化合物和/或其酯转化为氯醇和/或其酯的方法，其中一种或多种多羟基化脂族烃化合物和/或酯，和/或一氯代醇和/或其酯与至少一种氯化进料流一起包含至少一种氯化剂和至少一种沸点低于具有最低沸点的氯代醇产物的沸点的杂质在氢氯化条件下，任选地在氢氯化条件下在反应容器中存在水，一种或多种催化剂和/或一种或多种重质副产物，其中将液相反应混合物保持在温度低于在氢氯化条件下具有最低沸点的氯代醇产物的沸点并且大于至少一种杂质的沸点和气相排出流包括从液相反应混合物中除去至少一种杂质。在附图的图1中示出了适用于执行所公开的处理的装置。该方法和设备提高转化率和/或提供氯化剂的回收以降低运行成本。

2. 发明申请

WO2008128004A1 MULTI-STAGE PROCESS AND APPARATUS FOR RECOVERING DICHLOROHYDRINS 审中-公开
标题翻译：用于回收二氯乙烯的多级处理和装置
公开(公告)号：WO2008128004A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059968
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHRA, Anil
发明人： TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHRA, Anil
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： C07C29/82 , B01D3/14 , B01D3/146 , B01D3/38 , C07C2601/14 , C07C33/46 , C07C31/42 , C07C31/44 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is distilled or fractionated to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture to form a higher boiling fraction comprising the residue of the distillation or fractionation. The higher boiling fraction is stripped to recover remaining dichlorohydrins. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译：一种用于从包含二氯代醇的混合物中回收二氯代醇的方法和装置，一种或多种选自二氯丙醇，一氯代醇和/或其酯的化合物和多羟基化脂族烃化合物和/或其酯的化合物，以及任选的一种或多种包含水的物质，公开了氯化剂，催化剂和/或催化剂的酯。将混合物蒸馏或分馏以从混合物中分离包含二氯丙醇的低沸点馏分以形成包含蒸馏或分馏残余物的较高沸点馏分。汽提高沸点馏分以回收剩余的二氯代醇。优点包括为给定的蒸馏塔更有效地回收二氯代醇，避免了有利于形成重质副产品的条件减少浪费，减少回收设备的资本投入。

3. 发明申请

WO2012040187A1 PROCESS FOR THE PRODUCTION OF METHYLENE DIPHENYL DIISOCYANATE ISOMER MIXTURES WITH SPECIFIC ISOMER DISTRIBUTIONS AND NEW PRODUCTS DERIVED THEREFROM 审中-公开
标题翻译：生产甲基二苯甲酮二异氰酸酯异构体混合物的方法，具有特异性异构体分布和衍生自其的新产物
公开(公告)号：WO2012040187A1
公开(公告)日：2012-03-29
申请号：PCT/US2011/052332
申请日：2011-09-20
申请人： DOW GLOBAL TECHNOLOGIES LLC , MERENOV, Andrei S. , JEWELL, Dennis W. , GILLIS, Paul A. , JANSMA, Gerard I. , BREED, Ashley , ANDERSON, John Joseph , REED, Daniel J.
发明人： MERENOV, Andrei S. , JEWELL, Dennis W. , GILLIS, Paul A. , JANSMA, Gerard I. , BREED, Ashley , ANDERSON, John Joseph , REED, Daniel J.
IPC分类号： C07C263/10 , C07C263/20 , C07C265/12
CPC分类号： C07C263/20 , C07C263/10 , C07C265/14
摘要： The present invention a process and apparatus for the production of methylene diphenyl diisocyanate (MDI) isomer mixtures with a low 2,2'-MDI isomer content and a high 2,4'-MDI isomer content. The resulting mixtures have an increased reactivity and are acceptable in food grade application due to the reduction in primary aromatic amines formed during the curing process. The process and apparatus also include controlling the amount of 4,4'-MDI, which is the most reactive isomer in the mixture allowing use in a wide variety of applications.
摘要翻译：本发明涉及一种生产具有低2,2'-MDI异构体含量和高2,4'-MDI异构体含量的亚甲基二苯基二异氰酸酯（MDI）异构体混合物的方法和设备。所得到的混合物具有增加的反应性，并且在食品级应用中是可接受的，这是由于在固化过程中形成的伯芳族胺的还原。该方法和装置还包括控制4,4'-MDI的量，其为混合物中最具反应活性的异构体，可用于各种应用。

4. 发明申请

WO2009126415A1 MULTI-STAGE PROCESS AND APPARATUS FOR RECOVERING DICHLOROHYDRINS 审中-公开
标题翻译：用于回收二氯乙烯的多级处理和装置
公开(公告)号：WO2009126415A1
公开(公告)日：2009-10-15
申请号：PCT/US2009/037487
申请日：2009-03-18
申请人： DOW GLOBAL TECHNOLOGIES INC. , HOOK, Bruce, D. , TIRTOWIDJOJO, Dan , MERENOV, Andrei
发明人： HOOK, Bruce, D. , TIRTOWIDJOJO, Dan , MERENOV, Andrei
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： C07C29/82 , B01D3/14 , B01D3/36 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is distilled or fractionated to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture to form a higher boiling fraction comprising the residue of the distillation or fractionation. The higher boiling fraction is distilled or fractionated to separate remaining dichlorohydrin(s) from the above mixture to form an even higher boiling fraction comprising the residue of the distillation or fractionation. At least some of the lower boiling fraction and the dichlorohydrin(s) are recovered. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, reduced capital investment in recovery equipment, and reduced energy utilization while maintaining the quality of dichlorohydrin product produced and not increasing the amount of undesired byproducts formed.
摘要翻译：一种用于从包含二氯代醇的混合物中回收二氯代醇的方法和装置，一种或多种选自二氯丙醇，一氯代醇和/或其酯的化合物和多羟基化脂族烃化合物和/或其酯的化合物，以及任选的一种或多种包含水的物质，公开了氯化剂，催化剂和/或催化剂的酯。将混合物蒸馏或分馏以从混合物中分离包含二氯丙醇的低沸点馏分以形成包含蒸馏或分馏残余物的较高沸点馏分。将较高沸点馏分蒸馏或分馏以从上述混合物中分离剩余的二氯代醇，以形成包含蒸馏或分馏残余物的更高沸点馏分。回收至少一些较低沸点馏分和二氯代丙醇。优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少了浪费，减少了回收设备的资本投入，并降低了能源利用率，同时保持了生产的二氯丙醇产品的质量并且不增加形成不希望的副产物的量。

5. 发明申请

WO2010039972A3 APPARATUS, SYSTEMS, AND METHODS FOR PURIFICATION OF ISOCYANATE MIXTURES 审中-公开
标题翻译：用于纯化异氰酸酯混合物的装置，系统和方法
公开(公告)号：WO2010039972A3
公开(公告)日：2010-07-01
申请号：PCT/US2009059249
申请日：2009-10-01
申请人： DOW GLOBAL TECHNOLOGIES INC , MERENOV ANDREI S , BALBO LUCA , STALLARD DOUGLAS A , PENDERGAST JOHN G , GEHRKE JOERG-PETER , COLLADO AMILCAR R , HIBBITTS DAVID D
发明人： MERENOV ANDREI S , BALBO LUCA , STALLARD DOUGLAS A , PENDERGAST JOHN G , GEHRKE JOERG-PETER , COLLADO AMILCAR R , HIBBITTS DAVID D
IPC分类号： C07C263/20 , B01D3/00 , B01D3/14 , C07C265/04
CPC分类号： C07C263/20 , B01D3/14 , B01D3/141 , C07C265/04 , C07C265/14
摘要： The present disclosure relates, according to some embodiments, to apparatus, systems, and/or methods for fractionating a feed mixture comprising, for example, one or more isocyanates, light components, solvents and/or heavier components. In some embodiments, fractionating an isocyanate feed mixture may comprise distilling the feed mixture in a non-adiabatic fractionating apparatus comprising a prefractionating section and/or column and a main section and/or column, which comprises a rectification section, a side section, and a stripping section. For example, isocyanates may be separated from light component(s), solvent(s) and/or heavier component(s). A fractionating apparatus may be configured and arranged, in some embodiments, as a dividing wall column. According to some embodiments of the disclosure, apparatus, systems, and/or methods may be energy efficient and/or may have a broad operating range.
摘要翻译：根据一些实施方案，本公开涉及用于分馏包含例如一种或多种异氰酸酯，轻组分，溶剂和/或较重组分的进料混合物的装置，系统和/或方法。在一些实施方案中，分馏异氰酸酯进料混合物可以包括在包含预分馏段和/或塔以及主要段和/或柱的非绝热分馏设备中蒸馏进料混合物，所述主要段和/或柱包含精馏段，侧段和剥离部分。例如，异氰酸酯可与轻组分，溶剂和/或较重组分分离。在一些实施方案中，分馏装置可以构造和布置为分隔壁塔。根据本公开的一些实施例，装置，系统和/或方法可以是高效的和/或可以具有宽泛的操作范围。

6. 发明申请

WO2008128013A1 PROCESS AND APPARATUS FOR AZEOTROPIC RECOVERY OF DICHLOROHYDRINS 审中-公开
标题翻译：二氯乙烯的AZOOPOPIC恢复的方法和装置
公开(公告)号：WO2008128013A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059979
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHTA, Anil
发明人： TIRTOWIDJOJO, Dan , MERENOV, Andrei , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHTA, Anil
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： B01D3/38 , B01D3/14 , B01D3/146 , B01D3/36 , C07C29/82 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, water, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising chlorinating agents, catalysts and/or esters of catalysts is disclosed. A liquid aqueous phase is recycled to the distillation column while distilling or fractionating the mixture to separate dichlorohydrin(s) and water from the mixture. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译：一种用于从包含二氯代醇，水，一种或多种选自二氯代醇，一氯醇和/或其酯的酯和多羟基化脂族烃化合物和/或其酯的化合物的混合物中回收二氯代醇的方法和装置，以及任选的一种或多种物质公开了氯化剂，催化剂和/或催化剂的酯。将液体水相再循环到蒸馏塔中，同时蒸馏或分馏该混合物以从混合物中分离出二氯丙醇和水。优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少浪费，并减少了回收设备的资本投入。

7. 发明申请

WO2010039965A3 APPARATUS, SYSTEMS, AND METHODS FOR PURIFICATION OF ISOCYANATE MIXTURES 审中-公开
标题翻译：用于纯化异氰酸酯混合物的装置，系统和方法
公开(公告)号：WO2010039965A3
公开(公告)日：2010-05-27
申请号：PCT/US2009059241
申请日：2009-10-01
申请人： DOW GLOBAL TECHNOLOGIES INC , MERENOV ANDREI S , BALBO LUCA , STALLARD DOUGLAS A , PENDERGAST JOHN G , GEHRKE JOERG-PETER , COLLADO AMILCAR R , HIBBITTS DAVID D
发明人： MERENOV ANDREI S , BALBO LUCA , STALLARD DOUGLAS A , PENDERGAST JOHN G , GEHRKE JOERG-PETER , COLLADO AMILCAR R , HIBBITTS DAVID D
IPC分类号： C07C263/20 , B01D3/00 , B01D3/14 , C07C265/04 , C07C265/14
CPC分类号： C07C263/20 , B01D3/14 , B01D3/141 , C07C265/04 , C07C265/14
摘要： The present disclosure relates, according to some embodiments, to apparatus, systems, and/or methods for fractionating a feed mixture comprising, for example, one or more isocyanates, light components, solvents and/or heavier components. In some embodiments, fractionating an isocyanate feed mixture may comprise distilling the feed mixture in a non-adiabatic fractionating apparatus comprising a prefractionating section and/or column and a main section and/or column, which comprises a rectification section, a side section, and a stripping section. For example, isocyanates may be separated from light component(s), solvent(s) and/or heavier component(s). A fractionating apparatus may be configured and arranged, in some embodiments, as a dividing wall column. According to some embodiments of the disclosure, apparatus, systems, and/or methods may be energy efficient and/or may have a broad operating range.
摘要翻译：根据一些实施方案，本公开涉及用于分馏包含例如一种或多种异氰酸酯，轻组分，溶剂和/或较重组分的进料混合物的设备，系统和/或方法。在一些实施方案中，分馏异氰酸酯进料混合物可以包括将进料混合物蒸馏在包括初步分馏段和/或塔以及主段和/或塔的非绝热分馏装置中，该分离分馏装置包括整流段，侧段和剥离部分。例如，异氰酸酯可以与轻组分，溶剂和/或较重组分分离。在一些实施例中，分馏装置可以被配置和布置为分隔壁塔。根据本公开的一些实施例，设备，系统和/或方法可以是能量效率的和/或可以具有广泛的操作范围。

8. 发明申请

WO2010039972A2 APPARATUS, SYSTEMS, AND METHODS FOR PURIFICATION OF ISOCYANATE MIXTURES 审中-公开
标题翻译：用于纯化异氰酸酯混合物的装置，系统和方法
公开(公告)号：WO2010039972A2
公开(公告)日：2010-04-08
申请号：PCT/US2009/059249
申请日：2009-10-01
申请人： DOW GLOBAL TECHNOLOGIES INC. , MERENOV, Andrei S. , BALBO, Luca , STALLARD, Douglas A. , PENDERGAST, John G. , GEHRKE, Joerg-Peter , COLLADO, Amilcar R. , HIBBITTS, David D.
发明人： MERENOV, Andrei S. , BALBO, Luca , STALLARD, Douglas A. , PENDERGAST, John G. , GEHRKE, Joerg-Peter , COLLADO, Amilcar R. , HIBBITTS, David D.
IPC分类号： C07C263/20 , B01D1/30 , B01D3/00 , B01D3/02 , C07C265/04 , C07C265/14
CPC分类号： C07C263/20 , B01D3/14 , B01D3/141 , C07C265/04 , C07C265/14
摘要： The present disclosure relates, according to some embodiments, to apparatus, systems, and/or methods for fractionating a feed mixture comprising, for example, one or more isocyanates, light components, solvents and/or heavier components. In some embodiments, fractionating an isocyanate feed mixture may comprise distilling the feed mixture in a non-adiabatic fractionating apparatus comprising a prefractionating section and/or column and a main section and/or column, which comprises a rectification section, a side section, and a stripping section. For example, isocyanates may be separated from light component(s), solvent(s) and/or heavier component(s). A fractionating apparatus may be configured and arranged, in some embodiments, as a dividing wall column. According to some embodiments of the disclosure, apparatus, systems, and/or methods may be energy efficient and/or may have a broad operating range.
摘要翻译：根据一些实施方案，本公开涉及用于分馏包含例如一种或多种异氰酸酯，轻组分，溶剂和/或更重的进料混合物的装置，系统和/或方法组件。在一些实施方案中，分馏异氰酸酯进料混合物可以包括在包含预分馏段和/或塔以及主要段和/或柱的非绝热分馏设备中蒸馏进料混合物，所述主要段和/或柱包含精馏段，侧段和剥离部分。例如，异氰酸酯可与轻组分，溶剂和/或较重组分分离。在一些实施方案中，分馏装置可以构造和布置为分隔壁塔。根据本公开的一些实施例，装置，系统和/或方法可以是高效节能的和/或可以具有宽泛的操作范围。

9. 发明申请

WO2010039965A2 APPARATUS, SYSTEMS, AND METHODS FOR PURIFICATION OF ISOCYANATE MIXTURES 审中-公开
公开(公告)号：WO2010039965A2
公开(公告)日：2010-04-08
申请号：PCT/US2009/059241
申请日：2009-10-01
申请人： DOW GLOBAL TECHNOLOGIES INC. , MERENOV, Andrei S. , BALBO, Luca , STALLARD, Douglas A. , PENDERGAST, John G. , GEHRKE, Joerg-Peter , COLLADO, Amilcar R. , HIBBITTS, David D.
发明人： MERENOV, Andrei S. , BALBO, Luca , STALLARD, Douglas A. , PENDERGAST, John G. , GEHRKE, Joerg-Peter , COLLADO, Amilcar R. , HIBBITTS, David D.
IPC分类号： C07C263/20 , C07C265/04 , C07C265/14 , B01D1/30 , B01D3/00 , B01D3/02
CPC分类号： C07C263/20 , B01D3/14 , B01D3/141 , C07C265/04 , C07C265/14
摘要： The present disclosure relates, according to some embodiments, to apparatus, systems, and/or methods for fractionating a feed mixture comprising, for example, one or more isocyanates, light components, solvents and/or heavier components. In some embodiments, fractionating an isocyanate feed mixture may comprise distilling the feed mixture in a non-adiabatic fractionating apparatus comprising a prefractionating section and/or column and a main section and/or column, which comprises a rectification section, a side section, and a stripping section. For example, isocyanates may be separated from light component(s), solvent(s) and/or heavier component(s). A fractionating apparatus may be configured and arranged, in some embodiments, as a dividing wall column. According to some embodiments of the disclosure, apparatus, systems, and/or methods may be energy efficient and/or may have a broad operating range.

10. 发明申请

WO2008128010A1 PROCESS AND APPARATUS FOR RECOVERY OF DICHLOROHYDRINS VIA CODISTILLATION 审中-公开
标题翻译：通过CODISTILLATION恢复二氯乙酸的方法和装置
公开(公告)号：WO2008128010A1
公开(公告)日：2008-10-23
申请号：PCT/US2008/059976
申请日：2008-04-11
申请人： DOW GLOBAL TECHNOLOGIES INC. , TIRTOWIDJOJO, Danil , MERENOV, Andrei, S. , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHTA, Anil, J.
发明人： TIRTOWIDJOJO, Danil , MERENOV, Andrei, S. , KNEUPPER, Christian, D. , HOOK, Bruce, D. , MEHTA, Anil, J.
IPC分类号： C07C29/82 , C07C31/42 , B01D3/36
CPC分类号： B01D3/009 , B01D3/14 , B01D3/146 , B01D3/38 , C07C29/82 , C07C31/36
摘要： A process and apparatus for recovering dichlorohydrins from a mixture comprising dichlorohydrins, one or more compounds selected from esters of dichlorohydrins, monochlorohydrins and/or esters thereof, and multihydroxylated- aliphatic hydrocarbon compounds and/or esters thereof, and optionally one or more substances comprising water, chlorinating agents, catalysts and/or esters of catalysts is disclosed. The mixture is stripped to recover dichlorohydrin(s) while distilling or fractionating the mixture to separate a lower boiling fraction comprising dichlorohydrin(s) from the mixture in one step. Advantages include more efficient recovery of dichlorohydrins for a given distillation column, less waste due to avoiding the conditions conducive to the formation of heavy byproducts, and reduced capital investment in recovery equipment.
摘要翻译：一种用于从包含二氯代醇的混合物中回收二氯代醇的方法和装置，一种或多种选自二氯丙醇，一氯代醇和/或其酯的化合物和多羟基化脂族烃化合物和/或其酯的化合物，以及任选的一种或多种包含水的物质，公开了氯化剂，催化剂和/或催化剂的酯。将混合物汽提以回收二氯丙醇，同时蒸馏或分馏该混合物以在一个步骤中从混合物中分离包含二氯代丙醇的低沸点馏分。优点包括对于给定的蒸馏塔更有效地回收二氯代醇，由于避免了有利于形成重质副产物的条件而减少浪费，并减少了回收设备的资本投入。

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