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1. 发明授权

US08487011B2 Sulfided fischer-tropsch catalyst 有权
标题翻译：硫化费 - 托催化剂
公开(公告)号：US08487011B2
公开(公告)日：2013-07-16
申请号：US12951580
申请日：2010-11-22
申请人： Douglas E. Fjare , Joe D. Allison
发明人： Douglas E. Fjare , Joe D. Allison
IPC分类号： C07C27/00
CPC分类号： B01J23/75 , B01J35/002 , B01J37/14 , B01J37/18 , B01J37/20 , C10G2/332
摘要： Methods and compositions relate to a Fischer-Tropsch catalyst utilized to convert syngas into paraffins. The catalyst includes a given amount of sulfur content from contact of a catalytic supported metal with sulfur. Subsequent activation of the catalyst prepares the catalyst to be used for conversion of the syngas. The sulfur content maintained in the catalyst after being activated influences selectivity to paraffins over olefins and oxygenates.
摘要翻译：方法和组合物涉及用于将合成气转化为石蜡的费 - 托催化剂。催化剂包括由催化负载金属与硫接触的给定量的硫含量。催化剂的随后活化制备用于合成气转化的催化剂。激活后保持在催化剂中的硫含量影响链烷烃对烯烃和含氧化合物的选择性。

2. 发明申请

US20110124751A1 SULFIDED FISCHER-TROPSCH CATALYST 有权
标题翻译：硫化FISCHER-TROPSCH催化剂
公开(公告)号：US20110124751A1
公开(公告)日：2011-05-26
申请号：US12951580
申请日：2010-11-22
申请人： Douglas E. Fjare , Joe D. Allison
发明人： Douglas E. Fjare , Joe D. Allison
IPC分类号： C07C1/04 , B01J27/02
CPC分类号： B01J23/75 , B01J35/002 , B01J37/14 , B01J37/18 , B01J37/20 , C10G2/332
摘要： Methods and compositions relate to a Fischer-Tropsch catalyst utilized to convert syngas into paraffins. The catalyst includes a given amount of sulfur content from contact of a catalytic supported metal with sulfur. Subsequent activation of the catalyst prepares the catalyst to be used for conversion of the syngas. The sulfur content maintained in the catalyst after being activated influences selectivity to paraffins over olefins and oxygenates.
摘要翻译：方法和组合物涉及用于将合成气转化为石蜡的费 - 托催化剂。催化剂包括由催化负载金属与硫接触的给定量的硫含量。催化剂的随后活化制备用于合成气转化的催化剂。激活后保持在催化剂中的硫含量影响链烷烃对烯烃和含氧化合物的选择性。

3. 发明授权

US07922977B2 Catalyst system for enhanced flow syngas production 有权
标题翻译：用于增强流动合成气生产的催化剂体系
公开(公告)号：US07922977B2
公开(公告)日：2011-04-12
申请号：US11103724
申请日：2005-04-12
申请人： Bang Cheng Xu , Sriram Ramani , Kevin L. Ricketson , Gloria I. Straguzzi , Larry D. Swinney , Joe D. Allison
发明人： Bang Cheng Xu , Sriram Ramani , Kevin L. Ricketson , Gloria I. Straguzzi , Larry D. Swinney , Joe D. Allison
IPC分类号： B01D50/00
CPC分类号： B01J21/066 , B01J8/0415 , B01J8/0438 , B01J12/007 , B01J19/2485 , B01J21/06 , B01J23/63 , B01J35/0006 , B01J35/04 , B01J37/0205 , B01J2208/00548 , B01J2208/025 , B01J2219/00164 , B01J2219/00166 , B01J2219/182 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/1011 , C01B2203/1017 , C01B2203/1023 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C01B2203/143 , C01B2203/82 , Y02P20/52
摘要： A method and apparatus for converting a hydrocarbon and oxygen containing gas feed stream to a product stream, such as syngas, including catalytically partially oxidizing the hydrocarbon feed stream over a catalyst bed. The catalyst bed has a downstream zone which is less resistant to flow than the upstream zone.
摘要翻译：用于将含烃和含氧气体进料流转化为产物流如合成气的方法和装置，包括在催化剂床上催化部分氧化烃进料流。催化剂床具有比上游区域更不易流动的下游区域。

4. 发明授权

US07223354B2 Promoted nickel-magnesium oxide catalysts and process for producing synthesis gas 有权
标题翻译：促进镍 - 镁氧化物催化剂和合成气生产工艺
公开(公告)号：US07223354B2
公开(公告)日：2007-05-29
申请号：US10339109
申请日：2003-01-09
申请人： Sriram Ramani , Joe D. Allison , David M. Minahan , Harold A. Wright
发明人： Sriram Ramani , Joe D. Allison , David M. Minahan , Harold A. Wright
IPC分类号： C01B3/40
CPC分类号： B01J37/08 , B01J23/76 , B01J23/78 , B01J23/83 , B01J23/835 , B01J23/85 , B01J23/889 , B01J23/8892 , B01J23/894 , B01J23/8946 , B01J23/8986 , B01J23/8993 , B01J37/0205 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/1011 , C01B2203/1029 , C01B2203/1052 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , Y02P20/52
摘要： A process and catalyst are disclosed for the catalytic partial oxidation of light hydrocarbons to produce synthesis gas at superatmospheric pressures. A preferred catalyst used in the process includes a nickel-magnesium oxide solid solution and at least one promoter chosen from Cr, Mn, Mo, W, Sn, Re, Rh, Ru, Ir, Pt, La, Ce, Sm, Yb, Lu, Bi, Sb, In and P, and oxides thereof, carried on a refractory support.
摘要翻译：公开了用于轻烃的催化部分氧化以在超大气压下产生合成气的方法和催化剂。用于该方法的优选催化剂包括镍 - 镁氧化物固溶体和至少一种选自Cr，Mn，Mo，W，Sn，Re，Rh，Ru，Ir，Pt，La，Ce，Sm，Yb， Lu，Bi，Sb，In和P及其氧化物。

5. 发明授权

US06923922B2 Recover and recycle rhodium from spent partial oxidation catalysts 失效
标题翻译：从废部分氧化催化剂回收和回收铑
公开(公告)号：US06923922B2
公开(公告)日：2005-08-02
申请号：US10828598
申请日：2004-04-21
申请人： Zhen Chen , Kevin L. Ricketson , Baili Hu , Harold A. Wright , Joe D. Allison
发明人： Zhen Chen , Kevin L. Ricketson , Baili Hu , Harold A. Wright , Joe D. Allison
IPC分类号： B01J20/34 , C01B3/26 , C01B3/38 , C01G55/00 , C22B3/10 , C22B11/00 , C22B11/02
CPC分类号： C22B3/10 , C01B3/386 , C01B2203/0261 , C01B2203/1064 , C01B2203/1082 , C22B11/026 , C22B11/048 , Y02P10/214 , Y02P10/234
摘要： A method for the recovery of rhodium from spent supported catalysts. In one embodiment, a method for recovering rhodium from a host material includes roasting the host material in air at a temperature sufficient to convert at least a portion of rhodium to Rh2O3, leaching the host material in a solution with a leaching constituent which is reactive with Rh2O3 to form a first intermediate species, reacting the first intermediate species in a solution with an acidifying constituent or complexing agent to form a second intermediate species, and purifying the second intermediate species. Preferably, the roasting temperature is approximately from 600° C. to 800° C. for 0.5 to 10 hours. In some embodiments, the host material is ground to particles in the range of 0.1 to 10 mm.
摘要翻译：从废负载型催化剂中回收铑的方法。在一个实施方案中，用于从主体材料回收铑的方法包括在足以将至少一部分铑转化为Rh 2 O 3 N / N的温度下在空气中焙烧主体材料 >，将主体材料浸入具有与Rh 2 O 3 3反应的浸出成分的溶液中以形成第一中间物质，使第一中间物质溶于与酸化组分或络合剂形成第二中间体物质，并纯化第二中间物质。优选地，焙烧温度为约600℃至800℃，持续0.5至10小时。在一些实施方案中，将主体材料研磨至0.1至10mm范围内的颗粒。

6. 发明授权

US06887456B2 Catalyst system for enhanced flow syngas production 有权
标题翻译：用于增强流动合成气生产的催化剂体系
公开(公告)号：US06887456B2
公开(公告)日：2005-05-03
申请号：US10264554
申请日：2002-10-04
申请人： Bang Chen Xu , Sriram Ramani , Kevin L. Ricketson , Gloria I. Straguzzi , Larry D. Swinney , Joe D. Allison
发明人： Bang Chen Xu , Sriram Ramani , Kevin L. Ricketson , Gloria I. Straguzzi , Larry D. Swinney , Joe D. Allison
IPC分类号： B01J8/04 , B01J12/00 , B01J19/24 , B01J21/06 , B01J23/63 , B01J35/00 , B01J35/04 , B01J37/02 , C01B3/38 , C01B3/40 , C01B3/26
CPC分类号： B01J21/066 , B01J8/0415 , B01J8/0438 , B01J12/007 , B01J19/2485 , B01J21/06 , B01J23/63 , B01J35/0006 , B01J35/04 , B01J37/0205 , B01J2208/00548 , B01J2208/025 , B01J2219/00164 , B01J2219/00166 , B01J2219/182 , C01B3/386 , C01B3/40 , C01B2203/0261 , C01B2203/1011 , C01B2203/1017 , C01B2203/1023 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1235 , C01B2203/1241 , C01B2203/142 , C01B2203/143 , C01B2203/82 , Y02P20/52
摘要： A method and apparatus for converting a hydrocarbon and oxygen containing gas feed stream to a product stream, such as syngas, including catalytically partially oxidizing the hydrocarbon feed stream over a catalyst bed. The catalyst bed has a downstream section which is less resistant to flow than the upstream section.
摘要翻译：用于将含烃和含氧气体进料流转化为产物流如合成气的方法和装置，包括在催化剂床上催化部分氧化烃进料流。催化剂床具有比上游部分更不易流动的下游部分。

7. 发明授权

US06875339B2 Octane improvement of a hydrocarbon stream 有权
标题翻译：辛烷值改善烃流
公开(公告)号：US06875339B2
公开(公告)日：2005-04-05
申请号：US10795895
申请日：2004-03-08
申请人： Priya Rangarajan , Steven R. McDonald , Joe D. Allison , Keith H. Lawson , Oluwaseyi A. Odueyungbo , Doug S. Jack , Rafael L. Espinoza
发明人： Priya Rangarajan , Steven R. McDonald , Joe D. Allison , Keith H. Lawson , Oluwaseyi A. Odueyungbo , Doug S. Jack , Rafael L. Espinoza
IPC分类号： C07C2/00 , C07C7/00 , C07C27/06 , C10G20060101 , C10G9/00 , C10G59/02 , C10G54/00
CPC分类号： C10G59/00
摘要： The invention relates to methods for improving the octane number of a synthetic naphtha stream and optionally for producing olefins and/or solvents. In one embodiment, the method comprises aromatizing at least a portion of a synthetic naphtha stream to produce an aromatized hydrocarbon stream; and isomerizing at least a portion of the aromatized hydrocarbon stream to produce an isomerized aromatized hydrocarbon stream having a higher octane rating than the synthetic naphtha stream. Alternatively, the method comprises providing at least three synthetic naphtha cuts comprising a C4-C5 stream; a C6-C8 stream and a C9-C11 stream; aromatizing some of the C6-C8 stream to form an aromatized hydrocarbon stream with a higher octane number; steam cracking some of the C6-C8 stream and optionally the C9-C11 stream to form olefins; and selling some portions of C9-C11 stream as solvents. In preferred embodiments, the synthetic naphtha is derived from Fischer-Tropsch synthesis.
摘要翻译：本发明涉及用于改进合成石脑油流的辛烷值并任选地用于生产烯烃和/或溶剂的方法。在一个实施方案中，该方法包括将至少一部分合成石脑油流芳构化以产生芳族烃流; 并使至少一部分芳构化烃物流异构化以产生具有比合成石脑油流更高辛烷值的异构化芳构化烃物流。或者，该方法包括提供包含C4-C5流的至少三个合成石脑油切割; C6-C8流和C9-C11流; 使一些C 6 -C 8流芳构化以形成具有较高辛烷值的芳构化烃流; 蒸汽裂解一些C6-C8流和任选的C9-C11流以形成烯烃; 并将C9-C11流的一些部分作为溶剂出售。在优选的实施方案中，合成石脑油衍生自费 - 托合成。

8. 发明授权

US06773691B2 Controlling syngas H2:CO ratio by controlling feed hydrocarbon composition 失效
标题翻译：通过控制原料烃组成控制合成气H2：CO比
公开(公告)号：US06773691B2
公开(公告)日：2004-08-10
申请号：US10196028
申请日：2002-07-16
申请人： Sriram Ramani , Joe D. Allison , Alfred E. Keller
发明人： Sriram Ramani , Joe D. Allison , Alfred E. Keller
IPC分类号： C01B326
CPC分类号： C01B3/386 , C01B2203/0261 , C01B2203/1011 , C01B2203/1023 , C01B2203/1047 , C01B2203/1235 , C01B2203/169
摘要： A method for generating syngas having a H2:CO ratio of less than 2:1 including selecting a predetermined desired syngas H2:CO molar ratio, selecting a hydrocarbon with a natural H2:CO molar ratio less than the desired ratio, selecting a hydrocarbon with a natural H2:CO molar ratio greater than the desired ratio, mixing the two hydrocarbons such that the natural H2:CO molar ratio of the mixture is the desired ratio, and catalytically partially oxidizing the mixture to produce syngas with the desired ratio.
摘要翻译：一种生成H 2 :CO比小于2:1的合成气的方法，包括选择预定的合成气H 2 :CO摩尔比，选择天然H 2 :CO摩尔比小于所需比例的烃，选择烃天然的H 2 :CO摩尔比大于所需比例，混合两种烃，使得混合物的天然H 2 :CO摩尔比为所需比例，并催化部分氧化该混合物以产生所需比例的合成气。

9. 发明授权

US06730708B2 Fischer-Tropsch processes and catalysts using aluminum borate supports 失效
标题翻译：使用硼酸铝载体的费 - 托工艺和催化剂
公开(公告)号：US06730708B2
公开(公告)日：2004-05-04
申请号：US09898287
申请日：2001-07-03
申请人： Ajoy P. Raje , Joe D. Allison , Kevin L. Coy
发明人： Ajoy P. Raje , Joe D. Allison , Kevin L. Coy
IPC分类号： C07C2700
CPC分类号： C10G2/33 , B01J21/02 , B01J23/75 , B01J23/8896 , C10G2/332
摘要： A process is disclosed for the hydrogenation of carbon monoxide. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst system in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream, preferably comprising hydrocarbons. In accordance with this invention the catalyst system used in the process includes at least one catalytic material for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium), preferably comprising cobalt, and a support comprising aluminum borate. The catalyst system can be prepared by impregnating alumina with a boron-containing composition to form an aluminum borate support and applying a Fischer-Tropsch catalytically active material to the aluminum borate to form a supported catalyst system.
摘要翻译：公开了一氧化碳氢化的方法。该方法包括将包含氢气和一氧化碳的进料流与催化剂体系接触，反应区保持在转化促进条件下，有效地产生优选包含烃的流出物流。根据本发明，用于该方法的催化剂体系包括至少一种用于费 - 托反应的催化材料（例如铁，钴，镍和/或钌），优选包含钴，和包含硼酸铝的载体。可以通过用含硼组合物浸渍氧化铝以形成硼酸铝载体并将费 - 托催化活性材料施加到硼酸铝上以形成负载型催化剂体系来制备催化剂体系。

10. 发明授权

US4710305A Processes and oxidizing agents for oxidizing sulfide ion to innocuous, soluble sulfur species 失效
标题翻译：将硫化物氧化物氧化成无害的可溶性硫物质的方法和氧化剂
公开(公告)号：US4710305A
公开(公告)日：1987-12-01
申请号：US947327
申请日：1986-12-29
申请人： Joe D. Allison , J. W. Wimberley
发明人： Joe D. Allison , J. W. Wimberley
IPC分类号： C01B17/05 , C02F1/72 , C02F1/76
CPC分类号： C02F1/72 , C01B17/05 , Y10S210/916
摘要： Processes and oxidizing agents for oxidizing sulfide ion found in sour water to innocuous, soluble sulfur species are provided. The processes basically comprise contacting the sour water with a nitrogen halogenated triazine or a nitrogen halogenated derivative thereof for a period of time sufficient to convert the sulfide ion to sulfate ion. The processes are particularly useful for removing sulfide ion from oil field produced waters, particularly waters associated with secondary recovery or enhanced oil recovery operations.
摘要翻译：提供了将在酸性水中发现的硫化物离子氧化为无害的可溶性硫物质的方法和氧化剂。这些方法基本上包括使酸水与氮卤化三嗪或其氮卤化衍生物接触足以将硫化物离子转化成硫酸根离子的时间。该方法特别适用于从油田产生的水中除去硫离子，特别是与二次回收相关的水或强化采油操作。

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