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    • 2. 发明授权
    • Method for laser-assisted silicon etching using halocarbon ambients
    • 使用卤代烃环境的激光辅助硅蚀刻方法
    • US5385633A
    • 1995-01-31
    • US501707
    • 1990-03-29
    • Stephen D. RussellDouglas A. SextonRichard J. Orazi
    • Stephen D. RussellDouglas A. SextonRichard J. Orazi
    • B01D53/00B01J19/12H01L21/3065H01L31/0236B44S1/22
    • B01D53/007B01J19/121H01L21/3065H01L31/02363Y02E10/50
    • An etching process allows a selective single-step patterning of silicon devices in a noncorrosive environment. The etching of silicon relies on a maskless laser-assisted technique in a gaseous halocarbon ambient, such as the gaseous chlorofluorocarbons, dichlorodifluoromethane and chloropentafluoroethane. Laser-assisted photothermal chemical etching reactions on silicon occur in these ambients when the incident fluence from an excimer laser at 248 nm exceeds the melt threshold (approximately 0.75 J/cm.sup.2). When incident fluence exceeds the ablation threshold (approximately 2.2 J/cm.sup.2) an undesirable, increased surface roughness is observed. Etch rates as large as approximately 15 angstroms per pulse are attained within predetermined processing windows. This provides a means for thin membrane formation in silicon, rapid etches and processing of packaged devices or partially fabricated dies. The reduction in processing steps as compared to conventional wet chemical etches provides improvements in yield, reliability and cost.
    • 蚀刻工艺允许在非腐蚀性环境中硅器件的选择性单步图案化。 硅的蚀刻依赖于气态卤代烃环境中的无掩模激光辅助技术,例如气态氯氟烃,二氯二氟甲烷和氯五氟乙烷。 当来自248nm的准分子激光器的入射流量超过熔融阈值(约0.75J / cm 2)时,这些环境中的激光辅助光热化学蚀刻反应发生在这些环境中。 当入射注量超过烧蚀阈值(约2.2J / cm 2)时,观察到不期望的增加的表面粗糙度。 在预定的处理窗口内可获得每脉冲大约15埃的蚀刻速率。 这提供了一种在硅中薄膜形成,快速蚀刻和加工封装器件或部分制造的裸片的方法。 与常规湿式化学蚀刻相比,加工步骤的减少提高了产量,可靠性和成本。
    • 3. 发明授权
    • Method of laser processing ferroelectric materials
    • 激光加工铁电材料的方法
    • US5310990A
    • 1994-05-10
    • US709671
    • 1991-06-03
    • Stephen D. RussellDouglas A. Sexton
    • Stephen D. RussellDouglas A. Sexton
    • B23K26/00C21D8/12H01L21/02H01L21/3105H01L21/311H01L21/314B23K26/12
    • H01L28/55B23K26/362C21D8/1294H01L21/3105H01L21/31105H01L21/31116H01L21/31122
    • Processing methods transform ferroelectric precursor films into a desired crystalline structure without adversely heating nearby materials and circuitry such as those found associated with lead zirconate titanate films. The thin film sample is placed within an appropriate chamber, where a suitable ambient is in contact with the thin film sample. The ambient may be air, oxygen or any other ambient which is known in the art to be appropriate for annealing ferroelectric materials. In this regard annealing in air can done without the processing chamber. The process for annealing relies upon continuous wave (CW) laser annealing, pulse UV annealing with or without a laser and various combinations of thermal pretreatment and processing to allow solid state diffusion in accordance with parameters appropriate for a particular application. Methods of laser patterning thin film ferroelectrics without adversely damaging adjacent or underlying layers, e.g. electrodes, are also disclosed.
    • 加工方法将铁电前体膜转变成所需的晶体结构,而不会不利地加热附近的材料和电路,例如与锆钛酸铅薄膜相关的那些。 将薄膜样品放置在合适的室内,其中合适的环境与薄膜样品接触。 环境可以是空气,氧气或本领域已知的适于退火铁电材料的任何其它环境。 在这方面,空气中的退火可以在没有处理室的情况下完成。 退火的过程依赖于连续波(CW)激光退火,有或没有激光的脉冲UV退火以及热预处理和处理的各种组合,以根据适合于特定应用的参数进行固态扩散。 激光图案化薄膜铁电体的方法,而不会不利地损坏相邻或下层,例如, 电极也被公开。
    • 8. 发明授权
    • Excimer laser dopant activation of backside illuminated CCD's
    • 准分子激光掺杂剂激活背面照射CCD
    • US5688715A
    • 1997-11-18
    • US514922
    • 1995-08-14
    • Douglas A. SextonStephen D. RussellRonald E. ReedyEugene P. Kelley
    • Douglas A. SextonStephen D. RussellRonald E. ReedyEugene P. Kelley
    • G01R31/311H01L21/3065H01L27/148H01L31/0236H01L21/263
    • H01L21/3065H01L27/1464H01L27/14806H01L31/0236G01R31/311Y02E10/50Y10S148/09
    • A method uses an excimer laser to activate previously implanted dopant species in the backside of a backside-illuminated CCD or to incorporate dopant ions from a gaseous ambient into the backside of a backside-illuminated CCD and simultaneously activate. The controlled ion implantation of the backside and subsequent thin layer heating by the short wavelength pulsed excimer laser energy activates the dopant and provides for an improved dark current response and improved spectral response. The energy of the pulsed excimer laser is applied uniformly across a backside-illuminated CCD in a very thin layer of the semiconductor substrate (usually silicon) material that requires annealing to uniformly activate the dopant. The very thin layer of the material can be heated to exceedingly high temperatures on a nanosecond time scale while the bulk of the delicate CCD substrate remains at low temperature. Repair of semiconductor dies by effecting a uniform annealing enables salvage and utilization of otherwise discardable components by bringing their dark current response to within an acceptable range.
    • 一种方法使用准分子激光器激活背面照射的CCD的背面中的先前注入的掺杂物质,或者将来自气体环境的掺杂剂离子掺入背面照射的CCD的背面并同时激活。 通过短波长脉冲准分子激光能量的背侧和随后的薄层加热的受控离子注入激活掺杂剂并提供改进的暗电流响应和改进的光谱响应。 将脉冲准分子激光器的能量均匀地涂覆在半导体衬底(通常是硅)材料的非常薄的背面照射的CCD中,其需要退火以均匀地激活掺杂剂。 该材料的非常薄的层可以以纳秒级时间刻度加热至非常高的温度,同时大部分精细CCD基板保持在低温。 通过进行均匀退火对半导体管芯进行修复,可使其暗电流响应在可接受的范围内,从而能够回收和利用其他可丢弃元件。
    • 10. 发明授权
    • Method of rapid sample handling for laser processing
    • 激光加工快速样品处理方法
    • US5323013A
    • 1994-06-21
    • US861409
    • 1992-03-31
    • Eugene P. KellyStephen D. RussellDouglas A. Sexton
    • Eugene P. KellyStephen D. RussellDouglas A. Sexton
    • H01L21/677B01J19/12
    • H01L21/67778
    • A method of rapid sample handling in a production environment for laser processing of individual microelectronic die is particularly suited for handling partially fabricated die and die which are susceptible to mechanical and electrostatic damage, such as backside illuminated CCDs requiring backside dopant activation and laser texturing of sidewalls. Securing a die within a modified sample holder provides for electrostatic and mechanical protection during laser processing. Placing the modified die holder onto a feeder base portion that engages a "tractor-feed" translation subsystem protects the die during a translation and positioning of the die below and aligned with a laser processing structure. A window holder is engaged with the die holder to seal the die in a processing chamber and to assure an appropriate pressurizing with a gaseous ambient for a desired processing. Illuminating, repetitively if desired, the die in the chamber with a laser beam of appropriate size, laser fluence, repetition rate and number of pulses processes the die. Next, the processed die is translated from beneath laser processing structure while the next die is correctly positioned for processing.
    • 在用于单个微电子管芯的激光加工的生产环境中快速样品处理的方法特别适用于处理易受机械和静电损伤的部分制造的管芯和管芯,例如需要背面掺杂剂激活的背面照射CCD和侧壁的激光纹理化 。 固定在改进的样品架内的模头可在激光加工过程中提供静电和机械保护。 将改进的模具座放置在接合“拖拉机进给”翻译子系统的馈送器基座部分上,在下述的模具的平移和定位以及与激光加工结构对准的情况下,保护模具。 窗口支架与模具座接合以将模具密封在处理室中并且确保用气体环境适当地加压以进行所需的处理。 如果需要,重复地照明,具有适当尺寸的激光束的腔室中的模具,激光能量密度,重复率和脉冲数处理模具。 接下来,将加工的模具从激光加工结构下方转换,同时下一个模具被正确定位用于处理。