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1. 发明授权

US06304364B1 Elastomeric light valves 失效
标题翻译：弹性光阀
公开(公告)号：US06304364B1
公开(公告)日：2001-10-16
申请号：US08873191
申请日：1997-06-11
申请人： Dong Qin , Younan Xia , George M. Whitesides
发明人： Dong Qin , Younan Xia , George M. Whitesides
IPC分类号： G02B2600
CPC分类号： B82Y30/00 , B82Y10/00 , G02B5/122 , G02B5/201 , G02B5/206 , G02B5/24
摘要： Electromagnetic radiation valves are provided. In one system, a transparent, elastomeric article is provided having a contoured surface including protrusions and intervening indentations. The contoured surface is placed adjacent a transparent plate and a void pattern defined by indentations of the contoured surface is filled with an opaque fluid. The protrusions decrease in cross-sectional area in the direction in which they extend away from the bulk of the elastomeric article, thus compression of the elastomeric protrusions against the transparent plate results in an increase in surface area in elastomeric protrusions against the transparent plate due to deformation of the protrusions, and the opaque fluid is displaced from the voids. Increased transmission of the electromagnetic radiation results. In another system, a similar elastomeric article includes an array of corner cubes that are totally internally reflective of the electromagnetic radiation. Increased deformation of the protrusions of the transparent plate results in decreased total internal reflection of light, due to the progressive destruction of the corner-cube geometry, and the passage of light is increased with compression.
摘要翻译：提供电磁辐射阀。在一个系统中，提供透明的弹性制品，其具有包括突起和中间凹口的轮廓表面。轮廓表面放置在透明板附近，并且由不规则表面的凹痕限定的空隙图案填充有不透明流体。突出部分在其远离弹性体制品的本体延伸的方向上的横截面积减小，因此弹性体突起抵靠透明板的压缩导致弹性体突出物相对于透明板的表面积增加，由于突起的变形，不透明的液体从空隙中移位。增加电磁辐射的传播结果。在另一系统中，类似的弹性体制品包括完全内反射电磁辐射的角立方体阵列。由于角立方几何形状的逐渐破坏，透明板的突起的增加变形导致光的全内反射减少，并且光的通过随着压缩而增加。

2. 发明申请

US20090166903A1 MOLDED WAVEGUIDES 有权
标题翻译：模制波形
公开(公告)号：US20090166903A1
公开(公告)日：2009-07-02
申请号：US12398132
申请日：2009-03-04
申请人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Mara G. Prentiss , George M. Whitesides , Christian Marzolin
发明人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Mara G. Prentiss , George M. Whitesides , Christian Marzolin
IPC分类号： B29D11/00
CPC分类号： B81C1/00206 , A61K47/6957 , B01J19/0046 , B01J2219/00382 , B01J2219/00416 , B01J2219/0043 , B01J2219/00466 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00619 , B01J2219/00626 , B01J2219/0063 , B01J2219/00637 , B01J2219/00648 , B01J2219/00659 , B01J2219/00713 , B29C31/04 , B29C33/42 , B29C37/0053 , B29C39/24 , B29C43/021 , B29C67/246 , B29D11/00346 , B29D11/00663 , B29K2105/0002 , B29L2011/0016 , B81B2201/0214 , B81C1/00031 , B81C99/0085 , B81C2201/034 , B82Y30/00 , C40B60/14 , G01N21/7703 , G01N2021/7776 , G02B6/138 , H05K3/0079 , H05K3/061
摘要： Chemically or biochemically active agents or other species are patterned on a substrate surface by providing a micromold having a contoured surface and forming, on a substrate surface, a chemically or biochemically active agent or fluid precursor of a structure. A chemically or biochemically active agent or fluid precursor also can be transferred from indentations in an applicator to a substrate surface. The substrate surface can be planar or non-planar. Fluid precursors of polymeric structures, inorganic ceramics and salts, and the like can be used to form patterned polymeric articles, inorganic salts and ceramics, reactive ion etch masks, etc. at the surface. The articles can be formed in a pattern including a portion having a lateral dimension of less than about 1 millimeter or smaller. The indentation pattern of the applicator can be used to transfer separate, distinct chemically or biochemically active agents or fluid precursors to separate, isolated regions of a substrate surface. Waveguide arrays, combinatorial chemical or biochemical libraris, etc. can be made. Differences in refractive index of waveguide and cladding can be created by subjecting the waveguide and cladding, made of indentical prepolymeric material, to different polymerization or cross-linking conditions. Interferometers are defined by coupling arrays of waveguides, where coupling can be controlled by altering the difference in refractive index between cladding and waveguide at any desired location of the array. Alteration and refractive index can be created photochemically, chemically, or the like. Sensors also are disclosed, including biochemical sensors.
摘要翻译：化学或生物化学活性剂或其它物质通过提供具有轮廓表面的微胶体并在基底表面上形成结构的化学或生物化学活性剂或流体前体而在基底表面上图案化。化学或生物化学活性剂或流体前体也可以从敷料器中的凹陷转移到基底表面。衬底表面可以是平面的或非平面的。聚合物结构，无机陶瓷和盐等的流体前体可用于在表面形成图案化聚合物制品，无机盐和陶瓷，反应离子蚀刻掩模等。制品可以形成为包括横向尺寸小于约1毫米或更小的部分的图案。涂抹器的压痕图案可以用于将单独的，不同的化学或生物化学活性剂或流体前体转移到基底表面的分离的，分离的区域。可以制作波导阵列，组合化学或生化图谱等。波导和包层的折射率差异可以通过将由凹凸预聚物材料制成的波导和包层进行不同的聚合或交联条件来产生。干涉仪通过耦合波导阵列来定义，其中可以通过改变阵列的任何所需位置处的包层和波导之间的折射率差来控制耦合。改变和折射率可以通过光化学，化学等方式产生。还公开了传感器，包括生化传感器。

3. 发明申请

US20090001049A1 METHODS OF ETCHING ARTICLES VIA MICROCONTACT PRINTING 有权
标题翻译：通过微波打印消除文章的方法
公开(公告)号：US20090001049A1
公开(公告)日：2009-01-01
申请号：US12187070
申请日：2008-08-06
申请人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
发明人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
IPC分类号： C03C15/00
CPC分类号： B01L3/5085 , B01J2219/00382 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00617 , B01J2219/00619 , B01J2219/00621 , B01J2219/0063 , B01J2219/00637 , B01J2219/00659 , B01L3/5088 , B01L2300/0654 , B01L2300/0819 , B01L2300/0851 , B05D1/283 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C40B60/14 , G02B5/1857 , G02B6/124 , G02B6/136 , G02B2006/12102 , G02B2006/12104 , G02B2006/12107 , G03F7/0002 , G03F7/165 , H01L21/4867 , H01L21/768
摘要： Improved methods of forming a patterned self-assembled monolayer on a surface and derivative articles are provided. According to one method, an elastomeric stamp is deformed during and/or prior to using the stamp to print a self-assembled molecular monolayer on a surface. According to another method, during monolayer printing the surface is contacted with a liquid that is immiscible with the molecular monolayer-forming species to effect controlled reactive spreading of the monolayer on the surface. Methods of printing self-assembled molecular monolayers on nonplanar surfaces and derivative articles are provided, as are methods of etching surfaces patterned with self-assembled monolayers, including methods of etching silicon. Optical elements including flexible diffraction gratings, mirrors, and lenses are provided, as are methods for forming optical devices and other articles using lithographic molding. A method for controlling the shape of a liquid on the surface of an article is provided, involving applying the liquid to a self-assembled monolayer on the surface, and controlling the electrical potential of the surface.
摘要翻译：提供了在表面和衍生物品上形成图案化自组装单层的改进方法。根据一种方法，弹性印模在使用印模期间和/或之前变形，以在表面上印刷自组装分子单层。根据另一种方法，在单层印刷过程中，表面与与分子单层形成物质不混溶的液体接触，以实现单层在表面上的受控的反应性扩散。提供了在非平面表面和衍生物上印刷自组装分子单层的方法，以及用自组装单层蚀刻表面的方法，包括蚀刻硅的方法。提供包括柔性衍射光栅，反射镜和透镜的光学元件，以及用于使用光刻成型形成光学器件和其它制品的方法。提供了一种用于控制制品表面上的液体形状的方法，包括将液体施加到表面上的自组装单层，并控制表面的电位。

4. 发明授权

US08012382B2 Molded waveguides 有权
标题翻译：模制波导
公开(公告)号：US08012382B2
公开(公告)日：2011-09-06
申请号：US12398132
申请日：2009-03-04
申请人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Christian Marzolin , Mara G. Prentiss , George M. Whitesides
发明人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Christian Marzolin , Mara G. Prentiss , George M. Whitesides
IPC分类号： B29D11/00 , G02B6/00 , G02B6/10 , G02B1/12 , D04H1/20 , B29C45/14 , B29C43/00 , B29C35/08 , B29C39/00 , B29C41/00 , B28B1/14 , B44C1/22 , C03C15/00 , C03C25/68 , C23F1/00
CPC分类号： B81C1/00206 , A61K47/6957 , B01J19/0046 , B01J2219/00382 , B01J2219/00416 , B01J2219/0043 , B01J2219/00466 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00619 , B01J2219/00626 , B01J2219/0063 , B01J2219/00637 , B01J2219/00648 , B01J2219/00659 , B01J2219/00713 , B29C31/04 , B29C33/42 , B29C37/0053 , B29C39/24 , B29C43/021 , B29C67/246 , B29D11/00346 , B29D11/00663 , B29K2105/0002 , B29L2011/0016 , B81B2201/0214 , B81C1/00031 , B81C99/0085 , B81C2201/034 , B82Y30/00 , C40B60/14 , G01N21/7703 , G01N2021/7776 , G02B6/138 , H05K3/0079 , H05K3/061
摘要： Chemically or biochemically active agents or other species are patterned on a substrate surface by providing a micromold having a contoured surface and forming, on a substrate surface, a chemically or biochemically active agent or fluid precursor of a structure. A chemically or biochemically active agent or fluid precursor also can be transferred from indentations in an applicator to a substrate surface. The substrate surface can be planar or non-planar. Fluid precursors of polymeric structures, inorganic ceramics and salts, and the like can be used to form patterned polymeric articles, inorganic salts and ceramics, reactive ion etch masks, etc. at the surface. The articles can be formed in a pattern including a portion having a lateral dimension of less than about 1 millimeter or smaller. The indentation pattern of the applicator can be used to transfer separate, distinct chemically or biochemically active agents or fluid precursors to separate, isolated regions of a substrate surface. Waveguide arrays, combinatorial chemical or biochemical libraris, etc. can be made. Differences in refractive index of waveguide and cladding can be created by subjecting the waveguide and cladding, made of indentical prepolymeric material, to different polymerization or cross-linking conditions. Interferometers are defined by coupling arrays of waveguides, where coupling can be controlled by altering the difference in refractive index between cladding and waveguide at any desired location of the array. Alteration and refractive index can be created photochemically, chemically, or the like. Sensors also are disclosed, including biochemical sensors.
摘要翻译：化学或生物化学活性剂或其它物质通过提供具有轮廓表面的微胶体并在基底表面上形成结构的化学或生物化学活性剂或流体前体而在基底表面上图案化。化学或生物化学活性剂或流体前体也可以从敷料器中的凹陷转移到基底表面。衬底表面可以是平面的或非平面的。聚合物结构，无机陶瓷和盐等的流体前体可用于在表面形成图案化聚合物制品，无机盐和陶瓷，反应离子蚀刻掩模等。制品可以形成为包括横向尺寸小于约1毫米或更小的部分的图案。涂抹器的压痕图案可以用于将单独的，不同的化学或生物化学活性剂或流体前体转移到基底表面的分离的，分离的区域。可以制作波导阵列，组合化学或生化图谱等。波导和包层的折射率差异可以通过将由凹凸预聚物材料制成的波导和包层进行不同的聚合或交联条件来产生。干涉仪通过耦合波导阵列来定义，其中可以通过改变阵列的任何所需位置处的包层和波导之间的折射率差来控制耦合。改变和折射率可以通过光化学，化学等方式产生。还公开了传感器，包括生化传感器。

5. 发明授权

US06518168B1 Self-assembled monolayer directed patterning of surfaces 有权
标题翻译：表面自组装单层定向图案化
公开(公告)号：US06518168B1
公开(公告)日：2003-02-11
申请号：US09029317
申请日：1998-11-02
申请人： Paul G. Clem , Noo-Li Jeon , Milan Mrksich , Ralph G. Nuzzo , David A. Payne , George M. Whitesides , Younan Xia
发明人： Paul G. Clem , Noo-Li Jeon , Milan Mrksich , Ralph G. Nuzzo , David A. Payne , George M. Whitesides , Younan Xia
IPC分类号： H01L214763
CPC分类号： B82Y30/00 , B01J2219/00317 , B01J2219/00382 , B01J2219/00659 , B05D1/283 , B41M3/003 , B82Y10/00 , B82Y40/00 , C23C16/01 , C23C16/04 , C23C16/042 , C40B60/14 , G03F7/0002 , H01L21/28562 , H01L21/76879 , H01L21/76898
摘要： A technique for creating patterns of material deposited on a surface involves forming a self-assembled monolayer in a pattern on the surface and depositing, via chemical vapor deposition or via sol-gel processing, a material on the surface in a pattern complementary to the self-assembled monolayer pattern. The material can be a metal, metal oxide, or the like. The surface can be contoured, including trenches or holes, the trenches or holes remaining free of self-assembled monolayer while the remainder of the surface is coated. When exposed to deposition conditions, metal or metal oxide is deposited in the trenches or holes, and remaining portions of the article surface remain free of deposition. The technique finds particular use in creation of conductive metal pathways selectively within holes passing from one side of a substrate to another.
摘要翻译：用于产生沉积在表面上的材料图案的技术包括以表面上的图案形成自组装单层，并通过化学气相沉积或经由溶胶 - 凝胶加工，以与自身互补的图案沉积在表面上的材料组装的单层图案。该材料可以是金属，金属氧化物等。表面可以是轮廓，包括沟槽或孔，沟槽或孔保持没有自组装单层，而表面的其余部分被涂覆。当暴露于沉积条件时，金属或金属氧化物沉积在沟槽或孔中，并且制品表面的剩余部分保持不沉积。该技术特别用于在从衬底的一侧通过到另一侧的孔内选择性地形成导电金属通路。

6. 发明授权

US5900160A Methods of etching articles via microcontact printing 失效
标题翻译：通过微接触印刷蚀刻制品的方法
公开(公告)号：US5900160A
公开(公告)日：1999-05-04
申请号：US677309
申请日：1996-07-09
申请人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
发明人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
IPC分类号： B01L3/00 , B05D1/28 , C40B60/14 , G02B5/18 , G02B6/12 , G02B6/124 , G02B6/136 , G02B6/36 , G03F7/00 , G03F7/16 , H01L21/48 , H01L21/768 , B44C1/22
CPC分类号： B82Y30/00 , B01L3/5085 , B01L3/5088 , B05D1/283 , B82Y10/00 , B82Y40/00 , G02B5/1857 , G02B6/124 , G02B6/136 , G03F7/0002 , G03F7/165 , H01L21/4867 , H01L21/768 , B01J2219/00382 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00659 , B01L2300/0654 , B01L2300/0819 , B01L2300/0851 , C40B60/14 , G02B2006/12102 , G02B2006/12104 , G02B2006/12107
摘要： Improved methods of forming a patterned self-assembled monolayer on a surface and derivative articles are provided. According to one method, an elastomeric stamp is deformed during and/or prior to using the stamp to print a self-assembled molecular monolayer on a surface. According to another method, during monolayer printing the surface is contacted with a liquid that is immiscible with the molecular monolayer-forming species to effect controlled reactive spreading of the monolayer on the surface. Methods of printing self-assembled molecular monolayers on nonplanar surfaces and derivative articles are provided, as are methods of etching surfaces patterned with self-assembled monolayers, including methods of etching silicon. Optical elements including flexible diffraction gratings, mirrors, and lenses are provided, as are methods for forming optical devices and other articles using lithographic molding. A method for controlling the shape of a liquid on the surface of an article is provided, involving applying the liquid to a self-assembled monolayer on the surface, and controlling the electrical potential of the surface.
摘要翻译：提供了在表面和衍生物品上形成图案化自组装单层的改进方法。根据一种方法，弹性印模在使用印模期间和/或之前变形，以在表面上印刷自组装分子单层。根据另一种方法，在单层印刷过程中，表面与与分子单层形成物质不混溶的液体接触，以实现单层在表面上的受控的反应性扩散。提供了在非平面表面和衍生物上印刷自组装分子单层的方法，以及用自组装单层蚀刻表面的方法，包括蚀刻硅的方法。提供包括柔性衍射光栅，反射镜和透镜的光学元件，以及用于使用光刻成型形成光学器件和其它制品的方法。提供了一种用于控制制品表面上的液体形状的方法，包括将液体施加到表面上的自组装单层，并控制表面的电位。

7. 发明授权

US07875197B2 Methods of etching articles via microcontact printing 有权
标题翻译：通过微接触印刷蚀刻制品的方法
公开(公告)号：US07875197B2
公开(公告)日：2011-01-25
申请号：US12187070
申请日：2008-08-06
申请人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
发明人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
IPC分类号： C03C15/00 , C03C25/68
CPC分类号： B01L3/5085 , B01J2219/00382 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00617 , B01J2219/00619 , B01J2219/00621 , B01J2219/0063 , B01J2219/00637 , B01J2219/00659 , B01L3/5088 , B01L2300/0654 , B01L2300/0819 , B01L2300/0851 , B05D1/283 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C40B60/14 , G02B5/1857 , G02B6/124 , G02B6/136 , G02B2006/12102 , G02B2006/12104 , G02B2006/12107 , G03F7/0002 , G03F7/165 , H01L21/4867 , H01L21/768
摘要： Improved methods of forming a patterned self-assembled monolayer on a surface and derivative articles are provided. According to one method, an elastomeric stamp is deformed during and/or prior to using the stamp to print a self-assembled molecular monolayer on a surface. According to another method, during monolayer printing the surface is contacted with a liquid that is immiscible with the molecular monolayer-forming species to effect controlled reactive spreading of the monolayer on the surface. Methods of printing self-assembled molecular monolayers on nonplanar surfaces and derivative articles are provided, as are methods of etching surfaces patterned with self-assembled monolayers, including methods of etching silicon. Optical elements including flexible diffraction gratings, mirrors, and lenses are provided, as are methods for forming optical devices and other articles using lithographic molding. A method for controlling the shape of a liquid on the surface of an article is provided, involving applying the liquid to a self-assembled monolayer on the surface, and controlling the electrical potential of the surface.
摘要翻译：提供了在表面和衍生物品上形成图案化自组装单层的改进方法。根据一种方法，弹性印模在使用印模期间和/或之前变形，以在表面上印刷自组装分子单层。根据另一种方法，在单层印刷过程中，表面与与分子单层形成物质不混溶的液体接触，以实现单层在表面上的受控的反应性扩散。提供了在非平面表面和衍生物上印刷自组装分子单层的方法，以及用自组装单层蚀刻表面的方法，包括蚀刻硅的方法。提供包括柔性衍射光栅，反射镜和透镜的光学元件，以及用于使用光刻成型形成光学器件和其它制品的方法。提供了一种用于控制制品表面上的液体形状的方法，包括将液体施加到表面上的自组装单层，并控制表面的电位。

8. 发明授权

US06660192B1 Molded waveguides 有权
标题翻译：模制波导
公开(公告)号：US06660192B1
公开(公告)日：2003-12-09
申请号：US09634201
申请日：2000-08-09
申请人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Mara G. Prentiss , George M. Whitesides , Christian Marzolin
发明人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Mara G. Prentiss , George M. Whitesides , Christian Marzolin
IPC分类号： B29D1100
CPC分类号： B81C1/00206 , A61K47/6957 , B01J19/0046 , B01J2219/00382 , B01J2219/00416 , B01J2219/0043 , B01J2219/00466 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00619 , B01J2219/00626 , B01J2219/0063 , B01J2219/00637 , B01J2219/00648 , B01J2219/00659 , B01J2219/00713 , B29C31/04 , B29C33/42 , B29C37/0053 , B29C39/24 , B29C43/021 , B29C67/246 , B29D11/00346 , B29D11/00663 , B29K2105/0002 , B29L2011/0016 , B81B2201/0214 , B81C1/00031 , B81C99/0085 , B81C2201/034 , B82Y30/00 , C40B60/14 , G01N21/7703 , G01N2021/7776 , G02B6/138 , H05K3/0079 , H05K3/061
摘要： Chemically or biochemically active agents or other species are patterned on a substrate surface by providing a micromold having a contoured surface and forming, on a substrate surface, a chemically or biochemically active agent or fluid precursor of a structure. A chemically or biochemically active agent or fluid precursor also can be transferred from indentations in an applicator to a substrate surface. The substrate surface can be planar or non-planar. Fluid precursors of polymeric structures, inorganic ceramics and salts, and the like can be used to form patterned polymeric articles, inorganic salts and ceramics, reactive ion etch masks, etc. at the surface. The articles can be formed in a pattern including a portion having a lateral dimension of less than about 1 millimeter or smaller. The indentation pattern of the applicator can be used to transfer separate, distinct chemically or biochemically active agents or fluid precursors to separate, isolated regions of a substrate surface. Waveguide arrays, combinatorial chemical or biochemical libraris, etc. can be made. Differences in refractive index of waveguide and cladding can be created by subjecting the waveguide and cladding, made of indentical prepolymeric material, to different polymerization or cross-linking conditions. Interferometers are defined by coupling arrays of waveguides, where coupling can be controlled by altering the difference in refractive index between cladding and waveguide at any desired location of the array. Alteration and refractive index can be created photochemically, chemically, or the like. Sensors also are disclosed, including biochemical sensors.
摘要翻译：化学或生物化学活性剂或其它物质通过提供具有轮廓表面的微胶体并在基底表面上形成结构的化学或生物化学活性剂或流体前体而在基底表面上图案化。化学或生物化学活性剂或流体前体也可以从敷料器中的凹陷转移到基底表面。衬底表面可以是平面的或非平面的。聚合物结构，无机陶瓷和盐等的流体前体可用于在表面形成图案化聚合物制品，无机盐和陶瓷，反应离子蚀刻掩模等。制品可以形成为包括横向尺寸小于约1毫米或更小的部分的图案。涂抹器的压痕图案可以用于将单独的，不同的化学或生物化学活性剂或流体前体转移到基底表面的分离的，分离的区域。可以制作波导阵列，组合化学或生化图谱等。波导和包层的折射率差异可以通过将由凹凸预聚物材料制成的波导和包层进行不同的聚合或交联条件来产生。干涉仪通过耦合波导阵列来定义，其中可以通过改变阵列的任何所需位置处的包层和波导之间的折射率差来控制耦合。改变和折射率可以通过光化学，化学等方式产生。还公开了传感器，包括生化传感器。

9. 发明授权

US06355198B1 Method of forming articles including waveguides via capillary micromolding and microtransfer molding 失效
标题翻译：通过毛细管微成型和微转移成型形成包括波导的制品的方法
公开(公告)号：US06355198B1
公开(公告)日：2002-03-12
申请号：US09004583
申请日：1998-01-08
申请人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Mara G. Prentiss , George M. Whitesides , Christian Marzolin
发明人： Enoch Kim , Younan Xia , Milan Mrksich , Rebecca J. Jackman , Xiao-Mei Zhao , Stephen P. Smith , Mara G. Prentiss , George M. Whitesides , Christian Marzolin
IPC分类号： B29C3910
CPC分类号： B81C1/00206 , A61K47/6957 , B01J19/0046 , B01J2219/00382 , B01J2219/00416 , B01J2219/0043 , B01J2219/00466 , B01J2219/00605 , B01J2219/0061 , B01J2219/00612 , B01J2219/00619 , B01J2219/00626 , B01J2219/0063 , B01J2219/00637 , B01J2219/00648 , B01J2219/00659 , B01J2219/00713 , B29C31/04 , B29C33/42 , B29C37/0053 , B29C39/24 , B29C43/021 , B29C67/246 , B29D11/00346 , B29D11/00663 , B29K2105/0002 , B29L2011/0016 , B81B2201/0214 , B81C1/00031 , B81C99/0085 , B81C2201/034 , B82Y30/00 , C40B60/14 , G01N21/7703 , G01N2021/7776 , G02B6/138 , H05K3/0079 , H05K3/061
摘要： Chemically or biochemically active agents or other species are patterned on a substrate surface by providing a micromold having a contoured surface and forming, on a substrate surface, a chemically or biochemically active agent or fluid precursor of a structure. A chemically or biochemically active agent or fluid precursor also can be transferred from indentations in an applicator to a substrate surface. The substrate surface can be planar or nonplanar. Fluid precursors of polymeric structures, inorganic ceramics and salts, and the like can be used to form patterned polymeric articles, inorganic salts and ceramics, reactive ion etch masks, etc. at the surface. The articles can be formed in a pattern including a portion having a lateral dimension of less than about 1 millimeter or smaller. The indentation pattern of the applicator can be used to transfer separate, distinct chemically or biochemically active agents or fluid precursors to separate, isolated regions of a substrate surface. Waveguide arrays, combinatorial chemical or biochemical libraris, etc. can be made. Differences in refractive index of waveguide and cladding can be created by subjecting the waveguide and cladding, made of indentical prepolymeric material, to different polymerization or cross-linking conditions. Interferometers are defined by coupling arrays of waveguides, where coupling can be controlled by altering the difference in refractive index between cladding and waveguide at any desired location of the array. Alteration and refractive index can be created photochemically, chemically, or the like. Sensors also are disclosed, including biochemical sensors.
摘要翻译：化学或生物化学活性剂或其它物质通过提供具有轮廓表面的微胶体并在基底表面上形成结构的化学或生物化学活性剂或流体前体而在基底表面上图案化。化学或生物化学活性剂或流体前体也可以从敷料器中的凹陷转移到基底表面。衬底表面可以是平面或非平面的。聚合物结构，无机陶瓷和盐等的流体前体可用于在表面形成图案化聚合物制品，无机盐和陶瓷，反应离子蚀刻掩模等。制品可以形成为包括横向尺寸小于约1毫米或更小的部分的图案。涂抹器的压痕图案可以用于将单独的，不同的化学或生物化学活性剂或流体前体转移到基底表面的分离的，分离的区域。可以制作波导阵列，组合化学或生化图谱等。波导和包层的折射率差异可以通过将由凹凸预聚物材料制成的波导和包层进行不同的聚合或交联条件来产生。干涉仪通过耦合波导阵列来定义，其中可以通过改变阵列的任何所需位置处的包层和波导之间的折射率差来控制耦合。改变和折射率可以通过光化学，化学等方式产生。还公开了传感器，包括生化传感器。

10. 发明授权

US06180239B2 Microcontact printing on surfaces and derivative articles 失效
标题翻译：表面和衍生物品上的微接触印刷
公开(公告)号：US06180239B2
公开(公告)日：2001-01-30
申请号：US08676951
申请日：1996-07-08
申请人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
发明人： George M. Whitesides , Younan Xia , James L. Wilbur , Rebecca J. Jackman , Enoch Kim , Mara G. Prentiss , Milan Mrksich , Amit Kumar , Christopher B. Gorman , Hans Biebuyck , Karl K. Berggren
IPC分类号： B32B904
CPC分类号： B05D1/283 , B01J2219/00382 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00659 , B01L3/5085 , B01L3/5088 , B01L2300/0654 , B01L2300/0819 , B01L2300/0851 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C40B60/14 , G02B5/1857 , G02B6/124 , G02B6/136 , G02B2006/12102 , G02B2006/12104 , G02B2006/12107 , G03F7/0002 , G03F7/165 , H01L21/4867 , H01L21/768 , H01L24/95 , H01L2224/83192 , Y10T428/24802 , Y10T428/31504
摘要： Improved method of forming a patterned self-assembled monolayer on a surface and derivative articles are provided. According to one method, an elastomeric stamp is deformed during and/or prior to using the stamp to print a self-assembled molecular monolayer on a surface. According to another method, during monolayer printing the surface is contacted with a liquid that is immiscible with the molecular monolayer-forming species to effect controlled reactive spreading of the monolayer on the surface. Methods of printing self-assembled molecular monolayers on nonplanar surfaces and derivative articles are provided, as are methods of etching surfaces patterned with self-assembled monolayers, including methods of etching silicon. Optical elements including flexible diffraction gratings, mirrors, and lenses are provided, as are methods for forming optical devices and other articles using lithographic molding. A method for controlling the shape of a liquid on the surface of an article is provided, involving applying the liquid to a self-assembled monolayer on the surface, and controlling the electrical potential of the surface.
摘要翻译：提供了在表面和衍生物品上形成图案化自组装单层的改进方法。根据一种方法，弹性印模在使用印模期间和/或之前变形，以在表面上印刷自组装分子单层。根据另一种方法，在单层印刷过程中，表面与与分子单层形成物质不混溶的液体接触，以实现单层在表面上的受控的反应性扩散。提供了在非平面表面和衍生物上印刷自组装分子单层的方法，以及用自组装单层蚀刻表面的方法，包括蚀刻硅的方法。提供包括柔性衍射光栅，反射镜和透镜的光学元件，以及用于使用光刻成型形成光学器件和其它制品的方法。提供了一种用于控制制品表面上的液体形状的方法，包括将液体施加到表面上的自组装单层，并控制表面的电位。

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