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    • 1. 发明授权
    • Fungicidal N-(substituted thio)-pyridyl cyclopropane carboxamides
    • 杀真菌剂N-(取代硫代) - 吡啶基环丙烷甲酰胺
    • US4977164A
    • 1990-12-11
    • US250477
    • 1988-09-28
    • Don R. BakerKeith H. Brownell
    • Don R. BakerKeith H. Brownell
    • A01N53/00A01N53/04C07D213/75C07D213/76C07D405/12C07F7/10
    • C07D213/76A01N53/00C07D213/75C07D405/12C07F7/10
    • Novel fungicidal pyridyl cyclopropane carboxamides having the general structural formula ##STR1## wherein R is selected from the group consisting of haloalkyl, preferably C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.8 alkyl, aryl, substituted aryl, and arylalkyl wherein the preferred aryl is phenyl, the alkyl is C.sub.1 -C.sub.3 alkyl and the preferred substitutions are Cl, Br, F and nitro, alkanoyl, preferably C.sub.1 -C.sub.4 alkanoyl, ##STR2## wherein R.sub.3 and R.sub.4 can be alkyl, alkanoyl, alkoxycarbanoyl, benzyl, pyridyl and substituted pyridyl, and when R.sub.3 and Rhd 4 are alkyl together with --N they can form a heterocyclic ring such as piperidine, R.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy, preferably methoxy or halomethoxy and halogen wherein the halogen is chlorine, bromine or fluorine, R.sub.2 is hydrogen or methyl, and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein. These compounds provide excellent control of fungal growth.
    • 新颖的具有通式结构式为“IMAGE”的杀真菌吡啶环丙烷甲酰胺,其中R选自卤代烷基,优选C 1 -C 3卤代烷基,C 1 -C 8烷基,芳基,取代的芳基和芳基烷基,其中优选的芳基是苯基, 烷基是C 1 -C 3烷基,优选的取代是Cl,Br,F和硝基,烷酰基,优选C 1 -C 4烷酰基,其中R 3和R 4可以是烷基,烷酰基,烷氧基羰基,苄基,吡啶基和取代的吡啶基,和 当R3和Rhd4与-N一起烷基时,它们可以形成杂环,例如哌啶,R 1 -C 3烷氧基或C 1 -C 3卤代烷氧基,优选甲氧基或卤代甲氧基和卤素,其中卤素是氯,溴或氟,R 2是氢 或甲基,以及作为预防和治疗性杀真菌剂的高效杀真菌剂的杀真菌可接受的有机和无机盐。 这些化合物提供极好的真菌生长控制。
    • 2. 发明授权
    • Fungicidal pyridyl iminocarbonates
    • 杀真菌吡啶亚氨基碳酸盐
    • US4975443A
    • 1990-12-04
    • US308583
    • 1989-02-10
    • Don R. BakerKeith H. Brownell
    • Don R. BakerKeith H. Brownell
    • A01N47/42C07D213/75
    • C07D213/75A01N47/42
    • Novel fungicidal pyridyl iminocarbonates having the general structural formula ##STR1## wherein R is selected from the group consisting of C.sub.1 -C.sub.16 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.2 -C.sub.8 alkenyl, C.sub.2 -C.sub.8 substituted alkenyl, C.sub.3 -C.sub.4 carboalkoxyalkyl, aryl, arylalkyl having C.sub.1 -C.sub.3 alkyl, substituted aryl and arylalkyl wherein the substituents are --Cl, --Br, --F and --NO.sub.2 ; furfuryl, pyridyl, C.sub.1 -C.sub.6 alkyl substituted phosphorus, alkanoyl, alkoxycarbonyl, aroyl, preferably benzoyl, alkylthioarbonyl, alkylthioalkyl, alkoxyalkyl, alkoxybenzyl and ##STR2## wherein R.sub.3 and R.sub.4 are C.sub.1 -C.sub.10 alkyl and can form a heterocyclic ring;R.sub.1 is selected from the group consisting of halogen, C.sub.1 -C.sub.3 alkoxy, C.sub.3 -C.sub.4 alkenyloxy and C.sub.1 -C.sub.3 haloalkoxy;R.sub.2 is selected from the group consisting of C.sub.1 -C.sub.4 alkyl;X is sulfur or oxygen;Y is sulfur or oxygen; andZ is sulfur or oxygen;and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.
    • 新型的具有通式结构式为“IMAGE”的杀真菌吡啶基亚氨基碳酸酯,其中R选自C 1 -C 16烷基,C 3 -C 8环烷基,C 2 -C 8烯基,C 2 -C 8取代烯基,C 3 -C 4烷氧羰基烷基,芳基,芳烷基 具有C 1 -C 3烷基,取代的芳基和芳烷基,其中取代基是-Cl,-Br,-F和-NO 2; 糠基,吡啶基,C1-C6烷基取代的磷,烷酰基,烷氧基羰基,芳酰基,优选苯甲酰基,烷硫基羰基,烷硫基烷基,烷氧基烷基,烷氧基苄基和其中R3和R4是C1-C10烷基并且可以形成杂环; R 1选自卤素,C 1 -C 3烷氧基,C 3 -C 4烯氧基和C 1 -C 3卤代烷氧基; R2选自C1-C4烷基; X是硫或氧; Y是硫或氧; Z为硫或氧; 并且这里公开了作为预防和治疗性杀真菌剂的高效杀真菌剂的杀真菌可接受的有机和无机盐。
    • 4. 发明授权
    • Fungicidal pyridyl cyclopropane carboximides
    • 杀真菌性吡啶环丙烷甲脒
    • US4914115A
    • 1990-04-03
    • US193620
    • 1988-05-13
    • Don R. BakerCharles KezerianKeith H. Brownell
    • Don R. BakerCharles KezerianKeith H. Brownell
    • A01N53/00A01N53/04C07D213/75C07D213/76C07D405/12C07F7/10
    • C07D213/75A01N53/00C07D213/76C07D405/12C07F7/10
    • Novel fungicidal pyridyl cyclopropane carboxamides having the general structural formula ##STR1## wherein R is selected from the group consisting of cycloalkyl, preferably cyclopropyl, hydrogen, alkyl, haloalkyl, substituted alkyl, aryl, substituted aryl, heteroalkyl, alkenyl, OR.sub.1, SR.sub.1 and ##STR2## wherein n is 0-10, preferably 0-2, and R.sub.1 is C.sub.1 -C.sub.4 alkyl, and R.sub.2 is selected from the group consisting of halogen such as chlorine, fluorine and bromine, preferably chlorine, C.sub.1 -C.sub.3 alkoxy such as propoxyethoxy and methoxy, preferably methoxy and C.sub.1 -C.sub.3 haloalkoxy, R.sub.3 is selected from the group consisting of hydrogen and methyl, X is --O or --S and Y is --O or --S; and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.
    • 具有一般结构式的新型杀真菌吡啶环丙烷甲酰胺,其中R选自环烷基,优选环丙基,氢,烷基,卤代烷基,取代的烷基,芳基,取代的芳基,杂烷基,烯基,OR1,SR1和其中n为0-10,优选为0-2,并且R 1为C 1 -C 4烷基,R 2选自卤素如氯,氟和溴,优选氯,C 1 -C 3烷氧基如丙氧基乙氧基和 甲氧基,优选甲氧基和C 1 -C 3卤代烷氧基,R 3选自氢和甲基,X是-O或-S,Y是-O或-S; 并且这里公开了作为预防和治疗性杀真菌剂的高效杀真菌剂的杀真菌可接受的有机和无机盐。
    • 6. 发明授权
    • Fungicidal pyridyl imidates
    • 杀真菌吡啶亚胺酯
    • US5019565A
    • 1991-05-28
    • US444924
    • 1989-12-04
    • Don R. BakerKeith H. Brownell
    • Don R. BakerKeith H. Brownell
    • A01N53/00A01N57/16C07D213/74C07D405/12C07F9/58
    • C07D213/74A01N53/00A01N57/16C07D405/12C07F9/588
    • Fungicidal pyridyl imidates having the general structural formula ##STR1## wherein R is selected from the group consisting of C.sub.1 -C.sub.16 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.2 -C.sub.8 alkenyl, C.sub.2 -C.sub.8 substituted alkenyl, C.sub.3 -C.sub.4 carboalkoxyalkyl, aryl, arylalkyl having C.sub.1 -C.sub.3 alkyl, substituted aryl and arylalkyl wherein the substituents are -Cl, -Br, -F and -NO.sub.2, furfuryl pyridyl, C.sub.1 -C.sub.6 alkoxyl substituted thiophosphorus, and ##STR2## wherein R.sub.3 and R.sub.4 are C.sub.1 -C.sub.10 alkyl and can form a heterocyclic ring, R.sub.1 is selected from the group consisting of halogen, C.sub.1 -C.sub.3 alkoxy and C.sub.1 -C.sub.3 haloalkoxy, R.sub.2 is selected from the group consisting of methyl and hydrogen, and X is S or O; and fungicidally acceptable organic and inorganic salts thereof.
    • 具有通式结构式为“IMAGE”的杀真菌吡啶基亚胺化物,其中R选自C 1 -C 16烷基,C 3 -C 8环烷基,C 2 -C 8烯基,C 2 -C 8取代的烯基,C 3 -C 4碳烷氧基烷基,芳基,具有 C 1 -C 3烷基,取代的芳基和芳烷基,其中取代基是-Cl,-Br,-F和-NO 2,糠基吡啶基,C 1 -C 6烷氧基取代的硫代磷酸酯和其中R 3和R 4是C 1 -C 10烷基, 形成杂环,R 1选自卤素,C 1 -C 3烷氧基和C 1 -C 3卤代烷氧基,R 2选自甲基和氢,X是S或O; 和杀真菌可接受的有机和无机盐。