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1. 发明专利

JP2014002172A Ion detector and system 有权
标题翻译：离子检测器和系统
公开(公告)号：JP2014002172A
公开(公告)日：2014-01-09
申请号：JP2013208225
申请日：2013-10-03
申请人： Dionex Corp , ダイオネックスコーポレイション , Board Of Regents Of The University Of Texas System:The , ボードオブリージェンツオブザユニヴァーシティオブテキサスシステム
发明人： DASGUPTA PURNENDU K , YANG BINGCHENG , SRINIVASAN KANNAN
IPC分类号： G01N30/64 , G01N27/28 , G01N30/02 , G01N30/74
CPC分类号： G01N30/96 , G01N30/64 , Y02E60/366
摘要： PROBLEM TO BE SOLVED: To provide a device for detecting current or potential generated by ionic species in a liquid sample solution.SOLUTION: An apparatus and a method for detecting current or potential generated in a liquid sample suitable for use in a chromatography or other liquid sample analytical system. One embodiment is an electrolytic ion transfer device (62) comprising a single detector (32) in communication with electrodes (28a and 28b). Another embodiment is a combination of the ion transfer device (62) and an electrolyte generator (63). Yet another embodiment is another combination where the detector is substituted for the ion transfer device in the combination.
摘要翻译：要解决的问题：提供一种用于检测液体样品溶液中离子物质产生的电流或电位的装置。解决方案：用于检测适用于色谱法或其它液体的液体样品中产生的电流或电位的装置和方法样品分析系统。一个实施例是包括与电极（28a和28b）连通的单个检测器（32）的电解离子转移装置（62）。另一个实施方案是离子转移装置（62）和电解质发生器（63）的组合。另一个实施方案是另一组合，其中检测器代替组合中的离子转移装置。

2. 发明专利

JP2011180150A Membrane based volatile component-removal devices for liquid chromatography 审中-公开
标题翻译：用于液相色谱的基于膜的挥发性元件去除装置
公开(公告)号：JP2011180150A
公开(公告)日：2011-09-15
申请号：JP2011109549
申请日：2011-05-16
申请人： Dionex Corp , ダイオネックスコーポレイション
发明人： DASGUPTA PURNENDU K , ULLAH S M RAHMAT , SRINIVASAN KANNAN
IPC分类号： G01N30/84 , G01N30/02 , G01N30/26
CPC分类号： G01N30/96 , B01D19/0031 , G01N30/34 , G01N2030/8423
摘要： PROBLEM TO BE SOLVED: To remove at least part of a volatile component from the liquid sample by flowing the liquid sample stream through a volatile component-removal device including a porous wall having a surface coating of a permeable polymer less than 10 μm in thickness in a liquid chromatographic system. SOLUTION: A liquid chromatographic system is suitable for performing the method. Moreover, a liquid chromatographic system in which volatile component is removed prior to separation across the same type of membrane or across a membrane made of a copolymer of perfluoro-2,2-dimethyl-1,1-dioxole. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：通过使液体样品流通过挥发性成分去除装置从液体样品中除去至少一部分挥发性成分，该挥发性成分除去装置包括具有小于10μm的可渗透聚合物的表面涂层的多孔壁在液相色谱系统中的厚度。
解决方案：液相色谱系统适用于执行该方法。此外，在分离跨过相同类型的膜或通过由全氟-2,2-二甲基-1,1-二氧杂环戊烯的共聚物制成的膜上除去挥发性成分的液相色谱系统。版权所有（C）2011，JPO＆INPIT

3. 发明专利

JP2011033640A Method and apparatus for gas-assisted suppressed chromatography 有权
标题翻译：用于气体辅助抑制色谱的方法和装置
公开(公告)号：JP2011033640A
公开(公告)日：2011-02-17
申请号：JP2010258688
申请日：2010-11-19
申请人： Dionex Corp , ダイオネックスコーポレイション
发明人： SRINIVASAN KANNAN , POHL CHRISTOPHER A
IPC分类号： G01N30/02 , G01N30/26 , G01N30/60 , G01N30/64 , G01N30/88 , G01N30/96
CPC分类号： G01N30/96 , G01N2030/965
摘要： PROBLEM TO BE SOLVED: To provide a method which uses suppression of an effluent for the analysis of anions or cations in ion chromatography, and which reduces chemical regenerant consumption, waste amounts, and operational costs, and to provide an apparatus for it.
SOLUTION: The analysis method of ionic species in an aqueous sample stream and the apparatus include: (a) the step of chromatographically separating the ionic species in the sample stream in the presence of an aqueous eluent containing an electrolyte to form a chromatographic effluent, (b) the step of suppressing the electrolyte in the effluent by flowing the effluent through a suppressor to form a suppressed effluent, (c) the step of detecting the ionic species in the suppressed effluent, and (d) the step of regenerating the suppressor by flowing a mixture of a gas stream and a regenerant liquid stream through the suppressor.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种使用抑制流出物进行离子色谱法分析阴离子或阳离子并减少化学再生剂消耗，废物量和操作成本的方法，并为其提供一种装置。解决方案：水性样品流中离子物质的分析方法和装置包括：（a）在含有电解质的含水洗脱液存在下，将样品流中的离子物质层析分离以形成色谱步骤流出物，（b）通过使流出物流过抑制剂以形成抑制流出物来抑制流出物中的电解质的步骤，（c）检测被抑制的流出物中的离子物质的步骤，以及（d）再生步骤通过使气流和再生剂液体流的混合物流过抑制器来抑制抑制剂。版权所有（C）2011，JPO＆INPIT

4. 发明申请

WO2008157074A3 MEMBRANE BASED CONCENTRATORS 审中-公开
标题翻译：基于膜的浓缩器
公开(公告)号：WO2008157074A3
公开(公告)日：2010-01-21
申请号：PCT/US2008066015
申请日：2008-06-06
申请人： DIONEX CORP , UNIV TEXAS , TAKEUCHI MASAKI , SRINIVASAN KANNAN , DASGUPTA PURNENDU K
发明人： TAKEUCHI MASAKI , SRINIVASAN KANNAN , DASGUPTA PURNENDU K
IPC分类号： G01N1/40 , G01N30/96
CPC分类号： G01N30/08 , G01N1/4005 , G01N1/4022 , G01N30/96 , G01N2001/4011 , G01N2001/4027 , G01N2030/146 , Y10T436/255
摘要： A sample concentrator for concentrating analytes in a solvent-containing liquid sample stream, including concentrator housing having a sample stream How channel and a gas stream flow channel having an inlet and an outlet, a heater for gas in the gas stream conduit, and a hydrophilic ion exchange or non-ionic membrane barrier separating said gas stream flow channel and said sample stream fjow channel Solvent is evaporated from the liquid sample stream in said sample stream flow channel in or at the interface with said membrane, when the gas stream is at an elevated temperature. A regeneration step is used to regenerate the ion exchange membrane barrier.
摘要翻译：用于将分析物浓缩在含溶剂的液体样品流中的样品浓缩器，包括具有样品流的浓缩器壳体如何通道和气流流动通道具有入口和出口，气体流导管中的气体加热器和亲水分离所述气流流动通道和所述样品流流动通道的离子交换或非离子膜屏障当所述气流处于所述气流时，在所述样品流流动通道中或与所述膜的界面处从所述样品流流动通道中的液体样品流蒸发溶剂升温再生步骤用于再生离子交换膜屏障。

5. 发明申请

WO0042426A9 CURRENT-EFFICIENT SUPPRESSORS AND METHOD OF USE 审中-公开
标题翻译：电流效应抑制剂及其使用方法
公开(公告)号：WO0042426A9
公开(公告)日：2001-09-07
申请号：PCT/US0000822
申请日：2000-01-12
申请人： DIONEX CORP
发明人： SRINIVASAN KANNAN , BARRETO VICTOR-BERBER , POHL CHRISTOPHER A , THAYER JAMES R , AVDALOVIC NEBOJSA
IPC分类号： G01N27/08 , B01D61/44 , G01N30/02 , G01N30/60 , G01N30/96
CPC分类号： G01N30/96 , G01N2030/965
摘要： The application relates to a method and device for ion chromatography or pretreatment. In the chromatographic separation stage, ions of an injected sample are eluted through a separation column using an electrolyte as the eluent. In the suppression stage, electrical conductivity of the electrolyte is suppressed but not that of the separated ions so that the latter may be determined by a conductivity cell. The device comprises a self regenerating electrodialytic membrane suppressor (17) with an upstream portion sample stream flow channel defined on both sides by ion exchange membranes (34, 36) flanked by downstream portion ion receiving and source flow channels. In order to increase the current-efficiency without the detrimental effects of excess heat generation, there is provided a lower electrical resistance in the upstream portion compared to the electrical resistance of the downstream portion.
摘要翻译：本申请涉及用于离子色谱法或预处理的方法和装置。在色谱分离阶段，使用电解液作为洗脱液，通过分离柱将注入的样品的离子洗脱。在抑制阶段，抑制电解质的导电性而不是被分离的离子的导电性，使得后者可以通过电导池确定。该装置包括自再生电渗析膜抑制器（17），其上游部分样品流流动通道在两侧由位于下游部分离子接收和源流动通道两侧的离子交换膜（34,36）限定。为了提高电流效率而不会产生过多的热量的不利影响，与上游部分的电阻相比，在上游部分提供较低的电阻。

6. 发明申请

WO2011106720A2 THE INTERNATIONAL BUREAU ACKNOWLEDGES RECEIPT, ON [DATE], OF AMENDMENTS TO THE CLAIMS UNDER PCT ARTICLE 19(1). HOWEVER, THE APPLICANT IS URGENTLY REQUESTED TO SUBMIT REPLACEMENT SHEET(S) CONTAINING A COMPLETE SET OF CLAIMS IN REPLACEMENT OF ALL THE C 审中-公开
标题翻译：国际局在[日期]中承认根据PCT第19（1）条提出的索赔的修改。然而，申请人紧急要求提交更换所有C的完整索赔的提交表格
公开(公告)号：WO2011106720A2
公开(公告)日：2011-09-01
申请号：PCT/US2011026343
申请日：2011-02-25
申请人： DIONEX CORP , SRINIVASAN KANNAN , POHL CHRISTOPHER A , BHARDWAJ SHEETAL , LIN RONG
发明人： SRINIVASAN KANNAN , POHL CHRISTOPHER A , BHARDWAJ SHEETAL , LIN RONG
IPC分类号： B01J41/20
CPC分类号： B01D15/36 , B01D15/361 , B01J39/17 , B01J39/19 , B01J39/26 , B01J41/04 , B01J41/13 , B01J41/20 , B01J47/00
摘要： The present invention provides a new design for high capacity stationary phases for chromatography, for example, ion chromatography. The stationary phases include a first polymer layer in contact with and at least partially coating the substrate of the stationary phase. The first polymer layer serves as a foundation for the attachment, and in various embodiments, the growth and attachment, of a highly hyperbranched polymer structure, typically based on one or more products of condensation polymerization. Multiple components are of use in forming the first polymer layer and the hyperbranched polymer structure, thereby providing a stationary phase that can be engineered to have a desired property such as ion capacity, ion selectivity, and the like. Exemplary condensation polymers are formed by the reaction of at least one polyfunctional compound with at least one compound of complimentary reactivity, e.g., a nucleophilic polyfunctional compound reacting with an electrophilic compound.
摘要翻译：本发明提供了用于色谱法的高容量固定相的新设计，例如离子色谱法。固定相包括与固定相的基底接触并且至少部分地涂覆固定相的基底的第一聚合物层。第一聚合物层用作连接的基础，并且在各种实施方案中，通常基于一个或多个缩聚产物的高度超支化的聚合物结构的生长和附着。多个组分可用于形成第一聚合物层和超支化聚合物结构，从而提供可被工程化以具有所需性质如离子容量，离子选择性等的固定相。示例性缩合聚合物通过至少一种多官能化合物与至少一种互补反应性化合物的反应形成，例如与亲电子化合物反应的亲核多官能化合物。

7. 发明申请

WO2004070377A3 IMPROVED CAPACITY CHEMICAL SUPPRESSORS AND METHOD OF USE 审中-公开
标题翻译：改进的能力化学抑制剂和使用方法
公开(公告)号：WO2004070377A3
公开(公告)日：2005-01-13
申请号：PCT/US0339219
申请日：2003-12-09
申请人： DIONEX CORP , SRINIVASAN KANNAN , POHL CHRISTOPHER A
发明人： SRINIVASAN KANNAN , POHL CHRISTOPHER A
IPC分类号： B01D15/36 , B01D61/48 , G01N30/96 , B01D15/08 , B01D61/24
CPC分类号： G01N30/96 , B01D15/367 , B01D61/48 , Y10T436/25
摘要： A non-electrolytic method and apparatus for treating an aqueous sample stream including analyte ions and matrix ions of opposite charge, for pretreatment or suppression. The apparatus includes an ion exchange membrane capable of passing only ions of opposite charge to the analyte ions, a sample stream flow channel, a first aqueous stream ion receiving flow channel adjacent one side of the sample stream flow channel and separated therefrom by the first ion exchange membrane, and stationary flow-through ion exchange packing disposed in the sample stream flow channel. The ion receiving channel has an ion exchange capacity for the matrix ions less than about 25% of the ion exchange capacity for the matrix ions.
摘要翻译：一种用于处理包含分析物离子和相反电荷的基质离子的水样品流用于预处理或抑制的非电解方法和装置。该装置包括能够仅将相反电荷的离子通过到分析物离子的离子交换膜，样品流流动通道，邻近样品流流动通道的一侧的第一含水流离子接收流动通道，并由第一离子交换膜和设置在样品流流动通道中的固定流通离子交换填料。离子接收通道对于基质离子的离子交换容量小于基质离子的离子交换容量的约25％。

8. 发明申请

WO2013134098A3 SORPTION OF WATER FROM A SAMPLE USING A POLYMERIC DRYING AGENT 审中-公开
标题翻译：使用聚合物干燥剂从样品中吸收水分
公开(公告)号：WO2013134098A3
公开(公告)日：2014-01-16
申请号：PCT/US2013028821
申请日：2013-03-04
申请人： DIONEX CORP
发明人： POHL CHRISTOPHER A , SRINIVASAN KANNAN , ULLAH SM RAHMAT
IPC分类号： G01N1/40
CPC分类号： G01N1/405 , B01D11/04 , B01D11/0492 , B01J20/261 , C08F220/06 , C08F220/34 , C08F222/1006 , C08F228/02 , G01N1/10 , G01N1/34 , G01N1/4055 , G01N2001/4061
摘要： A method of extracting an analyte from a sample is described where the sample includes water. The sample and polymeric drying agent are added to a container. The polymeric drying agent includes a cationic monomer, an anionic monomer, and a crosslinker. The polymeric drying agent is configured to sorb water from the sample.
摘要翻译：描述了从样品中提取分析物的方法，其中样品包括水。将样品和聚合物干燥剂加入到容器中。聚合物干燥剂包括阳离子单体，阴离子单体和交联剂。聚合物干燥剂构造成从样品中吸收水分。

9. 发明申请

WO2009064797A3 BARRIER WITH A SEATED ION EXCHANGE BEAD AND METHOD 审中-公开
标题翻译：带有离子交换珠的方法和方法
公开(公告)号：WO2009064797A3
公开(公告)日：2009-09-24
申请号：PCT/US2008083256
申请日：2008-11-12
申请人： DIONEX CORP , UNIV TEXAS , DASGUPTA PURNENDU K , YANG BINGCHENG , SRINIVASAN KANNAN , TAKEUCHI MASAKI
发明人： DASGUPTA PURNENDU K , YANG BINGCHENG , SRINIVASAN KANNAN , TAKEUCHI MASAKI
IPC分类号： G01N30/96 , B01D61/42 , B01D69/14 , B01J47/00 , C08J5/20 , G01N30/34
CPC分类号： G01N30/96 , B01D15/166 , B01D71/32 , B01J47/08 , B01J47/12 , B01J49/57 , C25B1/16 , C25B1/22 , C25B13/08 , G01N30/34 , G01N2030/965
摘要： Ion transport apparatus (e.g. an electrolytic eluent generator or a suppressor for ion chromatography) in which ions in a first chamber are transported to a liquid in second chamber through a wall comprising an ion exchange bead sealed in a bead seat. The wall is capable of transport ions but of substantially blocking bulk liquid flow.
摘要翻译：将第一室中的离子通过密封在珠座中的离子交换珠的壁在第二室中的液体输送到离子迁移装置（例如电解洗脱液生成器或离子色谱抑制器）。该壁能够输送离子，但是基本上阻挡了大量的液体流动。

10. 发明申请

WO2006023510A3 MEMBRANE BASED VOLATILE COMPONENT-REMOVAL DEVICES FOR LIQUID CHROMATOGRAPHY 审中-公开
标题翻译：用于液相色谱的基于膜的挥发性元件去除装置
公开(公告)号：WO2006023510A3
公开(公告)日：2006-07-27
申请号：PCT/US2005029165
申请日：2005-08-15
申请人： DIONEX CORP , DASGUPTA PURNENDU K , ULLAH S M RAHMAT , SRINIVASAN KANNAN
发明人： DASGUPTA PURNENDU K , ULLAH S M RAHMAT , SRINIVASAN KANNAN
IPC分类号： G01N30/34 , B01D19/00 , G01N30/96
CPC分类号： G01N30/96 , B01D19/0031 , G01N30/34 , G01N2030/8423
摘要： In a liquid chromatographic system, removing at least part of a volatile component from the liquid sample stream after separation in a column (56) by flowing it through a volatile component-removal device (50) including a porous wall (68) having a surface coating of a permeable polymer less than 10 µm thick. A liquid chromatographic system in which volatile component is removed prior to separation across the same type of membrane or across a membrane made of a copolymer of perfluoro-2, 2-dimethyl-1,3-dioxole.
摘要翻译：在液相色谱系统中，通过使其流过挥发性成分去除装置（50），在柱（56）中分离后，从液体样品流中除去挥发性成分的至少一部分，所述挥发性成分除去装置（50）包括多孔壁（68）涂层厚度小于10μm的可渗透聚合物。一种液相色谱系统，其中挥发性组分在分离前通过相同类型的膜或通过由全氟-2,2-二甲基-1,3-二氧杂环戊烯的共聚物制成的膜去除。

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