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1. 发明申请

US20080200631A1 Enzymatic Production of (Meth)Acrylic Acid Esters 有权
标题翻译：（甲基）丙烯酸酯的酶促生产
公开(公告)号：US20080200631A1
公开(公告)日：2008-08-21
申请号：US11995628
申请日：2006-07-31
申请人： Dietmar Haring , Uwe Meisenburg , Bernhard Hauer , Frank Dietsche
发明人： Dietmar Haring , Uwe Meisenburg , Bernhard Hauer , Frank Dietsche
IPC分类号： C08F118/02
CPC分类号： C12P7/625
摘要： The present invention relates to a process for preparing (meth)acrylic esters of alcohols having C—C triple bonds, to processes for their preparation, and to their use.
摘要翻译：本发明涉及一种制备具有C-C三键的醇的（甲基）丙烯酸酯的方法，其制备方法及其用途。

2. 发明申请

US20060235189A1 Polyesters comprising groups that can be activated by actinic radiation, corresponding method and use 审中-公开
标题翻译：包含可通过光化辐射活化的基团的聚酯，相应的方法和用途
公开(公告)号：US20060235189A1
公开(公告)日：2006-10-19
申请号：US10542228
申请日：2004-01-23
申请人： Heinz-Peter Rink , Susanne Neumann , Uwe Meisenburg , Karl-Heinz Joost , Dietmar Haring , Bernhard Hauer
发明人： Heinz-Peter Rink , Susanne Neumann , Uwe Meisenburg , Karl-Heinz Joost , Dietmar Haring , Bernhard Hauer
IPC分类号： C08G63/00
CPC分类号： C08G63/916 , C08G63/914
摘要： Polyesters comprising at least one pendant and/or terminal group which can be activated with actinic radiation, preparable by reacting 1. a polyester (i) containing at least one pendant and/or terminal hydroxyl group with at least one carboxylic acid (i) or at least one ester (i) of a carboxylic acid (i) containing at least one bond which can be activated with actinic radiation, or 2. a polyester (ii) containing at least one pendant and/or terminal carboxylic acid group or at least one pendant and/or terminal carboxylic ester group with at least one hydroxyl-containing compound (ii) containing at least one bond which can be activated with actinic radiation in the presence of at least one organism and/or enzyme which catalyzes the transesterification or esterification; process for preparing them, and their use.
摘要翻译：聚酯包含至少一种可用光化辐射活化的侧基和/或末端基团，其可通过使含有至少一个侧链和/或末端羟基的聚酯（i）与至少一种羧酸（i）或至少一种含有至少一个可以用光化辐射活化的键的羧酸（i）的酯（i），或2.含有至少一个侧链和/或末端羧酸基团的聚酯（ii）或至少一个侧链和/或末端羧酸酯基团与至少一个含羟基的化合物（ii）（ii）含有至少一个键，其可以在催化酯交换或酯化的至少一种生物体和/或酶的存在下用光化辐射活化 ; 制备它们的过程及其用途。

3. 发明申请

US20060148975A1 Uv-active binding agent 失效
标题翻译： Uv活性结合剂
公开(公告)号：US20060148975A1
公开(公告)日：2006-07-06
申请号：US10532575
申请日：2003-11-05
申请人： Heinz Rink , Susanne Neumann , Uwe Meisenburg , Karl-Heinz Joost , Dietmar Haring , Bernhard Hauer
发明人： Heinz Rink , Susanne Neumann , Uwe Meisenburg , Karl-Heinz Joost , Dietmar Haring , Bernhard Hauer
IPC分类号： C09D5/02 , C08F8/14
CPC分类号： C12P7/625 , C08F8/00 , C09D133/04 , C09D133/14 , C12P7/62 , Y10S522/912 , C08F220/10
摘要： The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.
摘要翻译：本发明涉及通过制备含羟基官能侧链的聚（甲基）丙烯酸酯并酯交换或酯化含羟基的聚（甲基）丙烯酸酯而制备光化可辐射固化和/或双重固化的聚（甲基）丙烯酸酯的方法。具有（甲基）丙烯酸酯或（甲基）丙烯酸的官能侧链。本发明还涉及光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯本身以及使用光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯在制备分散体或作为包含至少一种光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯的涂料配方和面漆中的组分。

4. 发明授权

US08278077B2 Enzymatic production of (meth)acrylic acid esters 有权
标题翻译：（甲基）丙烯酸酯的酶促生产
公开(公告)号：US08278077B2
公开(公告)日：2012-10-02
申请号：US11995628
申请日：2006-07-31
申请人： Dietmar Haering , Uwe Meisenburg , Bernhard Hauer , Frank Dietsche
发明人： Dietmar Haering , Uwe Meisenburg , Bernhard Hauer , Frank Dietsche
IPC分类号： C12P7/62 , C07C67/03 , C07C69/52
CPC分类号： C12P7/625
摘要： The present invention relates to a process for preparing (meth)acrylic esters of alcohols having C—C triple bonds, to processes for their preparation, and to their use.
摘要翻译：本发明涉及一种制备具有C-C三键的醇的（甲基）丙烯酸酯的方法，其制备方法及其用途。

5. 发明授权

US08344072B2 Enzymatic preparation of (meth)acrylic esters 有权
标题翻译：（甲基）丙烯酸酯的酶制剂
公开(公告)号：US08344072B2
公开(公告)日：2013-01-01
申请号：US11169773
申请日：2005-06-30
申请人： Dietmar Haering , Uwe Meisenburg , Bernhard Hauer
发明人： Dietmar Haering , Uwe Meisenburg , Bernhard Hauer
IPC分类号： C08F8/14 , C08L33/00
CPC分类号： C12P7/62 , C07C69/54 , C08F220/28 , C08G18/672 , C09D4/00 , C09D175/16 , C12P7/625
摘要： Process for preparing partial (meth)acrylic esters of polyalcohols having different hydroxyl groups, process for their preparation, and use thereof.
摘要翻译：制备具有不同羟基的多元醇的部分（甲基）丙烯酸酯的方法，其制备方法及其用途。

6. 发明申请

US20060009589A1 Enzymatic preparation of (meth)acrylic esters 有权
公开(公告)号：US20060009589A1
公开(公告)日：2006-01-12
申请号：US11169773
申请日：2005-06-30
申请人： Dietmar Haering , Uwe Meisenburg , Bernhard Hauer
发明人： Dietmar Haering , Uwe Meisenburg , Bernhard Hauer
IPC分类号： C08F8/14 , C08L33/00
CPC分类号： C12P7/62 , C07C69/54 , C08F220/28 , C08G18/672 , C09D4/00 , C09D175/16 , C12P7/625
摘要： Process for preparing partial (meth)acrylic esters of polyalcohols having different hydroxyl groups, process for their preparation, and use thereof.

7. 发明申请

US20100291640A1 PROCESS FOR PREPARING URETHANE-CONTAINING (METH)ACRYLIC ESTERS 有权
标题翻译：制备含有（甲基）丙烯酸酯的方法
公开(公告)号：US20100291640A1
公开(公告)日：2010-11-18
申请号：US12776670
申请日：2010-05-10
申请人： Rainer Stuermer , Dejana Drew , Bernhard Hauer , Juergen Daeuwel , Uwe Meisenburg
发明人： Rainer Stuermer , Dejana Drew , Bernhard Hauer , Juergen Daeuwel , Uwe Meisenburg
IPC分类号： C12P13/00
CPC分类号： C12P13/02 , C12P7/62
摘要： A process for preparing urethane-containing (meth)acrylic esters (U) by reacting a urethane-containing alcohol (A) with a (meth)acrylic ester of a saturated alcohol (G) in the presence of at least one polymerization inhibitor (P) with an enzyme (E) as a catalyst in a reactor, wherein a) the saturated alcohol released and any entraining agent used form an azeotrope with the excess corresponding (meth)acrylic ester (G), the azeotrope is removed by distillation under reduced pressure and b) at least a substream from the bottom of the reactor is circulated via the top of the distillation column.
摘要翻译：在至少一种聚合抑制剂（P）的存在下，使含氨基甲酸酯的醇（A）与饱和醇（G）的（甲基）丙烯酸酯反应制备含氨基甲酸酯的（甲基）丙烯酸酯（U））与反应器中的催化剂（E）反应，其中a）所释放的饱和醇和任何使用的夹带剂与过量的相应的（甲基）丙烯酸酯（G）形成共沸物，通过在减压下蒸馏除去共沸物压力和b）来自反应器底部的至少一个子流经蒸馏塔的顶部循环。

8. 发明授权

US08399225B2 Process for preparing urethane-containing (meth)acrylic esters 有权
标题翻译：制备含氨基甲酸酯（甲基）丙烯酸酯的方法
公开(公告)号：US08399225B2
公开(公告)日：2013-03-19
申请号：US12776670
申请日：2010-05-10
申请人： Rainer Stürmer , Dejana Drew , Bernhard Hauer , Jürgen Däuwel , Uwe Meisenburg
发明人： Rainer Stürmer , Dejana Drew , Bernhard Hauer , Jürgen Däuwel , Uwe Meisenburg
IPC分类号： C12P7/60
CPC分类号： C12P13/02 , C12P7/62
摘要： The invention relates to a process for preparing urethane-containing acrylic- and (meth)acrylic esters by reacting a urethane-containing alcohol with a reactant acrylic- or (meth)acrylic ester of a saturated alcohol in the presence of at least one polymerization inhibitor and an enzyme as a catalyst within a reactor, wherein the saturated alcohol released in the process and optionally an entraining agent form an azeotrope with an excess of the reactant (meth)acrylic ester, such that the azeotrope is removed by distillation under reduced pressure and at least one substream from the bottom of the reactor is circulated through the top of the distillation column. Using this process, urethane-containing acrylic- and (meth)acrylic esters are prepared in high yields and high purities under mild conditions from economically obtainable reactants with no significant polymer formation.
摘要翻译：本发明涉及通过使含氨基甲酸酯的醇与饱和醇的反应性丙烯酸或（甲基）丙烯酸酯在至少一种聚合抑制剂的存在下反应来制备含氨基甲酸酯的丙烯酸和（甲基）丙烯酸酯的方法和作为反应器内的催化剂的酶，其中在该方法中释放的饱和醇和任选的夹带剂与过量的反应物（甲基）丙烯酸酯形成共沸物，使得通过减压蒸馏除去共沸物，来自反应器底部的至少一个子流通过蒸馏塔的顶部循环。使用该方法，在温和条件下从经济可获得的反应物中以高产率和高纯度制备含氨基甲酸酯的丙烯酸酯和（甲基）丙烯酸酯，没有显着的聚合物形成。

9. 发明授权

US07601765B2 UV-active binding agent 失效
标题翻译：紫外线活性粘合剂
公开(公告)号：US07601765B2
公开(公告)日：2009-10-13
申请号：US10532575
申请日：2003-11-05
申请人： Heinz-Peter Rink , Susanne Neumann , Uwe Meisenburg , Karl-Heinz Joost , Dietmar Häring , Bernhard Hauer
发明人： Heinz-Peter Rink , Susanne Neumann , Uwe Meisenburg , Karl-Heinz Joost , Dietmar Häring , Bernhard Hauer
IPC分类号： C08F2/46 , C08F2/00 , C08F2/38 , C08F22/10 , C08F22/00
CPC分类号： C12P7/625 , C08F8/00 , C09D133/04 , C09D133/14 , C12P7/62 , Y10S522/912 , C08F220/10
摘要： The present invention relates to processes for preparing actinic-radiation-curable and/or dual-cure poly(meth)acrylates by preparing a poly(meth)acrylate containing hydroxy-functional side chains and transesterifying or esterifying the poly(meth)acrylate containing hydroxy-functional side chains with a (meth)acrylate or (meth)acrylic acid. The present invention further relates to the actinic-radiation-curable and/or dual-cure poly(meth)acrylates themselves and to the use of the actinic-radiation-curable and/or dual-cure poly(meth)acrylates in the preparation of dispersions or as a component in coating formulations and topcoats comprising at least one actinic-radiation-curable and/or dual-cure poly(meth)acrylate.
摘要翻译：本发明涉及通过制备含羟基官能侧链的聚（甲基）丙烯酸酯并酯交换或酯化含羟基的聚（甲基）丙烯酸酯而制备光化可辐射固化和/或双重固化的聚（甲基）丙烯酸酯的方法。具有（甲基）丙烯酸酯或（甲基）丙烯酸的官能侧链。本发明还涉及光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯本身以及使用光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯在制备分散体或作为包含至少一种光化学辐射固化和/或双重固化的聚（甲基）丙烯酸酯的涂料配方和面漆中的组分。

10. 发明授权

US09150673B2 Process for preparing (meth)acrylic esters 有权
标题翻译：制备（甲基）丙烯酸酯的方法
公开(公告)号：US09150673B2
公开(公告)日：2015-10-06
申请号：US13543032
申请日：2012-07-06
申请人： Virginie Bette , Matthias Dust , Jochen Petzoldt , Uwe Meisenburg , Andrea Misske , Hermann Bergmann
发明人： Virginie Bette , Matthias Dust , Jochen Petzoldt , Uwe Meisenburg , Andrea Misske , Hermann Bergmann
IPC分类号： C07C67/02 , C08F20/06 , C07C67/03 , C07D233/32
CPC分类号： C08F20/06 , C07C67/03 , C07D233/32
摘要： The invention relates to a process for preparing (meth)acrylic esters by esterifying (meth)acrylic acid or transesterifying at least one (meth)acrylic ester with at least one compound comprising at least one OH group in the presence of a heterogeneous catalyst comprising at least one inorganic salt, wherein the esterification or transesterification is performed in the presence of 300 to 3000 ppm of water based on the total weight of the reaction mixture.
摘要翻译：本发明涉及一种制备（甲基）丙烯酸酯的方法，该方法是在非均相催化剂的存在下，通过酯化（甲基）丙烯酸或至少一种（甲基）丙烯酸酯与至少一种包含至少一个OH基团的化合物进行酯交换，至少一种无机盐，其中在300至3000ppm水的存在下，基于反应混合物的总重量进行酯化或酯交换。

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