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1. 发明授权

US07217828B2 Phosphinine compounds and metal complexes thereof 失效
标题翻译：膦化合物及其金属络合物
公开(公告)号：US07217828B2
公开(公告)日：2007-05-15
申请号：US10911499
申请日：2004-08-05
申请人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
发明人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
IPC分类号： C07F9/02
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

2. 发明申请

US20050043279A1 Novel phosphinine compounds and metal complexes thereof 失效
标题翻译：新型次膦化合物及其金属配合物
公开(公告)号：US20050043279A1
公开(公告)日：2005-02-24
申请号：US10911499
申请日：2004-08-05
申请人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
发明人： Detlef Selent , Armin Boerner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Roettger
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C45/50 , C07C47/02 , C07F9/6564 , C07F9/6584 , C07F15/00 , C07F15/06 , C07F9/547 , A61K31/66
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

3. 发明授权

US06403837B1 Process for the catalytic preparation of aldehydes from olefins using ligand mixtures 失效
标题翻译：使用配体混合物从烯烃催化制备醛的方法
公开(公告)号：US06403837B1
公开(公告)日：2002-06-11
申请号：US09708624
申请日：2000-11-09
申请人： Dieter Hess , Dirk Roettger , Detlef Selent , Armin Boerner
发明人： Dieter Hess , Dirk Roettger , Detlef Selent , Armin Boerner
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C47/02
摘要： A process for preparing aldehydes having from 4 to 25 carbon atoms by catalytic hydroformylation of the corresponding olefins, wherein the catalyst used comprises a metal of transition group 8 of the Periodic Table in the presence of a ligand A of the formula I where X=As, Sb or P and R1,R2,R3: are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where two of the radicals R1, R2, R3 can be covalently linked with the proviso that at least one of the hydrocarbon radicals R1, R2, R3 contains a heteroatom selected from the group consisting of O, S, N, F, Cl, Be, I, Se and Te, and a ligand B of the formula II where R4, R5, R6: are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon having from 1 to 50 carbon atoms, where two of the radicals R4, R5 and R6 can be covalently linked.
摘要翻译：通过相应烯烃的催化加氢甲酰化制备具有4至25个碳原子的醛的方法，其中所用的催化剂包括在式I的配体A的存在下的周期表的过渡族8的金属，其中X = As，Sb 或P和R 1，R 2，R 3：各自是具有1至50个碳原子的取代或未取代的脂族，脂环族或芳族烃基，其中基团R 1，R 2，R 3中的两个可以共价连接，条件是至少一个的烃基R1，R2，R3含有选自O，S，N，F，Cl，Be，I，Se和Te的杂原子和式II的配体B，其中R4，R5，R6：各自为具有1至50个碳原子的取代或未取代的脂族，脂环族或芳族烃，其中基团R 4，R 5和R 6中的两个可以共价连接。

4. 发明授权

US09359278B2 Organophosphorus compounds based on anthracenetriol 有权
标题翻译：基于蒽三醇的有机磷化合物
公开(公告)号：US09359278B2
公开(公告)日：2016-06-07
申请号：US14357090
申请日：2012-10-24
申请人： Andrea Christiansen , Robert Franke , Dirk Fridag , Dieter Hess , Burkard Kreidler , Detlef Selent , Armin Boerner
发明人： Andrea Christiansen , Robert Franke , Dirk Fridag , Dieter Hess , Burkard Kreidler , Detlef Selent , Armin Boerner
IPC分类号： C07F15/00 , C07F9/655 , C07C45/50 , C07F9/6574 , B01J31/22
CPC分类号： C07C45/505 , B01J31/2295 , C07C45/50 , C07F9/65746 , C07F15/0073 , C07F15/008 , C07C47/02
摘要： The subject matter of the present invention is a plurality of products and the use thereof as a catalytically active composition in a method for producing aldehydes.
摘要翻译：本发明的主题是多种产品及其在醛的生产方法中作为催化活性组合物的用途。

5. 发明申请

US20100036143A1 BISPHOSPHITE LIGANDS FOR HYDROFORMYLATION CATALYZED BY TRANSITION METALS 有权
标题翻译：用于过渡金属催化氢化的双相配位体
公开(公告)号：US20100036143A1
公开(公告)日：2010-02-11
申请号：US12515967
申请日：2007-11-13
申请人： Detlef Selent , Armin Boerner , Burkard Kreidler , Dieter Hess , Klaus-Diether Wiese
发明人： Detlef Selent , Armin Boerner , Burkard Kreidler , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/06 , C07C45/00
CPC分类号： C07F9/65746 , C07B41/06
摘要： The invention relates to a bisphosphite of the formula I where X=a divalent substituted or unsubstituted bisalkylene or bisarylene radical, Y=a divalent substituted or unsubstituted bisarylene or bisalkylene radical, Z=oxygen or NR9, and R1, R2, R3, R4 are identical or different, substituted or unsubstituted, linked, unlinked or fused aryl or heteroaryl radicals and R9 is hydrogen or a substituted or unsubstituted alkyl or aryl radical, a process for preparing it and also the use of this phosphite in catalysis in particular in the catalytic hydroformylation of olefins or organic compounds having C—C double bonds.
摘要翻译：本发明涉及式I的双亚磷酸酯，其中X =二价取代或未取代的双亚烷基或双亚芳基，Y =二价取代或未取代的双亚芳基或双亚烷基，Z =氧或NR 9，并且R 1，R 2，R 3，R 4为相同或不同的取代或未取代的连接的，未连接的或稠合的芳基或杂芳基，R 9为氢或取代或未取代的烷基或芳基，其制备方法，以及该亚磷酸酯在催化中的用途，特别是在催化烯烃或具有CC双键的有机化合物的羰基化。

6. 发明申请

US20140309423A1 NOVEL ORGANOPHOSPHORUS COMPOUNDS BASED ON ANTHRACENETRIOL 有权
标题翻译：基于蒽三酚的新型有机磷化合物
公开(公告)号：US20140309423A1
公开(公告)日：2014-10-16
申请号：US14357090
申请日：2012-10-24
申请人： Andrea Christiansen , Robert Franke , Dirk Fridag , Dieter Hess , Burkard Kreidler , Detlef Selent , Armin Boerner
发明人： Andrea Christiansen , Robert Franke , Dirk Fridag , Dieter Hess , Burkard Kreidler , Detlef Selent , Armin Boerner
IPC分类号： C07C45/50 , C07F15/00 , B01J31/22 , C07F9/6574
CPC分类号： C07C45/505 , B01J31/2295 , C07C45/50 , C07F9/65746 , C07F15/0073 , C07F15/008 , C07C47/02
摘要： The subject matter of the present invention is a plurality of products and the use thereof as a catalytically active composition in a method for producing aldehydes.
摘要翻译：本发明的主题是多种产品及其在醛的生产方法中作为催化活性组合物的用途。

7. 发明授权

US08404902B2 Method for separating 1-butene from C4-containing hydrocarbon streams by hydroformylation 有权
标题翻译：通过加氢甲酰化从含C4烃流中分离1-丁烯的方法
公开(公告)号：US08404902B2
公开(公告)日：2013-03-26
申请号：US12992032
申请日：2009-04-28
申请人： Burkard Kreidler , Klaus-Diether Wiese , Dieter Hess , Detlef Selent , Armin Boerner
发明人： Burkard Kreidler , Klaus-Diether Wiese , Dieter Hess , Detlef Selent , Armin Boerner
IPC分类号： C07C45/50 , C07C29/16
CPC分类号： C07C7/173 , C07C45/50 , C07C11/09 , C07C47/02
摘要： The invention relates to a method for separating 1-butene from C4-containing hydrocarbon mixtures, comprising isobutene and 1-butene, by hydroformylation, wherein the catalytic system used is made of one of the transition metals of the group 8 to 10, preferably rhodium, and a bisphosphite ligand of the formula (I), where X is a divalent substituted or unsubstituted bisalkylene or bisarylene group having one or more heteroatom(s), Y is a divalent substituted or unsubstituted bisarylene or bisalkylene group having one or more heteroatom(s), Z is oxygen or NR9, and R1, R2, R3, R4 are identical or different, substituted or unsubstituted, linked, unlinked or condensed aryl or heteroaryl groups, and R9 is hydrogen or a substituted or unsubstituted alkyl or aryl group having one or more heteroatom(s), wherein the bisphosphite ligand of the formula (I) is used in an excess of a molar ratio of 100:1 to 1:1 to the transition metal, and that with a 1-butene conversion of more than 95% less than 5% of the present isobutene is reacted method for separating 1-butene from c4-containing hydrocarbon streams by hydroformylation.
摘要翻译：本发明涉及通过加氢甲酰化从含有C4的烃混合物中分离出1-丁烯的方法，其中包括异丁烯和1-丁烯，其中使用的催化体系由8-10族的过渡金属之一制成，优选为铑和式（I）的双亚磷酸酯配体，其中X是具有一个或多个杂原子的二价取代或未取代的双亚烷基或双亚芳基，Y是具有一个或多个杂原子的二价取代或未取代的双亚芳基或双亚烷基 s），Z是氧或NR 9，R 1，R 2，R 3，R 4是相同或不同的取代或未取代的连接，未连接或稠合的芳基或杂芳基，并且R 9是氢或被取代或未取代的烷基或芳基，一个或多个杂原子，其中式（I）的二亚磷酸酯配体以过渡金属的过量摩尔比为100:1至1:1使用，而1-丁烯转化率更高比不到95％％的本异丁烯是通过加氢甲酰化从含C4的烃流中分离1-丁烯的反应方法。

8. 发明授权

US07161020B2 Phosphite compounds and novel phosphite metal complexes 失效
标题翻译：亚磷酸酯化合物和新型亚磷酸盐金属络合物
公开(公告)号：US07161020B2
公开(公告)日：2007-01-09
申请号：US10485811
申请日：2002-08-13
申请人： Detlef Selent , Armin Boerner , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
发明人： Detlef Selent , Armin Boerner , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/02
CPC分类号： C07F9/65744 , C07C45/50 , C07F15/0073 , C07C47/02
摘要： Phosphites of the formula I and phosphite-metal complexes, their preparation and their use in catalytic reactions, in particular in processes for the hydroformylation of olefins, are described.
摘要翻译：描述了式I的亚磷酸酯和亚磷酸盐 - 金属络合物，它们的制备及其在催化反应中的用途，特别是在烯烃的加氢甲酰化方法中的用途。

9. 发明授权

US08003816B2 Bisphosphite ligands for hydroformylation catalyzed by transition metals 有权
标题翻译：过渡金属催化加氢甲酰化的二亚磷酸酯配体
公开(公告)号：US08003816B2
公开(公告)日：2011-08-23
申请号：US12515967
申请日：2007-11-13
申请人： Detlef Selent , Armin Boerner , Burkard Kreidler , Dieter Hess , Klaus-Diether Wiese
发明人： Detlef Selent , Armin Boerner , Burkard Kreidler , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F15/04 , C07F9/02 , C07C45/50
CPC分类号： C07F9/65746 , C07B41/06
摘要： The invention relates to a bisphosphite of the formula I where X=a divalent substituted or unsubstituted bisalkylene or bisarylene radical, Y=a divalent substituted or unsubstituted bisarylene or bisalkylene radical, Z=oxygen or NR9, and R1, R2, R3, R4 are identical or different, substituted or unsubstituted, linked, unlinked or fused aryl or heteroaryl radicals and R9 is hydrogen or a substituted or unsubstituted alkyl or aryl radical, a process for preparing it and also the use of this phosphite in catalysis in particular in the catalytic hydroformylation of olefins or organic compounds having C—C double bonds.
摘要翻译：本发明涉及式I的双亚磷酸酯，其中X =二价取代或未取代的双亚烷基或双亚芳基，Y =二价取代或未取代的双亚芳基或双亚烷基，Z =氧或NR 9，并且R 1，R 2，R 3，R 4为相同或不同的取代或未取代的连接的，未连接的或稠合的芳基或杂芳基，R 9为氢或取代或未取代的烷基或芳基，其制备方法，以及该亚磷酸酯在催化中的用途，特别是在催化具有C-C双键的烯烃或有机化合物的加氢甲酰化反应。

10. 发明申请

US20110071321A1 METHOD FOR SEPERATING 1-BUTENE FROM C4-CONTAINING HYDROCARBON STREAMS BY HYDROFORMYLATION 有权
标题翻译：通过氢化方法从含C4氢碳氢化合物中分离1-丁烯的方法
公开(公告)号：US20110071321A1
公开(公告)日：2011-03-24
申请号：US12992032
申请日：2009-04-28
申请人： Burkard Kreidler , Klaus-Diether Wiese , Dieter Hess , Detlef Selent , Armin Boerner
发明人： Burkard Kreidler , Klaus-Diether Wiese , Dieter Hess , Detlef Selent , Armin Boerner
IPC分类号： C07C29/16 , C07C45/50
CPC分类号： C07C7/173 , C07C45/50 , C07C11/09 , C07C47/02
摘要： The invention relates to a method for separating 1-butene from C4-containing hydrocarbon mixtures, comprising isobutene and 1-butene, by hydroformylation, wherein the catalytic system used is made of one of the transition metals of the group 8 to 10, preferably rhodium, and a bisphosphite ligand of the formula (I), where X is a divalent substituted or unsubstituted bisalkylene or bisarylene group having one or more heteroatom(s), Y is a divalent substituted or unsubstituted bisarylene or bisalkylene group having one or more heteroatom(s), Z is oxygen or NR9, and R1, R2, R3, R4 are identical or different, substituted or unsubstituted, linked, unlinked or condensed aryl or heteroaryl groups, and R9 is hydrogen or a substituted or unsubstituted alkyl or aryl group having one or more heteroatom(s), wherein the bisphosphite ligand of the formula (I) is used in an excess of a molar ratio of 100:1 to 1:1 to the transition metal, and that with a 1-butene conversion of more than 95% less than 5% of the present isobutene is reacted method for separating 1-butene from c4-containing hydrocarbon streams by hydroformylation
摘要翻译：本发明涉及通过加氢甲酰化从含有C4的烃混合物中分离出1-丁烯的方法，其中包括异丁烯和1-丁烯，其中使用的催化体系由8-10族的过渡金属之一制成，优选为铑和式（I）的双亚磷酸酯配体，其中X是具有一个或多个杂原子的二价取代或未取代的双亚烷基或双亚芳基，Y是具有一个或多个杂原子的二价取代或未取代的双亚芳基或双亚烷基 s），Z是氧或NR 9，R 1，R 2，R 3，R 4是相同或不同的取代或未取代的连接，未连接或稠合的芳基或杂芳基，并且R 9是氢或被取代或未取代的烷基或芳基，一个或多个杂原子，其中式（I）的二亚磷酸酯配体以过渡金属的过量摩尔比为100:1至1:1使用，而1-丁烯转化率更高比不到95％％的本异丁烯是通过加氢甲酰化从含C4的烃流中分离1-丁烯的反应方法

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