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    • 5. 发明授权
    • Process for preparing diorganopolysiloxanes having terminal
triorganosiloxy units
    • 制备具有末端三有机甲硅烷氧基单元的二有机聚硅氧烷的方法
    • US4975510A
    • 1990-12-04
    • US270131
    • 1988-11-14
    • Karl-Heinrich WegehauptKarl BraunspergerJorg Patzke
    • Karl-Heinrich WegehauptKarl BraunspergerJorg Patzke
    • C08G77/04C08G77/06C08G77/08C08G77/20C08G77/32C08G77/36
    • C08G77/32C08G77/06C08G77/20
    • A process for preparing diorganopolysiloxanes containing terminal triorganosiloxy groups which comprises reacting in a 1st step, a cyclic diorganopolysiloxane and/or diorganodichlorosilane hydrolyzate with from 0.05 to 3 percent by weight of triorganochlorosilane, based on the weight of the cyclic diorganopolysiloxane and/or diorganodichlorosilane hydrolyzate employed in the presence of from 1 to 50 ppm by weight of phosphonitrile chloride, based on the total weight of the organosilicon compounds employed, to form a reaction mixture containing .alpha.-triorganosiloxy-.omega.-chlorodiorganopolysiloxane, and in a 2nd step, adding to the reaction mixture obtained in the 1st step and containing the .alpha.-triorganosiloxy-.omega.-chlorodiorganopolysiloxane, a diorganopolysiloxane having one Si-bonded hydroxyl group in each of the terminal units in an amount of from 1 to 1.2 gram-moles of Si-bonded hydroxyl group in this diorganopolysiloxane per gram-atom of Si-bonded chlorine in the triorganochlorosilane, and in a 3rd step, adding hexaorganodisilazane to the reaction mixture of the 2nd step in order to deactivate the phosphonitrile chloride and remove hydrogen chloride from the diorganopolysiloxanes containing terminal triorganosiloxy groups and thereafter removing the low-boiling components by distillation.
    • 一种制备含有末端三有机甲硅烷氧基的二有机聚硅氧烷的方法,其包括在第一步中,以0.05至3重量%的三有机氯硅烷为基础的环状二有机聚硅氧烷和/或二有机二氯硅烷水解产物,基于所用的环状二有机基聚硅氧烷和/或二有机二氯硅烷水解产物的重量 在1至50ppm重量的磷腈氯化物的存在下,基于所用有机硅化合物的总重量,形成含有α-三有机甲硅烷氧基-ω-氯二羟基聚硅氧烷的反应混合物,并且在第二步骤中,向反应中加入 混合物,其含有α-三有机甲硅烷氧基-ω-氯代二羟基聚硅氧烷,每个末端单元中具有1至1.2克摩尔Si键合的羟基的量的每个末端单元中具有一个Si键合的羟基的二有机基聚硅氧烷 这种二有机聚硅氧烷每克原子中的三键硅键合氯 并且在第3步骤中,向第2步骤的反应混合物中加入六有机二硅氮烷,以使磷腈氯化物失活,并从含有三有机甲硅烷氧基的二有机聚硅氧烷中除去氯化氢,然后通过蒸馏除去低沸点组分。