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    • 6. 发明授权
    • Scaffold materials-transition metal hydride complexes, intermediates therefor and method for preparing the same
    • 支架材料 - 过渡金属氢化物络合物,其中间体及其制备方法
    • US08536358B2
    • 2013-09-17
    • US13059345
    • 2010-01-22
    • Jong Sik KimDong Wook KimDong Ok KimGui Ryong AhnJeasung ParkHyo Jin JeonJisoon IhmMoon-Hyun Cha
    • Jong Sik KimDong Wook KimDong Ok KimGui Ryong AhnJeasung ParkHyo Jin JeonJisoon IhmMoon-Hyun Cha
    • C07F9/00C07F7/00C07F5/00
    • C01B3/0015C01B3/0026C01B6/02C07F3/003Y02E60/327Y02E60/328
    • The present invention relates to substances which can be applied to the technical fields of gas storages, polymerization catalysts and optical isomers, their intermediates, and processes for preparing the same, which is characterized in that 1) possible disintegration of structure of the scaffold material (SM) is impeded, and 2) they are prepared by a simple manufacturing system as compared to the substances conventionally suggested in the application field. Specifically, it relates to scaffold material-transition metal hydride complexes comprised of scaffold material (SM) and transition metal hydride (M1H(n-1)) which is chemically bonded to the functional groups formed on the scaffold material, SM-transition metal halide complex and SM-transition metal ligand complex as the precursors, and a process for preparing the same. The SM-transition metal hydride complex according to the present invention is a substance for hydrogen storage which adsorbs hydrogen via Kubas adsorption. The complex according to the invention can store high capacity of hydrogen with safety and reversibility, while disintegration of its structure does not occur even with repeated adsorption-desorption of hydrogen.
    • 本发明涉及可用于气体存储器,聚合催化剂和光学异构体的技术领域的物质,其中间体及其制备方法,其特征在于1)可能的支架材料的结构分解( SM)受阻,2)与应用领域通常建议的物质相比,它们通过简单的制造系统制备。 具体地说,它涉及由支架材料(SM)和过渡金属氢化物(M1H(n-1))构成的支架材料 - 过渡金属氢化物络合物,其与化学键合在支架材料上形成的官能团,SM-过渡金属卤化物 络合物和SM-过渡金属配体络合物作为前体,以及其制备方法。 根据本发明的SM-过渡金属氢化物络合物是通过Kubas吸附吸附氢的储氢物质。 根据本发明的复合物可以安全和可逆地存储高容量氢气,而即使反复进行氢的吸附 - 脱附也不会发生其结构的分解。
    • 9. 发明申请
    • Scaffold Materials-Transition Metal Hydride Complexes, Intermediates Therefor and Method for Preparing the Same
    • 支架材料 - 过渡金属氢化物络合物,其中间体及其制备方法
    • US20110201834A1
    • 2011-08-18
    • US13059345
    • 2010-01-22
    • Jong Sik KimDong Wook KimDong Ok KimGui Ryong AhnJeasung ParkHyo Jin JeonJisoon IhmMoon-Hyun Cha
    • Jong Sik KimDong Wook KimDong Ok KimGui Ryong AhnJeasung ParkHyo Jin JeonJisoon IhmMoon-Hyun Cha
    • C07F7/28B82Y30/00B82Y40/00
    • C01B3/0015C01B3/0026C01B6/02C07F3/003Y02E60/327Y02E60/328
    • The present invention relates to substances which can be applied to the technical fields of gas storages, polymerization catalysts and optical isomers, their intermediates, and processes for preparing the same, which is characterized in that 1) possible disintegration of structure of the scaffold material (SM) is impeded, and 2) they are prepared by a simple manufacturing system as compared to the substances conventionally suggested in the application field. Specifically, it relates to scaffold material-transition metal hydride complexes comprised of scaffold material (SM) and transition metal hydride (M1H(n-1)) which is chemically bonded to the functional groups formed on the scaffold material, SM-transition metal halide complex and SM-transition metal ligand complex as the precursors, and a process for preparing the same. The SM-transition metal hydride complex according to the present invention is a substance for hydrogen storage which adsorbs hydrogen via Kubas adsorption. The complex according to the invention can store high capacity of hydrogen with safety and reversibility, while disintegration of its structure does not occur even with repeated adsorption-desorption of hydrogen.
    • 本发明涉及可用于气体存储器,聚合催化剂和光学异构体的技术领域的物质,它们的中间体及其制备方法,其特征在于:1)支架材料的结构可能的分解( SM)受阻,2)与应用领域通常建议的物质相比,它们通过简单的制造系统制备。 具体地说,它涉及由支架材料(SM)和过渡金属氢化物(M1H(n-1))构成的支架材料 - 过渡金属氢化物络合物,其与化学键合在支架材料上形成的官能团,SM-过渡金属卤化物 络合物和SM-过渡金属配体络合物作为前体,以及其制备方法。 根据本发明的SM-过渡金属氢化物络合物是通过Kubas吸附吸附氢的储氢物质。 根据本发明的复合物可以安全和可逆地存储高容量氢气,而即使反复进行氢的吸附 - 脱附也不会发生其结构的分解。