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1. 发明专利

JP2012056833A Carbon nanostructure, metal-supported carbon nanostructure, lithium ion secondary battery, method for producing carbon nanostructure, and method for producing metal-supported carbon nanostructure 有权
标题翻译：碳纳米结构，金属担载的碳纳米结构，锂离子二次电池，生产碳纳米管结构的方法和生产金属担载的碳纳米结构的方法
公开(公告)号：JP2012056833A
公开(公告)日：2012-03-22
申请号：JP2011170836
申请日：2011-08-04
申请人： Denso Corp , National Institutes Of Natural Sciences , Nippon Steel Chem Co Ltd , 大学共同利用機関法人自然科学研究機構 , 新日鐵化学株式会社 , 株式会社デンソー
发明人： NISHI NOBUYUKI , ADACHI NORIKAZU , OBA YASUYUKI , YAMADA MANABU , KAMI KENICHIRO , MIZUUCHI KAZUHIKO
IPC分类号： C01B31/02 , B82Y30/00 , B82Y40/00 , H01G11/22 , H01G11/24 , H01G11/30 , H01G11/32 , H01M4/583 , H01M4/96
CPC分类号： H01M4/133 , H01G11/36 , H01G11/50 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/386 , H01M4/387 , H01M4/625 , H01M4/626 , H01M10/0525 , Y02E60/122 , Y02E60/13 , Y02P70/54
摘要： PROBLEM TO BE SOLVED: To provide a carbon nanostructure and metal-supported carbon nanostructure having a new structure used as a negative electrode material or the like of a lithium ion secondary battery.SOLUTION: This carbon nanostructure is produced, in which carbon-containing rod-shaped materials and/or carbon-containing sheet-shaped materials are bound three-dimensionally to each other and alveolar-like voids partitioned by graphene multilayer membrane walls are formed in the rod-shaped materials and/or the sheet-shaped materials. A metal-supported carbon nanostructure is also produced, which comprises the carbon nanostructure and a metal supported in the voids in the carbon nanostructure.
摘要翻译：要解决的问题：提供具有用作锂离子二次电池的负极材料等的新结构的碳纳米结构体和金属负载型碳纳米结构体。解决方案：生产这种碳纳米结构，其中含碳棒状材料和/或含碳片状材料彼此三维地结合，并且由石墨烯多层膜壁分隔的肺泡状空隙是形成在棒状材料和/或片状材料中。还产生了金属负载的碳纳米结构，其包括碳纳米结构和支撑在碳纳米结构中的空隙中的金属。版权所有（C）2012，JPO＆INPIT

2. 发明专利

JP2012062222A Carbon nanostructure 审中-公开
标题翻译：碳纳米结构
公开(公告)号：JP2012062222A
公开(公告)日：2012-03-29
申请号：JP2010207936
申请日：2010-09-16
申请人： Denso Corp , National Institutes Of Natural Sciences , Nippon Steel Chem Co Ltd , 大学共同利用機関法人自然科学研究機構 , 新日鐵化学株式会社 , 株式会社デンソー
发明人： NISHI NOBUYUKI , ADACHI NORIKAZU , OBA YASUYUKI , YAMADA MANABU , KAMI KENICHIRO , MIZUUCHI KAZUHIKO
IPC分类号： C01B31/02 , B82B1/00 , B82B3/00 , B82Y30/00 , B82Y40/00 , B82Y99/00 , H01G11/22 , H01G11/32 , H01G11/86 , H01M4/583 , H01M4/96
CPC分类号： Y02E60/50
摘要： PROBLEM TO BE SOLVED: To provide a new-structured carbon nanostructure which can be used as an electrode material, a catalyst carrier, or the like.SOLUTION: A carbon nanostructure having alveolus-like pores demarcated by graphene multilayer film walls is obtained: by blowing a methylacetylene gas into a solution containing a metal salt to make a wire-like crystal of a metal methylacetylide; subjecting the rod-like crystal and/or the plate-like crystal to a first heat treatment to segregate the metal of the metal methylacetylide and to segregate the carbon of the rod-like crystal and/or the plate-like crystal to thereby obtain a carbon nanostructure intermediate composed of three-dimensionally bonded carbon-containing rod-like and/or plate-like bodies and to make a metal inclusion carbon nanostructure composed of the carbon nanostructure intermediate and the metal included therein; bringing the metal inclusion carbon nanostructure into contact with nitric acid; and subjecting the resultant metal inclusion carbon nanostructure to a second heat treatment to eject the included metal from the metal inclusion carbon nanostructure.
摘要翻译：要解决的问题：提供可用作电极材料，催化剂载体等的新型结构的碳纳米结构。解决方案：获得具有由石墨烯多层膜壁划分的具有肺泡状孔的碳纳米结构体：通过将甲基乙炔气吹入含有金属盐的溶液中以制成金属甲基乙酰化物的丝状结晶; 对棒状晶体和/或板状晶体进行第一次热处理以分离金属甲基乙酰亚胺的金属并分离棒状晶体和/或板状晶体的碳，从而获得由三维结合的含碳棒状和/或板状体构成的碳纳米结构中间体，并且由碳纳米结构中间体和包含的金属构成的金属包覆碳纳米结构体; 使金属包覆碳纳米结构与硝酸接触; 并对所得的金属包覆碳纳米结构进行第二次热处理，以从金属包覆碳纳米结构中排出所含的金属。版权所有（C）2012，JPO＆INPIT

3. 发明专利

JP2010104958A Hydrogen occlusion nanowire and method of manufacturing hydrogen occlusion nanowire 审中-公开
标题翻译：氢化纳米管及其制造氢化纳米管的方法
公开(公告)号：JP2010104958A
公开(公告)日：2010-05-13
申请号：JP2008281741
申请日：2008-10-31
申请人： National Institutes Of Natural Sciences , Nippon Steel Chem Co Ltd , 大学共同利用機関法人自然科学研究機構 , 新日鐵化学株式会社
发明人： NISHI NOBUYUKI , SOSHIRO TAKESHI , MIZUUCHI KAZUHIKO
IPC分类号： B01J20/22 , B01J20/28 , C01B3/00
摘要： PROBLEM TO BE SOLVED: To provide a new structure which reveals high hydrogen occlusion function especially at a room temperature.
SOLUTION: The nanowire is manufactured in the way that a crystalline nanowire is formed self-organizedly through bringing acetylene gas into contact with CuCl as a raw material and thermally treating the nanowire under a non-oxidizable atmosphere at not less than 120°C.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种显示高吸氢功能的新结构，特别是在室温下。解决方案：纳米线以通过使乙炔气体与CuCl作为原料接触而自组织形成结晶纳米线并以不小于120°的非可氧化气氛热处理纳米线的方式制造 C。版权所有（C）2010，JPO＆INPIT

4. 发明专利

JP2008021876A Porous carbon material for non-aqueous electric double layer capacitor, manufacturing method thereof and non-aqueous electric double layer capacitor 审中-公开
标题翻译：非水电双层电容器的多孔碳材料及其制造方法和非水电双层电容器
公开(公告)号：JP2008021876A
公开(公告)日：2008-01-31
申请号：JP2006193217
申请日：2006-07-13
申请人： Nippon Steel Chem Co Ltd , 新日鐵化学株式会社
发明人： MIZUUCHI KAZUHIKO
IPC分类号： H01G11/22 , H01G11/14 , H01G11/24 , H01G11/34 , H01G11/38 , H01G11/42 , H01G11/44 , H01G11/58 , H01G11/86
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide a porous carbon material for a non-aqueous electric double layer capacitor which has high capacitance per volume of an electrode and low expansion of volume in charging, and a manufacturing method thereof and the non-aqueous electric double layer capacitor.
SOLUTION: A metal simple substance or a compound of the metal simple substance is blended with a coal pitch or a petrol pitch and a blended result is carbonized, the metal simple substance or the compound of the metal simple substance is cleaned with a soluble solvent, and is alkali-activated to obtain the porous carbon material for a non-aqueous electric double layer capacitor. Preferably, a primary quinoline insoluble component of the coal pitch is not more than 2 mass%, the metal simple substance is Fe, Si, Co, Cr or Ni, and the compound of the metal simple substance is a compound of Fe, Si, Co, Cr or Ni. More preferably, the compound of the metal simple substance is ferrite.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决的问题：为了提供一种用于非水电双层电容器的多孔碳材料及其制造方法和非水性的非水电双层电容器，其具有每单位体积电极的高容量和充电体积的低膨胀双电层电容器。解决方案：将金属单体或金属单体的化合物与煤沥青或汽油沥青混合并将混合结果碳化，金属单体或金属单体的化合物用并进行碱活化，得到非水电双层电容器用的多孔碳材料。优选煤沥青的主要喹啉不溶成分不超过2质量％，金属单体为Fe，Si，Co，Cr或Ni，金属单体的化合物为Fe，Si， Co，Cr或Ni。更优选地，金属单体的化合物是铁素体。版权所有（C）2008，JPO＆INPIT

5. 发明专利

JP2006269494A Carbonaceous material for polarized electrode for electric double-layer capacitor, and manufacturing method of polarized electrode 审中-公开
标题翻译：用于双层电容器的极化电极的碳材料和极化电极的制造方法
公开(公告)号：JP2006269494A
公开(公告)日：2006-10-05
申请号：JP2005081568
申请日：2005-03-22
申请人： Nippon Steel Chem Co Ltd , 新日鐵化学株式会社
发明人： MIZUUCHI KAZUHIKO
IPC分类号： C01B31/02 , H01G11/22 , H01G11/24 , H01G11/34 , H01G11/38 , H01G11/42 , H01G11/44
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide a carbonaceous material for the polarized electrode of an electric double-layer capacitor for obtaining high capacitance with a small amount of variation, and to provide a method for manufacturing the polarized electrode.
SOLUTION: The electric double-layer capacitor polarized electrode is manufactured by using a carbonaceous material in which a raw material is for example activated with non-baked coke originating from coal or oil, in which the thermal coefficient of expansion measured by an artificial graphite electrode testing method is adjusted within 0.8-2 as the raw material. In the case of the non-baked coke originating from coal, raw coke of coal-based pitch coke is used in which CTE is controlled manufactured by a delayed coker method by using coal-based tar having a quinolin insoluble content of 0.1% or smaller, or the raw coke of coal-based pitch coke is selected for use for satisfying a desired CTE range.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决的问题：提供一种用于双电层电容器的极化电极的碳质材料，用于获得具有少量变化的高电容，并提供一种制造极化电极的方法。解决方案：电双层电容器极化电极通过使用原料例如通过来自煤或油的非焙烧焦炭活化的碳质材料制造，其中由人造石墨电极测试方法调整为0.8-2以内的原料。在来自煤的非焙烧焦炭的情况下，通过使用喹啉不溶成分为0.1％以下的煤焦油，采用延迟焦化法制造CTE控制的煤焦油焦炭或者煤基沥青焦炭的原焦炭被选择用于满足期望的CTE范围。版权所有（C）2007，JPO＆INPIT

6. 发明专利

JP2006024779A Electric double layer capacitor and porous carbon material therefor 审中-公开
标题翻译：双电层电容器及其多孔碳材料
公开(公告)号：JP2006024779A
公开(公告)日：2006-01-26
申请号：JP2004202102
申请日：2004-07-08
申请人： Nippon Steel Chem Co Ltd , Nippon Steel Corp , 新日本製鐵株式会社 , 新日鐵化学株式会社
发明人： MIZUUCHI KAZUHIKO , SAITO KOUJI
IPC分类号： H01G11/22 , H01G11/24 , H01G11/26 , H01G11/30 , H01G11/34 , H01G11/42 , H01G11/44 , H01G11/54 , H01G11/58 , H01G11/60 , H01G11/62 , H01G11/86
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide an electric double layer capacitor having a high electrostatic capacity per unit volume.
SOLUTION: The electric double layer capacitor has a pair of positive and negative electrodes, at least the positive electrode containing a porous carbon material as its main component, and an electrolytic solution forming an electric double layer in each of interfaces with the pair of positive and negative electrodes. The electrolytic solution contains an anion having a boron atom. In a
11 B-MQMAS solid-state NMR spectrum for the positive electrode in a charge state, a peak belonging to the boron atom is split into three. Assuming that the peak is split into peaks a, b, and c sequentially from a higher magnetic field side of a chemical shift, and the respective peaks have signal heights Ia, Ib, and Ic, respectively; then a signal height ratio R is expressed as R=Ic/Ia≥0.1.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供每单位体积具有高静电容量的双电层电容器。解决方案：双电层电容器具有一对正极和负极，至少含有多孔碳材料作为其主要成分的正极和在每个界面中形成双电层的电解液的正极和负极。电解液含有具有硼原子的阴离子。在充电状态下的正极的 11 B-MQMAS固体NMR光谱中，属于硼原子的峰被分为三个。假设峰值从化学位移的较高磁场侧依次分成峰a，b和c，并且各峰分别具有信号高度Ia，Ib和Ic; 则信号高度比R表示为R = Ic /Ia≥0.1。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2010115636A Microporous carbonaceous material, method of manufacturing microporous carbonaceous material, and hydrogen storage method using microporous carbonaceous material 有权
标题翻译：微孔碳质材料，制造微孔碳材料的方法和使用微孔碳材料的氢储存方法
公开(公告)号：JP2010115636A
公开(公告)日：2010-05-27
申请号：JP2009040932
申请日：2009-02-24
申请人： Nippon Steel Chem Co Ltd , Nissan Motor Co Ltd , Tohoku Univ , 国立大学法人東北大学 , 新日鐵化学株式会社 , 日産自動車株式会社
发明人： ITO HITOSHI , KYOTANI TAKASHI , NISHIHARA HIROTOMO , HOU PENG-XIANG , LI LI-XIANG , HATA KYOHEI , MIZUUCHI KAZUHIKO
IPC分类号： B01J20/20 , C01B3/00 , C01B31/02 , C23C16/01
CPC分类号： C01B3/0021 , B01J20/20 , B01J20/2808 , B01J20/28097 , B01J20/3057 , B01J20/3236 , B82Y30/00 , C01B32/00 , C01B32/05 , C04B35/52 , C04B35/524 , C04B38/0022 , C04B2111/0081 , C04B2111/00853 , C04B2235/3472 , C04B2235/3481 , C04B2235/40 , C04B2235/408 , C04B2235/48 , Y02E60/325 , C04B38/0054 , C04B38/106
摘要： PROBLEM TO BE SOLVED: To provide a microporous carbonaceous material capable of expressing functions of a supported metal while maintaining such fine porosity functions that the microporous carbonaceous material originally possesses. SOLUTION: The microporous carbonaceous material 5 has a three-dimensional long-period ordered structure in the range of 0.7 nm to 2 nm and has micropores 2a, wherein a transition metal 4 is supported on the surface of the micropores 2a. The microporous carbonaceous material is provided by: a method including a process of introducing an organic compound onto the surface of porous material that contains a transition metal and into the micropores and carbonizing the organic compound according to a chemical vapor deposition method to obtain a composite of the microporous carbonaceous material containing the transition metal and a porous material and a process of removing the porous material; or a method including a process of introducing an organic compound onto the surface of the porous material to obtain a microporous carbonaceous material according to a chemical vapor deposition method and a process of immersing and impregnating the microporous carbonaceous material in a transition metal salt solution to support the transition metal onto the surface of the microporous carbonaceous material. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供能够表现支撑金属的功能的微孔碳质材料，同时保持微孔碳质材料最初具有的这种微孔隙功能。解决方案：微孔碳质材料5具有在0.7nm至2nm范围内的三维长周期有序结构，并且具有微孔2a，其中过渡金属4负载在微孔2a的表面上。微孔碳质材料是通过以下方法提供的：包括将有机化合物引入含有过渡金属的多孔材料的表面并进入微孔并根据化学气相沉积法使有机化合物碳化的方法，以获得含有过渡金属的微孔碳质材料和多孔材料以及除去多孔材料的方法; 或包括将有机化合物引入到多孔材料的表面上以根据化学气相沉积方法获得微孔碳质材料的方法的方法，以及将微孔碳质材料浸渍并浸渍在过渡金属盐溶液中以支撑的方法过渡金属在微孔碳质材料的表面上。版权所有（C）2010，JPO＆INPIT

8. 发明专利

JP2008021833A Porous carbon material for electric double layer capacitor, manufacturing method thereof, and non-aqueous electric double layer capacitor 审中-公开
标题翻译：用于电双层电容器的多孔碳材料及其制造方法和非水电双层电容器
公开(公告)号：JP2008021833A
公开(公告)日：2008-01-31
申请号：JP2006192582
申请日：2006-07-13
申请人： Nippon Steel Chem Co Ltd , 新日鐵化学株式会社
发明人： MIZUUCHI KAZUHIKO , MORITA KAZUHIRO , INAGAKI MICHIO
IPC分类号： H01G9/00 , H01G11/14 , H01G11/22 , H01G11/24 , H01G11/34 , H01G11/38 , H01G11/42 , H01G11/44 , H01G11/58 , H01G11/86
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide a porous carbon material for a non-aqueous electric double layer capacitor which is excellent in high-speed charging/discharging performance and has less expansion of its volume in charging, and to provide a manufacturing method thereof and a non-aqueous electric double layer capacitor.
SOLUTION: A metal compound is blended with a coal pitch or a petrol pitch and a blended result is carbonized, and a carbide is cleaned with a solvent capable of dissolving the metal compound to obtain the porous carbon material for an electric double layer capacitor. The coal pitch etc. to be used is preferably has a primary quinoline insoluble component of not more than 2 mass% and the metal compound is preferably an organic acid salt of magnesium. A mass ratio of the metal compound to the coal pitch etc. is preferably 95:5 or 5:95. Preferably, the porous carbon material has an average diameter of micropores of 1 nm-10 nm.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种非水电双层电容器的多孔碳材料，其具有优异的高速充电/放电性能，并且其充电容量的扩大较少，并且提供一种制造方法和非水电双层电容器。解决方案：将金属化合物与煤沥青或汽油沥青混合并将共混结果碳化，并且用能够溶解金属化合物的溶剂清洁碳化物，以获得用于双电层的多孔碳材料电容。所使用的煤沥青等优选为不超过2质量％的主要喹啉不溶成分，金属化合物优选为镁的有机酸盐。金属化合物与煤沥青等的质量比优选为95:5或5:95。优选地，多孔碳材料的微孔的平均直径为1nm〜10nm。版权所有（C）2008，JPO＆INPIT

9. 发明专利

JP2006295144A Porous carbon material for electric double layer capacitor polarizing electrode 审中-公开
标题翻译：电动双层电容器极化电极多孔碳材料
公开(公告)号：JP2006295144A
公开(公告)日：2006-10-26
申请号：JP2006068899
申请日：2006-03-14
申请人： Nippon Steel Chem Co Ltd , 新日鐵化学株式会社
发明人： MIZUUCHI KAZUHIKO
IPC分类号： H01G11/22 , H01G11/24 , H01G11/26 , H01G11/34 , H01G11/38 , H01G11/44 , H01G11/86
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide a porous carbon material for an electric double layer polarizing electrode obtaining an electric double layer capacitor of large electrostatic capacitance per an electrode volume at a low cost.
SOLUTION: The porous carbon material for an electric double layer capacitor polarizing electrode uses uncalcinated coke originated from carbon or petroleum whose thermal expansion factor that is measured by an artificial graphite electrode testing method is 2 or higher. The uncalcinated coke is such uncalcinated coke of pitch coke as manufactured by a delayed coking method. The uncalcinated coke is acquired by coking heavy oil originated from carbon or petroleum as it is or after blending it with resin. Otherwise, the uncalcinated coke is obtained by subjecting the heavy oil to dequinolinic insoluble content process in which carbon fine particles, being preheated, are dispersed.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：为了提供一种用于双电层极化电极的多孔碳材料，以低成本获得每个电极体积的具有大静电电容的双电层电容器。解决方案：用于双电层电容器极化电极的多孔碳材料使用源自碳或石油的未煅烧焦炭，其通过人造石墨电极测试方法测量的热膨胀系数为2或更高。未煅烧焦炭是通过延迟焦化方法制造的沥青焦炭的未煅烧焦炭。未煅烧的焦炭是通过焦化来自碳或石油的重油原样或与树脂混合后获得的。另外，未重结晶的焦炭是通过使重油经脱水的碳微粒被分散的脱喹啉不溶成分过程而得到的。版权所有（C）2007，JPO＆INPIT

10. 发明专利

JP2008288466A Method of manufacturing non-porous carbon material for electric dipole layer capacitor 审中-公开
标题翻译：电镀层电容器制造非多孔碳材料的方法
公开(公告)号：JP2008288466A
公开(公告)日：2008-11-27
申请号：JP2007133561
申请日：2007-05-19
申请人： Kyushu Univ , Nippon Steel Chem Co Ltd , 国立大学法人九州大学 , 新日鐵化学株式会社
发明人： MIZUUCHI KAZUHIKO , MITSUKI YOZO
IPC分类号： H01G9/00 , H01G11/00 , H01G11/34 , H01G11/38 , H01G11/42 , H01G11/84
CPC分类号： Y02E60/13
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a non-porous carbon material for an electric dipole layer capacitor which can suppress volume expansion during charging/discharging.
SOLUTION: Either of or both of a coal pitch and a petroleum pitch and carbon black are blended, the blend is carbonated, and carbide is alkali-activated to obtain a non-porous carbon material for an electric dipole layer capacitor. It is preferable to blend the carbon black in 1 to 20 pts.mass to either of or both of the coal pitch and the petroleum pitch in 100 pts.mass.
COPYRIGHT: (C)2009,JPO&INPIT

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