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1. 发明授权

US4393259A Process for conversion of propane or butane to gasoline 失效
标题翻译：将丙烷或丁烷转化为汽油的方法
公开(公告)号：US4393259A
公开(公告)日：1983-07-12
申请号：US290031
申请日：1981-08-05
申请人： Dennis J. Ward , Bipin V. Vora
发明人： Dennis J. Ward , Bipin V. Vora
IPC分类号： C07C11/02 , C07C11/107 , C10G49/22 , C10L1/06 , C07C2/08
CPC分类号： C10L1/06 , C07C11/02 , C07C11/107 , C10G2400/02 , Y02P20/582
摘要： A multi-step hydrocarbon conversion process for producing gasoline from propane or butane is disclosed. The feed hydrocarbon is passed into a dehydrogenation zone and the entire dehydrogenation zone effluent including hydrogen and light by-products is then passed into a catalytic condensation zone wherein the resulting olefins are converted into dimers and trimers. The condensation zone effluent stream is passed into a separation zone in which the dimers and trimers are concentrated into a product stream, with unconverted feed hydrocarbon and hydrogen being recycled to the dehydrogenation zone.
摘要翻译：公开了一种用于从丙烷或丁烷生产汽油的多步烃转化方法。进料碳氢化合物进入脱氢区，然后将包含氢气和轻质副产物的整个脱氢区流出物进入催化冷凝区，其中所得烯烃转化成二聚体和三聚体。冷凝区流出物流进入分离区，其中二聚体和三聚体浓缩成产物流，未转化的进料烃和氢气被再循环到脱氢区。

2. 发明授权

US4367356A Process for the production of gasoline from C.sub.4 hydrocarbons 失效
标题翻译：从C4碳氢化合物生产汽油的方法
公开(公告)号：US4367356A
公开(公告)日：1983-01-04
申请号：US272594
申请日：1981-06-11
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： C07C9/16 , C07C2/58
CPC分类号： C07C9/16 , Y02P20/582
摘要： A process for producing gasoline from a charge stream comprising a mixture of butanes and butylenes is disclosed. The quality of a product alkylate is improved by increasing the butene-2 content of an alkylation zone feed stream. A first portion of the charge stream is passed into a dimerization zone in which isobutylene is reacted with normal butylenes, with butene-1 being reacted to a greater extent than butene-2. A C.sub.8 hydrocarbon-containing product stream and a C.sub.4 stream having a higher butene-2 concentration than the charge stream are recovered from the dimerization zone. This high butene-2 content C.sub.4 stream is admixed with a second portion of the charge stream and passed into an alkylation zone wherein butylenes are reacted with isobutane to yield a second product stream containing C.sub.8 hydrocarbons.
摘要翻译：公开了一种从含有丁烷和丁烯的混合物的电荷流产生汽油的方法。烷基化产物的质量通过提高烷基化进料流中丁烯-2的含量得到改善。电荷流的第一部分进入二聚化区，其中异丁烯与正丁烯反应，丁烯-1比丁烯-2更大程度地反应。从二聚化区域回收含有C8烃的产物流和具有比电荷流更高的丁烯-2浓度的C4流。将该高丁烯-2含量的C4流与电荷流的第二部分混合，并进入烷基化区，其中丁烯与异丁烷反应，得到含有C8烃的第二产物流。

3. 发明授权

US4013737A Upgrading synthetic gasoline 失效
标题翻译：升级合成汽油
公开(公告)号：US4013737A
公开(公告)日：1977-03-22
申请号：US587467
申请日：1975-06-16
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： C10G17/095 , C10L1/02 , C07C5/24
CPC分类号： C10L1/023 , C10G2400/02 , Y10S208/95
摘要： Gasoline synthesized from carbon monoxide and hydrogen is contacted with a solid phosphoric acid catalyst to improve the octane number of the gasoline.

4. 发明授权

US4217461A Olefinic hydrocarbon isomerization process 失效
标题翻译：烯烃烃异构化过程
公开(公告)号：US4217461A
公开(公告)日：1980-08-12
申请号：US60714
申请日：1979-07-26
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： C07C5/22 , C07C11/08 , C07C5/24 , C07C11/02
CPC分类号： C07C11/08 , C07C5/2206
摘要： A process for the isomerization of normal olefinic hydrocarbons is disclosed. The feed stream is passed through a first reaction zone and is then cooled sufficiently to cause the condensation of from about 1 to 25 mole percent of the hydrocarbons in the isomerization zone effluent stream. The uncondensed portion of the effluent of the first reaction zone is heated and passed through a second reaction zone which is maintained at a lower temperature than the first reaction zone. The product isomer is recovered from the effluent of the second reaction zone.
摘要翻译：公开了正常烯烃的异构化方法。进料流通过第一反应区，然后充分冷却，使异构化区流出物流中约1至25摩尔％的烃缩合。将第一反应区的流出物的未冷凝部分加热并通过第二反应区，该第二反应区保持在低于第一反应区的温度。从第二反应区的流出物回收产物异构体。

5. 发明授权

US4104321A Process for the separation of olefins 失效
标题翻译：烯烃分离方法
公开(公告)号：US4104321A
公开(公告)日：1978-08-01
申请号：US779414
申请日：1977-03-18
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： C07C7/09 , C07C1/00 , C07C5/27 , C07C7/00 , C07C7/04 , C07C11/02 , C07C11/09 , C07C11/10 , C07C11/107 , C07C67/00 , C07C5/24
CPC分类号： C07C11/09 , C07C5/277 , C07C5/2772 , C07C7/005
摘要： A butene mixture is separated to yield an n-butene rich product and an isobutylene rich product in a fractionator system. The fractionator reflux is isomerized before introduction into the fractionator. Other suitable olefins may be separated in a similar manner.
摘要翻译：分离丁烯混合物以在分馏器系统中产生富含正丁烯的产物和富含异丁烯的产物。分馏塔回流在引入分馏塔之前被异构化。其它合适的烯烃可以以类似的方式分离。

6. 发明授权

US4072729A Simulated moving bed reaction process 失效
标题翻译：模拟移动床反应过程
公开(公告)号：US4072729A
公开(公告)日：1978-02-07
申请号：US768510
申请日：1978-02-07
申请人： Laurence O. Stine , Dennis J. Ward
发明人： Laurence O. Stine , Dennis J. Ward
IPC分类号： B01J8/04 , C07C2/58 , C07C2/66 , C07C3/52
CPC分类号： C07C2/58 , B01J8/0453 , C07C2/66 , C07C2529/06 , Y02P20/584 , Y10S585/906
摘要： A continuous catalytic reaction and catalyst reactivation process is performed using a simulated moving catalyst bed to effect simultaneously in different zones of a multi-zone fixed catalyst bed an alkylation reaction of olefinic and aromatic reactants and a reactivation of catalyst.
摘要翻译：使用模拟移动催化剂床进行连续催化反应和催化剂再活化过程，以在多区域固定催化剂床的不同区域同时进行烯烃和芳族反应物的烷基化反应和催化剂的再活化。

7. 发明授权

US4051191A Solid phosphoric acid catalyzed alkylation of aromatic hydrocarbons 失效
标题翻译：芳香烃类固体磷酸催化烷基化
公开(公告)号：US4051191A
公开(公告)日：1977-09-27
申请号：US756523
申请日：1977-01-03
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： B01J27/00 , C07B61/00 , C07C1/00 , C07C2/70 , C07C7/00 , C07C15/02 , C07C15/085 , C07C67/00 , C07C3/54
CPC分类号： C07C2/70 , C07C7/005 , C07C2527/173 , Y02P20/52
摘要： A process for the alkylation of aromatic hydrocarbons using a solid phosphoric acid catalyst in which liquid phosphoric acid is removed from the bottoms stream of the rectification column to which the alkylation zone effluent is charged. The acid is removed by passing the bottoms stream into a settling vessel operated at a lower pressure and temperature than the bottom of the rectification column.

8. 发明授权

US4008290A Cumene production 失效
标题翻译：库梅内生产
公开(公告)号：US4008290A
公开(公告)日：1977-02-15
申请号：US678005
申请日：1976-04-19
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： C07C2/70 , C07C6/12 , C07C15/085 , C07C3/62 , C07C3/54
CPC分类号： C07C15/085 , C07C2/70 , C07C6/126 , C07C2527/173 , Y02P20/582
摘要： A process to reduce utility consumption in the catalytic alkylation of benzene with propylene to form cumene. Propylene and benzene are reacted in an alkylation reaction zone, the effluent of which is divided into two portions, the first being recirculated to the inlet of the reaction zone and the second being passed into a separation zone wherein cumene product, di- and triisopropylbenzene and excess benzene are separated. A portion of the excess benzene is recycled to the inlet of the alkylation reaction zone, and a second portion is admixed with di- and triisopropylbenzene and passed into a transalkylation zone, the effluent of which is introduced into the separation zone. Utility consumption is reduced compared to prior art processes, as a result of a reduction of the portion of excess benzene separated and recycled to the alkylation reaction zone.
摘要翻译：一种降低苯与丙烯催化烷基化形成异丙苯的效用消耗的方法。丙烯和苯在烷基化反应区中反应，其流出物分为两部分，第一部分被再循环到反应区的入口，第二个进入分离区，其中异丙苯产物，二异丙基苯和三异丙基苯和过量的苯分离。一部分过量的苯被再循环到烷基化反应区的入口，第二部分与二异丙基苯和三异丙基苯混合并进入烷基转移区，将其流出物引入分离区。由于分离并再循环到烷基化反应区的过量苯部分减少，现有技术方法的效用降低。

9. 发明授权

US4709111A Oligomerization process with integrated heat utilization 失效
标题翻译：具有综合热利用的低聚过程
公开(公告)号：US4709111A
公开(公告)日：1987-11-24
申请号：US19824
申请日：1987-02-27
申请人： Dennis J. Ward
发明人： Dennis J. Ward
IPC分类号： C07C2/08 , C07C2/02
CPC分类号： C07C2/08 , Y10S585/911
摘要： A process flow for a catalytic oligomerization process is presented. The feed contacts a solid catalyst in a tubular reactor cooled by indirect heat exchange. The mixed-phase coolant used in the reactor is the reactor effluent itself, which has been cooled by indirect heat exchange and depressurized. The reactor effluent is then passed into a rectified separation zone. The heat picked up by the effluent stream in the reactor is thereby used in separating light hydrocarbons from the effluent to produce a recycle stream.
摘要翻译：提出了催化低聚方法的工艺流程。进料通过间接热交换冷却的管式反应器中的固体催化剂接触。反应器中使用的混合相冷却剂是反应器流出物本身，其通过间接热交换和减压而被冷却。然后将反应器流出物进入精馏分离区。由反应器中的流出物流吸收的热量用于从流出物中分离轻质烃以产生再循环流。

10. 发明授权

US4293722A Process for conversion of propane to gasoline 失效
标题翻译：将丙烷转化为汽油的方法
公开(公告)号：US4293722A
公开(公告)日：1981-10-06
申请号：US121353
申请日：1980-02-14
申请人： Dennis J. Ward , Bipin V. Vora
发明人： Dennis J. Ward , Bipin V. Vora
IPC分类号： C07C11/02 , C07C11/107 , C10G49/22 , C10L1/06 , C07C2/08 , C07C5/32
CPC分类号： C10L1/06 , C07C11/02 , C07C11/107 , C10G2400/02 , Y02P20/582
摘要： A multi-step hydrocarbon conversion process for producing gasoline from propane is disclosed. Propane is passed into a dehydrogenation zone and the entire dehydrogenation zone effluent is then passed into a catalytic condensation zone wherein propylene is converted into C.sub.6 and C.sub.9 hydrocarbons. The condensation zone effluent, a stripper overhead stream and an absorber bottoms stream are commingled and then separated into vapor and liquid portions. The liquid is passed into the stripper, and the vapor portion is contacted with stripper bottoms liquid in an absorber. The absorber overhead stream is contacted with liquid propane in a second absorber to remove C.sub.6 hydrocarbons and is then recycled to the dehydrogenation zone. Depropanizing a portion of the stripper bottoms yields the liquid propane and a gasoline product.
摘要翻译：公开了一种用于从丙烷生产汽油的多步烃转化方法。丙烷通入脱氢区，然后将全部脱氢区流出物送入催化冷凝区，其中丙烯转化为C6和C9烃。冷凝区流出物，汽提器顶部物流和吸收塔底物流混合，然后分离成蒸汽和液体部分。将液体通入汽提器中，蒸气部分与吸收器中的汽提塔底部液体接触。吸收塔顶流与第二吸收器中的液态丙烷接触以除去C6烃，然后再循环到脱氢区。脱胶一部分汽提塔底部产生液体丙烷和汽油产品。

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