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    • 6. 发明授权
    • Cold sealable cohesive terpolymers
    • 可冷密粘结三元共聚物
    • US5070164A
    • 1991-12-03
    • US401596
    • 1989-08-31
    • Taeik MinRobert E. Touhsaent
    • Taeik MinRobert E. Touhsaent
    • C08F214/08C08F220/12
    • C08F214/08C08F220/12
    • A cold sealable emulsion polymerized terpolymer cohesive formulation which has low surface tack characteristics, prepared from the emulsion polymerization of a first monomer selected from the group consisting of ethyl acrylate, hexyl acrylate, isooctyl acrylate, butyl acrylate, methyl acrylate and vinylidene chloride, a second monomer selected from the group consisting of vinyl acetate, methyl methacrylate, styrene, ethyl methacrylate and isobutyl methacrylate and a third monomer selected from the group consisting of methacrylic acid, acrylic acid, itaconic acid, sulfoethyl methacrylate and malic acid with the proviso that each of said first, second and third monomers are different.
    • 一种具有低表面粘性特性的可冷冻乳液聚合三元共聚物粘合制剂,其由选自丙烯酸乙酯,丙烯酸己酯,丙烯酸异辛酯,丙烯酸丁酯,丙烯酸甲酯和偏二氯乙烯的第一单体的乳液聚合制备,第二 选自乙酸乙烯酯,甲基丙烯酸甲酯,苯乙烯,甲基丙烯酸乙酯和甲基丙烯酸异丁酯的单体和选自甲基丙烯酸,丙烯酸,衣康酸,甲基丙烯酸磺乙酯和苹果酸的第三单体,条件是 所述第一,第二和第三单体是不同的。
    • 10. 发明授权
    • Metallized multilayer packaging film
    • 金属化多层包装膜
    • US6013353A
    • 2000-01-11
    • US646429
    • 1996-05-07
    • Robert E. Touhsaent
    • Robert E. Touhsaent
    • B32B15/085B32B15/08B32B27/00B32B27/28B32B27/32
    • B32B27/32Y10T428/24868Y10T428/24917Y10T428/2495Y10T428/31Y10T428/31692Y10T428/31909Y10T428/31913Y10T428/31935
    • A metallized multilayer film comprising a film substrate having a polymer core layer, e.g., a polypropylene homopolymer (OPP), on at least one surface of which is a polymer skin layer having a lower melting temperature than that of said core layer, the exposed surface of skin layer having been treated, e.g., flame or corona discharge treated, prior to coating to increase its adherence to other materials, the film substrate containing a metal deposit, e.g., aluminum, coated on the treated surface of the polymer skin layers, and a polymeric, low temperature sealable coating (LTSC) comprising a copolymer of about 10 to 35 wt. % of at least one .alpha.,.beta.-ethylenically unsaturated carboxylic acid, e.g., acrylic or methacrylic acid, with about 65 to 90 wt. % of ethylene, an alkyl acrylate or methacrylate, acrylonitrile, or mixtures thereof on the surface of the metal deposit. Optionally, the polymer substrate may contain another polymer skin layer on the other side of the core layer, another coating may be deposited on the surface of the film opposite that containing the metal deposit, and/or a printed ink pattern and overlacquer may be applied to the surface of the LTSC on the metal deposit or the coated or uncoated opposite surface of the film substrate. The film has excellent mechanical and barrier properties and can be used to overwrap food and non-food products such that the package has a protected metal layer and good seal strength.
    • 一种金属化多层膜,其包含具有聚合物芯层的膜基材,例如聚丙烯均聚物(OPP),其至少一个表面是具有比所述核心层低的熔融温度的聚合物表层,暴露表面 已经处理过的皮肤层,例如在涂覆之前进行火焰或电晕放电,以增加其对其他材料的粘附性,所述膜基材含有涂覆在聚合物表层的经处理表面上的金属沉积物,例如铝,以及 聚合物低温可密封涂层(LTSC),其包含约10至35wt。 %的至少一种α,β-烯键式不饱和羧酸,例如丙烯酸或甲基丙烯酸,约65至90wt。 %的乙烯,丙烯酸烷基酯或甲基丙烯酸烷基酯,丙烯腈或其混合物在金属沉积物的表面上。 任选地,聚合物基底可以在芯层的另一侧上包含另一个聚合物表皮层,另一涂层可以沉积在膜的相对于包含金属沉积物的表面上,和/或可以应用印刷油墨图案和多层涂层 到金属沉积物上的LTSC表面或薄膜基底的涂覆或未涂覆的相对表面。 该膜具有优异的机械和阻隔性能,可用于覆盖食品和非食品,使得包装具有受保护的金属层和良好的密封强度。