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1. 发明授权

US4517116A Electrically conducting compositions of doped polyphenylenes and shaped articles comprising the same 失效
标题翻译：掺杂聚苯的导电组合物和包含其的成型制品
公开(公告)号：US4517116A
公开(公告)日：1985-05-14
申请号：US569426
申请日：1984-01-09
申请人： Dawn M. Ivory , Granville G. Miller , Ronald R. Chance , Ray H. Baughman
发明人： Dawn M. Ivory , Granville G. Miller , Ronald R. Chance , Ray H. Baughman
IPC分类号： C08L65/02 , H01B1/12 , H01L51/30 , H01L51/42 , H01B1/00
CPC分类号： H01B1/128 , C08L65/02 , H01L51/0035 , C08G2261/312 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： Electrically conducting doped poly(paraphenylene) compositions, and process of making such compositions, having direct current conductivities of at least 10.sup.31 3 ohm.sup.-1 cm.sup.-1, at room temperature, and up to 100 ohm.sup.-1 cm.sup.-1 and above; especially wherein the doping agent is a Group IA metal arene, a Group V halide, chlorine, bromine, or a mixture thereof; in particular potassium naphthalene, sodium naphthalene, AsF.sub.5, chlorine, or a mixture thereof. The polymers are useful as electronic devices, as substrates for electroplating, as materials for absorption of solar and of radio frequency radiation, and in general wherever electrical conductivity of the metallic type or of the semiconductor type, and light weight, are desired.
摘要翻译：导电掺杂的聚（对苯乙烯）组合物和制备这种组合物的方法，在室温下具有至少1031 3欧姆-1厘米-1的直流电导率和高达100欧姆-1厘米-1以上的直流电导率; 特别是其中掺杂剂是IA族金属芳烃，V族卤化物，氯，溴或其混合物; 尤其是萘酚钠，萘钠，AsF5，氯或它们的混合物。这些聚合物可用作电子器件，作为用于电镀的基底，作为用于吸收太阳能和射频辐射的材料，并且通常在需要金属类型或半导体类型的电导率和重量的情况下都是有用的。

2. 发明授权

US4440669A Electrically conducting compositions of doped polyphenylenes and shaped articles comprising the same 失效
标题翻译：掺杂聚苯的导电组合物和包含其的成型制品
公开(公告)号：US4440669A
公开(公告)日：1984-04-03
申请号：US234511
申请日：1981-02-17
申请人： Dawn M. Ivory , Granville G. Miller , Ronald R. Chance , Ray H. Baughman
发明人： Dawn M. Ivory , Granville G. Miller , Ronald R. Chance , Ray H. Baughman
IPC分类号： C08L65/02 , H01B1/12 , H01L51/30 , H01L51/42 , H01B1/06
CPC分类号： H01B1/128 , C08L65/02 , H01L51/0035 , C08G2261/312 , H01L51/42 , Y02E10/549
摘要： Electrically conducting doped poly(paraphenylene) compositions, and process of making such compositions, having direct current conductivities of at least 10.sup.-3 ohm.sup.-1 cm.sup.-1, at room temperature, and up to 100 ohm.sup.1 cm.sup.-1 and above; especially wherein the doping agent is a Group IA metal arene, a Group V halide, chlorine, bromine, or a mixture thereof; in particular potassium naphthalene, sodium naphthalene, AsF.sub.5, chlorine, or a mixture thereof. The polymers are useful as electronic devices, as substrates for electroplating, as materials for absorption of solar and of radio frequency radiation, and in general wherever electrical conductivity of the metallic type or of the semiconductor type, and light weight, are desired.
摘要翻译：导电掺杂的聚（对苯乙烯）组合物，以及制备这种组合物的方法，其在室温下的直流电导率至少为10-3欧姆-1厘米-1，高达100欧姆·厘米-1以上; 特别是其中掺杂剂是IA族金属芳烃，V族卤化物，氯，溴或其混合物; 尤其是萘酚钠，萘钠，AsF5，氯或它们的混合物。这些聚合物可用作电子器件，作为用于电镀的基底，作为用于吸收太阳能和射频辐射的材料，并且通常在需要金属类型或半导体类型的电导率和重量的情况下都是有用的。

3. 发明授权

US4375427A Thermoplastic conductive polymers 失效
标题翻译：热塑性导电聚合物
公开(公告)号：US4375427A
公开(公告)日：1983-03-01
申请号：US241953
申请日：1981-03-09
申请人： Granville G. Miller , Dawn M. Ivory , Lawrence W. Shacklette , Ronald R. Chance , Ronald L. Elsenbaumer , Ray H. Baughman
发明人： Granville G. Miller , Dawn M. Ivory , Lawrence W. Shacklette , Ronald R. Chance , Ronald L. Elsenbaumer , Ray H. Baughman
IPC分类号： C08G61/12 , C08G75/00 , C08L71/12 , H01B1/12 , H01M4/60 , H01B1/02 , H01B1/06
CPC分类号： H01M4/60 , C08G61/123 , C08G75/00 , C08L71/126 , H01B1/127 , H01B1/128
摘要： An electrically conductive polymer, doped with at least one electron acceptor or electron donor, which polymer has a main chain of arylene units and interspersed regularly or irregularly between them one or more chalcogen atoms or groups of such atoms, especially sulfur and/or oxygen atoms; especially poly(p-phenylene sulfide) doped with an arsenical doping agent. These doped polymers have utility similar to semiconductors or to metals, particularly where light weight is desired, for example in battery electrodes.
摘要翻译：掺杂有至少一个电子受体或电子给体的导电聚合物，该聚合物具有亚芳基单元的主链，并且在它们之间规则地或不规则地散布有一个或多个硫属原子或这些原子的基团，特别是硫和/或氧原子 ; 特别是掺杂有砷掺杂剂的聚（对亚苯基硫醚）。这些掺杂的聚合物具有类似于半导体或金属的效用，特别是在需要重量的情况下，例如在电池电极中。

4. 发明授权

US4339951A Tempeature measurement and display of indicia using thermochromic polyacetylenes 失效
标题翻译：温度测量和使用热变色聚乙炔的标记显示
公开(公告)号：US4339951A
公开(公告)日：1982-07-20
申请号：US34112
申请日：1979-04-30
申请人： Kwok C. Yee , Anthony F. Preziosi , Gordhanbhai N. Patel , Ronald R. Chance , Granville G. Miller , Ray H. Baughman
发明人： Kwok C. Yee , Anthony F. Preziosi , Gordhanbhai N. Patel , Ronald R. Chance , Granville G. Miller , Ray H. Baughman
IPC分类号： C08F38/00 , G01K11/16
CPC分类号： G01K11/16 , C08F38/00
摘要： Certain polyacetylenes exhibit reversible color changes at transition temperatures in the range -180.degree. to 220.degree. C., wherein the thermochromic cycles can be repeated many times with no apparent degradation and little change in spectroscopic properties.These thermochromic polyacetylenes are useful in temperature-indicator and indicia-display device applications.A process for laser-beam recording of images is described employing a thermochromic polyacetylene, in which the hysteresis properties of the polyacetylene can be suitably altered allowing for selectively storing or erasing the formed image.
摘要翻译：某些聚乙炔在-180°至220℃范围内的转变温度下表现出可逆的颜色变化，其中热变色循环可以重复多次，没有明显的降解和光谱性质的变化很小。这些热变色聚乙炔可用于温度指示器和标记显示装置。使用热变色聚乙炔描述图像的激光束记录方法，其中可以适当地改变聚乙炔的滞后特性，允许选择性地存储或擦除形成的图像。

5. 发明授权

US4242440A Thermochromic polyacetylenes used in laser beam recording method 失效
标题翻译：用于激光束记录方法的热变色聚乙炔
公开(公告)号：US4242440A
公开(公告)日：1980-12-30
申请号：US34111
申请日：1979-04-30
申请人： Kwok C. Yee , Anthony F. Preziosi , Gordhanbhai N. Patel , Ronald R. Chance , Granville G. Miller , Ray H. Baughman
发明人： Kwok C. Yee , Anthony F. Preziosi , Gordhanbhai N. Patel , Ronald R. Chance , Granville G. Miller , Ray H. Baughman
IPC分类号： G01D15/10 , G01K11/16 , G03C1/73 , G03C5/04
CPC分类号： G01K11/16 , G01D15/10 , G03C1/73 , G03C1/733 , Y10S430/166
摘要： Certain polyacetylenes exhibit reversible color changes at transition temperatures in the range -180.degree. to 220.degree. C., wherein the thermochromic cycles can be repeated many times with no apparent degradation and little change in spectroscopic properties.These thermochromic polyacetylenes are useful in temperature-indicator and indicia-display device applications.A process for laser-beam recording of images is described employing a thermochromic polyacetylene, in which the hysteresis properties of the polyacetylene can be suitably altered allowing for selectively storing or erasing the formed image.
摘要翻译：某些聚乙炔在-180°至220℃范围内的转变温度下表现出可逆的颜色变化，其中热变色循环可以重复多次，没有明显的降解和光谱性质的变化很小。这些热变色聚乙炔可用于温度指示器和标记显示装置。使用热变色聚乙炔描述图像的激光束记录方法，其中可以适当地改变聚乙炔的滞后特性，允许选择性地存储或擦除形成的图像。

6. 发明授权

US4215208A Thermochromic polyacetylenes containing urethane groups 失效
标题翻译：含有氨基甲酸酯基团的热变性聚乙炔
公开(公告)号：US4215208A
公开(公告)日：1980-07-29
申请号：US839678
申请日：1977-10-05
申请人： Kwok C. Yee , Anthony F. Preziosi , Gordhanbhai N. Patel , Ronald R. Chance , Granville G. Miller , Ray H. Baughman
发明人： Kwok C. Yee , Anthony F. Preziosi , Gordhanbhai N. Patel , Ronald R. Chance , Granville G. Miller , Ray H. Baughman
IPC分类号： C08F38/00 , G01K11/16 , C08L49/00
CPC分类号： G01K11/16 , C08F38/00 , Y10S252/962 , Y10S430/146
摘要： Certain polyacetylenes exhibit reversible color changes at transition temperatures in the range -180.degree. to 220.degree. C., wherein the thermochromic cycles can be repeated many times with no apparent degradation and little change in spectroscopic properties.These thermochromic polyacetylenes are useful in temperature-indicator and indicia-display device applications.A process for laser-beam recording of images is described employing a thermochromic polyacetylene, in which the hysteresis properties of the polyacetylene can be suitably altered allowing for selectively storing or erasing the formed image.
摘要翻译：某些聚乙炔在-180°至220℃范围内的转变温度下表现出可逆的颜色变化，其中热变色循环可以重复多次，没有明显的降解和光谱性质的变化很小。这些热变色聚乙炔可用于温度指示器和标记显示装置。使用热变色聚乙炔描述图像的激光束记录方法，其中可以适当地改变聚乙炔的滞后特性，允许选择性地存储或擦除形成的图像。

7. 发明授权

US5042923A Adjustable tint window with electrochromic conductive polymer 失效
标题翻译：带有电致变色导电聚合物的可调式色调窗
公开(公告)号：US5042923A
公开(公告)日：1991-08-27
申请号：US425542
申请日：1989-10-23
申请人： James F. Wolf , Granville G. Miller , Lawrence W. Shacklette , Ronald L. Elsenbaumer , Ray H. Baughman
发明人： James F. Wolf , Granville G. Miller , Lawrence W. Shacklette , Ronald L. Elsenbaumer , Ray H. Baughman
IPC分类号： E06B3/67 , G02F1/153
CPC分类号： G02F1/1533 , E06B3/6722
摘要： A method is provided for decreasing radiative heat transfer and adjustably limiting visible light and near infrared radiation transfer and glare through a window. The method comprises the steps of: (a) mounting within a frame of the window a plurality of spaced window panes, a first and second of the panes having opposing faces; (b) assembling between the opposing faces a conductive polymer cell, the cell having a first wall composed of a transparent conductive layer affixed to the first pane and having deposited thereupon an electroactive electro-optically responsive conductive polymer, and a second wall comprised of a transparent conductive layer coated on the second pane, the layer being optionally coated with a second electro-optically responsive polymer, the first and second walls delimiting a cavity containing an ion-conducting electrolyte which contacts opposing surfaces of the first and second walls, and (c) applying a potential between the first and second walls to provide a selected light transmittance upon passage of current therebetween.
摘要翻译：提供了一种降低辐射热传递和可调节地限制可见光和近红外辐射传递和通过窗口眩光的方法。该方法包括以下步骤：（a）在窗口的框架内安装多个间隔开的窗玻璃，第一和第二窗格具有相对的面; （b）在相对面之间组装导电聚合物电池，所述电池具有由固定到第一玻璃板上的透明导电层构成的第一壁，并且在其上沉积有电活性电光响应导电聚合物，第二壁由涂覆在第二窗玻璃上的透明导电层，该层任选地涂覆有第二电光响应聚合物，第一和第二壁限定包含接触第一和第二壁相对表面的离子导电电解质的空腔，和 c）在第一和第二壁之间施加电位，以在其间的电流通过时提供所选择的透光率。

8. 发明授权

US4502981A Enhancing conductivity of donor-doped polyacetylene 失效
标题翻译：增强供体掺杂聚乙炔的电导率
公开(公告)号：US4502981A
公开(公告)日：1985-03-05
申请号：US475996
申请日：1983-03-16
申请人： Philippe G. Delannoy , Granville G. Miller , Helmut Eckhardt , Ray H. Baughman
发明人： Philippe G. Delannoy , Granville G. Miller , Helmut Eckhardt , Ray H. Baughman
IPC分类号： B29C71/02 , B29C71/00 , C08K3/08 , C08L49/00 , H01B1/12 , H01B1/06
CPC分类号： H01B1/125
摘要： Polyacetylene doped with potassium or rubidium cations (and optionally with other alkali metal cations) is heat treated at 60.degree.-400.degree. C., preferably 100.degree.-250 .degree. C., to achieve greatly enhanced room temperature conductivity. Products with relative conductivities 150%, 300%, 450% or more of the conductivity prior to heat treating are obtained, with room-temperature conductivities of 300 S/cm, 450 S/cm, or higher.
摘要翻译：掺杂有钾或铷阳离子（和任选与其它碱金属阳离子）的聚乙炔在60°-400℃，优选100-250℃下进行热处理，以达到极大提高的室温电导率。得到热处理前电导率为150％，300％，450％以上的相对电导率的产品，室温电导率为300S / cm，450S / cm以上。

9. 发明授权

US4472487A Battery having polymeric anode coated with reaction product of oxirane compound 失效
标题翻译：具有涂覆有环氧乙烷化合物的反应产物的聚合物阳极的电池
公开(公告)号：US4472487A
公开(公告)日：1984-09-18
申请号：US556735
申请日：1983-11-30
申请人： MacRae Maxfield , Granville G. Miller , Ray H. Baughman , Jane E. Frommer
发明人： MacRae Maxfield , Granville G. Miller , Ray H. Baughman , Jane E. Frommer
IPC分类号： H01M4/60 , H01M10/05 , H01M6/14
CPC分类号： H01M10/05 , H01M4/60
摘要： Rechargable battery with a conjugated backbone polymer anode which has been coated, when in the reduced state, by contact with a monomer with a reactive oxirane group. Reduced polyacetylene anodes, after reaction with ethylene oxide, offer improved stability to solvents.
摘要翻译：具有共轭主链聚合物阳极的可充电电池，当处于还原状态时，通过与具有反应性环氧乙烷基团的单体接触来涂覆。在与环氧乙烷反应后，还原的聚乙炔阳极提供了改进的溶剂稳定性。

10. 发明授权

US4893908A Adjustable tint window with electrochromic conductive polymer 失效
标题翻译：带有电致变色导电聚合物的可调式色调窗
公开(公告)号：US4893908A
公开(公告)日：1990-01-16
申请号：US211537
申请日：1988-06-27
申请人： James F. Wolf , Granville G. Miller , Lawrence W. Shacklette , Ronald L. Elsenbaumer , Ray H. Baughman
发明人： James F. Wolf , Granville G. Miller , Lawrence W. Shacklette , Ronald L. Elsenbaumer , Ray H. Baughman
IPC分类号： E06B3/66 , E06B3/67 , E06B9/24 , G02F1/15 , G02F1/153
CPC分类号： G02F1/1533 , E06B3/6722
摘要： A method is provided for decreasing radiative heat transfer and adjustably limiting visible light and near infrared radiation transfer and glare through a window. The method comprises the steps of: (a) mounting within a frame of the window a plurality of spaced window panes, a first and second of the panes having opposing faces; (b) assembling between the opposing faces a conductive polymer cell, the cell having a first wall composed of a transparent conductive layer affixed to the first pane and having deposited thereupon an electroactive electro-optically responsive conductive polymer, and a second wall comprised of a transparent conductive layer coated on the second pane, the layer being optionally coated with a second electro-optically responsive polymer, the first and second walls delimiting a cavity containing an ion-conducting electrolyte which contacts opposing surfaces of the first and second walls, and (c) applying a potential between the first and second walls to provide a selected light transmittance upon passage of current therebetween.
摘要翻译：提供了一种降低辐射热传递和可调节地限制可见光和近红外辐射传递和通过窗口眩光的方法。该方法包括以下步骤：（a）在窗口的框架内安装多个间隔开的窗玻璃，第一和第二窗格具有相对的面; （b）在相对面之间组装导电聚合物电池，所述电池具有由固定到第一玻璃板上的透明导电层构成的第一壁，并且在其上沉积有电活性电光响应导电聚合物，第二壁由涂覆在第二窗玻璃上的透明导电层，该层任选地涂覆有第二电光响应聚合物，第一和第二壁限定包含接触第一和第二壁相对表面的离子导电电解质的空腔，和 c）在第一和第二壁之间施加电位，以在其间的电流通过时提供所选择的透光率。

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