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1. 发明申请

US20110114323A1 Heat Generation Process for Treating Oilfield Deposits 有权
标题翻译：用于处理油田矿床的发热过程
公开(公告)号：US20110114323A1
公开(公告)日：2011-05-19
申请号：US12940691
申请日：2010-11-05
申请人： David W. Jennings , Samuel Asomaning , Michael E. Newberry
发明人： David W. Jennings , Samuel Asomaning , Michael E. Newberry
IPC分类号： E21B37/06 , B08B9/027
CPC分类号： E21B37/06 , B08B7/0071 , C09K8/52
摘要： Generating heat within a combination solvent/acid system removes undesirable deposits from petroleum reservoir formations (especially the near well-bore region), oilfield equipment, and petroleum processing equipment. An exothermic reaction occurs between the solvent and the acid and the heat evolved helps remove organic solid deposits. The acids may include organic acid compounds, such as sulfonic acids, sulfuric acid and nitric acid. The solvents may include terpene- and terpene-derivative-containing solvents, including, but not necessarily limited to, limonene, pinene, dipentene, myrcene, turpentines and compounds having at least one double bond, such as methyl furan, dienes, styrene, vinyl acetate and the like. The exothermic reaction produces a great amount of heat, and together with using certain acids and solvents already known as effective to remove paraffin and asphaltene deposition, removing such deposits is improved.
摘要翻译：在组合溶剂/酸系统内产生热量可从石油储层地层（特别是近井眼区域），油田设备和石油加工设备中除去不需要的沉积物。在溶剂和酸之间发生放热反应，放出的热量有助于去除有机固体沉积物。酸可以包括有机酸化合物，例如磺酸，硫酸和硝酸。溶剂可以包括萜烯和萜烯衍生物的溶剂，包括但不一定限于柠檬烯，蒎烯，二戊烯，月桂烯，松节油和具有至少一个双键的化合物，例如甲基呋喃，二烯，苯乙烯，乙烯基乙酸酯等。放热反应产生大量的热量，并且与使用已知有效除去石蜡和沥青质沉积物的某些酸和溶剂一起改善了这些沉积物的去除。

2. 发明授权

US08691731B2 Heat generation process for treating oilfield deposits 有权
标题翻译：处理油田沉积物的发热过程
公开(公告)号：US08691731B2
公开(公告)日：2014-04-08
申请号：US12940691
申请日：2010-11-05
申请人： David W. Jennings , Samuel Asomaning , Michael E. Newberry
发明人： David W. Jennings , Samuel Asomaning , Michael E. Newberry
IPC分类号： E21B21/00 , B08B9/00
CPC分类号： E21B37/06 , B08B7/0071 , C09K8/52
摘要： Generating heat within a combination solvent/acid system removes undesirable deposits from petroleum reservoir formations (especially the near well-bore region), oilfield equipment, and petroleum processing equipment. An exothermic reaction occurs between the solvent and the acid and the heat evolved helps remove organic solid deposits. The acids may include organic acid compounds, such as sulfonic acids, sulfuric acid and nitric acid. The solvents may include terpene- and terpene-derivative-containing solvents, including, but not necessarily limited to, limonene, pinene, dipentene, myrcene, turpentines and compounds having at least one double bond, such as methyl furan, dienes, styrene, vinyl acetate and the like. The exothermic reaction produces a great amount of heat, and together with using certain acids and solvents already known as effective to remove paraffin and asphaltene deposition, removing such deposits is improved.
摘要翻译：在组合溶剂/酸系统内产生热量可从石油储层地层（特别是近井眼区域），油田设备和石油加工设备中除去不需要的沉积物。在溶剂和酸之间发生放热反应，放出的热量有助于去除有机固体沉积物。酸可以包括有机酸化合物，例如磺酸，硫酸和硝酸。溶剂可以包括萜烯和萜烯衍生物的溶剂，包括但不一定限于柠檬烯，蒎烯，二戊烯，月桂烯，松节油和具有至少一个双键的化合物，例如甲基呋喃，二烯，苯乙烯，乙烯基乙酸酯等。放热反应产生大量的热量，并且与使用已知有效除去石蜡和沥青质沉积物的某些酸和溶剂一起，改善了除去这些沉积物。

3. 发明授权

US09637676B2 Asphaltene inhibitors for squeeze applications 有权
公开(公告)号：US09637676B2
公开(公告)日：2017-05-02
申请号：US13746441
申请日：2013-01-22
申请人： Geoffrey C. Leonard , Gordon T. Rivers , Samuel Asomaning , Patrick J. Breen
发明人： Geoffrey C. Leonard , Gordon T. Rivers , Samuel Asomaning , Patrick J. Breen
IPC分类号： C09K8/52 , E21B43/25 , C09K8/524
CPC分类号： C09K8/524 , C08G8/28 , E21B37/06 , E21B43/25
摘要： Reaction products of polymeric alkyl phenol formaldehyde resins are useful as additives to inhibit or prevent the deposition or precipitation of asphaltenes in hydrocarbon fluids, particularly crude oil produced from a subterranean formation. These reaction products are formed by reacting a polymeric alkyl phenol formaldehyde resin with a co-reactant having functional groups including, but not necessarily limited to, amines, esters, silanes, ketones, epoxides, alkoxides, aryloxides, halogens, alkali metals, alkali earth metals, acetamides, non-metal oxides, metal oxides, where the co-reactant optionally has a carbon chain length between 1 and 22 and the reaction is conducted in the presence of at least one of various solvents. In one non-limiting embodiment, the co-reactant is a silicon derivative. The asphaltene inhibitors have utility when injected into a subterranean formation while oil production temporarily halts, a process called “squeezing,” because they are retained to a degree in the formation as the crude oil is produced.

4. 发明申请

US20130096043A1 Additive to Improve Flow, Reduce Power Consumption and Pressure Drop in Heavy Oil Pipelines 有权
标题翻译：改善流量的添加剂，降低重油管道的功率消耗和压降
公开(公告)号：US20130096043A1
公开(公告)日：2013-04-18
申请号：US13693945
申请日：2012-12-04
申请人： Samuel Asomaning , Scott E. Lehrer
发明人： Samuel Asomaning , Scott E. Lehrer
IPC分类号： C10M145/20
CPC分类号： C10M145/20 , C08K5/17 , C08L61/14 , Y10T137/0391
摘要： A drag reducing additive for heavy oil, such as crude oil, includes a polymeric alkyl-substituted phenol formaldehyde resin and a solvent having at least one of an ester (e.g. ethyl acetate), an aldehyde (e.g. butyraldehyde), and an aromatic hydrocarbon (e.g. toluene, xylene, and the like), or mixtures thereof. When used together with a diluent (e.g. condensate, naphtha, or the like), the additive may reduce viscosity of the combined oil, diluent, and additive by at least 20%, increase throughput by at least 6%, reduce power consumption by at least 3%, reduce the diluent proportion by at least 3%, or some combination of these effects, as compared with an otherwise identical heavy oil without the additive.
摘要翻译：用于重油（例如原油）的减阻添加剂包括聚合烷基取代的酚醛树脂和具有酯（例如乙酸乙酯），醛（例如丁醛）和芳族烃（例如甲苯，二甲苯等）或其混合物。当与稀释剂（例如缩合物，石脑油等）一起使用时，添加剂可将组合的油，稀释剂和添加剂的粘度降低至少20％，将生产量提高至少6％，从而将功率消耗降低至至少3％，与没有添加剂的其他相同的重油相比，将稀释剂比例降低至少3％，或这些效果的某种组合。

5. 发明授权

US08003574B2 Inhibiting naphthenate solids and emulsions in crude oil 有权
标题翻译：抑制环烷酸固体和原油中的乳液
公开(公告)号：US08003574B2
公开(公告)日：2011-08-23
申请号：US12196781
申请日：2008-08-22
申请人： Justin D. Debord , Piyush Srivastava , Christopher Gallagher , Samuel Asomaning , Paul Hart
发明人： Justin D. Debord , Piyush Srivastava , Christopher Gallagher , Samuel Asomaning , Paul Hart
IPC分类号： C09K8/52 , E21B37/06
CPC分类号： C10G29/20 , C09K8/524 , C10G2300/1033 , C10G2300/203 , C10G2300/80
摘要： Naphthenic acid solids and/or emulsions can be inhibited by introducing an additive to crude oil prior to or concurrent with the deprotonation of the naphthenic acids present in the crude oil. The additives may be surfactants and can be amines, quaternary ammonium compounds, quaternary phosphonium compounds, and mixtures of both. The additives may also be linear compounds having at least two carboxylic acid or acrylic acid functional moieties.
摘要翻译：在原油中存在的环烷酸去质子化之前或同时将引入添加剂的添加剂加入到环烷酸固体和/或乳液中。添加剂可以是表面活性剂，可以是胺，季铵化合物，季鏻化合物，以及二者的混合物。添加剂也可以是具有至少两个羧酸或丙烯酸官能部分的线性化合物。

6. 发明申请

US20090036329A1 INHIBITING NAPHTHENATE SOLIDS AND EMULSIONS IN CRUDE OIL 有权
标题翻译：抑制石油中的硫酸盐固体和乳液
公开(公告)号：US20090036329A1
公开(公告)日：2009-02-05
申请号：US12196781
申请日：2008-08-22
申请人： Justin D. Debord , Piyush Srivastava , Christopher Gallagher , Samuel Asomaning , Paul Hart
发明人： Justin D. Debord , Piyush Srivastava , Christopher Gallagher , Samuel Asomaning , Paul Hart
IPC分类号： C09K8/52
CPC分类号： C10G29/20 , C09K8/524 , C10G2300/1033 , C10G2300/203 , C10G2300/80
摘要： Naphthenic acid solids and/or emulsions can be inhibited by introducing an additive to crude oil prior to or concurrent with the deprotonation of the naphthenic acids present in the crude oil. The additives may be surfactants and can be amines, quaternary ammonium compounds, quaternary phosphonium compounds, and mixtures of both. The additives may also be linear compounds having at least two carboxylic acid or acrylic acid functional moieties.
摘要翻译：在原油中存在的环烷酸去质子化之前或同时将引入添加剂的添加剂加入到环烷酸固体和/或乳液中。添加剂可以是表面活性剂，可以是胺，季铵化合物，季鏻化合物，以及二者的混合物。添加剂也可以是具有至少两个羧酸或丙烯酸官能部分的线性化合物。

7. 发明授权

US08575082B2 Additive to improve flow, reduce power consumption and pressure drop in heavy oil pipelines 有权
标题翻译：增加流量，减少重油管道的功耗和压降
公开(公告)号：US08575082B2
公开(公告)日：2013-11-05
申请号：US13693945
申请日：2012-12-04
申请人： Samuel Asomaning , Scott E. Lehrer
发明人： Samuel Asomaning , Scott E. Lehrer
IPC分类号： C07C39/06 , C10M145/20
CPC分类号： C10M145/20 , C08K5/17 , C08L61/14 , Y10T137/0391
摘要： A drag reducing additive for heavy oil, such as crude oil, includes a polymeric alkyl-substituted phenol formaldehyde resin and a solvent having at least one of an ester (e.g. ethyl acetate), an aldehyde (e.g. butyraldehyde), and an aromatic hydrocarbon (e.g. toluene, xylene, and the like), or mixtures thereof. When used together with a diluent (e.g. condensate, naphtha, or the like), the additive may reduce viscosity of the combined oil, diluent, and additive by at least 20%, increase throughput by at least 6%, reduce power consumption by at least 3%, reduce the diluent proportion by at least 3%, or some combination of these effects, as compared with an otherwise identical heavy oil without the additive.
摘要翻译：用于重油（例如原油）的减阻添加剂包括聚合烷基取代的酚醛树脂和具有酯（例如乙酸乙酯），醛（例如丁醛）和芳族烃（例如甲苯，二甲苯等）或其混合物。当与稀释剂（例如缩合物，石脑油等）一起使用时，添加剂可将组合的油，稀释剂和添加剂的粘度降低至少20％，将生产量提高至少6％，从而将功率消耗降低至至少3％，与没有添加剂的其他相同的重油相比，将稀释剂比例降低至少3％，或这些效果的某种组合。

8. 发明申请

US20130186629A1 Asphaltene Inhibitors for Squeeze Applications 有权
标题翻译：沥青抑制剂挤压应用
公开(公告)号：US20130186629A1
公开(公告)日：2013-07-25
申请号：US13746441
申请日：2013-01-22
申请人： Geoffrey C. Leonard , Gordon T. Rivers , Samuel Asomaning , Patrick J. Breen
发明人： Geoffrey C. Leonard , Gordon T. Rivers , Samuel Asomaning , Patrick J. Breen
IPC分类号： C09K8/524 , E21B43/25
CPC分类号： C09K8/524 , C08G8/28 , E21B37/06 , E21B43/25
摘要： Reaction products of polymeric alkyl phenol formaldehyde resins are useful as additives to inhibit or prevent the deposition or precipitation of asphaltenes in hydrocarbon fluids, particularly crude oil produced from a subterranean formation. These reaction products are formed by reacting a polymeric alkyl phenol formaldehyde resin with a co-reactant having functional groups including, but not necessarily limited to, amines, esters, silanes, ketones, epoxides, alkoxides, aryloxides, halogens, alkali metals, alkali earth metals, acetamides, non-metal oxides, metal oxides, where the co-reactant optionally has a carbon chain length between 1 and 22 and the reaction is conducted in the presence of at least one of various solvents. In one non-limiting embodiment, the co-reactant is a silicon derivative. The asphaltene inhibitors have utility when injected into a subterranean formation while oil production temporarily halts, a process called “squeezing,” because they are retained to a degree in the formation as the crude oil is produced.
摘要翻译：聚合烷基酚甲醛树脂的反应产物可用作抑制或防止沥青质沉积或沉淀在烃类流体中，特别是从地下地层产生的原油中的添加剂。这些反应产物通过聚合烷基酚甲醛树脂与具有官能团的共反应物反应形成，所述共反应物包括但不限于胺，酯，硅烷，酮，环氧化物，醇盐，芳氧化物，卤素，碱金属，碱土金属，乙酰胺，非金属氧化物，金属氧化物，其中共反应物任选具有1至22的碳链长度，并且反应在至少一种各种溶剂的存在下进行。在一个非限制性实施方案中，共反应物是硅衍生物。沥青质抑制剂在注入地下地层时具有实用性，而油生产暂时停止，这一过程称为“挤压”，因为它们在原油生产时被保留在地层中。

9. 发明授权

US08342198B2 Additive to improve flow, reduce power consumption and pressure drop in heavy oil pipelines 有权
公开(公告)号：US08342198B2
公开(公告)日：2013-01-01
申请号：US12547253
申请日：2009-08-25
申请人： Samuel Asomaning , Scott E. Lehrer
发明人： Samuel Asomaning , Scott E. Lehrer
IPC分类号： F17D1/16 , C10G31/00
CPC分类号： C10M145/20 , C08K5/17 , C08L61/14 , Y10T137/0391
摘要： A drag reducing additive for heavy oil, such as crude oil, includes a polymeric alkyl-substituted phenol formaldehyde resin and a solvent having at least one of an ester (e.g. ethyl acetate), an aldehyde (e.g. butyraldehyde), and an aromatic hydrocarbon (e.g. toluene, xylene, and the like), or mixtures thereof. When used together with a diluent (e.g. condensate, naphtha, or the like), the additive may reduce viscosity of the combined oil, diluent, and additive by at least 20%, increase throughput by at least 6%, reduce power consumption by at least 3%, reduce the diluent proportion by at least 3%, or some combination of these effects, as compared with an otherwise identical heavy oil without the additive.

10. 发明申请

US20100056408A1 Additive to Improve Flow, Reduce Power Consumption and Pressure Drop in Heavy Oil Pipelines 有权
标题翻译：改善流量的添加剂，降低重油管道的功率消耗和压降
公开(公告)号：US20100056408A1
公开(公告)日：2010-03-04
申请号：US12547253
申请日：2009-08-25
申请人： Samuel Asomaning , Scott E. Lehrer
发明人： Samuel Asomaning , Scott E. Lehrer
IPC分类号： C10M129/84 , C10M145/20 , C10M129/70 , C10M129/76
CPC分类号： C10M145/20 , C08K5/17 , C08L61/14 , Y10T137/0391
摘要： A drag reducing additive for heavy oil, such as crude oil, includes a polymeric alkyl-substituted phenol formaldehyde resin and a solvent having at least one of an ester (e.g. ethyl acetate), an aldehyde (e.g. butyraldehyde), and an aromatic hydrocarbon (e.g. toluene, xylene, and the like), or mixtures thereof. When used together with a diluent (e.g. condensate, naphtha, or the like), the additive may reduce viscosity of the combined oil, diluent, and additive by at least 20%, increase throughput by at least 6%, reduce power consumption by at least 3%, reduce the diluent proportion by at least 3%, or some combination of these effects, as compared with an otherwise identical heavy oil without the additive.
摘要翻译：用于重油（例如原油）的减阻添加剂包括聚合烷基取代的酚醛树脂和具有酯（例如乙酸乙酯），醛（例如丁醛）和芳族烃（例如甲苯，二甲苯等）或其混合物。当与稀释剂（例如缩合物，石脑油等）一起使用时，添加剂可将组合的油，稀释剂和添加剂的粘度降低至少20％，将生产量提高至少6％，从而将功率消耗降低至至少3％，与没有添加剂的其他相同的重油相比，将稀释剂比例降低至少3％，或这些效果的某种组合。

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