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    • 1. 发明授权
    • Separation and recovery of molybdenum values from uranium process waste
    • 从铀工艺废物中分离和回收钼值
    • US4584184A
    • 1986-04-22
    • US612282
    • 1984-05-21
    • David NalewajekLynn E. McCurryDavid J. FriedlandRichard E. Eibeck
    • David NalewajekLynn E. McCurryDavid J. FriedlandRichard E. Eibeck
    • C01G39/00C01G39/02C01G43/00C01G43/01C22B7/00C22B34/34C22B60/02
    • C01G43/01C01G39/00C01G39/02C01G43/00C22B34/34C22B60/0247C22B7/008C01P2006/80Y02P10/234
    • A method for treating process waste consisting of uranium hexafluoride, UF.sub.6, molybdenum hexafluoride, MoF.sub.6 and molybdenum oxytetrafluoride, MoOF.sub.4 is provided wherein the foregoing mixture is hydrolyzed in an aqueous solution of ammonium carbonate and ammonium hydroxide. The resulting mother liquor is digested at 60.degree.-80.degree. C. to drive off carbon dioxide and convert the ammonium uranyl carbonate, (NH.sub.4).sub.4 UO.sub.2 (CO.sub.3).sub.3 to ammonium diuranate, (NH.sub.4).sub.2 U.sub.2 O.sub.7. The pH is maintained above 9 to prevent premature precipitation of the molybdenum values as molybdic acid or uranyl molybdate.The ammonium diuranate which forms as a yellow solid is filtered, slurried in aqueous ammonium hydroxide, filtered and dried. The yield is quantitative. Pyrolysis results in conversion of the diuranate salt to uranium oxide, U.sub.3 O.sub.8, of suitable purity to be recycled in the uranium hexafluoride production process. The combined filtrates which contain the molybdenum values and ammonium fluoride by-product are diluted, and stirred, with 95% ethanol to precipitate white, crystalline, ammonium molybdate, (NH.sub.4).sub.2 MoO.sub.4. The ammonium fluoride remains soluble. The ammonium molybdate is filtered, dried and calcined at 600.degree. C. for 2 hours to yield molybdenum trioxide, MoO.sub.3 in >90% yield and essentially free of uranium contamination. Fluoride contamination in either of the reprocessed materials is minimal.
    • 一种用于处理由六氟化铀,UF 6,六氟化钼,MoF 6和四氟化钼组成的处理废物的方法,其中上述混合物在碳酸铵和氢氧化铵的水溶液中水解。 将得到的母液在60°-80℃下消化以除去二氧化碳,并将碳酸铀酸铵(NH4)4UO2(CO3)3转化成二氢铀酸铵(NH4)2U2O7。 pH值保持在9以上,以防止钼值过早沉淀为钼酸或钼酸铀。 过滤形成黄色固体的二异氰酸铵,在氢氧化铵水溶液中浆化,过滤并干燥。 产量是定量的。 热解导致将二铀酸盐转化为具有合适纯度的氧化铀U3O8,以在六氟化铀生产过程中再循环。 将含有钼值和氟化铵副产物的合并滤液稀释,并用95%乙醇搅拌,沉淀出白色,结晶,钼酸铵(NH 4)2 OO 4。 氟化铵保持溶解。 将钼酸铵过滤,干燥并在600℃下煅烧2小时,得到三氧化钼,MoO 3> 90%产率,基本上不含铀污染物。 任何一种后处理材料中的氟化物污染最小。
    • 3. 发明授权
    • Process for the electrolytic production of fluorine and novel cell
therefor
    • 氟电解生产工艺及其新型电池
    • US4511440A
    • 1985-04-16
    • US564639
    • 1983-12-27
    • Alexander M. SaprokhinDavid J. FriedlandRichard M. BaranJung T. KimLynn E. McCurry
    • Alexander M. SaprokhinDavid J. FriedlandRichard M. BaranJung T. KimLynn E. McCurry
    • C01B7/20C25B1/24C25B9/00C25B9/06C25B9/08C25B11/03C25B1/02C25B11/12
    • C25B1/245C25B11/03C25B9/06
    • A cell and process is provided for the production of fluorine comprising electrolyzing a liquid mixture of fluorides of alkali metal, ammonium and hydrogen fluoride. The cell anode comprises a stock of anode plates with internal passages or it may comprise a carbon shape provided with grooves and passages and fitted to a central conductor which conducts current from the exterior of the cell to the carbon anode plates within the cell. The anode having a substantially expanded working surface has the capability of removing fluorine internally. A louvered cathode permits most of the hydrogen to be vented away from the zone between the electrodes through which current passes thus reducing the ohmic voltage loss. The cathode, rather than being louvered, can be expanded metal or punched sheet or gauze. The anode, cathode and barrier may be cylindrical in form although other shapes, for instance rectangular or square in cross section or even of hexagonal section, may be used if desired. Combination of the segmented anode design with a louvered cathode provides a unique cell for fluorine production because virtually the same electrolysis condition exists at any part of the anode and cathode.
    • 提供了用于生产氟的电池和工艺,包括电解碱金属,铵和氟化氢的氟化物的液体混合物。 电池阳极包括具有内部通道的阳极板的原料,或者其可以包括具有沟槽和通道的碳形状,并且装配到中心导体,该中心导体将电流从电池的外部传导到电池内的碳阳极板。 具有基本上膨胀的工作表面的阳极具有内部除去氟的能力。 百叶窗阴极允许大部分氢气从电极之间的区域排出,从而减小电流损耗。 阴极而不是百叶窗,可以是金属或冲孔的片材或纱布。 阳极,阴极和屏障可以是圆柱形的,但是如果需要,也可以使用其它形状,例如矩形或正方形的横截面或甚至六边形截面。 分段阳极设计与百叶窗阴极的组合为氟生产提供了独特的电池,因为在阳极和阴极的任何部分都存在相同的电解条件。
    • 5. 发明授权
    • Aqueous battery with (C.sub.y F.sub.x Cl.sub.z).sub.n cathode
    • 带有(Cy Fx Clz)n阴极的水性电池
    • US4695522A
    • 1987-09-22
    • US900280
    • 1986-08-26
    • David NalewajekJung T. KimLynn E. McCurry
    • David NalewajekJung T. KimLynn E. McCurry
    • H01M4/58H01M6/04
    • H01M4/5835H01M6/04
    • A novel high energy density aqueous cell exhibiting superior electrochemical properties is described. The use of the novel cathode composition, (C.sub.y F.sub.x Cl.sub.z).sub.n, permits the construction of a novel high energy density aqueous cell comprised of an anode, an alkaline electrolyte and a cathode, said cathode comprised of carbon fluoride chloride of the type (C.sub.y F.sub.x Cl.sub.z).sub.n : wherein y is 1 or 2; x is greater than 0 up to about 1.2; z is greater than 0 up to 0.1; and n denotes an infinitely large two dimensional array of C.sub.y F.sub.x Cl.sub.z units.The carbon fluoride chloride is composed of carbon, fluorine and chlorine, wherein the carbon can be chosen from the group consisting of graphite, coke, needle coke, charcoal, activated carbon, carbon blacks and the like. The carbon fluoride chloride described herein can be made in several ways, e.g. carbon can be reacted with chlorine monofluoride, ClF, to produce (C.sub.y F.sub.x Cl.sub.z).sub.n or with mixtures of chlorine, Cl.sub.2, and fluorine, F.sub.2, to produce (C.sub.y F.sub.x Cl.sub.z).sub.n.
    • 描述了一种具有优异电化学特性的新型高能密度水溶液电池。 新型阴极组合物(CyFxClz)n的使用允许构建由阳极,碱性电解质和阴极组成的新型高能密度水溶液电池,所述阴极由(CyFxClz)n型碳氟化物 :其中y为1或2; x大于0至约1.2; z大于0至0.1; n表示CyFxClz单位的无限大的二维阵列。 碳氟化碳由碳,氟和氯组成,其中碳可选自石墨,焦炭,针状焦炭,活性碳,炭黑等。 本文所述的氟化碳氟化物可以以几种方式制备,例如, 碳可以与一氟化物ClF反应以产生(CyFxClz)n或与氯,Cl2和氟的混合物F2,以产生(CyFxClz)n。