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    • 3. 发明授权
    • Process for the separation of unbranched hydrocarbons from their branched isomers
    • 从支链异构体中分离未分支烃的方法
    • US08658849B2
    • 2014-02-25
    • US12668436
    • 2008-06-30
    • Markus SchubertUlrich MuellerChristoph KienerIngo RichterWilliam DolanFrank Poplow
    • Markus SchubertUlrich MuellerChristoph KienerIngo RichterWilliam DolanFrank Poplow
    • C07C7/13
    • C07C7/12B01J20/22B01J20/226B01J2220/56C07C7/135C10G25/003C07C9/00
    • The present invention relates to a process for the separation of at least one unbranched C4-C2O hydrocarbon from a fluid mixture containing the unbranched hydrocarbon and at least one branched isomer of the unbranched hydrocarbon, which comprises the step of—contacting the fluid mixture with an adsorbent comprising a porous metal organic framework material, which material comprises at least one at least bidentate organic compound coordinately bound to at least one metal ion, to get the unbranched hydrocarbon adsorbed, wherein the at least one at least bidentate organic compound is a monocyclic, bicyclic or polycyclic ring system which is derived from at least one heterocycle selected from the group consisting of pyrrole, alpha-pyridone and gamma-pyridone and has at least two ring nitrogens and is unsubstituted or bears one or more substituents selected independently from the group consisting of halogen, Ci-6-alkyl, phenyl, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl, where the substituents Ci_6-alkyl and phenyl are unsubstituted or bear one or more substituents selected independently from the group consisting of halogen, NH2, NH(d-6-alkyl), N(C1-6-alkyl)2, OH, Ophenyl and OCi-6-alkyl. The present invention also relates to the use of said porous metal-organic framework material in a process for the separation of unbranched hydrocarbons from their branched isomers.
    • 本发明涉及从含有非支链烃和非支链烃的至少一种支链异构体的流体混合物中分离至少一种未分支的C 4 -C 20烃的方法,其包括使流体混合物与 吸附剂,其包含多孔金属有机骨架材料,该材料包含与至少一种金属离子配位结合的至少一种至少二齿有机化合物,以获得非支化烃被吸附,其中至少一种至少二齿有机化合物是单环, 衍生自选自吡咯,α-吡啶酮和γ-吡啶酮的至少一种杂环的双环或多环系统,并且具有至少两个环氮并且是未取代的或带有一个或多个独立地选自以下的取代基: 的卤素,C 1-6 - 烷基,苯基,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH,苯基和OC 1-6 - 烷基 ,其中取代基C 1-6 - 烷基和苯基是未取代的或具有一个或多个独立地选自卤素,NH 2,NH(C 1-6 - 烷基),N(C 1-6 - 烷基)2,OH, 和OC 1-6烷基。 本发明还涉及所述多孔金属 - 有机骨架材料在从其支化异构体中分离未分支烃的方法中的用途。